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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 289 records · Page 16

Dynamic Distribution Voltage Stability Control Using Distributed Energy Resources for Improved Resiliency

The main goal of this paper is to present the development and simulation of a new dynamic voltage stability control technique, with a focus on effective control and coordination of all available reactive power generation resources in a microgrid setting. Both power electronics and synchronous generator based distributed energy resources (DERs), and grid-supporting functions, are considered to accommodate a high penetration of diverse DERs and energy storage by using an enhanced microgrid voltage stabilizer. A systematic controller parameter synthesizing method is employed, and the overall dynamic voltage stability of the system is studied and evaluated with a time-domain dynamic simulation during emergency, hazard and disaster events. The results with the new approach show significant improvements and enhancements on the dynamic voltage profile of the distribution system, leading towards a more resilient grid system with high penetration of diverse DERs during emergency, hazard and disaster events.

Hatipoglu, Kenan↗

Nitride stabilized core/shell nanoparticles

Nitride stabilized metal nanoparticles and methods for their manufacture are disclosed. In one embodiment the metal nanoparticles have a continuous and nonporous noble metal shell with a nitride-stabilized non-noble metal core. The nitride-stabilized core provides a stabilizing effect under high oxidizing conditions suppressing the noble metal dissolution during potential cycling. The nitride stabilized nanoparticles may be fabricated by a process in which a core is coated with a shell layer that encapsulates the entire core. Introduction of nitrogen into the core by annealing produces metal nitride(s) that are less susceptible to dissolution during potential cycling under high oxidizing conditions.

36 MATERIALS SCIENCE↗

Nitride stabilized core/shell nanoparticles

Nitride stabilized metal nanoparticles and methods for their manufacture are disclosed. In one embodiment the metal nanoparticles have a continuous and nonporous noble metal shell with a nitride-stabilized non-noble metal core. The nitride-stabilized core provides a stabilizing effect under high oxidizing conditions suppressing the noble metal dissolution during potential cycling.

36 MATERIALS SCIENCE↗

High performance porous Si anode enabled by an organic-solvent assisted etching process

Silicon (Si) is a promising anode for the next generation of lithium-ion batteries, but its large volume changes (~300 %) during cycling hindered its practical applications. One method to improve its stability is to etch micron sized Si/SiO 2 particles to form porous Si (p-Si) and accommodate volume changes internally. However, the conventional HF etching method generates excess gas/heat and is difficult to scale up. Herein, we developed an organic-solvent-assisted HF etching process (O-HF) using a mixture of benzene and saturated HF aqueous solution. The organic solvent can be preferentially absorbed on the surface of Si/SiO 2 powder so etching rate of SiO 2 can be controlled to avoid rapid gas/heat generation. This method can also prevent over-etching of Si by minimizing direct contact/react between water and newly exposed Si. Si||NMC622 cells using carbon coated p-Si particles prepared by optimized O-HF etching process demonstrate a capacity retention of 82.0 % after 500 cycles, which is much better than those prepared by conventional HF etching (73.7 %). The thickness of Si anode increases only ~10 % during the initial lithiation, which is comparable with those of graphite anode. In conclusion, the O-HF etching strategy developed in this work can also be applied to the etching of a broad range of materials.

HF etching↗

Systems and methods for dual comb spectroscopy

A frequency-measurement method uses a dual frequency-comb spectrometer as an optical wavemeter to measure the frequency of a reference laser that is used to frequency-stabilize the spectrometer. The method includes measuring a walking rate of center bursts in a sequence of interferograms recorded by the spectrometer, determining a number of teeth in each of a plurality of Nyquist windows formed by the dual frequency-comb spectrometer, and determining a Nyquist number of the one Nyquist window covering the laser frequency. The reference laser frequency can then be determined from the number of teeth in each Nyquist window, the Nyquist number, and the comb spacing of either one of the two frequency combs of the dual frequency-comb spectrometer. The reference laser frequency does not need to be measured with a separate wavemeter, or calibrated with respect to a known atomic or molecular transition.

Rieker, Gregory B.↗

Solvent Processing and Ionic Liquid-Enabled Long-Range Vertical Ordering in Block Copolymer Films with Enhanced Film Stability

Rapid and reliable processing methods for forming ordered block copolymer (BCP) materials with low defect density in a thin film geometry are required for many nanotechnology applications. Vertically aligned BCP structures, in particular, have applications ranging from nanolithography for electronics and photonics to nanoporous membranes for water remediation and novel batteries for flexible electronics. However, the attainment of nearly complete vertical orientational order of the BCP ordered phase remains challenging. Solvent-based techniques, such as direct immersion annealing (DIA) and solvent vapor annealing (SVA), have immense potential for these applications of BCP films, as it allows for tuning of their thermodynamic, structural, and chain mobility driven kinetic properties. We first demonstrate that DIA, using a judicious choice of binary solvent mixtures along with a relatively hydrophobic ionic liquid (IL), induces the rapid vertical ordering in polystyrene-b-polymethylmethacrylate (PS-PMMA) block copolymer in lamellar films. The IL establishes synergy to the binary solvent mixture of toluene and heptane to 1 create a near-neutral solvent environment for attaining the vertical microstructure of the BCP. Next, we show that IL can suppress the de-wetting of the PS-PMMA films to achieve long-range order using SVA in cylindrical films for long annealing times. Both vertical and horizontal morphology is attained in these films by selecting different solvent environments. Furthermore, attaining enhanced vertical and horizontal BCP structure with long-range defect-free order by tuning solvent quality and using additives like IL can render them useful for many nanotech applications.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

The Integrated Reference Region Analysis for Parallel DFIGs’ Interfacing Inductors

Although the traditional design of doubly-fed induction generators (DFIGs)’ interfacing inductors consider the peak ripple of the grid-side converter (GSC)’s output current, it does not consider the inductors’ impact on DFIGs’ smallsignal stability. Located in series between the GSC and the stator, the inappropriate selection of the interfacing inductor can easily result to system instability. Therefore, this paper first proposes the integrated reference region analysis for small wind farm's interfacing inductors to improve the traditional design method. Firstly, a new detailed parallel DFIGs’ smallsignal model that considers output currents’ coupling is built in d-q coordinate system with state-space approach. The model focuses on representing the operating states of parallel DFIGs in wind farm. Secondly, the linearized state-space matrix of parallel DFIGs is decomposed into nominal-value matrix and location matrix. Considering the traditional design requirements, the integrated reference region for interfacing inductor is proposed through spectral radius and bialternate matrix sum (BMS). Furthermore, it can provide better guidance for parameter selecting and stabilization method researches. Finally, the simulation and experimental results show that the proposed integrated reference region for parallel DFIGs’ interfacing inductors is accurate and instructive.

47 OTHER INSTRUMENTATION↗

Cold Spray Technology Applications for SRF Cavity Thermal and Mechanical Stabilization

The overall objective of the project is the development of a method allowing increased thermal and mechanical stabilization of SRF cavities by depositing a thick layer on the outer surface by cold-spray. Coating and testing of bi-metallic Nb/Cu and Nb/CuW samples were carried out to optimize the process parameters. The process developed on samples was applied to a single cell SRF cavity for proof-of-principle demonstration of improved thermal and mechanical stability.

36 MATERIALS SCIENCE↗

Structural Evolution of Mixed-Addenda Keggin Polyoxometalate Anions with Atom-by-Atom Substitution

Polyoxometalates (POMs) are molecular metal oxides with distinctive electronic properties that make them promising materials for applications in energy, sensors, and memory devices. One of the most promising methods of tuning the stability, photochromic, redox, and electron-spin properties of POMs is through the substitution of the metal “addenda” atoms that, along with oxygen, constitute their cage-like structures. Because traditional synthesis methods typically produce a distribution of POMs, the isolation and characterization of multimetallic POMs with predetermined stoichiometry remains challenging. The presence of multiple energetically accessible isomers further complicates the experimental characterization and theoretical modeling of multimetallic POMs. Herein, we leverage the distinguishing mass-selection capabilities of ion soft landing to prepare stoichiometrically selected Keggin PMo x W 12-x O 40 3- (x = 0 – 6, 8, 10, and 12) POMs on self-assembled monolayer surfaces free of the solvent molecules and counterions that often confound characterization of complex species at interfaces. The structures of the supported POMs are characterized with atom-by-atom precision using in situ infrared (IR) reflection absorption spectroscopy complemented by detailed density functional theory calculations. Our joint experimental and theoretical results reveal an almost linear shift in the positions of the IR bands towards lower wavenumbers with an increase in the number of lighter molybdenum atoms compared to heavier W atoms in PMoxW 12-x O 40 3- . The theoretical calculations also indicate that numerous isomeric structures may be populated at the experimental conditions and, consequently, contribute to the overall IR spectra. In conclusion, our findings indicate that in addition to the number of substituted addenda atoms and the presence of multiple isomeric structures, interactions with the surface play an important role in determining the IR spectra and structure of supported bimetallic POMs.

Prabhakaran, Venkateshkumar [Pacific Northwest Nat↗

Voltage Stability Assessment Using Synchronized Phasor Measurements Applied to the Argentine Power System

This paper presents tests of different methods for long term voltage stability analysis based on PMU measurements. In particular, Thevenin Impedance Matching and sensitivity calculation are studied. Simulation are performed in a modified Argentine power system model, to include the main components for studying long term voltage stability. Disconnection of a large Thermal Generating Station causing long-term voltage instability at Gran Buenos Aires Area is studied. It is shown that computing the apparent impedance of Thevenin equivalent at load bus from measurements taken at a single time but at various locations of the transmission corridor produce a significant reduction of the estimation error produce when only local measurements are used. Voltage Stability analysis is performed using a reduced power system model where changing parameters are fully computed through PMU data at each time. Over this reduced power system model, voltage stability index and sensibility calculations are performed.

Gill-Estebez, Pablo↗

An extension of the localized artificial diffusivity method for immiscible and high density ratio flows

The localized artificial diffusivity (LAD) method is widely regarded as the preferred multi-material regularization scheme for the compact finite difference method, because it is conservative, easy to implement, and generally robust for a wide range of multi-material problems. However, traditional LAD methods face significant challenges when applied to flows with large density ratios and when maintaining thermodynamic equilibrium across material interfaces. These limitations arise from the formulation of the artificial diffusivity flux and the reliance on enthalpy diffusion for interface regularization. Additionally, traditional LAD methods struggle to ensure stability under large density ratio conditions, fail to maintain a finite interface thickness, and are therefore unsuitable for modeling immiscible interfaces. Here, in this work, we discuss the origins of these issues in traditional LAD methods and propose modifications which enable the simulation of large density ratio and immiscible flows. The proposed method targets the artificial diffusion fluxes at gradients and ringing in the volume fraction, rather than the mass fraction in traditional methods, to consistently regularize large density ratio interfaces. Furthermore, the proposed method introduces an artificial bulk density diffusion term to enforce equilibrium conditions across interfaces. To address the challenge of modeling immiscible flows, a conservative diffuse interface term is incorporated into the formulation to ensure a finite interface thickness. Specific consideration is taken in the design of the method to ensure that these crucial properties are maintained for N -material flows. The effectiveness of the proposed method is demonstrated through a series of canonical test cases, and its accuracy is validated by comparison with experimental data on micro-bubble collapse in water. These results highlight the method’s robustness and its ability to overcome the limitations of traditional LAD approaches.

Artificial diffusivity↗

A phase-field method for boiling heat transfer

Here we present a phase field method for heat transfer in two-phase flow with boiling. The vapor/liquid interface evolution is modeled by the Cahn-Hilliard equation. The phase change rate is determined by accounting for the heat conduction balance on either vapor or liquid side of the interfacial area, depending on which side the temperature is assumed to be maintained at the saturation temperature during boiling. The velocity correction scheme proposed by Dong & Shen [27] is extended to solve the Navier-Stokes equations for a non-solenoidal velocity field, and the entropy viscosity method is employed for stabilization. The phase change model is verified by two-dimensional simulations of a vapor bubble growing in super-heated liquid and in film boiling. In both cases, mesh independence of the results is systematically performed. Subsequently, the method is applied to predict the growth of three-dimensional vapor bubble in a rectangular microchannel with boiling flow, achieving good agreement with experimental measurements and available simulation results using the level-set method. The numerical experiments demonstrate that the required mesh resolution for the phase field method is comparable with that of volume of fluid (VoF) and level-set methods.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

GAMMA SPECTRUM STABILIZATION FOR ENVIRONMENTAL RADIATION MONITORING STATIONS USING NAI(TL) DETECTOR

Abstract Gamma spectrum measured by an NaI(Tl) detector is known to be unstable with the in situ temperature. In the present work, an advanced method has been applied to stabilize the gamma spectrum measured by the NaI(Tl) detector at environmental radiation monitoring (ERM) stations. The method is based on experimental data obtained under controlled conditions in laboratory. In the temperature range from 4 to 45°C, the relative deviation of the peak positions within the stabilized gamma spectrum is less than 2%. To test this method in a real scenario, it has been integrated into the ERM station at the Military Institute of Chemical and Environmental Engineering in Hanoi, Vietnam. The results show that the proposed method is ready for a real application.

Hung, Dinh Tien↗

Safe Reinforcement Learning-Based Transient Stability Control for Islanded Microgrids With Topology Reconfiguration

This paper proposes a safe reinforcement learning (RL)-based transient stability emergency control (TSEC) method for islanded microgrids. RL requires extensive interaction with the environment to learn control strategies, hence, a data-driven approach is used as a substitute for time-consuming time-domain simulation calculations. Deep sigma point processes (DSPP), which is a Gaussian process model, is utilized to predict the normal distribution of transient stability of microgrids and to construct a transient stability chance constraint. Reward-constrained policy optimization (RCPO) can simultaneously achieve objective prediction, policy learning, and constraint cost coefficient update across multiple timescales. RCPO interacts with the DSPP-based microgrid environment through a multi-process parallel manner, greatly increasing the training speed. Case studies on a real islanded microgrid demonstrate that the proposed method can efficiently and quickly obtain the optimal emergency control strategy while adhering to all hard constraints.

14 SOLAR ENERGY↗

Neutron star under homotopy perturbation method

Highlights: • We study isotropic neutron star under Einstein’s General Relativity. • We get mass function by solving TOV equation via homotopy perturbation method. • Using causality and stability conditions we find allowed ranges of parameters. • We provide stable, physically valid and non-singular solution set. - Abstract: We obtain a mass function solving the Tolman–Oppenheimer–Volkoff (TOV) equation for isotropic and spherically symmetric system via homotopy perturbation method (HPM). Using the mass function we construct a stellar model which can be determined from the equation of state (EOS) parameter (ω) and a model parameter (n). With the help of Einstein field equations we develop three solutions which can describe different properties and the core–crust structure of neutron star (NS). Solution I is valid for NS having the inner and outer radius near the surface of the star. The star is physical up to the inner radius whereas negative density occurs and the energy conditions are violated in the upper region from the inner to outer radius. Solution II represents NS with high gravitational redshift as well as compactification factor. All the features of NS can be given by solution III which involves only the EOS parameter. Our model predicts maximum mass for a NS with the central density 5.5×10{sup 15} g/cm{sup 3} and surface redshift 0.69 is to be 2.01 M{sub ⊙} for the EOS parameter ω=0.73. The predicted range for the surface redshift is 0.57<Z{sub s}<1.95 for the allowed ranges 8.4<n<10.9 and 1/3<ω<1 in the presented NS model.

79 ASTRONOMY AND ASTROPHYSICS↗

Fluid-Dynamic Mechanisms Underlying Wind Turbine Wake Control with Strouhal-Timed Actuation

A reduction in wake effects in large wind farms through wake-aware control has considerable potential to improve farm efficiency. This work examines the success of several emerging, empirically derived control methods that modify wind turbine wakes (i.e., the pulse method, helix method, and related methods) based on Strouhal numbers on the O(0.3). Drawing on previous work in the literature for jet and bluff-body flows, the analyses leverage the normal-mode representation of wake instabilities to characterize the large-scale wake meandering observed in actuated wakes. Idealized large-eddy simulations (LES) using an actuator-line representation of the turbine blades indicate that the n=0 and ±1 modes, which correspond to the pulse and helix forcing strategies, respectively, have faster initial growth rates than higher-order modes, suggesting these lower-order modes are more appropriate for wake control. Exciting these lower-order modes with periodic pitching of the blades produces increased modal growth, higher entrainment into the wake, and faster wake recovery. Modal energy gain and the entrainment rate both increase with streamwise distance from the rotor until the intermediate wake. This suggests that the wake meandering dynamics, which share close ties with the relatively well-characterized meandering dynamics in jet and bluff-body flows, are an essential component of the success of wind turbine wake control methods. A spatial linear stability analysis is also performed on the wake flows and yields insights on the modal evolution. In the context of the normal-mode representation of wake instabilities, these findings represent the first literature examining the characteristics of the wake meandering stemming from intentional Strouhal-timed wake actuation, and they help guide the ongoing work to understand the fluid-dynamic origins of the success of the pulse, helix, and related methods.

17 WIND ENERGY↗