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At least 289 records · Page 16

Lensing Constraints on the Mass Profile Shape and the Splashback Radius of Galaxy Clusters

The lensing signal around galaxy clusters can, in principle, be used to test detailed predictions for their average mass profile from numerical simulations. However, the intrinsic shape of the profiles can be smeared out when a sample that spans a wide range of cluster masses is averaged in physical length units. This effect especially conceals rapid changes in gradient such as the steep drop associated with the splashback radius, a sharp edge corresponding to the outermost caustic in accreting halos. We optimize the extraction of such local features by scaling individual halo profiles to a number of spherical overdensity radii, and apply this method to 16 X-ray-selected, high-mass clusters targeted in the Cluster Lensing And Supernova survey with Hubble. By forward-modeling the weak- and strong-lensing data presented by Umetsu et al., we show that, regardless of the scaling overdensity, the projected ensemble density profile is remarkably well described by a Navarro–Frenk–White (NFW) or Einasto profile out to R∼2.5 h{sup −1} Mpc, beyond which the profiles flatten. We constrain the NFW concentration to c{sub 200c}=3.66±0.11 at M{sub 200c}≃1.0×10{sup 15} h{sup −1} M{sub ⊙}, consistent with and improved from previous work that used conventionally stacked lensing profiles, and in excellent agreement with theoretical expectations. Assuming the profile form of Diemer and Kravtsov and generic priors calibrated from numerical simulations, we place a lower limit on the splashback radius of the cluster halos, if it exists, of R{sub sp}{sup 3D}/r{sub 200m}>0.89 (R{sub sp}{sup 3D}>1.83 h{sup −1} Mpc) at 68% confidence. The corresponding density feature is most pronounced when the cluster profiles are scaled by r{sub 200m}, and smeared out when scaled to higher overdensities.

79 ASTRONOMY AND ASTROPHYSICS↗

Computation of sharp-fin-induced shockwave/turbulent boundary layer interactions

Solutions of the Reynolds-averaged Navier-Stokes equations are presented and are compared with a family of experimental results for the three-dimensional interaction of a sharp-fin-induced shock wave with a turbulent boundary layer. The solutions predict most of the essential features of the flow fields for various shock-wave strengths. However, some features of the measured flow fields, such as secondary separation and size of the largest separated zones were not accurately computed. The computed flow fields, aided by particle tracing techniques, display a prominent vortical structure which can be correlated with the observed surface phenomena.

Horstman, C. C.↗

High-resolution dynamical modelling of the Antarctic stratospheric vortex

Progress is reported on the high-resolution three-dimensional numerical simulation of flows characteristic of the Antarctic wintertime stratosphere. The numerical model is a modified version of the Reading University sigma-coordinate used previously for tropospheric studies. Physical parameterizations are kept to a minimum in order to concentrate as much computing power as possible on simulating details of the dynamical processes. The major question addressed is whether the features observed in recent high-resolution two-dimensional simulations - namely: (1) the formation of a sharp edge to the vortex (seen in the potential vorticity field), (2) the survival of the polar vortex in a material entity, and (3) the formation of small-scale eddies rough the break-up of tongues of high potential vorticity drawn out from the polar vortex - are realized in three-dimensional simulations.

Haynes, P. H.↗

The critical complex in nucleation is not the nucleus

A theory of nucleation is presented which combines features of classical nucleation. In this theory, the nucleus is a cluster of finite size with a sharp interface and spinodal decomposition, in which a fluctuation in density or composition generates the critical complex and nucleus. Thus, the nucleus is a product of nucleation. Schematic models for the classical and the proposed routes to nucleation are compared, focusing on the relation between pressure and volume in the models. In the proposed model, the critical complex, or critical state, is between the parent state and the nucleus.

Rasmussen, Don H.↗

K-Shell Photoionization of Nickel Ions Using R-Matrix

We present R-matrix calculations of photoabsorption and photoionization cross sections across the K edge of the Li-like to Ca-like ions stages of Ni. Level-resolved, Breit-Pauli calculations were performed for the Li-like to Na-like stages. Term-resolved calculations, which include the mass-velocity and Darwin relativistic corrections, were performed for the Mg-like to Ca-like ion stages. This data set is extended up to Fe-like Ni using the distorted wave approximation as implemented by AUTOSTRUCTURE. The R-matrix calculations include the effects of radiative and Auger dampings by means of an optical potential. The damping processes affect the absorption resonances converging to the K thresholds causing them to display symmetric profiles of constant width that smear the otherwise sharp edge at the K-shell photoionization threshold. These data are important for the modeling of features found in photoionized plasmas.

Witthoeft, M. C.↗

Role of weak interlayer coupling in ultrafast exciton-exciton annihilation in two-dimensional rhenium dichalcogenides

Strong interactions between excitons are a characteristic feature of two-dimensional (2D) semiconductors, determining important excitonic properties, such as exciton lifetime, coherence, and photon-emission efficiency. Rhenium disulfide (ReS 2 ), a member of the 2D transition-metal dichalcogenide (TMD) family, has recently attracted great attention due to its unique excitons that exhibit excellent polarization selectivity and coherence features. However, an in-depth understanding of exciton-exciton interactions in ReS 2 is still lacking. In this work, we used ultrafast pump-probe spectroscopy to study exciton-exciton interactions in monolayer (1L), bilayer (2L), and triple layer ReS 2 . Additionally, we directly measure the rate of exciton-exciton annihilation, a representative Auger-type interaction between excitons. It decreases with increasing layer number, as observed in other 2D TMDs. However, while other TMDs exhibit a sharp weakening of exciton-exciton annihilation between 1L and 2L, such behavior was not observed in ReS 2 . We attribute this distinct feature in ReS 2 to the relatively weak interlayer coupling, which prohibits a substantial change in the electronic structure when the thickness varies. This work not only highlights the unique excitonic properties of ReS 2 but also provides novel insight into the thickness dependence of exciton-exciton interactions in 2D systems.

36 MATERIALS SCIENCE↗

Sulfur Hydrides: Phase Diagram and the Transition into the Record-High T{sub c} State

Remarkable feature of the phase diagram of sulfur hydrides, the record-high T{sub c} superconductors, is a sharp increase near P ≈ 150 GPa from T{sub c} ≈ 120 to ≈ 200 K. This increase is a signature of the structural transition. The present study is concerned with the nature of this phase transition. One can demonstrate that the symmetry analysis along with an analysis of the impact of lattice deformations lead to the conclusion that we are dealing with the first-order transition. Such a transition is manifested in an abrupt appearance of small pockets on the Fermi surface and, correspondingly, the two-gap energy spectrum.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Superconductivity in the Narrow Gap Semiconductor RbBi 11/3 Te 6

Superconductivity was discovered in the layered compound RbBi 11/3 Te 6 , featuring Bi vacancies and a narrow band gap of 0.25(2) eV at room temperature. In addition, a sharp superconducting transition at similar to 3.2 K was observed in polycrystalline ingots. The superconducting volume fraction of oriented single crystals is almost 100%, confirming bulk superconductivity. Systematic Se and Sb substitutions in RbBi 11/3-y Sb y Se x Te 6-x , revealed a dependence of the superconducting transition on composition that can increase the T c up to similar to 10%. The RbBi 11/3 Te 6 system is the first member of the new homologous series Rb[Bi 2n+11/3 Te 3n+6 ] with infinite Bi 2 Te 3 -like layers. Lastly, the large degree of chemical tunability of the electronic structure of the homology via doping and/or substitution gives rise to a new family of superconductors.

36 MATERIALS SCIENCE↗

Unravelling ultralow thermal conductivity in perovskite Cs2AgBiBr6: dominant wave-like phonon tunnelling and strong anharmonicity

Abstract Understanding the lattice dynamics and heat transport physics in the lead-free halide double perovskites remains an outstanding challenge due to their lattice dynamical instability and strong anharmonicity. In this work, we investigate the microscopic mechanisms of anharmonic lattice dynamics and thermal transport in lead-free halide double perovskite Cs 2 AgBiBr 6 from first principles. We combine self-consistent phonon calculations with bubble diagram correction and a unified theory of lattice thermal transport that considers both the particle-like phonon propagation and wave-like tunnelling of phonons. An ultra-low thermal conductivity at room temperature (~0.21 Wm −1 K −1 ) is predicted with weak temperature dependence( ~ T −0.34 ), in sharp contrast to the conventional ~T −1 dependence. Particularly, the vibrational properties of Cs 2 AgBiBr 6 are featured by strong anharmonicity and wave-like tunnelling of phonons. Anharmonic phonon renormalization from both the cubic and quartic anharmonicities are found essential in precisely predicting the phase transition temperature in Cs 2 AgBiBr 6 while the negative phonon energy shifts induced by cubic anharmonicity has a significant influence on particle-like phonon propagation. Further, the contribution of the wave-like tunnelling to the total thermal conductivity surpasses that of the particle-like propagation above around 310 K, indicating the breakdown of the phonon gas picture conventionally used in the Peierls-Boltzmann Transport Equation. Importantly, further including four-phonon scatterings is required in achieving the dominance of wave-like tunnelling, as compared to the dominant particle-like propagation channel when considering only three-phonon scatterings. Our work highlights the importance of lattice anharmonicity and wave-like tunnelling of phonons in the thermal transport in lead-free halide double perovskites.

Chemistry↗

Complex interplay of interatomic bonding in a multi-component pyrophosphate crystal: K 2 Mg (H 2 P 2 O 7 ) 2 ·2H 2 O

The electronic structure and interatomic bonding of pyrophosphate crystal K 2 Mg (H 2 P 2 O 7 ) 2 ·2H 2 O are investigated for the first time showing complex interplay of different types of bindings. The existing structure from single-crystal X-ray diffraction is not sufficiently refined, resulting in unrealistic short O—H bonds which is rectified by high-precision density functional theory (DFT) calculation. K 2 Mg (H 2 P 2 O 7 ) 2 ·2H 2 O has a direct gap of 5.22 eV and a small electron effective mass of 0.14 m e . Detailed bond analysis between every pair of atoms reveals the complexity of various covalent, ionic, hydrogen bonding and bridging bonding and their sensitive dependence on structural differences. The K--O bonds are much weaker than Mg--O bonds and contributions from the hydrogen bonds are non-negligible. Quantitative analysis of internal cohesion in terms of total bond order density and partial bond order density divulges the relative importance of different types of bonding. The calculated optical absorptions show multiple peaks and a sharp Plasmon peak at 23 eV and a refractive index of 1.44. The elastic and mechanical properties show features unique to this low-symmetry crystal. Phonon calculation gives vibrational frequencies in agreement with reported Raman spectrum. These results introduce new insights indicating that acidic pyrophosphates could have a variety of unrealized applications in advanced technology.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

The ultraviolet aurora - The spectrum between 2100 A and 2300 A

Rocket-borne spectroscopic observations of the ultraviolet aurora between 2100 A and 2300 A reveal bands from the N2 Lyman-Birge-Hopfield and Vegard-Kaplan systems. A strong feature at 2144 A is identified as the quintet doublet of N II. This emission feature is shown from altitude profiles to have little if any quenching.

Sharp, W. E.↗

SiC Composite Turbine Vanes

Turbine inlet guide vanes have been fabricated from composites of silicon carbide fibers in silicon carbide matrices. A unique design for a cloth made from SiC fibers makes it possible to realize the geometric features necessary to form these vanes in the same airfoil shapes as those of prior metal vanes. The fiber component of each of these vanes was made from SiC-fiber cloth coated with boron nitride. The matrix was formed by chemical-vapor infiltration with SiC, then slurry-casting of SiC, followed by melt infiltration with silicon. These SiC/SiC vanes were found to be capable of withstanding temperatures 400 F (222 C) greater than those that can be withstood by nickel-base-superalloy turbine airfoils now in common use in gas turbine engines. The higher temperature capability of SiC/SiC parts is expected to make it possible to use them with significantly less cooling than is used for metallic parts, thereby enabling engines to operate more efficiently while emitting smaller amounts of NOx and CO. The SiC/SiC composite vanes were fabricated in two different configurations. Each vane of one of the configurations has two internal cavities formed by a web between the suction and the pressure sides of the vane. Each vane of the other configuration has no web (see Figure 1). It is difficult to fabricate components having small radii, like those of the trailing edges of these vanes, by use of stiff stoichiometric SiC fibers currently preferred for SiC/SiC composites. To satisfy the severe geometric and structural requirements for these vanes, the aforementioned unique cloth design, denoted by the term Y-cloth, was conceived (see Figure 2). In the regions away from the trailing edge, the Y-cloth features a fiber architecture that had been well characterized and successfully demonstrated in combustor liners. To form a sharp trailing edge (having a radius of 0.3 mm), the cloth was split into two planes during the weaving process. The fiber tows forming the trailing-edge section were interlocked, thereby enhancing through-thickness strength of the resulting composite material. For vanes of the webless configuration, each made from a layup of six plies of Ycloth, the length of each Y-cloth layer was cut so that the two strips corresponding to the aforementioned two planes would wrap around the perimeter of a graphite vane preform tool with a 10-mm overlap. The overlap was used to join the two strips in a fringe splice. To make the external sixth ply, a standard woven cloth was cut to the required final length and a fringe splice joined the two ends of the cloth at the trailing edge. The cloth was then prepregged. The entire assembly was then placed into an aluminum compaction tool designed to form the outer net shape of the vane. After the prepreg material was allowed to dry, the preform was removed from the aluminum tooling and placed into an external graphite tool before being shipped to a vendor for matrix infiltration. To make the SiC fiber preform for a vane having an internal web, a slightly different initial approach was followed. Each of two sections forming the internal cavities (and ultimately the web) was created by first slipping two concentric layers of a two-dimensional, 2-by-2, 45 - braided tube around a net-shape graphite mandrel. The tubes on both mandrels were prepregged and allowed to dry. The resulting two subassemblies were put together, then four additional plies were wrapped around them in the same fashion as that described above for the six plies of the vaneless configuration. The consolidation of the SiC fiber preforms into SiC/SiC composite parts was performed by commercial vendors using their standard processes. The capability of two of the webless SiC/SiC turbine vanes was demonstrated in tests in a turbine environment. The tests included 50 hours of steady-state operation and 102 two-minute thermal cycles. A surface temperature of 1,320 C was reached during the tests.

Calomino, Anthony M.↗

Tip-based proximity ferroelectric switching and piezoelectric response in wurtzite multilayers

Proximity ferroelectricity is a paradigm for inducing ferroelectricity when a nonferroelectric polar material (such as Al⁢ N), which is unswitchable with an external field below the dielectric breakdown field, becomes a practically switchable ferroelectric in direct contact with a thin switchable ferroelectric layer (such as Al 1−𝑥 ⁢Sc 𝑥 ⁢N). Here, we develop a Landau-Ginzburg-Devonshire approach to study the proximity effect of local piezoelectric response and polarization reversal in wurtzite ferroelectric multilayers under a sharp electrically biased tip. Using finite-element modeling, we analyze the probe-induced nucleation of nanodomains, the features of local polarization hysteresis loops and coercive fields in the Al 1−𝑥 ⁢Sc 𝑥 ⁢N/Al⁢ N bilayers and three-layers. Similar to the wurtzite multilayers sandwiched between two parallel electrodes, the regimes of “proximity switching” (when all layers collectively switch) and the regime of “proximity suppression” (when they collectively do not switch) are the only two possible regimes in the probe-electrode geometry. However, the parameters and asymmetry of the local piezoresponse and polarization hysteresis loops depend significantly on the sequence of the layers with respect to the probe. The physical mechanism of proximity ferroelectricity in the local probe geometry is a depolarizing electric field determined by the polarization of the layers and their relative thickness. The field, whose direction is opposite to the polarization vector in the layer(s) with the larger spontaneous polarization (such as Al⁢ N), renormalizes the double-well ferroelectric potential to lower the steepness of the switching barrier in the “otherwise unswitchable” polar layers. Tip-based control of domains in otherwise nonferroelectric layers using proximity ferroelectricity can provide nanoscale control of domain reversal in memory, actuation, sensing, and optical applications. The ability of the tip-induced proximity switching to differentially switch multilayers, based on the order of the layers, provides a powerful tool for selective domain engineering.

36 MATERIALS SCIENCE↗

Convective Transition Statistics over Tropical Oceans for Climate Model Diagnostics: Observational Baseline

Convective transition statistics, which describe the relation between column-integrated water vapor (CWV) and precipitation, are compiled over tropical oceans using satellite and ARM site measurements to quantify the temperature and resolution dependence of the precipitation–CWV relation at fast time scales relevant to convection. At these time scales, and for precipitation especially, uncertainties associated with observational systems must be addressed by examining features with a variety of instrumentation and identifying robust behaviors versus instrument sensitivity at high rain rates. Here the sharp pickup in precipitation as CWV exceeds a certain critical threshold is found to be insensitive to spatial resolution, with convective onset occurring at higher CWV but at lower column relative humidity as bulk tropospheric temperature increases. Mean tropospheric temperature profiles conditioned on precipitation show vertically coherent structure across a wide range of temperature, reaffirming the use of a bulk temperature measure in defining the convective transition statistics. The joint probability distribution of CWV and precipitation develops a peak probability at low precipitation for CWV above critical, with rapidly decreasing probability of high precipitation below and near critical, and exhibits systematic changes under spatial averaging. The precipitation pickup with CWV is reasonably insensitive to time averaging up to several hours but is smoothed at daily time scales. This work demonstrates that CWV relative to critical serves as an effective predictor of precipitation with only minor geographic variations in the tropics, quantifies precipitation-related statistics subject to different spatial–temporal resolution, and provides a baseline for model comparison to apply these statistics as observational constraints on precipitation processes.

54 ENVIRONMENTAL SCIENCES↗

The energy balance of wind waves and the remote sensing problem

Measurements of wave growth indicate an energy balance of the wave spectrum governed primarily by input from the atmosphere, nonlinear transfer to shorter and longer waves, and advection. The pronounced spectral peak and sharp low frequency cut-off characteristic of fetch-limited spectra are explained as a self-stabilizing feature of the nonlinear wave-wave interactions. The momentum transferred from the atmosphere to the wind waves accounts for a large part of the wind drag. These findings are relevant for remote microwave sensing of the sea surface by backscatter and passive radiometry methods.

Hasselmann, K.↗

Compact far ultraviolet emission source with rich spectral emission 1150-3100 A

The article describes a compact hollow Pt cathode emission source for the far UV, developed for use as a high-resolution wavelength standard in laboratory work or on spacecraft (specifically, the NASA International UV Explorer - IUE). The source is small, rugged, lightweight, spectrally rich, bright in the 1150-3200 A region, features long service life, low operating voltage, and lower power drain, and stably emits a large number of very sharp lines with a spectrum lending itself to projection onto the focal plane of a spectrograph. The source has successfully passed exacting environmental tests, and serves as a transfer standard for absolute sensitivity calibration of spectrometric instruments.

Mount, G. H.↗

Comparison of computations and experimental data for leading edge vortices - Effects of yaw and vortex flaps

Computations are presented using the conical Euler equations for swept delta wings with leading edge vortices. All the wings have sharp leading edges swept at 75 degrees to the freestream. In addition to an idealized flat plate model, geometrical features also included are thickness, centerbody, and two vortex flaps. Freestream Mach numbers of 1.7 to 2.8, angles of attack of 10 and 12 degrees, and angles of yaw of 0 and 8 degrees are considered. The computations are compared with pitot pressure traverses for one case. Other calculations are compared with pitot pressure traverses for one case. Other calculations are compared with surface pressure data and vapor screen pictures recently obtained at NASA Langley Research Center. The comparisons indicate that the dominant features of these flows are adequately modeled by the Euler equations, but viscous models are needed for the surface boundary layer and secondary separations.

Murman, E. M.↗