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At least 289 records · Page 16

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NASA NTRS1988

Air-sea interactions and cirrus cloud-radiation feedbacks on climate

A single cloud-radiation feedback mechanism, which may play a role in the climate changes expected from increased atmospheric concentrations of carbon dioxide and other trace greenhouse gases, is described. An improved radiative-convective model was developed and used to study the role of cirrus clouds in the optical thickness feedback mechanism. The model includes prescribed relative humidity and ozone profiles and a surface energy balance. The results suggest that the cloud optical thickness feedback mechanism can cause a substantial reduction in the surface warming due to doubling CO2, even in the presence of cirrus clouds.

Somerville, Richard C. J.↗

NASA NTRS1994

In situ Mars ozone detector

We propose sending a balloon-borne UV photometer sensor package to measure atmospheric ozone on Mars, and this package could be a Discovery Program sensor candidate. Past measurements of ozone on Mars are highly uncertain, perhaps a factor of 3 or so uncertain, due primarily to interference and masking by cloud and dust. In-situ balloon measurements would avoid these problems, and would provide 'ground truth' which remote sensing techniques cannot. We have explored this approach to measure ozone abundance in the terrestrial stratosphere with a balloon-borne UV absorption photometer. Atmospheric pressures and temperatures and ozone concentrations near the surface of Mars are similar to those in the terrestrial stratosphere.

Lindner, Bernhard Lee↗

NASA NTRS2001

Living With a Star, the Geospace Mission Definition Team and Aeronomy

To gain an understanding of the Sun-Earth system, including how and why the sun varies, how the earth responds, and the impacts on humanity, research is needed that has a integrated and systematic approach. The Living With a Star (LWS) program represents an important element in this regard both to continued progress in space science in general and in Aeronomy in particular. A fundamental question in Aeronomy is how the variable sun affects the ionosphere, thermosphere, and mesosphere. The LWS program focuses on those areas of scientific understanding that promote progress in areas that have human impact and can be investigated with space borne instruments. The Geospace Mission Definition Team is charged with investigating the science priorities identified by the LWS Science Architecture Team and developing an approach to making the necessary measurements in concert with other missions and programs. An important aspect of this approach is that all LWS measurement programs are operating simultaneously for several years. We will review some of the areas that the LWS SAT have emphasized in Aeronomy, including understanding the effects of solar variability on ionospheric density and irregularities, the effects of solar variability on the mass density of the atmosphere at LEO altitudes, and the effects of solar variability on near-surface temperatures and on ozone distribution.

Kintner, Paul M., Jr.↗

NASA NTRS2014

Development of Genesis Solar Wind Sample Cleanliness Assessment: Initial Report on Sample 60341 Optical Imagery and Elemental Mapping

Since 2005 the Genesis science team has experimented with techniques for removing the contaminant particles and films from the collection surface of the Genesis fragments. A subset of ~40 samples have been designated as "cleaning matrix" samples. These are small samples to which various cleaning approaches are applied and then cleanliness is assessed optically, by TRXRF, SEM, ToF-SIMS, XPS, ellipsometry or other means [1-9]. Most of these sam-ples remain available for allocation, with cleanliness assessment data. This assessment allows evaluation of various cleaning techniques and handling or analytical effects. Cleaning techniques investigated by the Genesis community include acid/base etching, acetate replica peels, ion beam, and CO2 snow jet cleaning [10-16]. JSC provides surface cleaning using UV ozone exposure and ultra-pure water (UPW) [17-20]. The UPW rinse is commonly used to clean samples for handling debris between processing by different researchers. Optical microscopic images of the sample taken before and after UPW cleaning show what has been added or removed during the cleaning process.

Gonzalez, C. P.↗

NASA NTRS2016

Exploring and Analyzing Climate Variations Online by Using NASA MERRA-2 Data at GES DISC

NASA Giovanni (Goddard Interactive Online Visualization ANd aNalysis Infrastructure) (http:giovanni.sci.gsfc.nasa.govgiovanni) is a web-based data visualization and analysis system developed by the Goddard Earth Sciences Data and Information Services Center (GES DISC). Current data analysis functions include Lat-Lon map, time series, scatter plot, correlation map, difference, cross-section, vertical profile, and animation etc. The system enables basic statistical analysis and comparisons of multiple variables. This web-based tool facilitates data discovery, exploration and analysis of large amount of global and regional remote sensing and model data sets from a number of NASA data centers. Long term global assimilated atmospheric, land, and ocean data have been integrated into the system that enables quick exploration and analysis of climate data without downloading, preprocessing, and learning data. Example data include climate reanalysis data from NASA Modern-Era Retrospective analysis for Research and Applications, Version 2 (MERRA-2) which provides data beginning in 1980 to present; land data from NASA Global Land Data Assimilation System (GLDAS), which assimilates data from 1948 to 2012; as well as ocean biological data from NASA Ocean Biogeochemical Model (NOBM), which provides data from 1998 to 2012. This presentation, using surface air temperature, precipitation, ozone, and aerosol, etc. from MERRA-2, demonstrates climate variation analysis with Giovanni at selected regions.

knowledge base↗

NASA NTRS2022

Editorial: DSCOVR EPIC/NISTAR: 5Years of Observing Earth From the First Lagrangian Point

The Deep Space Climate Observatory (DSCOVR) was launched in February 2015 to a Sun-Earth Lagrange-1 (L1) orbit, approximately 1.5 million kilometers from the sunlit side of the Earth. In many regards, the DSCOVR is a unique mission: for the first time, it delivers well-calibrated and multi-spectral measurements of Earth from the L1 point. This unique location allows near-hourly views of the entire illuminated disk of the Earth, multiple times a day. The moderately high observational cadence results in cloud-free views of nearly the entire Earth land surface and global ocean with significantly higher frequency than is available to the operational polar orbiters, and at a near-global scale inaccessible to geostationary sensors.

EPIC↗

NASA NTRS1998

Global Surface Ultraviolet Radiation Climatology from TOMS and ERBE Data

The overall goal of this project has been to develop a method for calculating the distribution of solar ultraviolet radiation (UVR) over most of the earth's surface using NASA's Total Ozone Mapping Spectrometer (TOMS) and Earth Radiation Budget Experiment (ERBE) data, and to use this method to develop a UVR climatology that is useful in the context of the global ozone depletion issue. The research carried out with this support has resulted the following accomplishments: (1) a radioactive transfer method. based on the delta-Eddington approximation, was successfully developed; (2) the method was applied to the five years of overlapping TOMS and ERBE Monthly-Hourly data to examine the impact of global variability in cloud cover on trends in surface UVR; (3) a presentation was made on effects of stratospheric ozone depletion; (4) the radioactive transfer model was finally applied to all daylight hours to make a through study of the global effect of cloud cover;and (6) a five-year global climatology of surface UVR based on all of the research has been prepared for general distribution.

Lubin, Dan↗

NASA NTRS1980

Surface pressure response to elevated tidal heating sources - Comparison of earth and Mars

Modern atmospheric tidal theory has shown that the dominance of the terrestrial semidiurnal surface pressure oscillation, relative to its diurnal counterpart, is the result of the elevated heating source generated by solar heating of stratospheric ozone. Observations of the daily surface pressure variation at the Viking Lander 1 site on Mars reveal a similar predominance of the semidiurnal surface pressure oscillation only during the onset of a Martian great dust storm. Application of a classical, analytic tidal model to the Viking Lander 1 data indicates that elevating the effective heat source due to solar heating of airborne dust by a few kilometers during the onset of a Martian great dust storm can account for the observed semidiurnal surface pressure variation.

Zurek, R. W.↗

NASA NTRS1977

A mechanism for inducing climatic variations through the stratosphere - Screening of cosmic rays by solar and terrestrial magnetic fields

The ability of heliomagnetic and geomagnetic fields to bring about climatic variations of long period is examined theoretically. A chemical relationship between low-energy cosmic rays and ozone balance in the stratosphere is sought as a crucial clue to historical changes in earth climate. A perturbation analysis is developed to arrive at zone depletion and reduction of stratospheric solar heating resulting from increased NOx concentration; temperature feedback and opacity feedback are allowed for. Modulation of galactic cosmic-radiation fluxes and ozone destruction in the stratosphere, colder surface temperatures associated with reduced magnetic shielding, and redistribution with height of total ozone decrease are explored.

Chamberlain, J. W.↗

DOE OSTI2024

Distinguishing Surface and Bulk Reactivity: Concentration-Dependent Kinetics of Iodide Oxidation by Ozone in Microdroplets

Iodine oxidation reactions play an important role in environmental, biological, and industrial contexts. The multiphase reaction between aqueous iodide and ozone is of particular interest due to its prevalence in the marine atmosphere and unique reactivity at the air–water interface. Here, we explore the concentration dependence of the I – + O 3 reaction in levitated microdroplets under both acidic and basic conditions. To interpret the experimental kinetics, molecular simulations are used to benchmark a kinetic model, which enables insight into the reactivity of the interface, the nanometer-scale subsurface region, and the bulk interior of the droplet. For all experiments, a kinetic description of gas- and liquid-phase diffusion is critical to interpreting the results. We find that the surface dominates the iodide oxidation kinetics under concentrated and acidic conditions, with the reactive uptake coefficient approaching an upper limit of 10 –2 at pH 3. In contrast, reactions in the subsurface dominate under more dilute and alkaline conditions, with inhibition of the surface reaction at pH 12 and an uptake coefficient that is 10× smaller. In conclusion, the origin of a changing surface mechanism with pH is explored and compared to previous ozone-dependent measurements.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

NASA NTRS1991

Predicted rocket and shuttle effects on stratospheric ozone

The major chemical effluents of either solid- or liquid-fueled rockets that can potentially perturb stratospheric ozone include chlorine compounds (HCl), nitrogen compounds (NO(x)), and hydrogen compounds (H2 and H2O). Radicals (Cl, ClO, H, OH, HO2, NO, and NO2) formed directly or indirectly from rocket exhaust can cause the catalytic destruction of ozone. Other exhaust compounds that could presumably lead to ozone destruction either by direct reaction with ozone or by providing a surface for heterogeneous processes include the particulates Al2O3, ice, and soot. These topics are discussed in terms of the possible effects of rocket exhausts on stratospheric ozone.

Harwood, Robert S.↗

NASA NTRS2008

Global Radiative Forcing of Coupled Tropospheric Ozone and Aerosols in a Unified General Circulation Model

Global simulations of sea salt and mineral dust aerosols are integrated into a previously developed unified general circulation model (GCM), the Goddard Institute for Space Studies (GISS) GCM II', that simulates coupled tropospheric ozone-NOx-hydrocarbon chemistry and sulfate, nitrate, ammonium, black carbon, primary organic carbon, and secondary organic carbon aerosols. The fully coupled gas-aerosol unified GCM allows one to evaluate the extent to which global burdens, radiative forcing, and eventually climate feedbacks of ozone and aerosols are influenced by gas-aerosol chemical interactions. Estimated present-day global burdens of sea salt and mineral dust are 6.93 and 18.1 Tg with lifetimes of 0.4 and 3.9 days, respectively. The GCM is applied to estimate current top of atmosphere (TOA) and surface radiative forcing by tropospheric ozone and all natural and anthropogenic aerosol components. The global annual mean value of the radiative forcing by tropospheric ozone is estimated to be +0.53 W m(sup -2) at TOA and +0.07 W m(sup -2) at the Earth's surface. Global, annual average TOA and surface radiative forcing by all aerosols are estimated as -0.72 and -4.04 W m(sup -2), respectively. While the predicted highest aerosol cooling and heating at TOA are -10 and +12 W m(sup -2) respectively, surface forcing can reach values as high as -30 W m(sup -2), mainly caused by the absorption by black carbon, mineral dust, and OC. We also estimate the effects of chemistry-aerosol coupling on forcing estimates based on currently available understanding of heterogeneous reactions on aerosols. Through altering the burdens of sulfate, nitrate, and ozone, heterogeneous reactions are predicted to change the global mean TOA forcing of aerosols by 17% and influence global mean TOA forcing of tropospheric ozone by 15%.

Liao, Hong↗

NASA NTRS2010

21st Century Trends in Antarctic Temperature and Polar Stratospheric Cloud (PSC) Area in the GEOS Chemistry-Climate Model

This study examines trends in Antarctic temperature and APSC, a temperature proxy for the area of polar stratospheric clouds, in an ensemble of Goddard Earth Observing System (GEOS) chemistry-climate model (CCM) simulations of the 21st century. A selection of greenhouse gas, ozone-depleting substance, and sea surface temperature scenarios is used to test the trend sensitivity to these parameters. One scenario is used to compare temperature trends in two versions of the GEOS CCM. An extended austral winter season is examined in detail. In May, June, and July, the expected future increase in CO2-related radiative cooling drives temperature trends in the Antarctic lower stratosphere. At 50 hPa, a 1.3 K cooling is expected between 2000 and 2100. Ozone levels increase, despite this robust cooling signal and the consequent increase in APSC, suggesting the enhancement of stratospheric transport in future. In the lower stratosphere, the choice of climate change scenarios does not affect the magnitude of the early winter cooling. Midwinter temperature trends are generally small. In October, APSC trends have the same sign as the prescribed halogen trends. That is, there are negative APSC trends in "grealistic future" simulations, where halogen loading decreases in accordance with the Montreal Protocol and CO2 continues to increase. In these simulations, the speed of ozone recovery is not influenced by either the choice of sea surface temperature and greenhouse gas scenarios or by the model version.

Hurwitz, M. M.↗

NASA NTRS2023

Impacts of Stratospheric Ozone Recovery on Southern Ocean Temperature and Heat Budget

The impacts of stratospheric ozone recovery on Southern Ocean surface and interior temperature, heat content, heat uptake, and heat transport are investigated by contrasting two ensemble chemistry-climate model simulations in 2005–2099: one with fixed ozone depleting substances (ODSs) and another with decreasing ODSs. In our simulations ozone recovery significantly affects Southern Ocean temperature, with large latitudinal and vertical variations. Ozone recovery causes a dipole change of the full-depth ocean heat content (OHC) with an increase south of 60°S and a decrease between 45°S and 60°S. Integrated over latitudes south of 40°S, OHC decreases in response to ozone recovery. This ocean heat loss is shown to be driven by weakened poleward ocean heat transport (OHT) across 40°S, which is partly canceled by enhanced heat uptake. The weakening of poleward OHT into the Southern Ocean is caused by the ozone-induced equatorward shift of the meridional overturning circulation.

stratospheric ozone↗

NASA NTRS2002

Airborne DIAL Ozone and Aerosol Trends Observed at High Latitudes Over North America from February to May 2000

Ozone (O3) and aerosol scattering ratio profiles were obtained from airborne lidar measurements on thirty-eight aircraft flights over seven aircraft deployments covering the latitudes of 40 deg.-85 deg.N between 4 February and 23 May 2000 as part of the TOPSE (Tropospheric Ozone Production about the Spring Equinox) field experiment. The remote and in situ O3 measurements were used together to produce a vertically-continuous O3 profile from near the surface to above the tropopause. Ozone, aerosol, and potential vorticity (PV) distributions were used together to identify the presence of pollution plumes and stratospheric intrusions. The number of observed pollution plumes was found to increase into the spring along with a significant increase in aerosol loading. Ozone was found to increase in the middle free troposphere (4-6 km) at high latitudes (60 deg.-85 deg. N) by an average of 4.3 ppbv/mo from about 55 ppbv in early February to over 72 ppbv in mid-May. The average aerosol scattering ratios in the same region increased at an average rate of 0.37/mo from about 0.35 to over 1.7. Ozone and aerosol scattering were highly correlated over entire field experiment. Based on the above results and the observed aircraft in-situ measurements, it was estimated that stratospherically-derived O3 accounted for less than 20% of the observed increase in mid tropospheric O3 at high latitudes. The primary cause of the observed O3 increase was found to be the photochemical production of O3 in pollution plumes.

Hair, Jonathan W.↗

NASA NTRS1980

Climatic effects due to halogenated compounds in the earth's atmosphere

Using a one-dimensional radiative-convective model, a sensitivity study is performed of the effect of ozone depletion in the stratosphere on the surface temperature. There could be a cooling of the surface temperature by approximately 0.2 K due to chlorofluoromethane-induced ozone depletion at steady state (assuming 1973 release rates). This cooling reduces significantly the greenhouse effect due to the presence of chlorofluoromethanes. Carbon tetrafluoride has a strong nu sub 3 band at 7.8 microns, and the atmospheric greenhouse effect is shown to be 0.07 and 0.12 K/ppbv with and without taking into account overlap with CH4 and N2O bands. At concentrations higher than 1 ppbv, absorption by the nu sub 3 band starts to saturate and the greenhouse effect becomes less efficient.

Wang, W.-C.↗

NASA NTRS2017

Accounting for the Effects of Surface BRDF on Satellite Cloud and Trace-Gas Retrievals: A New Approach Based on Geometry-Dependent Lambertian-Equivalent Reflectivity Applied to OMI Algorithms

Most satellite nadir ultraviolet and visible cloud, aerosol, and trace-gas algorithms make use of climatological surface reflectivity databases. For example, cloud and NO2 retrievals for the Ozone Monitoring Instrument (OMI) use monthly gridded surface reflectivity climatologies that do not depend upon the observation geometry. In reality, reflection of incoming direct and diffuse solar light from land or ocean surfaces is sensitive to the sun-sensor geometry. This dependence is described by the bidirectional reflectance distribution function (BRDF). To account for the BRDF, we propose to use a new concept of geometry-dependent Lambertian equivalent reflectivity (LER). Implementation within the existing OMI cloud and NO2 retrieval infrastructure requires changes only to the input surface reflectivity database. The geometry-dependent LER is calculated using a vector radiative transfer model with high spatial resolution BRDF information from the Moderate Resolution Imaging Spectroradiometer (MODIS) over land and the Cox-Munk slope distribution over ocean with a contribution from water-leaving radiance. We compare the geometry-dependent and climatological LERs for two wavelengths, 354 and 466 nm, that are used in OMI cloud algorithms to derive cloud fractions. A detailed comparison of the cloud fractions and pressures derived with climatological and geometry-dependent LERs is carried out. Geometry-dependent LER and corresponding retrieved cloud products are then used as inputs to our OMI NO2 algorithm. We find that replacing the climatological OMI-based LERs with geometry-dependent LERs can increase NO2 vertical columns by up to 50% in highly polluted areas; the differences include both BRDF effects and biases between the MODIS and OMI-based surface reflectance data sets. Only minor changes to NO2 columns (within 5 %) are found over unpolluted and overcast areas.

Lambert-equivalent reflectivity↗

NASA NTRS1978

Remote sensing of the ozone profile in the lower stratosphere using UV and IR measurements from Nimbus-4

A method of combining the information from the infrared interferometer spectrometer (IRIS) and the backscatter ultraviolet spectrometer (BUV) on board the Nimbus-4 satellite to derive the ozone profile from 10 mb to surface is described. The radiance in the IRIS 9-micron band can be related to the ozone profile by the radiative transfer equation. The IR intensity due to ozone is dependent on the pressure broadening of spectral lines, and an estimate of a weighted mean pressure of the ozone layer can be obtained from total ozone supplied by BUV long wave intensity measurements. With the aid of the Chapman function, a model of the ozone concentration profile described by three parameters is obtained. Given the ozone concentration at 10 mb one calculates several possible combinations of the three parameters that can produce the required total ozone, and the final choice of parameter is determined from IR measurements. An ozone profile calculated in this way reproduces well the gross features of balloon ozone sounding results. Meridional cross sections of ozone concentration have also been derived which are in reasonably good agreement with balloon-derived cross-section for the northern latitudes and tropics.

Prabhakara, C.↗