Kinetics of oxide film growth on metal crystals - Thermal electron emission and ionic diffusion.
Thermal oxidation kinetics of oxide film growth on metal crystals, considering ion diffusion and thermionic electron emission
Cook, E. L.↗
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Thermal microwave emission from half-space random media
Brightness temperatures resulting from microwave thermal emission from a half-space random medium are calculated. The random medium has a nonuniform temperature profile and is characterized by correlation functions that possess both vertical and lateral variations. Radiative transfer equations are derived. They are solved with an iterative integral equation approach for small scattering albedo and with a numerical approach for general cases. New results are illustrated, discussed, and compared with various special cases. Phenomena caused by resonant scattering, which is absent under Rayleigh approximations, are revealed. Scattering in the lateral direction contributes to the decrease of the equivalent reflectivity and the increase of the brightness temperature.
Tsang, L.↗
Thermal infrared emission of the jovian disk.
Thermal 8-14 micron IR emission of Jupiter in December 1963
PLANETARY RADIATION↗
Laser-metal interaction dynamics during additive manufacturing resolved by detection of thermally-induced electron emission
In situ monitoring is required to improve the understanding and increase the reliability of additive manufacturing methods such as laser powder bed fusion (LPBF). Current diagnostic methods for LPBF capture optical images, X-ray radiographs, or measure the emission of thermal or acoustic signals from the component. Herein, a methodology based on the thermal emission of electrons - thermionic emission - from the metal surface during LPBF is proposed which can resolve laser-material interaction dynamics. The high sensitivity of thermionic emission to surface temperature and surface morphology is revealed to enable precise determination of the transition between conduction and keyhole mode melting regimes. Increases in thermionic emission are correlated to laser scanning conditions that give rise to pore formation and regions where surface defects are pronounced. The information presented here is a critical step in furthering our understanding and validation of laser-based metal additive manufacturing.
36 MATERIALS SCIENCE↗
Titan - Far-infrared and microwave remote sensing of methane clouds and organic haze
Titan's surface and plausible atmospheric thermal opacity sources, which include gaseous N2, CH4, and H2, together with CH4 clouds and organic haze, are sufficient to match available earth-based and Voyager observations of Titan's thermal emission spectrum. Dominant thermal emission sources are the surface, at greater than 1 cm wavelengths, atmospheric N2 for the 1-200 micron range, condensed and gaseous CH4 for 200-20 microns, and molecular bands and organic haze at less than 20 microns.
Thompson, W. R.↗
Theory of thermal microwave emission from a two-layer medium
Thermal microwave emission from a scattering layer overlying a homogeneous half space is studied with the radiative transfer approach. Scattering models of random medium and discrete spherical scatterers are used. The radiative transfer equations are solved by both the classical method and the invariant imbedding method. The brightness temperatures of the two-layer model exhibit distinguishing features important to microwave passive remote sensing.
Tsang, L.↗
Thermal radio emission from the major planets.
The use of long-wavelength radio measurements of brightness temperature to remotely measure the thermal structure of the atmospheres of the major planets at great depths is discussed. Data are presented which show that the gross features of Jupiter's and Saturn's microwave spectra, as determined from ground based observations, can be explained in terms of thermal emission from ammonia in deep convective atmospheres of He and H2.
Gulkis, S.↗
Observed Limits on Charge Exchange Contributions to the Diffuse X-Ray Background
We present a high-resolution spectrum of the diffuse X-ray background from 0.1 to 1 keV for an approximately 1 sr region of the sky centered at l = 90 degrees b = +60 degrees using a 36 pixel array of microcalorimeters flown on a sounding rocket. With an energy resolution of 11 eV FWHM below 1 keV, the spectrum s observed line ratios help separate charge exchange contributions originating within the heliosphere from thermal emission of hot gas in the interstellar medium. The X-ray sensitivity below 1 keV was reduced by about a factor of four from contamination that occurred early in the flight, limiting the significance of the results. The observed centroid of helium-like O VII is 568 (sup +2 (sub -3) eV at 90% confidence. Since the centroid expected for thermal emission is 568.4 eV and for charge exchange is 564.2 eV, thermal emission appears to dominate for this line complex. The dominance of thermal emission is consistent with much of the high-latitude O VII emission originating in 2-3 x 10(exp 6) K gas in the Galactic halo. On the other hand, the observed ratio of C VI Lygamma to Lyalpha is 0.3 plus or minus 0.2. The expected ratios are 0.04 for thermal emission and 0.24 for charge exchange, indicating that charge exchange must contribute strongly to this line and therefore potentially to the rest of the ROSAT R12 band usually associated with 10(sup 6) K emission from the Local Hot Bubble. The limited statistics of this experiment and systematic uncertainties due to the contamination require only greater than 32% thermal emission for O VII and greater than 20% from charge exchange for C VI at the 90% confidence level. An experimental gold coating on the silicon substrate of the array greatly reduced extraneous signals induced on nearby pixels from cosmic rays passing through the substrate, reducing the triggered event rate by a factor of 15 from a previous flight of the instrument.
Crowder, S. G.↗
Observed Limits on Charge Exchange Contributions to the Diffuse X-Ray Background
We present a high-resolution spectrum of the diffuse X-ray background from 0.1 to 1 keV for an approximately 1 sr region of the sky centered at l = 90 degrees b = +60 degrees using a 36 pixel array of microcalorimeters flown on a sounding rocket. With an energy resolution of 11 eV FWHM below 1 keV, the spectrum s observed line ratios help separate charge exchange contributions originating within the heliosphere from thermal emission of hot gas in the interstellar medium. The X-ray sensitivity below 1 keV was reduced by about a factor of four from contamination that occurred early in the flight, limiting the significance of the results. The observed centroid of helium-like O VII is 568 (sup +2 (sub -3) eV at 90% confidence. Since the centroid expected for thermal emission is 568.4 eV and for charge exchange is 564.2 eV, thermal emission appears to dominate for this line complex. The dominance of thermal emission is consistent with much of the high-latitude O VII emission originating in 2-3 x 10(exp 6) K gas in the Galactic halo. On the other hand, the observed ratio of C VI Lygamma to Lyalpha is 0.3 plus or minus 0.2. The expected ratios are 0.04 for thermal emission and 0.24 for charge exchange, indicating that charge exchange must contribute strongly to this line and therefore potentially to the rest of the ROSAT R12 band usually associated with 10(sup 6) K emission from the Local Hot Bubble. The limited statistics of this experiment and systematic uncertainties due to the contamination require only greater than 32% thermal emission for O VII and greater than 20% from charge exchange for C VI at the 90% confidence level. An experimental gold coating on the silicon substrate of the array greatly reduced extraneous signals induced on nearby pixels from cosmic rays passing through the substrate, reducing the triggered event rate by a factor of 15 from a previous flight of the instrument.
Crowder, S. G.↗
Mid and Thermal Infrared Remote Sensing at the Jet Propulsion Laboratory
The mid and thermal infrared (MTIR) for the Earth surface is defined between 3 and 14µm. In the outer solar system, objects are colder and their Planck response shifts towards longer wavelengths. Hence for these objects (e.g. icy moons, polar caps, comets, Europa), the thermal IR definition usually stretches out to 50µm and beyond. Spectroscopy has been a key part of this scientific exploration because of its ability to remotely determine elemental and mineralogical composition. Many key gas species such as methane, ammonia, sulfur, etc. also have vibrational bands which show up in the thermal infrared spectrum above the background response. Over the past few decades, the Jet Propulsion Laboratory has been building up a portfolio of technology to capture the MTIR for various scientific applications. Three recent sensors are briefly reviewed: The airborne Hyperspectral thermal emission spectrometer (HyTES), the ECOsystem Spaceborne Thermal Radiometer Experiment on Space Station (ECOSTRESS) and Mars Climate Sounder (MCS)/DIVINER. Each of these sensors utilize a different technology to provide a remote sensing product based on MTIR science. For example, HyTES is a push-brooming hyperspectral imager which utilizes a large format quantum well infrared photodetector (QWIP). The goal is to transition this to a new complementary barrier infrared photodetector (CBIRD) with a similar long wave cut-off and increased sensitivity. ECOSTRESS is a push-whisk Mercury Cadmium Telluride (MCT) based high speed, multi-band, imager which will eventually observe and characterize plant/vegetation functionality and stress index from the International Space Station (ISS) across the contiguous United States (CONUS). MCS/DIVINER utilizes thermopile technology to capture the thermal emission from the polar caps and shadow regions of the moon. Each sensor utilizes specific JPL technology to capture unique science. similar long wave cut-off and increased sensitivity. ECOSTRESS is a push-whisk Mercury Cadmium Telluride (MCT) based high speed, multi-band, imager which will eventually observe and characterize plant/vegetation functionality and stress index from the International Space Station (ISS) across the contiguous United States (CONUS). MCS/DIVINER utilizes thermopile technology to capture the thermal emission from the polar caps and shadow regions of the moon. Each sensor utilizes specific JPL technology to capture unique science.
Johnson, William R.↗
Galactic radio emissions
Thermal electron density and cosmic ray flux in galactic radio emissions
Alexander, J. K., Jr.↗
Far-infrared observations of thermal dust emission from supernova 1987A
Observations of SN1987A in the spectral range 18-35 microns taken on November 16 and 23, 1988, 632 and 639 days after core collapse, are reported. A strong and rather flat continuum underlies weak fine-structure lines from heavy elements and declines slowly between 24 and 30 microns. The spectral shape indicates thermal emission from an almost featureless dust component, probably graphite, with silicates contributing less than 20 percent of the emitting dust mass. Some of the emission may be an 'echo' of supernova light reflected from a preexisting dust cloud, but a better explanation which can account for the entirety of emission from infrared to gamma wavelengths, is that dust is being formed in the supernova ejecta. This also accounts more naturally for the inferred dust composition.
Moseley, S. H.↗
A NICER Look at the Aql X-1 Hard State
We report on a spectral-timing analysis of the neutron star low-mass X-ray binary(LMXB)AqlX-1 with the Neutron Star Interior Composition Explorer (NICER) on the International Space Station (ISS). AqlX-1 wasobserved with NICER during a dim outburst in 2017 July, collecting approximately 50 ks of good exposure. The spectral and timing properties of the source correspond to that of a (hard) extreme island state in the atoll classification. We find that the fractional amplitude of the low-frequency (<0.3Hz) band-limited noise shows adramatic turnover as a function of energy: it peaks at 0.5keV with nearly 25% rms, drops to 12% rms at 2keV,and rises to 15% rms at 10keV. Through the analysis of covariance spectra, we demonstrate that band-limited noise exists in both the soft thermal emission and the power-law emission. Additionally, we measure hard timelags, indicating the thermal emission at 0.5keV leads the power-law emission at 10 keV on a timescale of 100ms at 0.3Hz to10ms at 3Hz. Our results demonstrate that the thermal emission in the hard state is intrinsically variable, and is driving the modulation of the higher energy power-law. Interpreting the thermal spectrum as disk emission, we find that our results are consistent with the disk propagation model proposed for accretion onto black holes.
Bult, Peter↗
Thermal Infrared Emission Spectroscopy of Synthetic Allophane and its Potential Formation on Mars
Allophane is a poorly-crystalline, hydrous aluminosilicate with variable Si/Al ratios approx.0.5-1 and a metastable precursor of clay minerals. On Earth, it forms rapidly by aqueous alteration of volcanic glass under neutral to slightly acidic conditions [1]. Based on in situ chemical measurements and the identification of alteration phases [2-4], the Martian surface is interpreted to have been chemically weathered on local to regional scales. Chemical models of altered surfaces detected by the Mars Exploration Rover Spirit in Gusev crater suggest the presence of an allophane-like alteration product [3]. Thermal infrared (TIR) spectroscopy and spectral deconvolution models are primary tools for determining the mineralogy of the Martian surface [5]. Spectral models of data from the Thermal Emission Spectrometer (TES) indicate a global compositional dichotomy, where high latitudes tend to be enriched in a high-silica material [6,7], interpreted as high-silica, K-rich volcanic glass [6,8]. However, later interpretations proposed that the high-silica material may be an alteration product (such as amorphous silica, clay minerals, or allophane) and that high latitude surfaces are chemically weathered [9-11]. A TIR spectral library of pure minerals is available for the public [12], but it does not contain allophane spectra. The identification of allophane on the Martian surface would indicate high water activity at the time of its formation and would help constrain the aqueous alteration environment [13,14]. The addition of allophane to the spectral library is necessary to address the global compositional dichotomy. In this study, we characterize a synthetic allophane by IR spectroscopy, X-ray diffraction (XRD), and transmission electron microscopy (TEM) to create an IR emission spectrum of pure allophane for the Mars science community to use in Martian spectral models.
Rampe, E. B.↗
Stellar ionization of the thermal radio emission regions of the Galactic Center
We have used the Anglo-Australian Telescope imaging spectrometer IRIS to search for hot young stars which may ionize the thermal radio emission regions within the inner 40 pc of the Galaxy. Several hot stars were discovered based on their Br gamma (2.165 micron) and He I (2.058 micron) emission, including a cluster of possible WN 8-9 stars. Comparison of the spectra of the new stars with optically classified stars suggests a spectral classification of B(e) and WN7-9. Based on the calculated luminosity of the new stars and comparisons with radio data, the emission stars could be largely responsible for the ionization of the thermal radio emission regions.
Cotera, Angela S.↗
Physical processes and infrared emission from the Cassiopeia A supernova remnant
IRAS 12-100 micron data on the Cas A remnant are presented, and various physical mechanisms and astrophysical sites that may contribute to the observed infrared emission are analyzed. The contributions of various sources of infrared emission to the IRAS fluxes are found to be small. The residual infrared emission is attributed to thermal emission from dust which is swept up by the expanding supernova blast wave and collisionally heated by the postshock X-ray emitting gas. The calculations are consistent with a shock velocity of 1800 km/s and a preshock gas density of about 2/cu cm. The mass of the swept-up gas is about 0.6 solar mass. An excess of 12 micron thermal emission in the spectrum of Cas A suggests the presence of very small particles in the preshocked gas.
Dwek, E.↗
Plasmon-phonon coupling between mid-infrared chiral metasurfaces and molecular vibrations
Plasmon-phonon coupling between metamaterials and molecular vibrations provides a new path for studying mid-infrared light-matter interactions and molecular detection. So far, the coupling between the plasmonic resonances of metamaterials and the phonon vibrational modes of molecules has been realized under linearly polarized light. Here, mid-infrared chiral plasmonic metasurfaces with high circular dichroism (CD) in absorption over 0.65 in the frequency range of 50 to 60 THz are demonstrated to strongly interact with the phonon vibrational resonance of polymethyl methacrylate (PMMA) molecules at 52 THz, under both left-handed and right-handed circularly polarized (LCP and RCP) light. The mode splitting features in the absorption spectra of the coupled metasurface-PMMA systems under both circular polarizations are studied in PMMA layers with different thicknesses. The relation between the mode splitting gap and the PMMA thickness is also revealed. The demonstrated results can be applied in areas of chiral molecular sensing, thermal emission, and thermal energy harvesting.
42 ENGINEERING↗