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NASA NTRS2016

Analysis of Ozone in Cloudy Versus Clear Sky Conditions

Convection impacts ozone concentrations by transporting ozone vertically and by lofting ozone precursors from the surface, while the clouds and lighting associated with convection affect ozone chemistry. Observations of the above-cloud ozone column (Ziemke et al., 2009) derived from the OMI instrument show geographic variability, and comparison of the above-cloud ozone with all-sky tropospheric ozone columns from OMI indicates important regional differences. We use two global models of atmospheric chemistry, the GMI chemical transport model (CTM) and the GEOS-5 chemistry climate model, to diagnose the contributions of transport and chemistry to observed differences in ozone between areas with and without deep convection, as well as differences in clean versus polluted convective regions. We also investigate how the above-cloud tropospheric ozone from OMI can provide constraints on the relationship between ozone and convection in a free-running climate simulation as well as a CTM.

Cloud↗

NASA NTRS1999

Interpretation of Lidar and Satellite Data Sets Using a Global Photochemical Model

A primary goal of the NASA Tropospheric Chemistry Program (TCP) is to "contribute substantially to scientific understanding of human impacts on the global troposphere". In order to analyze global or regional trends and factors of the troposphere chemistry, for example, its oxidation capacity or composition, a continuous global/regional data coverage as well as model simulations are needed. The Global Tropospheric Experiment (GTE), a major component of the TCP, provides data vital to these questions via aircraft measurement of key trace chemical species in various remote regions of the world. Another component in NASA's effort are satellite projects for exploration of tropospheric chemistry and dynamics. A unique data product is the Tropospheric Ozone Residual (TOR) utilizing global tropospheric ozone data. Another key research tool are simulation studies of atmospheric chemistry and dynamics for the theoretical understanding of the atmosphere, the extrapolation of observed trends, and for sensitivity studies assessing a changing anthropogenic impact to air chemistry and climate. In the context with model simulations, field data derived from satellites or (airborne) field missions are needed for two purposes: 1. To initialize and validate model simulations, and 2., to interpret field data by comparison to model simulation results in order to analyze global or regional trends and deviations from standard tropospheric chemistry and transport conditions as defined by the simulations. Currently, there is neither a sufficient global data coverage available nor are existing well established global circulation models. The NASA LARC CTM model is currently not yet in a state to accomplish a sufficient tropospheric chemistry simulation, so that the current research under this cooperative agreement focuses on utilizing field data products for direct interpretation. They will be also available for model testing and a later interpretation with a finally utilized model.

Zenker, Thomas↗

NASA NTRS2000

SHADOZ Comparisons with TOMS

One year of balloon-sonde profiles taken from the Southern Hemisphere ADditional OZonesondes (SHADOZ) archive have been compared with data from the Earth Probe Total Ozone Mapping Spectrometer (TOMS) by integrating the balloon profiles to obtain total column ozone. The TOMS backscattered ultraviolet measurement loses sensitivity to ozone in the lowest five to ten kilometers of the atmosphere, limiting the accuracy of the TOMS measurement of tropospheric ozone. This is shown by the increased deviation between TOMS total ozone and the sonde total in the tropical Pacific, where tropospheric ozone is known to be lower than the tropical climatological average. The TOMS underestimate is further confirmed by the correlation of deviations between TOMS and the sondes with changes in lower tropospheric ozone. After allowing for the TOMS offset, the sondes appear to underestimate ozone by three to five percent. This is confirmed by a limited number of comparisons with Dobson data.

McPeters, Richard D.↗

NASA NTRS2004

Brown Cloud Pollution and Smog Ozone Transport 6,000 km to the Tropical Atlantic: Mechanism and Sensing

We have found repeated illustrations in the maps of Total Tropospheric Ozone (TTO) of apparent transport of ozone from the Indian Ocean to the Equatorial Atlantic Ocean. Most interesting are examples that coincide with the INDOEX observations of late northern winter. Three soundings with the SHADOZ (Southern Hemisphere Additional Ozonesondes) network help confirm and quantify degree of influence of pollution, lightning, and stratospheric sources, suggesting that perhaps 40% of increased Atlantic ozone could be Asian pollution during periods of maximum identified in the TTO maps. This analysis also indicates a mechanism for such extended transport. We outline recurrent periods of apparent ozone transport from Indian to Atlantic Ocean regions outside the late-winter period. Clearly brown-cloud aerosol affects tropospheric ozone, both limiting its chemical production and also potentially obscuring its detection by the TOMS instrument. Introductory statistical studies will be presented, evaluating the role of tropopause meteorology, aerosol, and other factors in the modifying the relationship between true tropospheric ozone measured by SHADOZ and the TTO product, with suggestions for extending the product.

Chatfield, Robert B.↗

NASA NTRS2000

Tropospheric Total Ozone in the Region of the Equatorial south Atlantic Ocean

As a consequence of the SHADOZ effort it is possible to examine Tropospheric Total Ozone TTO, over Ascension Island (8S,14W) and compare results with similar ozone soundings for the period July 1990 through October 1992. Because of the nearly 20-year long cooperation between NASA and INPE it is possible to also compare the Ascension Island results with the long-term ozone data set available from Natal, Brazil (6S,35W). The Natal site meets requirements of the SHADOZ program. The tropopause is determined objectively using the World Meteorological Organization (WMO) criteria and the radiosonde's temperature and altitude parameters. Once tropopause heights are determined TTO can be calculated. Time-series profiles illustrate changes in TTO over the period of record.

Schmidlin, Francis J.↗

NASA NTRS2008

Assimilation of Aura Ozone Data and Comparisons with In Situ Observations

Ozone data from the Ozone Monitoring Instrument (OMI) and the Microwave Limb Sounder (MLS) onboard EOS Aura satellite were assimilated into the Goddard Earth Observing System Version 4 (GEOS-4) ozone assimilation system. Comparison of assimilated ozone with ozone sonde and MOZAIC data indicate an agreement within 10% in the lower stratosphere, where dynamical processes dominate. Assimilation of OMI and MLS data improves tropospheric column estimates in the Atlantic region, but leads to an overestimation in the tropical Pacific in comparison with SHADOZ sondes. Transport and data biases are considered in order to understand these discrepancies. Comparisons of assimilated tropospheric ozone columns with ozone sonde data reveal root-mean-square (RMS) differences of 2.9 to 7.2 DU, which are typically smaller than the model-sonde RMS differences. Four different definitions of the tropopause using temperature lapse rate, potential vorticity (PV) and isentropic surfaces or ozone isosurfaces are compared with respect to their global impact on the estimated tropospheric ozone column. The largest sensitivity in the tropospheric ozone column is found near the subtropical jet, where the ozone or PV determined tropopause typically lies below the lapse rate tropopause.

Stajner, Ivanka↗

NASA NTRS1995

High Resolution Numerical Simulations and Diagnostic Studies Atmospheric Transport During TRACE-A

The enclosed publications constitute our final report. These are publications completed in referred journals. The completed work includes: Meteorological conditions associated with vertical distributions of aerosols off the west coast of Africa. TRACE-A trajectory intercomparison 2. Isentropic and kinematic methods. Chemical characteristics of tropospheric air over the tropical South Atlantic Ocean: Relationship to trajectory history. Passive Tracer Transport Relevant to the TRACE-A Experiment. The meteorological environment of the tropospheric ozone maximum over the tropical south Atlantic Ocean. : Influence of a middle-latitude cyclone on tropospheric ozone distributions during a period of TRACE-A. All of this work provided the meteorological background for the Transport of Atmospheric Chemistry near the Equator (TRACE-A) project sponsored by Dr,, Joe McNeal of NASA. Our principal findings are that bio-mass burning sources from Africa and South America did contribute to the accumulation of tropospheric ozone over the tropical Atlantic Ocean. Other findings relate to circulations, advections of Ozone and other plausible sources for the TOMS based ozone maximum over the Atlantic Ocean.

Krishnamurti, T. N.↗

NASA NTRS2019

Trend Quality Ozone from NPP OMPS: The Version 2 Processing

A version 2 processing of data from two ozone monitoring instruments on Suomi NPP, the OMPS nadir ozone mapper and the OMPS nadir ozone profiler, has now been completed. The previously released data were useful for many purposes but were not suitable for use in ozone trend analysis. In this processing, instrument artifacts have been identified and corrected, an improved scattered light correction and wavelength registration have been applied, and soft calibration techniques were implemented to produce a calibration consistent with data from the series of SBUV/2 instruments. The result is a high-quality ozone time series suitable for trend analysis. Total column ozone data from the OMPS nadir mapper now agree with data from the SBUV/2 instrument on NOAA 19 with a zonal average bias of −0.2 % over the 60° S to 60° N latitude zone. Differences are somewhat larger between OMPS nadir profiler and N19 total column ozone, with an average difference of −1.1 % over the 60° S to 60° N latitude zone and a residual seasonal variation of about 2 % at latitudes higher than about 50°. For the profile retrieval, zonal average ozone in the upper stratosphere (between 2.5 and 4 hPa) agrees with that from NOAA 19 within ±3 % and an average bias of −1.1 %. In the lower stratosphere (between 25 and 40 hPa) agreement is within ±3 % with an average bias of +1.1 %. Tropospheric ozone produced by subtracting stratospheric ozone measured by the OMPS limb profiler from total column ozone measured by the nadir mapper is consistent with tropospheric ozone produced by subtracting stratospheric ozone from MLS from total ozone from the OMI instrument on Aura. The agreement of tropospheric ozone is within 10 % in most locations.

OMPS nadir ozone mapper↗

NASA NTRS2020

Stratospheric Impact on the Northern Hemisphere Winter and Spring Ozone Interannual Variability in the Troposphere

In this study we use ozone and stratospheric ozone tracer simulations from the high-resolution (0.5°x0.5°) Goddard Earth Observing System, Version 5 (GEOS-5) in a replay mode to study the impact of stratospheric ozone on tropospheric ozone interannual variability (IAV). We use these simulations in conjunction with ozone sonde measurements from 1990 to 2016 during the winter and spring seasons. The simulations include a stratospheric ozone tracer (StratO3) to aid 15in the evaluation of the impact of stratospheric ozone IAV on the IAV of tropospheric ozone at different altitudes and location. The model is in good agreement with the observed interannual variation of tropospheric ozone, except for the post-Pinatubo period(1992-1994)over the region of North America. Ozone sonde data show a negative ozone anomaly in 1992-1994 following the Pinatubo eruption, with recovery thereafter. The simulated anomaly is only half the magnitude of that observed. Our analysis suggests that the simulated Stratosphere-troposphere exchange (STE)flux deduced from the analysis 20might be too strong over the North American (50°N-70°N) region after the Mt. Pinatubo eruption in the early 1990s,maskingthe impact of lower stratospheric ozone concentration on tropospheric ozone. European ozone sonde measurements show a similar but weaker ozone depletion after the Mt. Pinatubo eruption, which is fully reproduced by the model. Analysis based on the stratospheric ozone tracer (StratO3) identifies differences in strength and vertical extent of stratospheric ozone impact on the tropospheric ozone interannual variation (IAV)between North America and Europe. Over NorthAmerica25stations, the StratO3IAV has a significant impact on tropospheric ozone from the upper to lower troposphere and explains about 60% and 66% of the simulated ozone IAV at 400 hPa, and ~11% and 34% at 700 hPa in winter and spring respectively. Over European stations, the influence is limited to the middle to upper troposphere, and becomes much smaller at 700 hPa. The Modern-Era Retrospective analysis for Research and Applications, Version 2 (MERRA-2)assimilated fields exhibit strong longitudinal variations over northern hemisphere (NH) mid-high latitudes, with lower tropopause height and 30lower geopotential height over North America than Europe. These variations associated with the relevant variations in the location of tropospheric jet flows are responsible for the longitudinal differences in the stratospheric ozone impact, with stronger effects over North America than over Europe

tropospheric ozone IAV, Model, ozonesonde, stratos↗

NASA NTRS2014

Long-Term Changes in Lower Tropospheric Baseline Ozone Concentrations:

Two recent papers have quantified long-term ozone (O3) changes observed at northernmidlatitude sites that are believed to represent baseline (here understood as representative of continental to hemispheric scales) conditions. Three chemistry-climate models (NCAR CAM-chem, GFDL-CM3, and GISS-E2-R) have calculated retrospective tropospheric O3 concentrations as part of the Atmospheric Chemistry and Climate Model Intercomparison Project and Coupled Model Intercomparison Project Phase 5 model intercomparisons. We present an approach for quantitative comparisons of model results with measurements for seasonally averaged O3 concentrations. There is considerable qualitative agreement between the measurements and the models, but there are also substantial and consistent quantitative disagreements. Most notably, models (1) overestimate absolute O3 mixing ratios, on average by approximately 5 to 17 ppbv in the year 2000, (2) capture only approximately 50% of O3 changes observed over the past five to six decades, and little of observed seasonal differences, and (3) capture approximately 25 to 45% of the rate of change of the long-term changes. These disagreements are significant enough to indicate that only limited confidence can be placed on estimates of present-day radiative forcing of tropospheric O3 derived from modeled historic concentration changes and on predicted future O3 concentrations. Evidently our understanding of tropospheric O3, or the incorporation of chemistry and transport processes into current chemical climate models, is incomplete. Modeled O3 trends approximately parallel estimated trends in anthropogenic emissions of NO(sub x), an important O3 precursor, while measured O3 changes increase more rapidly than these emission estimates.

atmospheric composition↗

NASA NTRS2017

Quantifying TOLNet Ozone Lidar Accuracy During the 2014 DISCOVER-AQ and FRAPPE Campaigns

The Tropospheric Ozone Lidar Network (TOLNet) is a unique network of lidar systems that measure high-resolution atmospheric profiles of ozone. The accurate characterization of these lidars is necessary to determine the uniformity of the network calibration. From July to August 2014, three lidars, the TROPospheric OZone (TROPOZ) lidar, the Tunable Optical Profiler for Aerosol and oZone (TOPAZ) lidar, and the Langley Mobile Ozone Lidar (LMOL), of TOLNet participated in the Deriving Information on Surface conditions from Column and Vertically Resolved Observations Relevant to Air Quality (DISCOVER-AQ) mission and the Front Range Air Pollution and Photochemistry Experiment (FRAPPA) to measure ozone variations from the boundary layer to the top of the troposphere. This study presents the analysis of the intercomparison between the TROPOZ, TOPAZ, and LMOL lidars, along with comparisons between the lidars and other in situ ozone instruments including ozonesondes and a P-3B airborne chemiluminescence sensor. The TOLNet lidars measured vertical ozone structures with an accuracy generally better than +/-15 % within the troposphere. Larger differences occur at some individual altitudes in both the near-field and far-field range of the lidar systems, largely as expected. In terms of column average, the TOLNet lidars measured ozone with an accuracy better than +/-5 % for both the intercomparison between the lidars and between the lidars and other instruments. These results indicate that these three TOLNet lidars are suitable for use in air quality, satellite validation, and ozone modeling efforts.

TOLNet↗

NASA NTRS2006

Exploration of OMI Products for Air Quality Applications Through Comparisons with Models and Observations

The Ozone Monitoring Instrument (OMI) on board NASA s Aura satellite was launched in July 2004, and is now providing daily global observations of total column ozone, NO2, and SO2, as well as aerosol information. Algorithms have also been developed to produce daily tropospheric ozone and NO2 products. The tropospheric ozone product reported here is a tropospheric residual computed through use of Aura Microwave Limb Sounder (MLS) ozone profile data to quantify stratospheric ozone. We are investigating the applicability of OMI products for use in air quality modeling, forecasting, and analysis. These investigations include comparison of the OMI tropospheric O3 and NO2 products with global and regional models and with lower tropospheric aircraft observations. Large-scale transport of pollution seen in the OM1 tropospheric O3 data is compared with output from NASA's Global Modeling Initiative global chemistry and transport model. On the regional scale we compare the OMI tropospheric O3 and NO2 with fields from the National Oceanic and Atmospheric Administration and Environmental Protection Agency (NOAA/EPA) operational Eta/CMAQ air quality forecasting model over the eastern United States. This 12-km horizontal resolution model output is roughly of equivalent resolution to the OMI pixel data. Correlation analysis between lower tropospheric aircraft O3 profile data taken by the University of Maryland over the Mid-Atlantic States and OMI tropospheric column mean volume mixing ratio for O3 will be presented. These aircraft data are representative of the lowest 3 kilometers of the atmosphere, the region in which much of the locally-generated and regionally-transported ozone exists.

Pickering, K. E.↗

NASA NTRS2003

Ozone Pollution, Transport and Variability: Examples from Satellite and In-Situ Observations

Regional and intercontinental transport of ozone has been observed from satellite, aircraft and sounding data. Over the past several years, we have developed new tropospheric ozone retrieval techniques from the TOMS (Total Ozone Mapping Spectrometer) satellite instrument that are of sufficient resolution to follow pollution episodes. The modified-residual technique uses Level 2 total ozone and was used to follow the 1997 fires in the wake of the El-Nino-related fires in southeast Asia and the Indonesian maritime continent. The TOMS-direct method ('TDOT' = TOMS Direct Ozone in the Troposphere) is a newer algorithm that uses TOMS radiances directly to extract tropospheric ozone. Ozonesonde data that have been taken in campaigns (e.g. TRACE-P) and more consistently in the SHADOZ (Southern Hemisphere Additional Ozonesondes) project, reveal layers of pollution traceable with trajectories. Examples will be shown of long-range transport and recirculation over Africa during SAFARI-2000.

Thompson, Anne↗

NASA NTRS1998

Development of a Compact, Ground-Based Ozone DIAL System

We are developing a portable, eye-safe, ground-based ozone lidar instrument specialized for ozone differential absorption lidar (DIAL) measurements in the troposphere. This prototype instrument is intended to operate at remote field sites and to serve as the basic unit for future monitoring projects requiring multi-instrument networks, such as that proposed for the Global Tropospheric Ozone Project (GTOP). GTOP is currently being formulated by a scientific panel of the International Global Atmospheric Chemistry Project to meet its goal to better understand the processes that control the global distribution of tropospheric ozone. In order for the lidar to be widely deployed in networks, it must be fairly easy to use and maintain as well as being cost-competitive with ground station launching ozone sondes which operate several times a day. To achieve these goals, emphasis is placed upon the incorporation of: (1) all-solid state transmitters which can reliably produce 20-40 mJ pulses; (2) a highly efficient, narrow-bandpass receiver; (3) dual analog and photon-counting detector channels; and (4) flexible, user-friendly control software.

Chyba, T. H.↗

NASA NTRS2007

Surface and Lightning Sources of Nitrogen Oxides over the United States: Magnitudes, Chemical Evolution, and Outflow

We use observations from two aircraft during the International Consortium for Atmospheric Research on Transport and Transformation (ICARTT) campaign over the eastern United States and North Atlantic during summer 2004, interpreted with a global 3-D model of tropospheric chemistry (GEOS-Chem) to test current understanding of the regional sources, chemical evolution, and export of nitrogen oxides. The boundary layer NO(x) data provide top-down verification of a 50% decrease in power plant and industry NO(x) emissions over the eastern United States between 1999 and 2004. Observed 8-12 8 km NO(x) concentrations in ICARTT were 0.55 +/- 36 ppbv, much larger than in previous United States aircraft campaigns (ELCHEM, SUCCESS, SONEX). We show that regional lightning was the dominant source of this NO(x) and increased upper tropospheric ozone by 10 ppbv. Simulating the ICARTT upper tropospheric NO(x) observations with GEOS-Chem require a factor of 4 increase in the model NO(x) yield per flash (to 500 mol/flash). Observed OH concentrations were a factor of 2 lower than can be explained from current photochemical models, and if correct would imply a broader lightning influence in the upper troposphere than presently thought.An NO(y)-CO correlation analysis of the fraction f of North American NO(x) emissions vented to the free troposphere as NO(y) (sum of NO(x) and its oxidation products PAN and HNO3) s shows observed f=16+/-10 percent and modeled f=14 +/- 8 percent, consistent with previous studies. Export to the lower free troposphere is mostly HNO3 but at higher altitudes is mostly PAN. The model successfully simulates NO(y) export efficiency and speciation, supporting previous model estimates of a large U.S. contribution to tropospheric ozone through NO(x) and PAN export.

Hudman, Rynda C.↗

NASA NTRSDate not supplied

Wildfire Emission Transport and Its Impact on the Local Air Quality – Case Study Example from the LISTOS Campaign

The high O3 concentration and large aerosol backscatter were measured in New York City(NYC) region and Connecticut (CT) coastline between August 15-16, 2018 during the Long Island Sound Tropospheric Ozone Study (LISTOS) campaign. Two TOLNet ozone lidar systems, NASA Goddard Space Flight Center Tropospheric Ozone Differential Absorption Lidar (GSFC TROPOZ DIAL)and Langley Research Center (LaRC) Mobile Ozone Lidar (LMOL),were used to obtain vertical and temporal variation of local O3 concentration. The airborne High Altitude Lidar Observatory (HALO) system was used to detect the regional aerosol characteristic during this episode. The complex relationship between ozone and aerosol characteristics of wildfire emission layers was investigated. The HYSPLIT back-trajectory of the measured air parcel shows that the increase of the O3 concentration and aerosol backscatter are attributed to the significant wildfires in the Pacific Northwest and British Columbia regions during August 2018. Through correlation analyses, unique clustering relationships are identified between ozone and aerosol for different air mass types. This case study is further investigated in relation to satellite data from MODIS, MISR and CALIPSO to characterize plume behavior during transport. The importance of wildfire emission transport will be discussed in context of its impact to surface air quality at significant distances from fire events.

Liqiao Lei↗

NASA NTRSDate not supplied

Assessment of Long-term Trends in the Collection 4 Total Ozone Record from the Ozone Monitoring Instrument

Long-term changes in total ozone affect the amount of harmful UV radiation reaching Earth’s surface and reflect progress made towards recovery of stratospheric ozone. Satellite total ozone data are also used to estimate long-term trends in tropospheric ozone, a reactive and potent greenhouse gas, by subtracting the stratospheric column timeseries from that of total ozone. For these scientific applications, the long-term stability should be better than 1%. Left unchecked, instrument calibration drift can produce a trend of this magnitude or greater. NASA has produced nearly twenty years of total ozone data from the Ozone Monitoring Instrument (OMI) using the Total Ozone Mapping Spectrometer (TOMS) algorithm. The drift in the OMI instrument as monitored by ice radiance calibration has been relatively slow, but it has reached a level of ~3% over the mission lifetime. This drift was corrected in the recently released Collection 4 OMI calibrated radiances, updating the Collection 3 calibration released in 2006. We have reprocessed the OMI total ozone record using the Collection 4 calibration and updates to the TOMS algorithm. We summarize these changes and evaluate their impact by comparing to the previous Collection 3 OMI dataset, the Suomi NPP Ozone Mapping and Profiler Suite Nadir Mapper (OMPS-NM) and Solar Backscatter UV (SBUV) Merged Ozone Dataset (MOD) total ozone records and other independent satellite total ozone datasets. Climatological radiance residuals from OMI and OMPS-NM are calculated and compared to investigate differences in spectral calibration that can cause drifts in long-term total ozone trends. We also analyze the tropospheric ozone record produced using the Collection 4 OMI total ozone and stratospheric column ozone from MLS. Collection 3 OMI data processed with the TOMS algorithm show a positive drift relative to other satellite and ground-based data of 1-2 DU per decade. Initial results show that this drift is reduced in Collection 4 OMI, due to the updated OMI calibration. In this work we will quantify the improvements in Collection 4 OMI relative to independent data sources at both the ozone and radiance level

Collection 4 OMI Total Ozone↗

NASA NTRS2003

Convective Lofting Links Indian Ocean Air Pollution to Paradoxical South Atlantic Ozone Maxima

We describe a broad resolution of the "Atlantic Paradox" concerning the seasonal and geographic distribution of tropical tropospheric ozone. We describe periods of significant maximum tropospheric O3 for Jan.-April, 1999, exploiting satellite estimates and SHADOZ (Southern Hemisphere Additional Ozonesondes). Trajectory analyses connecting sondes and Total Tropospheric Ozone (TTO)O3 maps suggest a complex influence from the Indian Ocean: beginning with mixed combustion sources, then low level transport, cumulonimbus venting, and finally high-level transport to the west, with possible mixing over Africa. For the Jan.- March highest column-O3 periods in the Atlantic, distinct sounding peaks trace to specific NO sources, especially lightning, while in the same episodes, recurring every 30 or 60 days, more diffuse buildups of Indian-to-Atlantic pollution make important contributions.

Chatfield, Robert B.↗