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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 289 records · Page 16

Predictive Models and Novel Accelerated Tests for the Reliability of Cell Metallization in Photovoltaic Modules (Final Report)

Studies of metallization corrosion m photovoltaics have mainly been limited to comparisons of modules placed in accelerated chambers to fielded modules [1]. Damp Heat accelerated tests and phenomenological equations [2] are used to assess metallization corrosion without understanding the effect of UV light and temperature and humidity cycles on encapsulant adhesion degradation. The roles of encapsulant in-and out-diffusions of moisture and encapsulant impurities are important. Furthermore, few photovoltaic metallization corrosion studies included the role of bias and leakage currents, which are crucial in the electrochemical reaction of metallization. Leakage currents can highly accelerate the corrosion mechanism and are important to include in the studies of corrosion. In our research plan, we will address the following gaps in the PV community's understanding of metallization corrosion: (1) metallization corrosion with bias, humidity, and impurities in the encapsulant or metallization; (2) humidity diffusion through fresh and degraded encapsulants; and (3) comparison of model predictions with outdoor field modules and SunPower's extensive data for its back-contact and front-contact fleets [2] along with NREL's store of >20 year old modules. Our goal is to build models and accelerated tests to predict long term degradation of metallization corrosion of photovoltaic modules in the field. Our studies will include metals used in c-Si solar cells (Cu, Ag, and Al) and commonly used encapsulants (EV A (ethylene vinyl acetate), TPO (thermoplastic olefin), and silicone).

14 SOLAR ENERGY↗

Tuning Catalytically Active Single Sites in Nonstoichiometric, Mixed Metal Oxides for Oxygen Electrocatalysis (Final Technical Report)

The objective of the proposed work is to employ controlled synthesis, advanced characterization, detailed electrochemical testing and theoretical calculations to develop a framework that would guide the design of robust, non-stoichiometric mixed metal oxides for oxygen electrocatalysis. In this research plan, we focus around the idea of tuning the metal ion composition and environment to create single atom centers with the utmost electrocatalytic activity. We hypothesized that tuning the cationic sites in nonstoichiometric mixed metal oxides will lead to single 4d/5d metal surface sites with optimal catalytic activity for low temperature oxygen reduction (ORR) and oxygen evolution (OER) at solid/liquid interfaces. We will focus on different crystal structures of these oxides including Ruddlesden-Popper (R-P) oxides, simple perovskites and pyrochlores due to their flexibility in accommodating different metal cation dopants, and the fact that they represent variations in the cationic arrangements in non-stoichiometric mixed metal oxide structures, which will lead to an understanding of how bulk crystal structure effects catalytic activity and stability of these systems.

08 HYDROGEN↗

Cell and Stack Degradation Evaluation and Modeling

Presentation on NETL's solid oxide fuel cell (SOFC) work plan research (FWP 1022411) given by invitation to the 2024 Hydrogen Program Annual Merit Review meeting in Arlington, VA on May 7, 2024.

Abernathy, Harry↗

Strategy to Develop a Control Scheme for Core Thermal Performance Optimization

This report outlines a three-year research plan for optimizing reactor core thermal performance through use of a Digital Twin (DT) model and a set of neutron detectors to correspondingly adapt the reactor control strategy. It identifies reactor features and achievable neutron measurements that factor into this optimization task. It considers spatial effects that are important and how they can be managed by a real-time algorithm that controls reactivity actuators. The report presents a set of tasks, along with corresponding methods, for accomplishing this objective. The final task in this set is to validate the combined optimization procedure in the Purdue University’s PUR-1 reactor, for which we have an agreement of understanding. Additionally, we describe an alternative approach for overcoming some of the limitations inherent in the above approach, which includes the computational costs of high-fidelity simulations and achievable integration of neutron measurements into the DT. The proposed algorithms lower the technology readiness level (TRL) of the overall approach as some additional analysis and the development of a new neutron detector concept are necessary. In particular, a sensor measuring the gradient of the neutron flux is required, and the prototype is expected to be validated in the PUR-1 reactor. The potential benefits and the opportunity to significantly push forward the state-of-the-art make this approach worthy of further exploration in the upcoming years.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Lighting for Health and Wellness Recommendations in Offices: A Circadian Lighting Pilot Project in Chicago, IL

In 2019 Cook County initiated a request for proposals for a pilot project aimed at designing and specifying an advanced tunable lighting system for government offices in Chicago, Illinois. The primary goal of the project was to replace the existing tubular LED (TLED) lighting system with a lighting system that supported the circadian rhythms and wellbeing their office employees. A secondary goal was to evaluate the potential impacts of the new lighting system, informing Cook County’s internal workplace design standards. Schuler Shook, a Chicago-based lighting design firm, was awarded the Circadian Lighting Pilot Project in October 2019 and invited Pacific Northwest National Laboratory (PNNL) to contribute as a research partner. Based on the initial project goals, Schuler Shook and PNNL established design objectives that would enable a human factors study in the office spaces, investigating the benefits and drawbacks of using a tunable LED lighting system to meet existing recommendations for lighting and health. The following report details the lighting design process through design development, with summaries of the relevant circadian lighting metrics, simulation tools, energy considerations, and research plan for the Circadian Lighting Pilot Project.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Exploring Actinide Nanocrystal Growth towards Defining 5f Surface Chemistry (Final Technical Report)

When particles are very small, down to the nanometer length scale, they display unusual properties not typical of larger materials. Most of the atoms in these structures are at the surface of the particles, which give them different electronic properties. While these unusual properties have been studied in most of the periodic table, little is known about how the electronic properties of the actinides, such as neptunium and plutonium, behave when they become so small. This planned research will study growth pathways of actinide nanoscale particles. Interestingly, the shapes of the particles change depending on the specific actinide species, spanning from thorium through americium, despite having otherwise identical arrangements of atoms. This project will use differences in the shapes and growth pathways of different actinide particles to learn about trends in electronic properties at surfaces across the actinide row. Growth pathways will be determined using a combination of synthesis and the use of advanced X-ray characterization tools. These X-ray characterization tools can provide information about electronic properties and also local bonding characteristics. This project will also inform how to make unprecedented actinide oxide nanoparticles using very small quantities of material. This will enable safe working with radioactive materials and the study of materials that never before have been made into nanoparticles. Meanwhile, students will be trained in working with these exotic materials.

36 MATERIALS SCIENCE↗

Quantum Foundations of Classical Reversible Computing

The reversible computation paradigm aims to provide a new foundation for general classical digital computing that is capable of circumventing the thermodynamic limits to the energy efficiency of the conventional, non-reversible digital paradigm. However, to date, the essential rationale for, and analysis of, classical reversible computing (RC) has not yet been expressed in terms that leverage the modern formal methods of non-equilibrium quantum thermodynamics (NEQT). In this paper, we begin developing an NEQT-based foundation for the physics of reversible computing. We use the framework of Gorini-Kossakowski-Sudarshan-Lindblad dynamics (a.k.a. Lindbladians) with multiple asymptotic states, incorporating recent results from resource theory, full counting statistics and stochastic thermodynamics. Important conclusions include that, as expected: (1) Landauer’s Principle indeed sets a strict lower bound on entropy generation in traditional non-reversible architectures for deterministic computing machines when we account for the loss of correlations; and (2) implementations of the alternative reversible computation paradigm can potentially avoid such losses, and thereby circumvent the Landauer limit, potentially allowing the efficiency of future digital computing technologies to continue improving indefinitely. We also outline a research plan for identifying the fundamental minimum energy dissipation of reversible computing machines as a function of speed.

97 MATHEMATICS AND COMPUTING↗

An Evaluation of AI Models’ Performance for Three Geothermal Sites

Current artificial intelligence (AI) applications in geothermal exploration are tailored to specific geothermal sites, limiting their transferability and broader applicability. This study aims to develop a globally applicable and transferable geothermal AI model to empower the exploration of geothermal resources. This study presents a methodology for adopting geothermal AI that utilizes known indicators of geothermal areas, including mineral markers, land surface temperature (LST), and faults. The proposed methodology involves a comparative analysis of three distinct geothermal sites—Brady, Desert Peak, and Coso. The research plan includes self-testing to understand the unique characteristics of each site, followed by dependent and independent tests to assess cross-compatibility and model transferability. The results indicate that Desert Peak and Coso geothermal sites are cross-compatible due to their similar geothermal characteristics, allowing the AI model to be transferable between these sites. However, Brady is found to be incompatible with both Desert Peak and Coso. The geothermal AI model developed in this study demonstrates the potential for transferability and applicability to other geothermal sites with similar characteristics, enhancing the efficiency and effectiveness of geothermal resource exploration. This advancement in geothermal AI modeling can significantly contribute to the global expansion of geothermal energy, supporting sustainable energy goals.

Energy & Fuels↗

A single-point modeling approach for the intercomparison and evaluation of ozone dry deposition across chemical transport models (Activity 2 of AQMEII4)

A primary sink of air pollutants and their precursors is dry deposition. Dry deposition estimates differ across chemical transport models, yet an understanding of the model spread is incomplete. Here, we introduce Activity 2 of the Air Quality Model Evaluation International Initiative Phase 4 (AQMEII4). We examine 18 dry deposition schemes from regional and global chemical transport models as well as standalone models used for impact assessments or process understanding. We configure the schemes as single-point models at eight Northern Hemisphere locations with observed ozone fluxes. Single-point models are driven by a common set of site-specific meteorological and environmental conditions. Five of eight sites have at least 3 years and up to 12 years of ozone fluxes. The interquartile range across models in multiyear mean ozone deposition velocities ranges from a factor of 1.2 to 1.9 annually across sites and tends to be highest during winter compared with summer. No model is within 50 % of observed multiyear averages across all sites and seasons, but some models perform well for some sites and seasons. For the first time, we demonstrate how contributions from depositional pathways vary across models. Models can disagree with respect to relative contributions from the pathways, even when they predict similar deposition velocities, or agree with respect to the relative contributions but predict different deposition velocities. Both stomatal and nonstomatal uptake contribute to the large model spread across sites. Our findings are the beginning of results from AQMEII4 Activity 2, which brings scientists who model air quality and dry deposition together with scientists who measure ozone fluxes to evaluate and improve dry deposition schemes in the chemical transport models used for research, planning, and regulatory purposes.

54 ENVIRONMENTAL SCIENCES↗

Hypersonic Research Facilities Study - Volume IV, Part 1: Phase III Final Studies Flight Research Facilities

The Phase III analyses of Flight Research Facilities performed as a portion of the Hypersonic Research Facilities (HYFAC) Study are presented herein. Two attractive flight research vehicle concepts, geared to the development needs of future (1980-2n00) operational hypersonic aircraft systems, are defined. The inherent research capability of each concept is further expanded by incorporating provisions within the basic vehicle design to accommodate the testing of several additional research options. The design feasibility of this approach to achieving increased research flexibility is examined. Near term propulsion systems are employed as the basic power plants to shorten acquisition time, reduce development costs, and provide high confidence in attaining the performance capability desired, Performance is determined for each basic vehicle and for the vehicles when incorporating several optional research packages. Total program cost estimates are developed for each vehicle and for the various research options. This study provides the necessary framework for the formulation of an attractive and needed flight research program which is a key element in the systematic development of an overall advanced research plan.

Source record↗

Lunar soil properties and soil mechanics

The study to identify and define recognizable fabrics in lunar soil in order to determine the history of the lunar regolith in different locations is reported. The fabric of simulated lunar soil, and lunar soil samples are discussed along with the behavior of simulated lunar soil under dynamic and static loading. The planned research is also included.

Mitchell, J. K.↗

Information services for comparative analysis of biorhythm research

References and full text documents are presented in support of continuing research and research planning for the NASA behavioral physiology program. Areas covered include: (1) desynchronosis and performance; (2) effects of alcohol, common colds, drugs, and toxic hazards on performance; (3) effects of stress on rhythm of plasma steroids; (4) data processing of biological rhythms; (5) pharmacology and biological rhythms; (6) mechanisms of biological rhythms; and (7) development of biological rhythms.

Source record↗

A Proposal for Precambrian Mineral Resource Evaluation in Minnesota Utilizing ERTS Imagery

An investigation was made of Minnesota. These rock units hold promise for potential mineral resources as do important ore deposits found in similar rocks to the north in Canada. The research planned involves the discrimination of rock types to show their aerial extent and an interpretation of the structural relationships between and within the various rock units.

Davidson, D., Jr.↗

Applicability of ERTS to Antarctic iceberg resources

The author has identified the following significant results. This investigation explorers the applicability of ERTS to (1) determine the Antarctic sea ice and environmental behavior that may influence the harvesting of icebergs, and (2) monitor iceberg locations, characteristics, and evolution. Imagery has shown that the potential applicability of ERTS to the research, planning, and harvesting operations can contribute importantly to the glowing promise derived from broader scope studies for the use of Antarctic icebergs to relieve a growing global thirst for fresh water. Several years of comprehensive monitoring will be necessary to characterize sea ice and environmental behavior and iceberg evolution. Live ERTS services will assist harvesting control and claiming operations and offer a means of harmonizing entitlements of iceberg resources. The valuable ERTS services will be more cost effective than other means will be easily justified and borne by the iceberg harvesting operations.

Hult, J. L.↗

Applicability of ERTS for surveying Antarctic iceberg resources

The author has identified the following significant results. This investigation explores the applicability of ERTS to (1) determine the Antarctic sea ice and environmental behavior that may influence the harvesting of icebergs, and (2) monitor iceberg locations, characteristics, and evolution. From image sampling, it is found that the potential applicability of ERTS to the research, planning, and harvesting operations can contribute importantly to the promise derived from broader scope studies for the use of Antarctic iceberg to relieve fresh Thermal sensor bands will provide coverage in daylight and darkness. Several years of comprehensive monitoring will be necessary to characterize sea ice and environmental behavior and iceberg evolution. Live ERTS services will assist harvesting control and claming operations and offer a means for harmonizing entitlements to iceberg resources. The valuable ERTS services will be more cost effective than other means and will be easily justified and borne by the iceberg harvesting operation.

Hult, J. L.↗

Applicability of ERTS to Antarctic iceberg resources

This investigation explores the applicability of ERTS to: (1) determine the Antarctic sea ice and environmental behavior that may influence the harvesting of icebergs, and (2) monitor iceberg locations, characteristics, and evolution. Imagery sampling in the western Antarctic between the Peninsula and the Ross Sea is used in the analysis. It is found that the potential applicability of ERTS to the research, planning, and harvesting operations can contribute importantly to the glowing promise derived from broader scope studies for the use of Antarctic icebergs to relieve a growing global thirst for fresh water. Several years of comprehensive monitoring will be necessary to characterize sea-ice and environmental behavior and iceberg evolution. Live ERTS services will assist harvesting control and claiming operations and offer a means for harmonizing entitlements to iceberg resources.

Hult, J. L.↗

Research in millimeter wave techniques

A model 180-GHz radiometer, employing a Cassegrain feed geometry with a parabolic main reflector and a subreflector fed by a corrugated conical horn, was constructed and tested. An absorber-coated chopper is used to modulate the signal, which is down-converted in a cross-guide harmonic mixer. A 100-GHz source was used to evaluate mixer performance and to optimize system parameters. Preliminary results indicate a noise figure of approximately 20 db is being achieved. Preliminary design studies and on-going research plans are discussed.

Dees, J. W.↗