Search NASA⌕ Search

SEARCH · Search NASA

Results for “small scale processes”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 289 records · Page 16
All sourcesNASA NTRSDOE OSTI
DOE OSTI2015

Semiconductor nanocrystal quantum dot synthesis approaches towards large-scale industrial production for energy applications

This study reviews the experimental synthesis and engineering developments that focused on various green approaches and large-scale process production routes for quantum dots. Fundamental process engineering principles were illustrated. In relation to the small-scale hot injection method, our discussions focus on the non-injection route that could be scaled up with engineering stir-tank reactors. In addition, applications that demand to utilize quantum dots as "commodity" chemicals are discussed, including solar cells and solid-state lightings.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2017

The Eruption of a Small-scale Emerging Flux Rope as the Driver of an M-class Flare and of a Coronal Mass Ejection

Solar flares and coronal mass ejections are the most powerful explosions in the Sun. They are major sources of potentially destructive space weather conditions. However, the possible causes of their initiation remain controversial. Using high-resolution data observed by the New Solar Telescope of Big Bear Solar Observatory, supplemented by Solar Dynamics Observatory observations, we present unusual observations of a small-scale emerging flux rope near a large sunspot, whose eruption produced an M-class flare and a coronal mass ejection. The presence of the small-scale flux rope was indicated by static nonlinear force-free field extrapolation as well as data-driven magnetohydrodynamics modeling of the dynamic evolution of the coronal three-dimensional magnetic field. During the emergence of the flux rope, rotation of satellite sunspots at the footpoints of the flux rope was observed. Meanwhile, the Lorentz force, magnetic energy, vertical current, and transverse fields were increasing during this phase. The free energy from the magnetic flux emergence and twisting magnetic fields is sufficient to power the M-class flare. These observations present, for the first time, the complete process, from the emergence of the small-scale flux rope, to the production of solar eruptions.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2017

Vitrification of Sellafield Wastes with High Metallic Magnesium Alloy Content - 17495

The Sellafield nuclear complex, located in northwest England, is the largest such site in the United Kingdom. Sellafield Limited, which is the operating contractor for the Nuclear Decommissioning Authority, is evaluating thermal treatment technologies for a potential future facility to process a variety of Intermediate Level Waste sludges and slurries accumulated from historical site operations. In support of that effort, Atkins and the Vitreous State Laboratory (VSL) of The Catholic University of America conducted studies to evaluate the feasibility and implications of installing a joule-heated ceramic melter (JHCM) vitrification system to process a variety of sludge and slurry radioactive wastes at the Sellafield site. These sludges have the potential to contain a significant proportion of reactive metals in localized regions. The metallic fraction derives from unreacted Magnox spent fuel cladding. Thus, an important objective of this work was to investigate the performance of JHCM technology for the treatment of streams with localized regions of high reactive metal contents. The present work was focused on Site Ion Exchange Effluent Plant (SIXEP) Magnox sludges, investigated previously. Suitable waste simulants were developed for the SIXEP Magnox sludge waste stream, which included surrogates for all important radionuclides. High waste-loading, fully compliant glass formulations were designed using a combination of previous experience, extensive waste glass data bases, and small-scale crucible melts. Glasses from the test melts were characterized for properties that are important for processability and product quality. The most viable compositions were then selected for small-scale melter trials to collect information on processing rates and behavior, off-gas and secondary waste compositions, and overall system mass balance. These data were used to support the technology evaluation, which considered such factors as minimization of inactive additions, waste volume reduction, retention of radionuclides, minimization of secondary wastes, and overall process efficiency and effectiveness. The data were also used to develop sizing estimates for the full-scale facility and to estimate treatment durations under various treatment scenarios. A series of tests was then performed with partial replacement of the magnesium hydroxide with a metallic magnesium alloy that is close in composition to Magnox alloy. A commercially available magnesium alloy, Elecktron AZ31B, which has a nominal magnesium content of 95.7%, was used for this purpose. The testing was performed on a DuraMelter 10 (DM10) JHCM system to characterize the melter off-gas, glass product, and the effects of magnesium alloy particle size on feed processing. Data on processing rate and any processing issues, product glass composition, off-gas composition including hydrogen, and system operating parameters, including flows, temperatures, pressures, etc., were collected and analyzed to evaluate the effects of magnesium alloy on the vitrification process. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2015

Anaerobic sequencing batch reactor in pilot scale for treatment of tofu industry wastewater

The small industry of tofu production process releases the waste water without being processed first, and the wastewater is directly discharged into water. In this study, Anaerobic Sequencing Batch Reactor in Pilot Scale for Treatment of Tofu Industry was developed through an anaerobic process to produce biogas as one kind of environmentally friendly renewable energy which can be developed into the countryside. The purpose of this study was to examine the fundamental characteristics of organic matter elimination of industrial wastewater with small tofu effective method and utilize anaerobic active sludge with Anaerobic Sequencing Bath Reactor (ASBR) to get rural biogas as an energy source. The first factor is the amount of the active sludge concentration which functions as the decomposers of organic matter and controlling selectivity allowance to degrade organic matter. The second factor is that HRT is the average period required substrate to react with the bacteria in the Anaerobic Sequencing Bath Reactor (ASBR).The results of processing the waste of tofu production industry using ASBR reactor with active sludge additions as starter generates cumulative volume of 5814.4 mL at HRT 5 days so that in this study it is obtained the conversion 0.16 L of CH{sub 4}/g COD and produce biogas containing of CH{sub 4}: 81.23% and CO{sub 2}: 16.12%. The wastewater treatment of tofu production using ASBR reactor is able to produce renewable energy that has economic value as well as environmentally friendly by nature.

09 BIOMASS FUELS↗
DOE OSTI2025

Pursuing small-scale measures of penetration resistance in Ti-5553 alloy

This work was originally proposed to illustrate the performance of a particular set of differently processed Ti-5553 plates under dynamic threats. It became clear that the larger question, at present, is whether the small-scale shaped charge design of an RP-4 detonator can be employed to efficiently explore the dynamic penetration resistance of representative test articles. The initial penetration testing that employed three variants of thermomechanical processing of Ti-5553 plates appeared to demonstrate that there was a noticeable difference in their performance. The remaining pertinent question was regarding the variation in the shaped charge performance and how it compares to the variation from the three titanium plate tests. Based on the limited testing presented here the RP-4 shaped charge detonator appears to have an average depth of penetration in 6061 aluminum of 90mm with a 1.5CD stand off.

shaped charge penetration↗
DOE OSTI2024

Impacts of Topography-Based Subgrid Scheme and Downscaling of Atmospheric Forcing on Modeling Land Surface Processes in the Conterminous US

The effects of small-scale topography-induced land surface heterogeneity are not well represented in current Earth System Models (ESMs). In this study, a new topography-based subgrid structure referred to as topographic units (TGU) designed to better capture subgrid topographic effects, and methods to downscale atmospheric forcing to the land TGUs have been implemented in the Energy Exascale Earth System Model (E3SM) Land Model (ELM). Effects of the subgrid scheme and downscaling methods on ELM simulated land surface processes are evaluated over the conterminous United States (CONUS). For this purpose, ELM simulations are performed using two configurations without (NoD ELM) and with (D ELM) downscaling, both using TGUs derived for the 0.5-degree grids and the same land surface parameters. Simulations using the two ELM configurations are compared over the CONUS domain, regional levels, and at observational sites (e.g., SNOTEL). The CONUS-level results suggest that D ELM simulates more snowfall and snow water equivalent (SWE), higher runoff, and less ET during spring and summer. Regional-level results suggest more pronounced impacts of downscaling over regions dominated by higher elevation TGUs and regions with maximum precipitation occurring during cool seasons. Results at the SNOTEL sites suggest that D ELM has superior capability of reproducing the observed SWE at 83% of the sites, with more pronounced performance over topographically heterogeneous TGUs with their maximum precipitation occurring during cool seasons. The results highlight the importance of improving representation of small-scale surface heterogeneity in ESMs and motivate future research to understand their effects on land-atmosphere interactions, streamflow, and water resources management over mountainous regions.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1993

General-Purpose Element-Extracting Process

Proposed ore-refining or element-extracting process nonspecific: decomposes any ore or other raw material into constituent elements, regardless of composition. Enables conversion of ores into elements and recombination of elements into usefulmaterials as necessary. Effected on small scale to supplement such other mineral-refining processes as fluidized-bed reduction or carbochlorination. Alternatively, effected on large scale to produce wide range of materials. Conceived to provide materials for self-sufficient lunar base from such local ores as anorthite, ilmenite, and olivine. Proves useful on Earth in recovery or extraction of scarce, valuable, or hazardous materials.

Curreri, Peter A.↗
NASA NTRS1990

Minimal spectrum of long-wave perturbations - Is linear growth correct only in the nonlinear regime?

Very high resolution two-dimensional simulations are used to test the generation and growth of the so-called 'minimal' k exp 4 power spectrum which develops from initial conditions which have power only on small scales, such as might result from some process in the early universe. It is confirmed that the amplitude of minimal long-wave power grows proportionally to a exp 4, not a-squared, where a is the scale factor of the expanding universe. It reverts to a-squared only after the short-wave modes are effectively saturated, and by that time an effective long-wave power law closer to k-cubed is found. Small-scale perturbations may result in much more long-wave power than has been generally assumed.

Shandarin, Sergei F.↗
NASA NTRSDate not supplied

Plasma Assisted Nutrient Recovery from Inedible Biomass via Ash Leaching

Sustaining a human presence on the Moon, Mars, or deep space will require closing loops on many life support systems. Some form of agriculture will be required because plants produce the vitamins, antioxidants, and essential oils in our diets that degrade over time in stored foods. In addition, they provide dietary fiber, revitalize air and purify water. It is estimated that 93 kg of plant nutrients are required to support one crew member per year. Growing plants will require recycling nutrients trapped in inedible plant stems, leaves and debris. We examined the effects of using thermal plasma and various carrier gases to breakdown inedible plant biomass and aid in nutrient recovery. Previous work demonstrated a thermally degrading environment such as a muffle furnace improved nutrient recovery from inedible biomass prior to an acid leaching process, however, a muffle furnace is an inefficient process. We tested the ability of a small scale, thermal plasma using carbon dioxide, nitrogen, or air as plasma carrier gases to degrade pelleted plant biomass. The gases were chosen to explore variations in recovery and potential chemical by-products. Plasma treated and untreated biomass was leached with different concentrations of acid to determine the extraction of nutrients (potassium, magnesium, calcium, and. phosphorus) for reuse in the crop production cycle. Results are presented showing the impact of plasma processing prior to acid leaching on recovery of plant nutrients.

Plasma↗
DOE OSTI2022

Chemistry-mediated Ostwald ripening in carbon-rich C/O systems at extreme conditions

Abstract There is significant interest in establishing a capability for tailored synthesis of next-generation carbon-based nanomaterials due to their broad range of applications and high degree of tunability. High pressure (e.g., shockwave-driven) synthesis holds promise as an effective discovery method, but experimental challenges preclude elucidating the processes governing nanocarbon production from carbon-rich precursors that could otherwise guide efforts through the prohibitively expansive design space. Here we report findings from large scale atomistically-resolved simulations of carbon condensation from C/O mixtures subjected to extreme pressures and temperatures, made possible by machine-learned reactive interatomic potentials. We find that liquid nanocarbon formation follows classical growth kinetics driven by Ostwald ripening (i.e., growth of large clusters at the expense of shrinking small ones) and obeys dynamical scaling in a process mediated by carbon chemistry in the surrounding reactive fluid. The results provide direct insight into carbon condensation in a representative system and pave the way for its exploration in higher complexity organic materials. They also suggest that simulations using machine-learned interatomic potentials could eventually be employed as in-silico design tools for new nanomaterials.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRSDate not supplied

Plasmaspheric Plume Turbulence: Signature of an Electrostatic Corotation Convection Shear-Layer Instability

As demonstrated by IMAGE-EUV observations, plasmaspheric drainage plumes are a common feature emanating from the plasmasphere during periods of enhanced convection. Concurrent IMAGE-EUV and LANL-MPA observations reveal that plasmaspheric plumes are not a uniform density structure that extends out to geosynchronous orbit and beyond. Instead, in–situ observations reveal a large spatial-scale structure populated by small-scale density structures suggestive of the presence of a turbulent process. Here, we investigate the occurrence and nature of plasmaspheric drainage plumes as observed by concurrent EUV-MPA observations, as well as explore the possibility that the in–situ observed small-scale density structures are the signature of an instability produced by the sheared velocity found within the plasmaspheric layers separating the corotation of the main plasmasphere from the convection-driven flow generating the plume. Particle-in-cell simulations indicate that the generation of shear-flow driven instabilities is possible under plasmaspheric plasma conditions. The initial results of these simulations indicate that the plasmaspheric instabilities generated are electrostatic in nature, consist with in–situ plume observations.

Mark L Adrian↗
DOE OSTI2019

Laboratory-Scale Melter Systems for Simulated and Real AP-105 Tank Waste - 19301

The Hanford Tank Waste Treatment and Immobilization Plant is being constructed to vitrify the nuclear waste stored in underground tanks on the Hanford Site. Through this conversion process, waste components become partitioned into one of two product streams: glass and off-gas, including condensate. A small-scale melter system is appropriate for analyzing the waste-to-glass process because it does not require the high volumes of input waste or resource commitment of a large-scale melter system while providing dynamic information that can be difficult to determine from batch reactions in a crucible system. A continuous laboratory-scale melter (CLSM) was sized to collect the relevant process and chemical information from obtainable volumes of Hanford tank waste and designed to operate with a continuous feeding process while periodically pouring glass product and collecting off-gas. Two CLSMs were constructed: one in a non-radioactive environment for processing waste simulants and another in a fume hood capable of handling radioactive material for processing actual Hanford tank waste. Multiple waste simulants were first tested in the non-radioactive CLSM to determine the processability and desired operating window for actual tank waste. About 12 liters of real waste from Hanford tank 241-AP-105 were received, filtered, and ion exchanged for removal of Cs-137. This quantity of waste was vitrified into 9.5 kg of glass product over the course of ∼15 hours of feeding to the CLSM. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2024

Invertible Temper Modeling using Normalizing Flows and the Effects of Structure Preserving Loss

Advanced manufacturing research and development is typically small-scale, owing to costly experiments associated with these novel processes. Deep learning techniques could help accelerate this development cycle but frequently struggle in small-data regimes like the advanced manufacturing space. While prior work has applied deep learning to modeling visually plausible advanced manufacturing microstructures, little work has been done on data-driven modeling of how microstructures are affected by heat treatment, or assessing the degree to which synthetic microstructures are able to support existing workflows. We propose to address this gap by using invertible neural networks (normalizing flows) to model the effects of heat treatment, e.g., tempering. The model is developed using scanning electron microscope imagery from samples produced using shear-assisted processing and extrusion (ShAPE) manufacturing. This approach not only produces visually and topologically plausible samples, but also captures information related to a sample’s material properties or experimental process parameters. We also demonstrate that topological data analysis, used in prior work to characterize microstructures, can also be used to stabilize model training, preserve structure, and improve downstream results. We assess directions for future work and identify our approach as an important step towards end-to-end deep learning system for accelerating advanced manufacturing research and development.

Howland, Sylvia↗
DOE OSTI2018

Use of High-Throughput Automated Microbioreactor System for Production of Model IgG1 in CHO Cells

Automated microscale bioreactors (15 mL) can be a useful tool for cell culture engineers. They facilitate the simultaneous execution of a wide variety of experimental conditions while minimizing potential process variability. Applications of this approach include: clone screening, temperature and pH shifts, media and supplement optimization. Furthermore, the small reactor volumes are conducive to large Design of Experiments that investigate a wide range of conditions. This allows upstream processes to be significantly optimized before scale-up where experimentation is more limited in scope due to time and economic constraints. Automated microscale bioreactor systems offer various advantages over traditional small scale cell culture units, such as shake flasks or spinner flasks. However, during pilot scale process development significant care must be taken to ensure that these advantages are realized. When run with care, the system can enable high level automation, can be programmed to run DOE's with a higher number of variables and can reduce sampling time when integrated with a nutrient analyzer or cell counter. Integration of the expert-derived heuristics presented here, with current automated microscale bioreactor experiments can minimize common pitfalls that hinder meaningful results. In the extreme, failure to adhere to the principles laid out here can lead to equipment damage that requires expensive repairs. Furthermore, the microbioreactor systems have small culture volumes making characterization of cell culture conditions difficult. The number and amount of samples taken in-process in batch mode culture is limited as operating volumes cannot fall below 10 mL. This method will discuss the benefits and drawbacks of microscale bioreactor systems.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2020

Learning from existing photovoltaic technologies to identify alternative perovskite module designs

Perovskite solar cells have now become the most efficient of all multicrystalline thin film photovoltaic technologies, reaching 25.2% in 2019. This outstanding figure of merit has only been achieved on small lab-scale devices, with significantly lower performance when processed on larger more industrially relevant substrate sizes. Perovskite modules, connecting several smaller area cells together, are commonly demonstrated with a superstrate monolithic interconnection method. However, several other module designs exist and remain largely unexplored by the perovskite community. In this work, we review and highlight those alternatives and discuss their advantages and limitations. We propose that a singulated substrate-oriented module design, using metallic substrates, could provide a quicker path to seeing highly efficient, lightweight, and flexible perovskite modules on the market, while mitigating near-term technical risks. Finally, as an experimental starting-point towards this design, we demonstrate a substrate-oriented all-perovskite 2-terminal tandem with 18% efficiency.

14 SOLAR ENERGY↗
DOE OSTI2015

MAGNETOHYDRODYNAMIC KINK WAVES IN NONUNIFORM SOLAR FLUX TUBES: PHASE MIXING AND ENERGY CASCADE TO SMALL SCALES

Magnetohydrodynamic (MHD) kink waves are ubiquitously observed in the solar atmosphere. The propagation and damping of these waves may play relevant roles in the transport and dissipation of energy in the solar atmospheric medium. However, in the atmospheric plasma dissipation of transverse MHD wave energy by viscosity or resistivity needs very small spatial scales to be efficient. Here, we theoretically investigate the generation of small scales in nonuniform solar magnetic flux tubes due to phase mixing of MHD kink waves. We go beyond the usual approach based on the existence of a global quasi-mode that is damped in time due to resonant absorption. Instead, we use a modal expansion to express the MHD kink wave as a superposition of Alfvén continuum modes that are phase mixed as time evolves. The comparison of the two techniques evidences that the modal analysis is more physically transparent and describes both the damping of global kink motions and the building up of small scales due to phase mixing. In addition, we discuss that the processes of resonant absorption and phase mixing are closely linked. They represent two aspects of the same underlying physical mechanism: the energy cascade from large scales to small scales due to naturally occurring plasma and/or magnetic field inhomogeneities. This process may provide the necessary scenario for efficient dissipation of transverse MHD wave energy in the solar atmospheric plasma.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2012

Recovering Americium and Curium from Mark-42 Target Materials- New Processing Approaches to Enhance Separations and Integrate Waste Stream Disposition - 12228

Oak Ridge National Laboratory (ORNL) is investigating flowsheets to enhance processing efficiencies and to address waste streams associated with recovery of americium (Am) and curium (Cm) from Mark-42 (Mk-42) target materials stored at ORNL. The objective of this work was to identify the most effective flowsheet with which to process the 104 Mk-42 oxide capsules holding a total of 80 g of plutonium (Pu), 190 g of Cm, 480 g of Am, and 5 kg of lanthanide (Ln) oxides for the recovery and purification of the Am/Cm for future use as feedstock for heavy actinide production. Studies were also conducted to solidify the process flowsheet waste streams for disposal. ORNL is investigating flowsheets to enhance processing efficiencies and address waste streams associated with recovery of Am and Cm from Mk-42 target materials stored at ORNL. A series of small-scale runs are being performed to demonstrate an improved process to recover Am/Cm and to optimize the separations of Ln fission products from the Am/Cm constituents. The first of these runs has been completed using one of the Am/Cm/Ln oxide capsules stored at ORNL. The demonstration run showed promising results with a Ln DF of 40 for the Am/Cm product and an Am/Cm DF of 75 for the Ln product. In addition, the total losses of Am, Cm, and Ln to the waste solvents and raffinates were very low at <0.2%, 0.02%, and 0.04%, respectively. However, the Ln-actinide separation was less than desired. For future Reverse TALSPEAK demonstration runs, several parameters will be adjusted (flow rates, the ratio of scrub to strip stages, etc.) to improve the removal of Ln from the actinides. The next step will also include scale-up of the processing flowsheet to use more concentrated solutions (15 g/L Ln versus 5 g/L) and larger volumes and to recycle the HDEHP solvent. This should improve the overall processing efficiency and further reduce losses to waste streams. Studies have been performed with simulated wastes to develop solidification processes for disposal of the secondary waste streams generated by this flowsheet. Formulations were successfully developed for all the waste simulants. Additional tests with actual waste will be the next step in this effort. Future plans are to process all of the remaining 103 capsules in storage at ORNL. A nine-capsule test is now under way to provide additional information to scale-up the process to a target 20-capsule batch size for future processing runs. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
NASA NTRS1981

Acoustic and turbulence measurements of a tone-excited jet with and without flight simulation

Acoustic as well as turbulence measurements were made of tone-excited jets to obtain an understanding of the broadband noise augmentation mechanism. Results for both heated and unheated jets with and without flight simulation are presented for a range of excitation frequencies and levels, as well as for the zero order and first order spinning modes. It is argued that although the phase-locked large-scale turbulence structure is at the root of the noise amplification process, the actual noise generation mechanism lies in the small-scale turbulence. Results show that (1) the phase velocity of the excited large scale instability waves is subsonic relative to the ambient fluid and (2) broadband jet noise is almost uniform at all frequencies. Moreover, when the large-scale and small-scale structures are plotted against forward velocity (for a given upstream excitation level of 141 dB), the change in large-scale turbulence is negligible with forward velocity, whereas the small-scale turbulence decreases for both excited and unexcited jets. Also, the corresponding difference in far-field noise does not appear to change significantly, indicating that the changes in small-scale turbulence are responsible for jet noise amplification.

Ahuja, K. K.↗