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At least 289 records · Page 16

Zero Trust Cybersecurity: Concepts and Models for Application

Zero Trust is a cybersecurity paradigm centered on the idea that a network breach is inevitable and so no user or asset should be implicitly trusted. Entities on the network are continuously monitored and access-granting decisions are based on dynamic risk assessment using multiple inputs. To limit the damage from an attack, privileges and lateral access are constrained by default. This report provides an overview of current models and constructs employed in building out these concepts into a zero trust architecture.

97 MATHEMATICS AND COMPUTING↗

Broad Frequency Shift of Parametric Processes in Epsilon-Near-Zero Time-Varying Media

The ultrafast changes of material properties induced by short laser pulses can lead to a frequency shift of reflected and transmitted radiation. Recent reports highlight how such a frequency shift is enhanced in spectral regions where the material features a near-zero real part of the permittivity. Here, we investigate the frequency shift for fields generated by four-wave mixing. In our experiment, we observed a frequency shift of more than 60 nm (compared to the pulse width of ~40 nm) in the phase conjugated radiation generated by a 500 nm aluminium-doped zinc oxide (AZO) film pumped close to the epsilon-near-zero wavelength. Our results indicate applications of time-varying media for nonlinear optics and frequency conversion.

36 MATERIALS SCIENCE↗

Comparison of Experimental and Theoretical Zero-Lift Wave-Drag Results for Various Wing-Body-Tail Combinations at Mach Numbers up to 1.9

Comparisons are made of experimental and theoretical zero-lift wave drag for several nose shapes, wing-body combinations, and models of current airplanes at Mach numbers up to 1.0. The experimental data were obtained from tests in the Ames 6- by6-foot supersonic wind tunnel and at the NACA Wallops Island facility. The theoretical drag was found by use of linear theory utilizing model area distributions. The agreement between theoretical and experimental zero-lift wave-drag coefficients was generally very good, especially for a fuselage or for fuselage-wing combinations that were vertically symmetrical. For other models that had rapid changes in body shape and/or were not vertically symmetrical, the agreement of theory with experiment ranged from fair to poor, depending on the severity of the change in shape.

DRAG COEFFICIENT↗

Design of an Auto-zeroed, Differential, Organic Thin-film Field-effect Transistor Amplifier for Sensor Applications

Organic strain gauge and other sensors require high-gain, precision dc amplification to process their low-level output signals. Ideally, amplifiers would be fabricated using organic thin-film field-effect transistors (OTFT's) adjacent to the sensors. However, OTFT amplifiers exhibit low gain and high input-referred dc offsets that must be effectively managed. This paper presents a four-stage, cascaded differential OTFT amplifier utilizing switched capacitor auto-zeroing. Each stage provides a nominal voltage gain of four through a differential pair driving low-impedance active loads, which provide common-mode output voltage control. p-type pentacence OTFT's are used for the amplifier devices and auto-zero switches. Simulations indicate the amplifier provides a nominal voltage gain of 280 V/V and effectively amplifies a 1-mV dc signal in the presence of 500-mV amplifier input-referred dc offset voltages. Future work could include the addition of digital gain calibration and offset correction of residual offsets associated with charge injection imbalance in the differential circuits.

large-area electronics↗

Zero Trust and Identity Access Management in Support of Service-Based Urban Air Mobility Applications

Urban Air Mobility environments will contain of a collection of service-based services, which will be typically hosted within cloud infrastructures. The underlying data for these UAM services will need to be secured. One approach to securing these UAM services would be to leverage the Zero Trust framework, that focuses on securing services and associated data, instead of securing the network. An early step in moving towards a Zero Trust framework is to standardize identity access manage support for an ever-widening set of services, where users must explicitly be granted access to each service.

UAM↗

Zero-Trust Architecture for Autonomous Edge Computing

We are at the apex of an aviation revolution where autonomy will play a central role in enabling complex, multi-agent systems to communicate, interact, and collaborate on a myriad of applications spanning autonomous swarms to wild-fire management. Autonomy is not an absolute but rather a spectrum ranging from a system requiring significant human intervention to one requiring little to none [1]. For example, the extreme, in the case of an autonomous aircraft, is one that operates independently in the airspace interacting with all other elements (air traffic controllers, other pilots) as if it were a human pilot. Critical to this vision is an architecture that enables autonomous agents to interact with minimal latency. Edge computing is an emerging architecture where compute and storage is pushed to the ‘edge’ of the network in order to minimize the round-trip time from agent to resource thereby mitigating the latency associated with cloud-only based approaches. Additionally, services can generate massive amounts of data (e.g., video feeds), which may require analysis in near real-time. Moving this data to the cloud for further processing may not be feasible due to latency, bandwidth, and cost. Privacy, security, and reliability can also be improved by edge computing architectures. However, this geo-distributed and dynamic* architecture complicates the establishment of unambiguous network security boundaries and can lead to vulnerabilities including man in the middle attacks, replay attacks, physical security breaches of edge nodes, signal interception, etc. This motivates the need for zero-trust architectures [2–4] which de-emphasize the notion of static network perimeters and, as the name implies, do not instill any innate trust in any particular agent. It is required that all agents must be authorized and approved in every transaction. In this paper, we present a zero-trust architecture suitable for edge-computing applications that demand significant low-latency, security, privacy, and reliability.

zero trust↗

CFD Modeling & Validation of Single Bubble Growth During Cavitation in Zero Gravity

Cryogenic Fluid Management (CFM) in zero gravity represents a vital area of research as NASA pursues future long-duration space missions. Success of these missions relies heavily on the ability to store and transfer the cryogenic liquid fuels efficiently and safely. In the Zero Boil-Off Tank (ZBOT-1) Experiment in 2018, unexpected and intense phase change occurred at the screened Liquid Acquisition Device (LAD) during tank pressure control that was later attributed to cavitation. The cavitation ultimately resulted in pump failure. Since cryogen cavitation during storage and transfer of propellants in microgravity has been a source of serious concern for the aerospace community, a series of drop tower experiments with liquid methane were also performed at the University of Bremen to carefully study cavitation from a single bubble nucleus in an engineered micron-sized wall cavity. As the test cell is depressurized during the 10-second drop, cavitation causes bubble growth from the nucleus. Here, in a collaboration between the Case Western Reserve University and University of Bremen, we present a two-phase Computational Fluid Dynamics (CFD) model of bubble growth from a single wall cavity during depressurization in microgravity. Both 2D axisymmetric and 3D parametric simulation case studies are performed to show the evolution of the bubble growth. The model uses a Volume of Fluid (VOF) approach with and without adaptive mesh refinement and adaptive time stepping to capture the growth dynamics using an explicit formulation with algebraic reconstruction of the interface. CFD results show good agreement with corresponding experiment. Based on the velocity, temperature, and volume fraction fields generated by the validation case studies, detailed discussion and analysis of fluid flow and heat transfer during bubble growth process are presented to delineate the intricacies of the cavitation process. Strengths and shortcomings of the present numerical approach in capturing this phenomenon are also highlighted.

Two Phase Flow↗

Achieving Economy-wide Net-Zero Emissions: Is it an impossible goal?

Meeting growing energy demands while eliminating emissions, maintaining affordability, and ensuring energy justice is one of the most significant grand challenges of our time. Governments and private industry around the world have established aggressive goals to achieve net-zero emissions by mid-century. In the U.S., this equates to a net-zero electricity sector by 2035 and across all energy use sectors—including electricity, industry, and transportation—by 2050. The key question then becomes: Can we get there from here? Meeting these aggressive goals demands immediate action, and they require us to think more holistically about our clean energy options. Currently, almost 85% of global energy demands are met by unabated fossil fuels. That means we have a lot of work to do, and we need to consider all of the non-emitting generation options available in each region—including fossil with carbon capture, renewables, and nuclear. And we need to reach our goal while establishing energy justice, which refers to the goal of achieving equity in social and economic participation in the energy system, while remediating past social, economic, and health burdens on communities that have been brought about by our energy system. This presentation will describe U.S. and global efforts focused on novel energy system solutions that strive to maximize use of all clean energy generation options to meet our energy demands, while ensuring sustainability, customer affordability, and a just energy system.

08 HYDROGEN↗

Enabling a Sustainable Future: Zero-Emission Vehicles Cost Analysis to Inform Decarbonization Pathways

Despite being only 5% of vehicles on the road, medium- and heavy-duty vehicles (MHDVs) are the second largest contributor to transportation emissions (21%) and a major source of local air pollution disproportionally affecting disadvantaged communities. This talk summarizes a cost analysis for zero emissions vehicles (battery electric EVs and hydrogen fuel cell FCEVs) for all medium and heavy duty applications, ranging from large pick-up trucks, to delivery vans, buses, and heavy trucks. Results show that with continued improvements in vehicle and fuel technologies (in line with U.S. Department of Energy targets and vetted with industry), zero-emission vehicles (ZEVs) can reach total-cost-of-driving parity with conventional diesel vehicles by 2035 for all medium- and heavy-duty (MD/HD) vehicle classes without incentives. Assuming economics drives adoption, ZEV sales could reach 42% of all MD/HD trucks by 2030, reflecting lower combined vehicle purchase and operating costs (using real-world payback periods). Two technological solutions - battery electric vehicles (BEVs) and fuel cell electric vehicles (FCEVs) - are viable in multiple market segments, offering alternative pathways for decarbonization: a) BEVs tend to become cost-competitive for smaller trucks before 2030 and for short-haul (<500-mile) heavy trucks before 2035. b) Hydrogen FCEVs tend to become cost-competitive for long-haul (>500-mile) heavy trucks by 2035. Results are very sensitive to technology improvement trajectories, adoption decision-making, and uncertain assumptions about future freight demand, logistics, and vehicle use explored in multiple scenarios.

ADVANCED PROPULSION SYSTEMS,ENERGY PLANNING, POLIC↗

Achieving a Net-Zero Future: The Role of Nuclear Energy

Governments and private industry around the world have established aggressive goals to achieve net-zero emissions for the power, industrial, and transportation sectors by 2050. These aggressive goals demand immediate action if we are to be successful, and they require us to think more holistically about our clean energy options. Programs within the U.S. Department of Energy (DOE) are addressing these holistic solutions. Traditionally, electricity generation and management are considered independently from meeting energy demands for industry and transportation. As we seek to eliminate emissions across all energy use sectors we need to reassess how energy demands are met. When we consider overall energy use, only one-third is in the form of electricity. Additional energy demands are in the form of heat or steam for industrial processes, in addition to direct fuel use for transportation. These sectors are much harder to abate, and electrification may not be the best option. Reducing environmental emissions at an affordable cost, while maintaining grid reliability and resilience, will require us to leverage all of the clean energy resources available. The DOE Office of Nuclear Energy (DOE-NE) program on Integrated Energy Systems (IES) is led by researchers at Idaho National Laboratory (INL), and work is conducted in partnership with an array of other DOE laboratories, industry, and academia. The primary focus of IES research is to assess the technical and economic potential of nuclear-driven IES to enhance the flexibility and utilization of nuclear reactors working alongside renewable generators to meet an array of energy demands—thereby maximizing the utilization of clean energy resources across all energy sectors. Various energy applications and product streams beyond electricity are being evaluated, ranging from generation of potable water to production of hydrogen, fertilizers, synthetic fuels, and various chemicals. The DOE-NE program additionally partners with the Hydrogen and Fuel Cell Technologies Office under the DOE Office of Energy Efficiency and Renewable Energy to jointly fund the development of analysis tools, technologies, and nuclear-integrated hydrogen demonstration projects. This presentation will highlight the wide array of R&D being conducted across multiple DOE-funded programs to develop and deploy nuclear-based IES that will be key to achieving our net-zero goals. By working with key collaborators in the nuclear industry, analytical studies are now becoming a reality in demonstration projects.

08 HYDROGEN↗

Developing an AI-Powered Zero-Trust Cybersecurity Framework for Malware Prevention in Nuclear Power Plants

This study presents the development of an AI-powered Zero-Trust cybersecurity framework for malware prevention in nuclear power plants. The framework aims to enhance the security of critical systems within nuclear power plants by adopting the principles of Zero-Trust and leveraging artificial intelligence (AI) technologies. By assuming no implicit trust in any user or device and continuously authenticating and authorizing access, the framework ensures a robust defense against malware attacks. The integration of AI allows for the detection and prevention of malware through behavioral analytics, endpoint protection, network segmentation, and continuous monitoring. The paper discusses the key considerations, steps, and technologies involved in developing this framework, emphasizing the importance of regular updates, training, compliance, and auditing. The proposed framework serves as a comprehensive approach to safeguarding nuclear power plants from sophisticated malware threats and protecting the integrity and safety of critical infrastructure.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

The Importance of Decarbonylation Mechanisms in the Atomic Layer Deposition of High-Quality Ru Films by Zero-Oxidation State Ru(DMBD)(CO) 3

Achieving facile nucleation of noble metal films through atomic layer deposition (ALD) is extremely challenging. To this end, η 4 -2,3-dimethylbutadiene ruthenium tricarbonyl (Ru(DMBD)(CO) 3 ), a zero-valent complex, has recently been reported to achieve good nucleation by ALD at relatively low temperatures and mild reaction conditions. Here, we study the growth mechanism of this precursor by in situ quartz-crystal microbalance and quadrupole mass spectrometry during Ru ALD, complemented by ex situ film characterization and kinetic modeling. These studies reveal that Ru(DMBD)(CO) 3 produces high-quality Ru films with excellent nucleation properties. This results in smooth, coalesced films even at low film thicknesses, all important traits for device applications. However, Ru deposition follows a kinetically limited decarbonylation reaction scheme, akin to typical CVD processes, with a strong dependence on both temperature and reaction timescale. The non-self-limiting nature of the kinetically driven mechanism presents both challenges for ALD implementation and opportunities for process tuning. By surveying reports of similar precursors, we suggest that the findings can be generalized to the broader class of zero-oxidation state carbonyl-based precursors used in thermal ALD, with insight into the design of effective saturation studies.

chemical vapor deposition↗

Generalized parton distributions through universal moment parameterization: non-zero skewness case

We present the first global analysis of generalized parton distributions (GPDs) combing lattice quantum chromodynamics (QCD) calculations and experiment measurements including global parton distribution functions (PDFs), form factors (FFs) and deeply virtual Compton scattering (DVCS) measurements. Following the previous work where we parameterize GPDs in terms of their moments, we extend the framework to allow for the global analysis at non-zero skewness. Together with the constraints at zero skewness, we fit GPDs to global DVCS measurements from both the recent JLab and the earlier Hadron-Electron Ring Accelerator (HERA) experiments with two active quark flavors and leading order QCD evolution. With certain choices of empirical constraints, both sea and valence quark distributions are extracted with the combined inputs, and we present the quark distributions in the proton correspondingly. We also discuss how to extend the framework to accommodate more off-forward constraints beyond the small ξ expansion, especially the lattice calculated GPDs.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Pressure-induced cation and vacancy disorder-order transition and near-zero τ f in deficient hexagonal perovskite Ba 8 ZnTa 6 O 24 dielectrics

Pressure applications can enable the tuning of atomic/defect ordering and provide access to new functional materials. Here, in this study, we report that pressure-induced structural transformation featuring disorder-order transition of both cations and vacancies in the 8-layer deficient hexagonal perovskite tantalate dielectrics Ba 8 ZnTa 6 O 24 , which transformed the structure from twin to shift and remarkably lowered the temperature coefficient of resonant frequency τ f down to near zero (∼0.56 ppm/°C) from 38 ppm/°C for the twinned precursor. The atomic scale STEM-HAADF and EDS results confirm the ordering of Zn in the Ta host at the nanometer scale in the shifted material featuring well-ordered Ba 8 ZnTa 6 O 24 slabs intergrown with Ba 3 ZnTa 2 O 9 and Ba 5 Ta 4 O 15 monolayers and anti-phase grain boundaries as planar defects. The pressure-induced twin-shift structural transformation of Ba 8 ZnTa 6 O 24 features the rare constant concentration of the hexagonal stacked layers, which is allowed by the vacancy ordering at the central layers of face-shared octahedral (FSO) trimers avoiding the FSO B-B repulsion, and remarkably the faster cationic ordering kinetics compared with the 2:1 ordered complex perovskites. Although the inclusion of numerous planar defects and the oxidizable atomic defects led to significant p-type conduction and inhomogeneous electrical microstructures, resulting in an extraordinarily high extrinsic dielectric loss for the high-pressure shifted Ba 8 ZnTa 6 O 24 pellet, the intrinsically near-zero τ f could make the shifted Ba 8 ZnTa 6 O 24 perovskite an ideal microwave dielectric resonator candidate if the defects could be eliminated.

high pressure↗

Integration of hydrophobic gas diffusion layers for zero-gap electrolyzers to enable highly energy-efficient CO 2 electrolysis to C 2 products

Electrochemical CO 2 reduction (eCO2R) is an attractive route for mitigating global CO 2 emissions while producing value-added chemicals. Ethylene is one product of eCO2R and is an essential industrial precursor with a global market of $230 billion. The large-scale implementation of C 2 H 4 -selective CO 2 electrolyzers remains challenging because of low energy efficiencies. In this work, we develop the design principles necessary for incorporating an expanded polytetrafluoroethylene (ePTFE) electrode into a zero-gap electrolyzer while simultaneously developing an integrated electrical front contact that reduces the ohmic resistances inherent to electrically insulating gas diffusion layers. By co-designing the catalyst layer, gas diffusion medium, and operating conditions for a zero-gap ePTFE gas diffusion electrode (GDE), we achieved a full-cell voltage of 2.5 V at 200 mA cm −2 at 25 cm 2 geometric area cell with Faradaic efficiencies of 48% for ethylene and 40% for ethanol. This work highlights strategies for developing a scalable, stable, and highly energy-efficient eCO2R for C 2 products.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

SAM-I-Am: Semantic boosting for zero-shot atomic-scale electron micrograph segmentation

Image segmentation is a critical enabler for tasks ranging from medical diagnostics to autonomous driving. However, the correct segmentation semantics — where are boundaries located? what segments are logically similar? — change depending on the domain, such that state-of-the-art foundation models can generate meaningless and incorrect results. Moreover, in certain domains, fine-tuning and retraining techniques are infeasible: obtaining labels is costly and time-consuming; domain images (micrographs) can be exponentially diverse; and data sharing (for third-party retraining) is restricted. To enable rapid adaptation of the best segmentation technology, we propose the concept of semantic boosting: given a zero-shot foundation model, guide its segmentation and adjust results to match domain expectations. Here, we apply semantic boosting to the Segment Anything Model (SAM) to obtain microstructure segmentation for transmission electron microscopy. Our booster, SAM-I-Am, serves as a post-processing engine that extracts geometric and textural features of various intermediate masks to perform mask removal and mask merging operations. We demonstrate a zero-shot performance increase of (absolute) +21.35%, +12.6%, +5.27% in mean IoU, and a -9.91%, -18.42%, -4.06% drop in mean false positive masks across images of three difficulty classes over vanilla SAM (ViT-L).

36 MATERIALS SCIENCE↗

Transportation in net-zero emissions futures: Insights from the EMF-37 model intercomparison study

Transportation is currently the largest source of U.S. anthropogenic CO 2 emissions, at about a third of the total. Achieving net-zero emissions by mid-century will require substantial reductions in transportation emissions across passenger and freight travel. Here we leverage a model intercomparison study to explore the role of transportation in scenarios achieving net-zero economy-wide CO 2 emissions by 2050. We find the transport sector is poised to play the most significant role in reducing demand-side emissions, mostly driven by technology substitution, as modeling results suggest a limited role for mode shifting and for reduced use of personal car travel in the U.S. Among various technology solutions, models show agreement that passenger on-road vehicles will largely transition to electric vehicles (EVs), while solutions to decarbonize heavier travel modes are more diverse and include greater use of liquid biofuels and hydrogen. Research should continue to investigate the evolution of on-road electrification, the role of biofuels and hydrogen across heavier travel modes, and the role of mode shifting and travel behavior change to support personal transportation decarbonization at national and regional scales to temper the rapid growth in clean fuel and electricity demand.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Quantifying policy gaps for achieving the net-zero GHG emissions target in the U.S. light-duty vehicle market through electrification

The U.S. light-duty vehicle (LDV) industry, a major greenhouse gas (GHG) emitting sector, is embracing decarbonization. Considering only electrification pathways, this study uses publicly-available tools – MA3T and VISION on vehicle market penetration, fleet accounting and life-cycle analysis to quantify the policy gaps for LDVs to achieve the net-zero GHG emissions target in nine vehicle penetration cases under two electricity mix scenarios, including the U.S. administration's decarbonization strategy – 100% clean electricity by 2035. The MA3T model is a multinomial discrete choice model for market share projection by vehicle technology, and the VISION is a vehicle stocks and GHG emissions projection model by using vehicle and travel characteristics. This study projects the impacts of technology and policy enforcement on shaping the dynamics and decarbonization of the LDV market. Additionally, achieving the expected improvement of battery technology and charging infrastructure is critical but can only reduce the 2050 GHG emissions to 48–54% of the 2020 level under the electricity renewable mix scenario. It is almost impossible to achieve a 100% battery electric vehicle stock by 2050 and the 2050 net-zero target in the LDV industry unless ban of internal combustion engine technology is implemented starting in 2035 and under the 2035 100% clean electricity scenario. These extreme conditions also sacrifice most from the consumer welfare perspective. A greater policy forcing intensity accelerates plug-in electric vehicle penetration, while with declining marginal effect and reduced consumer welfare. Among the investigated policy scenarios, the policy forcing intensity equivalent to a fuel tax of $1–2 per gasoline gallon reduces the most GHG emissions while keeping a positive consumer welfare.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗