The effect of thermal cycling on the structure and properties of a Co, Cr, Ni-TaC directionally solidified eutectic alloy
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In the investigation the alloy was melted, heated to 750 C, and atomized into fine droplets. The droplets were rapidly quenched against a heavy copper disk rotating at 1725 rpm. The resultant splat cooled flakes were screened. Three flake sizes were finally separated. Flakes of each size were separately processed. The characteristics of the splat cooling process and the properties of the obtained products are discussed. Splat cooling against a metallic substrate permits cooling rates up to about 1,000,000 deg C/sec. Increases in yield strength and tensile strength of 14 to 19% are observed for the splat products. Other improvements are connected with increases in fatigue life and stress rupture performance.
Tension, notched tension, compression, density, thermal conductivity, and thermal expansion tests were conducted on Incoloy 903 over the temperature range 20 K (-423 F) through 1033 K (1400 F). Fracture toughness tests were performed at room temperature (RT). Creep and rupture tests were conducted at 811 K (1000 F), 922 K (1200 F), and 1033 K (1400 F) for this alloy. Transverse unnotched and notched fatigue tests at R = 0.1 were performed at RT and 922 K (1200 F). For CTX-1 alloy, tension, Charpy V-notch impact, density, thermal conductivity, and thermal expansion tests were conducted over the temperature range 20 K (-423 F) through 1033 K (1400 F). Poisson's ratio was determined at RT, 811 K (1000 F), 922 K (1200 F), and 1033 K (1400 F). Notched tension and compression tests were performed at 20 K (-423 F), RT, and 922 K (1200 F); plane strain fracture toughness tests were conducted at RT, 77 K (-320 F), and 20 K (-423 F). Creep and rupture tests were performed at 811 K (1000 F), 922 K (1200 F), and 1033 K (1400 F); longitudinal unnotched and notched fatigue tests at R = 0.1 were conducted at RT and 922 K (1200 F). Results are presented and discussed.
Theoretical physical models of the Martian interior are presented in the light of recent and revised data and constraints. These models include thermal evolution, densities, and seismic-wave velocities. The interior of Mars appears to be earthlike in many respects. Although thermal models indicate that Mars has passed its peak of evolution, it may still have an asthenosphere and may be moderately active tectonically. Mars has an Fe-FeS core with a radius of 1500-2000 km. The mantle is enriched in FeO with an olivine composition of about Fo75. Theoretically determined seismic-wave velocities are relatively well constrained in the mantle, with upper-mantle P-wave velocities ranging from 7.64 to 7.80 km/sec. However, there are wide variations in P-wave velocity in the core, dependent on composition. The shadow zone due to the core is larger than earth's.
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Voyager 1 plasma-wave observations have revealed the existence of an earthlike continuum radiation trapped in Jupiter's magnetospheric cavity at frequencies below the solar-wind plasma frequency. This radiation serves as an accurate diagnostic of the local electron number density throughout most of Jupiter's outer magnetosphere and yields information regarding the gross configuration of the magnetoplasmadisk as well as its kinematical properties. Magnetic-field observations are used to construct radial profiles of plasma pressure, density, and temperature from 20-80 Jupiter radii in the early-morning plasma sheet, along with plasma-sheet crossings and estimated thicknesses. The study suggests that hot protons (about 10 keV) are the dominant constituents of the plasma sheet (average thickness about 4.2 Jupiter radii) out to 80 Jupiter radii, beyond which centrifugal effects take over and distort the sheet toward the rotational equator.
Diffusion assisted bonds are formed in 17-4 PH, 15-5 PH, type 347 and Nitronic 40 stainless steels using electrodeposited copper as the bonding agent. The bonds are analyzed by conventional metallographic, electron microprobe analysis, and scanning electron microscopic techniques as well as Charpy V-notch impact tests at temperatures of 77 and 300 K. Results are discussed in terms of a postulated model for the bonding process.
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A series of 2024 type aluminum alloys modified by additions of 1 to 2% Li were studied to determine the role of the Cu:Li and the (Cu + Mg):Li ratios on resultant strength, ductility, notch-tensile behavior, and crack propagation rates. Ultrasonically gas atomized powders with quench rates of 10 to 100 thousand degrees/s were atomized in an argon atmosphere, producing yields of powder such that almost 100% was finer than 250 microns. The powders are free of gases and porosity, are quite spherical, have few satellites (adhering fine powder particles) and are of uniform microstructure. Strength properties are such that yield strength is 20% greater than for lithium-free 2024 ingot alloy, tensile strength is 10% greater than that of 2024 ingot material, and ductilities are comparable. In terms of specific strength and specific modulus, these RS 2024-Li alloys are significantly better than IM 2024.
The amount of columbium which can be removed from Inconel alloy 718 without degrading its high temperature properties was determined. The elements that are substituted are: vanadium and tungsten together and separately; increasing the molybdenum level from 3.0% to 5.8% and increasing the boron to 0.04%.
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CoAl and FeAl compounds are developed along two directions. Magnetic susceptibility and specific heat at low temperature on (NiCo)Al and (CoFe)Al ternary alloys are in good agreement with band calculations. Results on magnetization and specific heat under field at low temperature on nonstoichiometric compounds show clearly the importance of the nearest neighbor effects. In the case of CoAl, the isolated cobalt atoms substituting aluminum are characterized by a Kondo behavior, and, for FeAl, the isolated extra iron atoms are magnetic and polarize the matrix. Moreover, for the two compounds, clusters of higher order play a considerable part in the magnetic properties for CoAl, these clusters also seem to be characterized by a Kondo behavior, for FeAl, these clusters whose moment is higher than in the case of isolated atoms, could be constituted of excess parts of iron atoms.
A series of alloys was developed having a base composition similar to Inconel 718, with reduced Cb levels of 3.00 and 1.10 wt% Cb. Substitutions of 3.0% W, 3.0W + 0.9V or Mo increased from 3.0% to 5.8% were made for the Cb in these alloys. Two additional alloys, one containing 3.49% Cb and 1.10% Ti and another containing 3.89% Cb and 1.29% Ti were also studied. Tensile properties at rooom and elevated temperatures, stress-rupture tests, and an analysis of extracted phases were carried out for each of the alloys. Additions of solid solution elements to a reduced Cb alloy had no significant effect on the properties of the alloys under either process condition. The solution and age alloys with substitutions of 1.27% i at 3.89% Cb had tensile properties similar top hose of the original alloy and stress-rupture properties superior to the original alloy. The improved stress-rupture properties were the result of significant precipitation of Ni3Ti-gamma prime in the alloy, which is more stable than gamma' at the elevated temperatures. At lower temperatures, the new alloy benefits from gamma' strengthening. With more precise control and proper processing, the reduced Cb direct-age alloy could substitute for Alloy 718 in high strength applications.
The following features of five polyethylene films used by NASA in the construction of heavy lift balloons have been examined: molecular weight, molecular weight distribution, branching, melting behavior, density, surface texture, birefringence, orientation of crystalline regions, unlaxial deformation in the machine and transverse directions, and the effect of sample geometry and strain rate on deformation behavior. The goal of this exploratory study was to determine whether there are significant differences in any of the above mentioned features, or combination of features between the films. The acquisition of such information is a first step towards determining whether there are any specific correlations between film characteristics and the incidence of catastrophic failure of balloons during ascent through the troposphere. This exploratory study has resulted in the identification of similarities and differences between various features of the films.
The 30 meter and 100 meter drop tubes at the Marshall Space Flight Center offer a unique opportunity to study solidification in a containerless, microgravity environment. Samples are melted in a furnace at the top of the drop tube and solidify during a 4.5 second free fall in the 100 meter drop tube or a 2.6 second free fall in the 30 meter drop tube. The cooling rate obtained in the drop tubes is lower than cooling rates in atomization and splat-quenching processes. Decoupling the rapid solidification process allows the study of the effects of undercooling and recalescence on alloy morphologies. The research therefore has a three-fold purpose. The first is examination of the limits of undercooling of niobium and niobium-base alloys in the drop tube. The second purpose is the observation of microstructures resulting from the solidification of samples at large undercoolings and moderate cooling rates. The third purpose is the observation of metastable phase formation in highly undercooled samples.
The RS-PM aluminum alloys which show less than anticipated toughness properties were studied. After eliminating negative variables such as sodium and potassium in lithium containing alloys, hydrogen in all Al alloys, and trapped impurities from the atomization processing the data pointed to fine oxides, as the primary cause of poor toughness properties. The oxide content of aluminum powders increases with: decreasing powder size, deviations from spherical powder shapes, exposure to moist atmospheres either during atomization or in subsequent powder handling, and alloy compositions which contain significant amounts of lithium, magnesium, cerium, and other reactive elements.
The tribological and lubricated behavior of both oxide and nonoxide ceramics are reviewed in this chapter. Ceramics are examined in contact with themselves, other harder materials and metals. Elastic, plastic and fracture behavior of ceramics in solid state contact is discussed. The contact load necessary to initiate fracture in ceramics is shown to be appreciably reduced with tangential motion. Both friction and wear of ceramics are anisotropic and relate to crystal structure as has been observed with metals. Grit size effects in two and three body abrasive wear are observed for ceramics. Both free energy of oxide formation and the d valence bond character of metals are related to the friction and wear characteristics for metals in contact with ceramics. Surface contaminants affect friction and adhesive wear. For example, carbon on silicon carbide and chlorine on aluminum oxide reduce friction while oxygen on metal surfaces in contact with ceramics increases friction. Lubrication increases the critical load necessary to initiate fracture of ceramics both in indentation and with sliding or rubbing. Ceramics compositions both as coatings and in composites are described for the high temperature lubrication of both alloys and ceramics.
A development program has been conducted to improve the cyclic properties of the PWA 1480 single-crystal superalloy by reducing or entirely eliminating casting porosity at fatigue-initiation sites, through the use of improved casting process parameters and HIPing; potential mechanical property improvements in a high-pressure hydrogen environment were also sought in alternatives to the standard coating and heat-treatment cycle. High thermal gradient casting was found to yield a reduction in overall casting porosity density and pore sizes. The most dramatic mechanical property improvement resulted from HIPing.