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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 289 records · Page 16
All sourcesNASA NTRSDOE OSTI
DOE OSTI2026

Protein Adhesion on Semi-Fluorinated Polystyrene Surfaces in Static and Dynamic Measurements

Reducing protein adhesion is a critical strategy in fouling-resistant material innovation, with broad applications spanning biomedical and healthcare devices, biosensors, industrial and environmental systems, and other important technological domains. Here, in this study, we elucidated protein adhesion behavior on polystyrene-based thin films by neutron reflectometry (NR) and quartz crystal microbalance with dissipation (QCM-D), using both lysozyme and bovine serum albumin (BSA) as model proteins. To this end, semifluorinated polystyrene thin films with gradient wettability and surface energy were fabricated through dry processing using plasma oxidation and gas-phase deposition. Although it is believed that a fully fluorinated alkyl chain offers extremely low surface energy, thus rejecting foulants, and has been used in many fouling-resistant surface designs, enhanced protein–surface interactions were observed consistently in NR and QCM-D results, due to the combined effects of surface morphology and chemistry. On the contrary, depositing shorter fluorinated silane onto a hydrophilic PS surface contributed to a more homogeneous nanoscale fluorine coating, resulting in less initial protein adsorption and improved surface recovery. Comparative analysis of proteins with different sizes on the nanopatterned semifluorinated surface revealed the influence of molecular characteristics on surface interactions. Lysozyme, being smaller and more compact, showed faster adsorption kinetics and higher surface coverage but largely reversible binding, whereas BSA, with its larger and more flexible structure, formed broader and more stable interfacial layers. This study fills the gap in understanding protein adhesion within the range of hydrophobicity (water contact angle ∼90°), as current strategies often associate with extreme hydrophilic and superhydrophobic surfaces due to hydration or low-surface-energy rejection mechanisms, respectively. It also provides in-depth insights into current combinatorial fouling-resistant surface design.

Yuan, Yue [Oak Ridge National Laboratory (ORNL), O↗
NASA NTRS1971

The interaction of O(plus) ions with the interior surface of a copper chamber

Modulated beams of 0(+), Ar(+), and Kr(+) in the 100-300 eV range are directed into a copper box simulating the ante-chamber of an orbiting mass spectrometer. An RF quadrupole mass spectrometer and phase sensitive detection extract the component of the internal mass spectrum correlated with the beam. Intense Ar and Kr signals are observed; however, no O or O2 is detectable, indicating loss of the primary O(+) beam to surface interactions. All four primary ions stimulate sizeable signals at masses 26 and 28. The relevance of these experiments to the interpretation of mass spectra obtained by orbiting satellites is discussed.

Siegel, M. W.↗
NASA NTRS1982

On the interaction of surface heating anomalies with zonally symmetric and asymmetric atmospheric flows

Models of intermediate complexity have been used to study some aspects of the climatic effects of anomalous heating, but many aspects of the problem have yet to be explored thoroughly. The present study represents a preliminary investigated of the gaps in scientific understanding of the interaction of heating and atmospheric dynamics. The principle research tool is a model of intermediate complexity, including a time-dependent, nonlinear-two-layer quasi-geostrophic model of relatively high horizontal resolution which incorporates simple heating parameterizations. The model is used to examine systematically the interaction of heating arising from anomalies in surface temperature with zonally symmetric and zonally asymmetric flows characterized by different values of static stability and mean vertical wind shear.

Phillips, T. J.↗
NASA NTRS1981

Review of biased solar array - Plasma interaction studies

Possible high voltage surface interactions on the Solar Electric Propulsion System (SEPS) are examined, with particular regard for potential effects on SEPS performance. The SEPS is intended for use for geosynchronous and planetary missions, and derives power from deployed solar cell arrays which are susceptible to collecting ions and electrons from the charged and thermal particle environment of space. The charge exchange plasma which provides the thrust force can also enhance the natural charged particle environment and increase interactions between the thrust system and the biased solar array surface. Tests of small arrays have shown that snapover, where current collection becomes proportional to the panel area, can be avoided by larger cell sizes. Arcing is predicted to diminish with larger array sizes, while the problems of efflux environments are noted to be as yet undefined and require further study.

Stevens, N. J.↗
NASA NTRS1974

Reflection of a thick planar shock wave from a coplanar surface

The reflection of a thick shock wave from an adsorbing surface has been studied for argon and neon test gases using the direct simulation Monte Carlo method and laboratory shock-tube experiments. In the simulation, collisions between gas atoms were calculated with a point-center repulsive intermolecular potential, and collisions between gas atoms and the surface were described by a simple two-parameter model which includes the effects of adsorption and thermal accommodation. Experimental data included normal stress and temperature time histories on the surface of a shock-tube and wall. These data and published data of density variations near the end wall were compared with simulation results to assess the influence of adsorption and accommodation on the flowfield and the surface and also to infer optimum values for the surface-interaction model parameters. Good quantitative agreement between simulation and laboratory data was found with this simple surface-interaction model.

Deiwert, G. S.↗
NASA NTRS1993

Mechanical and thermal buckling analysis of sandwich panels under different edge conditions

By using the Rayleigh-Ritz method of minimizing the total potential energy of a structural system, combined load (mechanical or thermal load) buckling equations are established for orthotropic rectangular sandwich panels supported under four different edge conditions. Two-dimensional buckling interaction curves and three dimensional buckling interaction surfaces are constructed for high-temperature honeycomb-core sandwich panels supported under four different edge conditions. The interaction surfaces provide easy comparison of the panel buckling strengths and the domains of symmetrical and antisymmetrical buckling associated with the different edge conditions. Thermal buckling curves of the sandwich panels also are presented. The thermal buckling conditions for the cases with and without thermal moments were found to be identical for the small deformation theory. In sandwich panels, the effect of transverse shear is quite large, and by neglecting the transverse shear effect, the buckling loads could be overpredicted considerably. Clamping of the edges could greatly increase buckling strength more in compression than in shear.

Ko, William L.↗
NASA NTRS1994

Mechanical and thermal buckling analysis of rectangular sandwich panels under different edge conditions

The combined load (mechanical or thermal load) buckling equations were established for orthotropic rectangular sandwich panels under four different edge conditions by using the Rayleigh-Ritz method of minimizing the total potential energy of a structural system. Two-dimensional buckling interaction curves and three-dimensional buckling interaction surfaces were constructed for high-temperature honeycomb-core sandwich panels supported under four different edge conditions. The interaction surfaces provide overall comparison of the panel buckling strengths and the domains of symmetrical and antisymmetrical buckling associated with the different edge conditions. In addition, thermal buckling curves of these sandwich panels are presented. The thermal buckling conditions for the cases with and without thermal moments were found to be identical for the small deformation theory.

Ko, William L.↗
DOE OSTI2026

Multi‐Scale Model‐Informed Deep Learning for Plasma‐Nanoparticle Interaction

The Overarching Goal of this proposed research is to understand and quantitively determine the interactions between non-thermal plasma (hot electrons, reactive radicals, vibrationally excited species) and surface reactions on influencing the activity and selectivity of the desired reactions via developing multi-scale model informed deep learning algorithm. Investigating non-thermal plasma-surface interaction is feasible due to the low bulk temperature in the discharge region. To investigate the role of plasma-nanoparticle interaction on enhancing the reaction kinetics, we will focus on ammonia cracking to generate clean hydrogen over earth-abundant, non-critical metallic nanoparticles, which is of great significance for decarbonization. We hypothesize that (1) reactive radicals interacting with surface reaction species via Eley–Rideal mechanism will significantly lower the energetics of the potential rate-limiting step of nitrogen formation; (2) the surface will be charged heterogeneously under non-thermal plasma conditions and the charged site will lower the energetics of ammonia cracking through Langmuir– Hinshelwood mechanism; (3) vibrationally excited ammonia will further promote the initial N-H bond cleavage. To access the hypothesis, we will (1) reveal the surface charge effects on tunning the reaction energetics via interpretable, physics-informed deep learning accelerated density functional theory (DFT) calculations; (2) determine the reactive radicals interacting with surface reaction species on tuning the reaction energetics via DFT; (3) reveal the surface charge effects on tunning the reaction energetics via DFT and deep learning models, (4) quantify how vibrationally excited species, reactive radicals, and surface charging effects on enhancing the catalysis via developing DFT-based microkinetic modeling (MKM) and active learning. Deep and active learning of plasma-nanoparticle interactions effects on enhancing ammonia cracking to generate hydrogen represents a new paradigm for designing high performance plasma materials. The fundamental science of how plasma-nanoparticle interactions will change the plasma kinetics and will improve the energy efficiency for decarbonization and sustainability. The interpretable and physics-informed machine learning model will accelerate low temperature plasma chemistry and material discovery with physics rules and model interpretation.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
NASA NTRS2012

Monte Carlo Model Insights into the Lunar Sodium Exosphere

Sodium in the lunar exosphere is released from the lunar regolith by several mechanisms. These mechanisms include photon stimulated desorption (PSD), impact vaporization, electron stimulated desorption, and ion sputtering. Usually, PSD dominates; however, transient events can temporarily enhance other release mechanisms so that they are dominant. Examples of transient events include meteor showers and coronal mass ejections. The interaction between sodium and the regolith is important in determining the density and spatial distribution of sodium in the lunar exosphere. The temperature at which sodium sticks to the surface is one factor. In addition, the amount of thermal accommodation during the encounter between the sodium atom and the surface affects the exospheric distribution. Finally, the fraction of particles that are stuck when the surface is cold that are rereleased when the surface warms up also affects the exospheric density. In [1], we showed the "ambient" sodium exosphere from Monte Carlo modeling with a fixed source rate and fixed surface interaction parameters. We compared the enhancement when a CME passes the Moon to the ambient conditions. Here, we compare model results to data in order to determine the source rates and surface interaction parameters that provide the best fit of the model to the data.

Hurley, Dana M.↗
NASA NTRS2007

Development of Hairpin Vortices in Turbulent Spots and End-Wall Transition

The end-stage phase of boundary layer transition is characterized by the development of hairpin-like vortices which evolve rapidly into patches of turbulent behavior. In general, the characteristics of the evolution form this hairpin stage to the turbulent stage is poorly understood, which has prompted the present experimental examination of hairpin vortex development and growth processes. Two topics of particular relevance to the workshop focus will be covered: 1) the growth of turbulent spots through the generatio and amalgamation of hairpin-like vortices, and 2) the development of hairpin vortices during transition in an end-wall junction flow. Brief summaries of these studies are described below. Using controlled generation of hairpin vortices by surface injection in a critical laminar boundary layer, detailed flow visualization studies have been done of the phases of growth of single hairpin vortices, from the initial hairgin generation, through the systematic generation of secondary hairpin-like flow structures, culminating in the evolution to a turbulent spot. The key to the growth process is strong vortex-surface interactions, which give rise to strong eruptive events adjacent to the surface, which results in the generation of subsequent hairpin vortex structures due to inviscid-viscuous interactions between the eruptive events and the free steam fluid. The general process of vortex-surface fluid interaction, coupled with subsequent interactions and amalgamation of the generated multiple hairpin-type vortices, is demonstrated as a physical mechanism for the growth and development of turbulent spots. When a boundary layer flow along a surface encounters a bluff body obstruction extending from the surface (such as cylinder or wing), the strong adverse pressure gradients generated by these types of flows result in the concentration of the impinging vorticity into a system of discrete vortices near the end-wall juncture of the obstruction, with the extensions of the vortices engirdling the obstruction to form "necklace" or "horseshoe" vortices. Recent hydrogen bubble and particle image visualization have shown that as Reynolds number is increased for a laminar approach flow, the flow will become critical, and a destabilization of the necklace vortices results in the development of an azimuthal waviness, or "kinks", in the vortices. These vortex kinks are accentuated by Biot-Savart effects, causing portions of a distorted necklace vortex to make a rapid approach to the surface, precipitating processes of localized, three-dimensional surface interactions. These interactions result in the rapid generation, focussing, and ejection of thin tongues of surface fluid, which rapidly roll-over and appear as hairpin vortices in the junction region. Subsequent amalgamation of these hairpin vortices with the necklace vortices produces a complex transitional-type flow. A presentation of key results from both these studies will be done, emphasizing both the ubiquity of such hairpin-type flow structures in manifold transitional-type flows, and the importance of vortex-surface interactions n the development of hairpin vortices.

Smith, Charles R.↗
NASA NTRS2013

Structure of the Small Amplitude Motion on Transversely Sheared Mean Flows

This paper considers the small amplitude unsteady motion of an inviscid non-heat conducting compressible fluid on a transversely sheared mean flow. It extends a previous result given in Goldstein (1978(b) and 1979(a)) which shows that the hydrodynamic component of the motion is determined by two arbitrary convected quantities in the absence of solid surfaces or other external sources. The result is important because it can be used to specify appropriate boundary conditions for unsteady surface interaction problems on transversely sheared mean flows in the same way that the vortical component of the Kovasznay (1953) decomposition is used to specify these conditions for surface interaction problems on uniform mean flows. But unlike the Kovasznay (1953) case the arbitrary convected quantities no longer bear a simple relation to the physical variables. One purpose of this paper is to derive a formula that relates these quantities to the (physically measurable) vorticity and pressure fluctuations in the flow.

Goldstein, Marvin E.↗
NASA NTRS1984

Analysis of glow discharges for understanding the process of film formation

The physical and chemical processes which occur during the formation of different types of films in a variety of glow discharge plasmas are discussed. Emphasis is placed on plasma diagnostic experiments using spectroscopic methods, probe analysis, mass spectrometric sampling and magnetic resonance techniques which are well suited to investigate the neutral and ionized gas phase species as well as some aspects of plasma surface interactions. The results on metallic, semi-conducting and insulating films are reviewed in conjunction with proposed models and the problem encountered under film deposition conditions. It is concluded that the understanding of film deposition process requires additional experimental information on plasma surface interactions of free radicals and the synergetic effects where photon, electron and ion bombardment change the reactivity of the incident radical with the surface.

Venugopalan, M.↗
NASA NTRS1978

Some features of a wake tone flow field

An experimental investigation of a two-dimensional model of bluff body wake-surface interaction noise examines the changes in the flow field associated with changes in sound generated. Results show three distinct flow regimes separated by large differences in wake structure. In the first, with the surface in the near wake, discrete frequency sound is totally suppressed. At greater separation distances an amplified discrete frequency tone, a wake tone, is generated with the frequency a function of the separation distance. The final regime, with the surface in the far wake, is similar to a wake with no surface interaction.

Smith, C. A.↗
NASA NTRS1996

Numerical Study of Steady and Unsteady Canard-Wing-Body Aerodynamics

The use of canards in advanced aircraft for control and improved aerodynamic performance is a topic of continued interest and research. In addition to providing maneuver control and trim, the influence of canards on wing aerodynamics can often result in increased maximum lift and decreased trim drag. In many canard-configured aircraft, the main benefits of canards are realized during maneuver or other dynamic conditions. Therefore, the detailed study and understanding of canards requires the accurate prediction of the non-linear unsteady aerodynamics of such configurations. For close-coupled canards, the unsteady aerodynamic performance associated with the canard-wing interaction is of particular interest. The presence of a canard in close proximity to the wing results in a highly coupled canard-wing aerodynamic flowfield which can include downwash/upwash effects, vortex-vortex interactions and vortex-surface interactions. For unsteady conditions, these complexities of the canard-wing flowfield are further increased. The development and integration of advanced computational technologies provide for the time-accurate Navier-Stokes simulations of the steady and unsteady canard-wing-body flox,fields. Simulation, are performed for non-linear flight regimes at transonic Mach numbers and for a wide range of angles of attack. For the static configurations, the effects of canard positioning and fixed deflection angles on aerodynamic performance and canard-wing vortex interaction are considered. For non-static configurations, the analyses of the canard-wing body flowfield includes the unsteady aerodynamics associated with pitch-up ramp and pitch oscillatory motions of the entire geometry. The unsteady flowfield associated with moving canards which are typically used as primary control surfaces are considered as well. The steady and unsteady effects of the canard on surface pressure integrated forces and moments, and canard-wing vortex interaction are presented in detail including the effects of the canard on the static and dynamic stability characteristics. The current study provides an understanding of the steady and unsteady canard-wing-body flowfield. Emphasis is placed on the effects of the canard on aerodynamic performance as well as the detailed flow physics of the canard-wing flowfield interactions. The computational tools developed to accurately predict the time-accurate flowfield of moving canards provides for the capability of coupled fluids-controls simulations desired in the detailed design and analysis of advanced aircraft.

Eugene, L. Tu↗
DOE OSTI2025

Perspectives and challenges of ultra-high temperature ceramics for fusion plasma-facing applications

Ultra-high temperature ceramics (UHTCs) offer several potential advantages as plasma-facing components (PFCs) in fusion reactors due to their extreme melting points, tailorable thermal conductivity, and attractive unirradiated mechanical properties including fracture toughness comparable or superior to tungsten. Here, recent developments and material properties of UHTCs are briefly reviewed, along with an overview of limited studies on their responses to neutron irradiation and an evaluation of plasma-surface interactions. Five key research pathways, primarily focused on irradiation effects, for advancing UHTCs in PFC applications are discussed: (1) assessing irradiation effects on the coupled thermal–mechanical performance (2) addressing the lack of studies on irradiation, plasma-surface interactions, and their synergistic effects; (3) investigating high-temperature (>1000 °C) neutron irradiation effects critical for PFC performance; (4) optimizing multi-component UHTC compositions or composites to improve thermal or mechanical properties; (5) enhancing radiation resistance to mitigate microcracking and void swelling through strategies such as increasing sink strength by reducing grain size, introducing fine particles, and leveraging complex concentrated alloy concepts.

36 MATERIALS SCIENCE↗
NASA NTRS1992

Simulation of Martian surface-atmosphere interaction in a space-simulator: Technical considerations and feasibility

The Space Simulator of the German Aerospace Research Establishment at Cologne, formerly used for testing satellites, is now, since 1987, the central unit within the research sub-program 'Comet-Simulation' (KOSI). The KOSI team has investigated physical processes relevant to comets and their surfaces. As a byproduct we gained experience in sample-handling under simulated space conditions. In broadening the scope of the research activities of the DLR Institute of Space Simulation an extension to 'Laboratory-Planetology' is planned. Following the KOSI-experiments a Mars Surface-Simulation with realistic minerals and surface soil in a suited environment (temperature, pressure, and CO2-atmosphere) is foreseen as the next step. Here, our main interest is centered on thermophysical properties of the Martian surface and energy transport (and related gas transport) through the surface. These laboratory simulation activities can be related to space missions as typical pre-mission and during-the-mission support of the experiments design and operations (simulation in parallel). Post mission experiments for confirmation and interpretation of results are of great value. The physical dimensions of the Space Simulator (cylinder of about 2.5 m diameter and 5 m length) allows for testing and qualification of experimental hardware under realistic Martian conditions.

Moehlmann, D.↗
DOE OSTI2026

The Role of Cooperative Interactions Among Surfaces, Solvents, and Reactive Intermediates on Catalysis at Liquid–Solid Interfaces (Final Report DE-SC0020224)

This project established quantitative links between inner‑sphere chemistry (active metal identity, coordination, and zeolite topology) and outer‑sphere organization (solvent identity, hydrogen‑bond networks, and pore condensation) that govern rates, activation barriers, and selectivities for alkene epoxidation and epoxide ring‑opening at solid–liquid and quasi‑liquid–solid interfaces. We deconvoluted contributions from covalent interactions at active sites and noncovalent, solvent‑mediated interactions within pores by pairing well‑defined metal substituted zeolites with controlled solvent environments. We then mapped those contributions onto measurable kinetics (ΔH‡, ΔS‡), adsorption thermodynamics (ITC), and in situ spectroscopy. The transferrable outcomes include a set of design rules that include the following understandings. First, tune silanol ((SiOH)x) density and pore topology to organize solvent networks that selectively stabilize transition states. Second, exploit activity‑coefficient‑normalized rates and adsorption– barrier correlations to diagnose when solvent reorganization rather than surface chemistry limits performance. Third, use partial pore condensation (e.g., acetonitrile, water but also generalizable to other solvents) to elicit liquid‑like stabilization effects even in nominally vapor‑phase reactors. Collectively, these results provide strategies to increase epoxidation rates, improve oxidant utilization (i.e., selectivities), and steer regioselectivity in zeolite‑based catalytic processes relevant to sustainable oxidation chemistry. These outcomes should be transferable to other classes of reactions that proceed in microporous materials and under confinement provided by organized solvents (e.g., electrochemical double layers).

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗