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At least 289 records · Page 16

Fluctuations of the Phase Difference Across an Array of Josephson Junctions in Superfluid He-4

We present a formal thermodynamic treatment of superfluid flow in a Josephson junction. We show that the current and the phase difference are thermodynamic conjugate variables. We derive quantitative expressions for the rms fluctuations of these variables. Also, we discuss the thermodynamic stability and the thermal activation to the phase slip region. We apply the developed formalism to show why an array of apertures in He-4 can exhibit the Josephson effect near the Lambda transition despite strong thermal fluctuations.

Chui, T.↗

Improving our Understanding of Atlantic Tropical Cyclones through Knowledge of the Saharan Air Layer: Hope or Hype?

The existence of the Saharan air layer (SAL), a layer of warm, dry, dusty air that frequently moves westward off of the Saharan desert of Africa and over the tropical Atlantic Ocean, has long been appreciated. As air moves over the desert, it is strongly heated from below, producing a very hot air mass at low levels. Because there is no moisture source over the Sahara, the rise in temperature causes a sharp drop in relative humidity, thus drying the air. In addition, the warm air produces a very strong jet of easterly flow in the middle troposphere called the African easterly jet that is thought to play a critical role in hurricane formation. In recent years, there has been an increased focus on the impact that the SAL has on the formation and evolution of hurricanes in the Atlantic. However, the nature of its impact remains unclear, with some researchers arguing that the SAL amplifies hurricane development and with others arguing that it inhibits it. The argument for positively influencing hurricane development is based upon the fact that the African easterly jet produces the waves that eventually form hurricanes and that it leads to rising motion south of the jet that favors the development of deep thunderstorm clouds. The potential negative impacts of the SAL include 1) low-level vertical wind shear associated with the African easterly jet; 2) warm SAL air aloft, which increases thermodynamic stability and suppresses cloud development; and 3) dry air, which produces cold downdrafts in precipitating regions, thereby removing energy needed for storm development. As part of this recent focus on the SAL and hurricanes (which motivated a 2006 NASA field experiment), there has been little emphasis on the SAL s potential positive influences and almost complete emphasis on its possible negative influences, almost to the point of claims that the SAL is the major suppressing influence on hurricanes in the Atlantic. Multiple NASA satellite data sets (TRMM, MODIS, and AIRS/AMSU) and National Centers for Environmental Prediction global analyses are used to characterize the SAL s properties and evolution in relation to developing hurricanes. The results show that storms generally form on the southern side of the jet, where favorable background rotation is high. The jet often helps to form the northern side of the storms and rarely moves over their inner cores, so jet-induced vertical wind shear does not appear to be a negative influence on developing storms. Warm SAL air is confined to regions north of the jet and generally does not impact the tropical cyclone precipitation south of the jet. Of the three proposed negative influences, dry air appears to be the key influence; however, the presence of dry SAL air is not a good indicator of whether a storm will weaken since many examples of intensifying storms surrounded by such dry air can be found. In addition, a global view of relative humidity shows moisture distributions in other ocean basins that are almost identical to the Atlantic. The dry zones correspond to regions of descending air on the eastern and equatorward sides of semi-permanent oceanic high pressure systems. Thus, the dry air over the Atlantic appears to be primarily a product of the large-scale flow, but with enhanced drying at low levels associated with the Sahara. As a result, we conclude that the SAL is not a major negative influence on hurricanes. It is just one of many possible influences and can be both positive and negative.

Braun, Scott A.↗

Improving Our Understanding of Atlantic Hurricanes Through Knowledge of the Saharan Air Layer: Hope Or Hype?

The existence of the Saharan air layer (SAL), a layer of warm, dry, dusty air frequently present over the tropical Atlantic Ocean, has long been appreciated. The nature of its impact on hurricanes remains unclear, with some researchers arguing that the SAL amplifies hurricane development and with others arguing that it inhibits it. The potential negative impacts of the SAL include 1) low-level vertical wind shear associated with the African easterly jet; 2) warm air aloft, which increases thermodynamic stability; and 3) dry air, which produces cold downdrafts. Some investigators have assumed the validity of these proposed negative influences and have frequently used them to explain the failure of individual storms to intensify or to explain the relative inactivity of recent hurricane seasons. Multiple NASA satellite data sets and National Centers for Environmental Prediction global analyses are used to characterize the SAL's properties and evolution in relation to developing hurricanes. The results will shows that neither jet--induced vertical wind shear nor warm SAL air (high stability) produce significant negative impacts on Atlantic storms. Dry air appears to be a key mechanism for SAL influence, but the presence of dry SAL air is not always a good indicator of whether a storm will weaken since many examples of intensifying storms surrounded by such dry air can be found. Idealized simulations will be used to evaluate the role of dry air. Finally, two case studies of supposedly "prime examples" of SAL influence will show that the negative influences of the SAL are perhaps too readily ascribed to individual storms that fail to reach their maximum potential intensity.

Braun, Scott↗

Reevaluating the Role of Saharan Air Layer in Atlantic Tropical Cyclogenesis and Evolution

The existence of the Saharan air layer (SAL), a layer of warm, dry, dusty air that frequently moves westward off of the Saharan desert of Africa and over the tropical Atlantic Ocean, has long been appreciated. As air moves over the desert, it is strongly heated from below, producing a very hot air mass at low levels. Because there is no moisture source over the Sahara, the rise in temperature causes a sharp drop in relative humidity, thus drying the air. In addition, the warm air produces a very strong jet of easterly flow in the middle troposphere called the African easterly jet that is thought to play a critical role in hurricane formation. In recent years, there has been an increased focus on the impact that the SAL has on the formation and evolution of hurricanes in the Atlantic. However, the nature of its impact remains unclear, with some researchers arguing that the SAL amplifies hurricane development and with others arguing that it inhibits it. The argument for positively influencing hurricane development is based upon the fact that the African easterly jet provides an energy source for the waves that eventually form hurricanes and that it leads to rising motion south of the jet that favors the development of deep thunderstorm clouds. The potential negative impacts of the SAL include 1) low-level vertical wind shear associated with the African easterly jet; 2) warm SAL air aloft, which increases thermodynamic stability and suppresses cloud development; and 3) dry air, which produces cold downdrafts in precipitating regions, thereby removing energy needed for storm development. As part of this recent focus on the SAL and hurricanes (which motivated a 2006 NASA field experiment), there has been little emphasis on the SAL s potential positive influences and almost complete emphasis on its possible negative influences, almost to the point of claims that the SAL is the major suppressing influence on hurricanes in the Atlantic. In this study, multiple NASA satellite data sets (TRMM, MODIS, CALIPSO, and AIRS/AMSU) and National Centers for Environmental Prediction global analyses are used to see if the proposed negative influences deserve all of the attention they have recently received. The results show that storms generally form on the southern side of the African jet, where favorable background rotation is high. The jet often helps to form the northern side of the storms and is typically stronger in storms that intensify than those that weaken, suggesting that jet-induced vertical wind shear is not a negative influence on developing storms. Warm SAL air is confined to regions north of the jet and generally does not impact the tropical cyclone precipitation south of the jet. A comparison of the environments of strongly strengthening storms and of weakening storms shows no differences in SAL structure, indicating that the SAL has little influence on whether storms weaken or intensify. The large-scale flow at upper levels above the SAL was found to be most important, with the environment of strengthening storms having very little vertical wind shear and also favoring more expansive outflow from the storm. The SAL is shown to occur in a large-scale environment that is already characteristically dry as a result of large-scale subsidence (sinking air motions). Strong surface heating and deep dry convective mixing enhance dryness at low levels, but moisten the air at midlevels. Therefore, mid-to-upper-level dryness is not a defining characteristic of the SAL, but is instead a signature of subsidence. As a result, we conclude that the SAL is not the major negative influence on hurricanes that recent studies have emphasized. It is just one of many possible influences and can be both positive and negative.

Braun, Scott A.↗

Re-Evaluating the Role of the Saharan Air Layer in Atlantic Tropical Cyclogenesis and Evolution

The existence of the Saharan air layer (SAL), a layer of warm, dry, dusty air frequently present over the tropical Atlantic Ocean, has long been appreciated. The nature of its impact on hurricanes remains unclear, however, with some researchers arguing that the SAL amplifies hurricane development and with others arguing that it inhibits it. Most research in recent years has emphasized the potential negative impacts of the SAL, but is this emphasis justified? The potential negative impacts of the SAL include 1) vertical wind shear associated with the African easterly jet; 2) warm air aloft, which increases thermodynamic stability at the base of the SAL; and 3) dry air, which produces cold downdrafts. Multiple NASA satellite data sets and NCEP global analyses are used to characterize the SAL's properties and evolution in relation to tropical cyclones and to evaluate these potential negative influences. The results suggest that the negative influences of the SAL have been significantly over-emphasized, in part because of several false assumptions about the structure and role of the SAL.

Braun, Scott A.↗

Improved Mo-Re VPS Alloys for High-Temperature Uses

Dispersion-strengthened molybdenum- rhenium alloys for vacuum plasma spraying (VPS) fabrication of high-temperature-resistant components are undergoing development. In comparison with otherwise equivalent non-dispersion-strengthened Mo-Re alloys, these alloys have improved high-temperature properties. Examples of VPS-fabricated high-temperature-resistant components for which these alloys are expected to be suitable include parts of aircraft and spacecraft engines, furnaces, and nuclear power plants; wear coatings; sputtering targets; x-ray targets; heat pipes in which liquid metals are used as working fluids; and heat exchangers in general. These alloys could also be useful as coating materials in some biomedical applications. The alloys consist of 60 weight percent Mo with 40 weight percent Re made from (1) blends of elemental Mo and Re powders or (2) Re-coated Mo particles that have been subjected to a proprietary powder-alloying-and-spheroidization process. For most of the dispersion- strengthening experiments performed thus far in this development effort, 0.4 volume percent of transition-metal ceramic dispersoids were mixed into the feedstock powders. For one experiment, the proportion of dispersoid was 1 volume percent. In each case, the dispersoid consisted of either ZrN particles having sizes <45 m, ZrO2 particles having sizes of about 1 m, HfO2 particles having sizes <45 m, or HfN particles having sizes <1 m. These materials were chosen for evaluation on the basis of previously published thermodynamic stability data. For comparison, Mo-Re feedstock powders without dispersoids were also prepared.

Hickman, Robert↗

The Impact of Stable Layers on Downdrafts in Tropical Convection

While the idea that downdraft vertical velocity is influenced by thermodynamic stability may seem obvious, there remains a gap in the scientific literature surrounding the interaction between downdrafts and stable layers. A number of questions remain unanswered. Can a stable layer stop the downward progression of a downdraft or merely slow its velocity? Related to this, can a stable layer stop the injection of low entropy air into the boundary layer? Do downdrafts modify the environment in a way that removes pre-existing stable layers (limiting the influence of the stable layer)? Is it possible for evaporative cooling to generate and maintain a stable layer that is sufficiently strong to stop the downward progression of downdrafts?The present study aims to answer these questions using a combination of high-altitude airborne radar and dropsonde observations, both collected within four tropical cyclones (Gaston, Hermine, Karl, and Matthew) during the 2016 NOAA SHOUT field campaign, as well as idealized simulations of tropical deep convection. This presentation will focus on the potential for a stable layer to halt the downward progression of a downdraft (and the associated low entropy air) with particular attention given to conditions and processes that might enhance or mitigate the influence of the stable layer.

Helms, Charles N.↗

Frequency-dependent hydrodynamic inductance and the determination of the thermal and quantum noise of a superfluid gyroscope

We reexamine mass flow in a superfluid gyroscope containing a superfluid Josephson weak link. We introduce a frequency-dependent hydrodynamic inductance to account for an oscillatory flow of the normal fluid component in the sensing loop. With this hydrodynamic inductance, we derive the thermal phase noise, and hence the thermal rotational noise of the gyroscope. We examine the thermodynamic stability of the system based on an analysis of the free energy. We derive a quantum phase noise, which is analogous to the zero-point motion of a simple harmonic oscillator. The configuration of the studied gyroscope is analogous to a conventional superconducting RF SQUID. We show that the gyroscope has very low intrinsic noise (1.9x10(-13) rad s(-1)/root Hz), and it can potentially be applied to study general relativity, Earth science, and to improve global positioning systems (GPS).

Penanen, Konstantin↗

Differences in Tropical High Clouds Among Reanalyses: Origins and Radiative Impacts

We examine differences among reanalysis highcloud products in the tropics, assess the impacts of these differences on radiation budgets at the top of the atmosphere and within the tropical upper troposphere and lower stratosphere (UTLS), and discuss their possible origins in the context of the reanalysis models. We focus on the ERA5 (fifthgeneration European Centre for Medium-range Weather Forecasts – ECMWF – reanalysis), ERA-Interim (ECMWF Interim Reanalysis), JRA-55 (Japanese 55-year Reanalysis), MERRA-2 (Modern-Era Retrospective Analysis for Research and Applications, Version 2), and CFSR/CFSv2 (Climate Forecast System Reanalysis/Climate Forecast System Version 2) reanalyses. As a general rule, JRA-55 produces the smallest tropical high-cloud fractions and cloud water contents among the reanalyses, while MERRA-2 produces the largest. Accordingly, long-wave cloud radiative effects are relatively weak in JRA-55 and relatively strong in MERRA-2. Only MERRA-2 and ERA5 among the reanalyses produce tropical-mean values of outgoing long-wave radiation (OLR) close to those observed, but ERA5 tends to underestimate cloud effects, while MERRA-2 tends to overestimate variability. ERA5 also produces distributions of longwave, short-wave, and total cloud radiative effects at the top of the atmosphere that are very consistent with those observed. The other reanalyses all exhibit substantial biases in at least one of these metrics, although compensation between the long-wave and short-wave effects helps to constrain biases in the total cloud radiative effect for most reanalyses. The vertical distribution of cloud water content emerges as a key difference between ERA-Interim and other reanalyses. Whereas ERA-Interim shows a monotonic decrease of cloud water content with increasing height, the other reanalyses all produce distinct anvil layers. The latter is in better agreement with observations and yields very different profiles of radiative heating in the UTLS. For example, whereas the altitude of the level of zero net radiative heating tends to be lower in convective regions than in the rest of the tropics in ERAInterim, the opposite is true for the other four reanalyses. Differences in cloud water content also help to explain systematic differences in radiative heating in the tropical lower stratosphere among the reanalyses. We discuss several ways in which aspects of the cloud and convection schemes impact the tropical environment. Discrepancies in the vertical profiles of temperature and specific humidity in convective regions are particularly noteworthy, as these variables are directly constrained by data assimilation, are widely used, and feed back to convective behaviour through their relationships with thermodynamic stability.

High Clouds↗

Joint cloud water path and rainwater path retrievals from airborne ORACLES observations

This study presents a new algorithm that combines W-band reflectivity measurements from the Airborne Precipitation Radar – third generation (APR-3) passive radiometric cloud optical depth and effective radius retrievals from the Research Scanning Polarimeter (RSP) to estimate total liquid water path in warm clouds and identify the contributions from cloud water path (CWP) and rainwater path (RWP). The resulting CWP estimates are primarily determined by the optical depth input, although reflectivity measurements contribute ∼10 %–50 % of the uncertainty due to attenuation through the profile. Uncertainties in CWP estimates across all conditions are 25 % to 35 %, while RWP uncertainty estimates frequently exceed 100 %. Two-thirds of all radar-detected clouds observed during the ObseRvations of Aerosols above CLouds and their intEractionS (ORACLES) campaign that took place from 2016–2018 over the southeast Atlantic Ocean have CWP between 41 and 168 g/sq. m and almost all CWPs (99 %) between 6 to 445 g/sq. m. RWP, by contrast, typically makes up a much smaller fraction of total liquid water path (LWP), with more than 70 % of raining clouds having less than 10 g/sq. m of rainwater. In heavier warm rain (i.e., rain rate exceeding 40 mm/h or 1000 mm/d), however, RWP is observed to exceed 2500 g/sq. m. CWP (RWP) is found to be approximately 30 g/sq. m (7 g/sq. m) larger in unstable environments compared to stable environments. Surface precipitation is also more than twice as likely in unstable environments. Comparisons against in situ cloud microphysical probe data spanning the range of thermodynamic stability and meteorological conditions encountered across the southeast Atlantic basin demonstrate that the combined APR-3 and RSP dataset enable a robust joint cloud–precipitation retrieval algorithm to support future ORACLES precipitation susceptibility and cloud–aerosol–precipitation interaction studies.

algorithm↗

The Influence of Sea ice on Arctic Cloud Properties: What Can We Learn by Applying a In Situ Observational Strategy to Satellite Data?

Sea ice is declining because of anthropogenic climate change. This change alters many aspects of the Arctic climate system, including the way that the surface and atmosphere interact. Atmosphere-surface coupling processes represent an important cloud feedback mechanism that can alter the Arctic surface energy budget. For the Arctic, it has been hypothesized that a reduction in sea ice cover could lead to an increase in clouds. If this process were to occur as originally hypothesized, sea ice loss in all seasons would lead to an increase in clouds. Recent observational studies find a cloud response to sea ice loss in non-summer months and no cloud response in summer months. However, previous studies rely on inter-annual variability and reanalysis to control for the influence of meteorology, reducing the confidence in the resulting conclusions. We adopt a phenomenological, event-based approach that does not need to use meteorological reanalysis. The approach analyzes cloud properties derived from CALIPSO-CloudSat over sea ice and adjacent ice-free footprints by compositing individual satellite ground tracks that cross the Arctic sea ice edge. The underlying assumption, which we verify, is that footprints that are close to each other in space and time experience similar large-scale meteorological conditions. Our results show larger cloud fraction and more cloud liquid water over ice-free than over sea ice footprints and provide additional evidence for a seasonal dependence of cloud-sea ice coupling that is in line with previous work. We find a different result where the maximum cloud property differences between sea ice and ice-free ocean occurs in spring, not fall as earlier studies suggest. We argue that these cloud differences between sea ice and ice-free ocean are primarily caused by the influence of the surface type on the thermodynamic stability of the lower troposphere and not principally from an increase in surface evaporation. In addition, we explore the sensitivity of these results to marginal ice zone width, season, Atlantic vs. Pacific sector, and the cloud property dependence on the distance from the sea ice edge. Overall, our results provide further evidence that cloud-sea ice coupling processes are not offsetting the observed surface energy budget perturbation due to sea ice loss in summer; thus, the cloud response to declining sea ice appears to contribute to amplified Arctic warming.

Patrick C Taylor↗

The stability analysis of magnetohydrodynamic equilibria - Comparing the thermodynamic approach with the energy principle

This paper is a contribution to the stability analysis of current-carrying plasmas, i.e., plasma systems that are forced by external mchanisms to carry a nonrelaxing electrical current. Under restriction to translationally invariant configurations, the thermodynamic stability criterion for a multicomponent plasma is rederived within the framework of nonideal MHD. The chosen dynamics neglects scalar resistivity, but allows for other types of dissipation effects both in Ohm's law and in the equation of motion. In the second section of the paper, the thermodynamic stability criterion is compared with the ideal MHD based energy principle of Bernstein et al. With the help of Schwarz's inequality, it is shown that the former criterion is always more 'pessimistic' than the latter, i.e., that thermodynamic stability implies stability according to the MHD principle, but not vice versa. This reuslt confirms the physical plausible idea that dissipational effects tend to weaken the stability properties of current-carrying plasma equilibria by breaking the constraints of ideal MHD and allowing for possibly destabilizing effects such as magnetic field line reconfiguration.

Brinkmann, R. P.↗

Calorimetric Study of Mixed Phosphates Na 4 M 3 (PO 4 ) 2 P 2 O 7 (M = Mn 2+ , Fe 2+ , Co 2+ , Ni 2+ ) to Evaluate the Electrochemical Trends

Mixed polyanionic compounds have been studied extensively as viable cathode materials for sodium-ion batteries. Mixed phosphates, Na 4 M 3 (PO 4 ) 2 P 2 O 7 (M = Mn 2+ , Fe 2+ , Co 2+ , Ni 2+ ), provide a low barrier for Na-ion diffusion, being advantageous in comparison to phosphates and pyrophosphates. The reported order of sodium extraction is ambiguous and remains unclear. Despite being structurally similar, electrochemical performance differs for all four analogues with different degrees of (de)sodiation, according to the transition element present. High-temperature oxide melt solution calorimetry has been used to establish the relation between thermodynamic phase stability and observed capacity for this series of mixed phosphates. Thermodynamic phase stability largely depends on the kind of structure, type of bonding, and size of the cations present. So, according to our results, the thermodynamic phase stability follows the order Na 4 Mn 3 (PO 4 ) 2 P 2 O 7 > Na 4 Fe 3 (PO 4 ) 2 P 2 O 7 > Na 4 Co 3 (PO 4 ) 2 P 2 O 7 > Na 4 Ni 3 (PO 4 ) 2 P 2 O 7 . The thermodynamic studies serve as guidelines for the selection of compositions with the potential for fabricating advanced cathode materials with maximum performance.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

A Novel Thermodynamical Predictor of Tropical High‐Cloud Area Coverage: Estimated Anvil‐Outflow Stability

The stability at the lapse-rate tropopause (LRT) was previously defined as the upper-tropospheric stability (UTS and SUT) but might underestimate the stability control on high-level clouds, since there is little direct connection between convective processes and the thermal stratification at the LRT. Here, a novel estimated anvil-outflow stability (EAS) based on the minimum stability in the upper troposphere is proposed. At the Manus site, the results show that small and large values of the LRT-based UTS and SUT both correspond to strong divergence and frequent occurrence of high-level ice clouds. In contrast, smaller EAS corresponds to stronger convective outflows to produce likely more high-level ice clouds, with a strong negative correlation. In tropics, EAS better explains the geographic distribution of high-level cloud coverage (HCC) and its temporal variations than UTS and SUT. With a strong linear correlation, EAS is likely a simple useful predictor of HCC.

54 ENVIRONMENTAL SCIENCES↗

Thermodynamics of gallium-stabilized delta-plutonium: A high-temperature drop calorimetry study

Throughout the Cold War (1947–1991), both the United States and the former Soviet Union independently derived a phase diagram for the Pu-Ga system that has different implications on Pu phase stability. In the phase diagram produced by the United States, the Pu δ-phase is thermodynamically stable at room temperatures when Ga content is between 2 and 9 at. %. The diagram produced by the Soviet Union shows the δ-phase undergoing an eutectoid decomposition into the α-Pu + α-Pu 3 Ga at 7.9 at. % Ga and 370 K. This would suggest that Ga-stabilized δ-Pu is metastable with respect to α-Pu + α-Pu 3 Ga at 298 K. To investigate this, and the thermodynamic behavior of Ga in the FCC lattice of δ-Pu, we have utilized high-temperature drop calorimetry to study the enthalpy of formation of two δ-Pu 1−x Ga x compositions. In doing so, mixing models (regular and subregular) were developed to understand the thermodynamic behavior of Ga in the FCC lattice of δ-Pu and found a strong departure from ideal conditions, which suggests Ga ordering in the FCC lattice of δ-Pu. Overall, it was found that δ-Pu 1−x Ga x is enthalpically metastable with respect to α-Pu + Pu 3 Ga at 298 K.

36 MATERIALS SCIENCE↗

Thermodynamic analysis of chemical stability of ceramic materials in hydrogen-containing atmospheres at high temperatures

The chemical stability of several ceramic materials in hydrogen-containing environments was analyzed with thermodynamic considerations in mind. Equilibrium calculations were made as a function of temperature, moisture content, and total system pressure. The following ceramic materials were considered in this study: SiC, Si3N4, SiO2, Al2O3, mullite, ZrO2, Y2O3, CaO, MgO, BeO, TiB2, TiC, HfC, and ZrC. On the basis of purely thermodynamic arguments, upper temperature limits are suggested for each material for long-term use in H2-containing atmospheres.

Misra, Ajay K.↗