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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 307 records · Page 17
All sourcesNASA NTRSDOE OSTI
DOE OSTI2018

Air turbulence characteristics at multiple sites in and above the Amazon rainforest canopy

Atmospheric turbulence characteristics within and above rain forest canopies are investigated at several sites located in the Amazon region of Brazil. Turbulence data provided by bi- and three-dimensional sonic anemometers, which were deployed at heights ranging from near the forest floor to about 80 m, are analyzed to describe the principal features of atmospheric turbulence, sensible heat flux (H), and components of the turbulent kinetic energy (TKE) budget equation. The analyses focused on weak (WW) and strong (SW) wind conditions to achieve the research objectives of evaluating the turbulence structure above and below the rain forest canopy and estimating the degree of coupling between air layers above the forest and deep in the canopy. Turbulence statistical moments show that atmospheric eddies, generated above the canopy, hardly penetrate the region below 0.5h (h is the canopy height). Forest-atmosphere exchanges of heat differ depending on the observed wind regimes. Sensible heat fluxes decrease with canopy depth for SW conditions and are approximately constant with the height for WW above the canopy. Sensible heat flux profiles reveal a transition layer (around 0.6h) which sometimes exchanges heat with the upper and sometimes with the lower forest canopy, depending on time of day and weather conditions. TKE balance results show that during the daytime period in SW conditions the shear production is at least an order of magnitude greater than the buoyancy above the forest canopy. This turbulence, however, is practically all dissipated in the region above 0.5h. Thus, the air layer from the soil surface to 0.5h is largely decoupled from the upper part of the forest canopy. This feature of having the bottom of the canopy mostly decoupled from the air aloft in the dense and tall rain forest can exert control on the residence times and turbulent transport of plant-emitted gases out of the forest canopy.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2022

Turbulent transport and reactions of plant-emitted hydrocarbons in an Amazonian rain forest

The processes governing the temporal and spatial patterns of isoprene and monoterpenes emitted by a rainforest in the central Amazon region of Brazil is investigated using a combination of field experiments and numerical simulations. Specifically, Large Eddy Simulations (LES) were used to resolve emissions of isoprene and monoterpenes, turbulent transport, and air chemistry. The coupled chemistry-transport LES included the effects of isoprene and monoterpenes reactivity due to reactions with hydroxyl radical and ozone. The LES results are used to compute vertically resolved budgets of isoprene and monoterpenes in the rainforest canopy in response to emissions, turbulent transport, surface deposition, and air chemistry. Our results indicated that emission and dispersion dominated the isoprene budget as the gases were transported out of the canopy space. In a region limited by nitrogen oxides (with prevailing nitric oxide levels of < 0.5 parts per billion), the in-canopy chemical destruction removed approximately 10% of locally emitted monoterpenes. Hydroxyl radical production rates from the ozonolysis of monoterpenes amounted to ≈ 2 x 10 6 radicals cm -3 s -1 and had similar magnitude to the light-dependent hydroxyl radical formation. One key conclusion was that the Amazonia rainforest abundantly emitted monoterpenes whose in-canopy ozonolysis yielded hydroxyl radicals in amounts similar to the magnitude of light-dependent formation. Reactions of monoterpenes and isoprene with hydroxyl radical and ozone were necessary for the maintenance of the Amazon rainforest canopy as a photochemically active environment suitable to generate oxidants and secondary organic aerosols.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2020

The impacts of building characteristics, social psychological and cultural factors on indoor environment quality productivity belief

Indoor environmental quality (IEQ) plays a key role in determining occupants' productivity at work; however, analyses of the interconnected factors among building physical, attitudinal, social and demographic components in one study are lacking. To fill this research gap, this study investigates these interconnected factors' influence on occupants’ IEQ-productivity belief, defined as a personal, subjective evaluation of the linkage between the impacts of five IEQ aspects (the quality of indoor temperature, air, natural and electric lighting, and acoustics) and productivity. A cross-sectional survey data was collected in university offices from six countries (Brazil, Italy, Poland, Switzerland, Taiwan and the U.S.). Results of multiple linear regression models indicate that IEQ satisfaction is the strongest positive predictor of the IEQ-productivity belief and this relationship is stronger in private offices. Country of residence is the second primary predictor. Several attitudinal-behavioral factors, including thermal comfort, perceived ease of controlling indoor environmental features, and attitudes toward sharing controls are all positively associated with IEQ-productivity belief. Interestingly, the level of control accessibility to light switches has the strongest impact as opposed to other controls. On the other hand, group norms and conformity intention are not significant predictors. Regarding demographics, men are more likely than women to perceive the IEQs to have positive impacts on their productivity, without considering other variables in the regression model; however, women are more likely than men to consider all IEQs as having positive impacts on productivity, after considering other variables. Furthermore, our findings provide suggestions for prioritizing wellness in the workplace since the early design stage.

99 GENERAL AND MISCELLANEOUS↗
DOE OSTI2021

Intersecting heuristic adaptive strategies, building design and energy saving intentions when facing discomfort environment: A cross-country analysis

Occupants' adaptive strategies play an important role in the energy consumption of office buildings. Previous research has mostly focused on the adaptive strategies triggered by occupants' indoor discomfort; however, it is crucial to understand if specific adaptive strategies are linked to occupants' energy-saving intentions. This study explores the relationships among employees’ heuristic decision-making in their first choice of adaptive strategies (technological solutions or personal adjustments) when facing extreme discomfort conditions, and their energy-saving intentions, then links these patterns with building design, workplace contextual factors, and demographics. A cross-sectional survey was collected among university employees from China, Brazil, Italy, Poland, Switzerland, and the US. Our results demonstrated that the accessibility to indoor environmental controls (IECs) and office type are the significant factors for adaptive strategies. There was a positive relationship between the number of IEC features and the percentage of employees choosing a technological solution. When feeling too hot, occupants in private offices are more likely to adopt a technological solution, whereas occupants in cubicles are more likely to choose a personal adjustment. Occupants with energy-saving intentions are less likely to choose thermostat adjustments or use portable devices as adaptive strategies than their counterparts. Lastly, the cluster analysis suggests females were more likely to use adaptive strategies for energy-saving purposes than males. The majority of occupants would turn on/off lighting to save energy. The study provides the contributions in the connection between the heuristic decision-making process and energy-saving intentions and recommendations on design strategies for building architects, engineers, and managers.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2025

Refining seasonal performance metrics for room air-conditioning in emerging markets: Integrating building simulations with real-world equipment performance data

Buildings significantly impact worldwide energy consumption, emphasizing the need to reduce the cooling energy demand, especially in warm climates. Minimum energy performance standards (MEPS) and seasonal performance metrics such as the Cooling Seasonal Performance Factor (CSPF) are crucial for improving room air conditioning (RAC) efficiency. However, challenges remain, particularly in emerging markets like Brazil, where seasonal performance metrics have recently been introduced. This study assesses the factors influencing country-level seasonal efficiency metrics and proposes a framework to refine these calculations by considering local climates and expected RAC usage in real-world households via building simulations. Key considerations include outdoor air temperature binning for different climates, RAC usage patterns (i.e., daytime and nighttime usages), envelope thermal performance of households, and urban heat island (UHI) effects. The results reveal that CSPF values can vary significantly based on climate conditions, with observed CSPF ranging from 4.10 to 11.59 Wh/Wh across 577 Brazilian climates. The inclusion of UHI effects led to a reduction in CSPF values by up to 29% during nighttime operations in hot urban areas. Additionally, building envelope efficiency showed contrasting impacts on RAC performance, with CSPFs reaching up to 15.35 Wh/Wh under specific optimized conditions. These findings highlight the need for transparent policymaking in RAC performance databases, facilitating the application of approaches like those proposed in this study and supporting diverse stakeholders in decision-making.

Bavaresco, Mateus↗
DOE OSTI2020

Manganese: The overlooked contaminant in the world largest mine tailings dam collapse

Manganese (Mn) is an abundant element in terrestrial and coastal ecosystems and an essential micronutrient in the metabolic processes of plants and animals. Mn is generally not considered a potentially toxic element due to its low content in both soil and water. However, in coastal ecosystems, the Mn dynamic (commonly associated with the Fe cycle) is mostly controlled by redox processes. Here, we assessed the potential contamination of the Rio Doce estuary (SE Brazil) by Mn after the world’s largest mine tailings dam collapse, potentially resulting in chronic exposure to local wildlife and humans. Estuarine soils, water, and fish were collected and analyzed seven days after the arrival of the tailings in 2015 and again two years after the dam collapse in 2017. Using a suite of solid-phase analyses including X-ray absorption spectroscopy and sequential extractions, our results indicated that a large quantity of Mn II arrived in the estuary in 2015 bound to Fe oxyhydroxides. Over time, dissolved Mn and Fe were released from soils when Fe III oxyhydroxides underwent reductive dissolution. Due to seasonal redox oscillations, both Fe and Mn were then re-oxidized to Fe III , Mn III , and Mn IV and re-precipitated as poorly crystalline Fe oxyhydroxides and poorly crystalline Mn oxides. In 2017, redox conditions (Eh: -47 ± 83 mV; pH: 6.7 ± 0.5) favorable to both Fe and Mn reduction led to an increase (~880%) of dissolved Mn (average for 2015: 66 ± 130 μg L -1 ; 2017: 582 ± 626 μg L -1 ) in water and a decrease (~75%, 2015: 547 ± 498 mg kg -1 ; 2017: 135 ± 80 mg kg -1 ) in the total Mn content in soils. The crystalline Fe oxyhydroxides content significantly decreased while the fraction of poorly ordered Fe oxides increased in the soils limiting the role of Fe in Mn retention. The high concentration of dissolved Mn found within the estuary two years after the arrival of mine tailings indicates a possible chronic contamination scenario, which is supported by the high levels of Mn in two species of fish living in the estuary. Our work suggests a high risk to estuarine biota and human health due to the rapid Fe and Mn biogeochemical dynamic within the impacted estuary.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2018

Soil carbon inventory to quantify the impact of land use change to mitigate greenhouse gas emissions and ecosystem services

We report that currently the land use and land use change (LULUC) emits 1.3 ± 0.5 Pg carbon (C) year -1 , equivalent to 8% of the global annual emissions. The objectives of this study were to quantify (1) the impact of LULUC on greenhouse gas (GHG) emissions in a subtropical region and (2) the role of conservation agriculture to mitigate GHG emissions promoting ecosystem services. We developed a detailed IPCC Tier 2 GHG inventory for the Campos Gerais region of southern Brazil that has large cropland area under long-term conservation agriculture with high crop yields. The inventory accounted for historical and current emissions from fossil fuel combustion, LULUC and other minor sources. We used Century model to simulate the adoption of conservation best management practices, to all croplands in the region from 2017 to 2117. Our results showed historical (1930 – 2017) GHG emissions of 412 Tg C, in which LULUC contributes 91% (376±130 Tg C), the uncertainties ranged between 13 and 36%. Between 1930 and 1985 LULUC was a major source of GHG emission, however from 1985 to 2015 fossil fuel combustion became the primary source of GHG emission. Forestry sequestered 52 ± 24 Tg C in 0.6 Mha in a period of 47 years (1.8 Tg C Mha -1 year -1 ) and no-till sequestered 30.4 ± 24 Tg C in 2 Mha in a period of 32 years (0.5 Tg C Mha -1 year -1 ) being the principal GHG mitigating activities in the study area. Lastly, the model predictions showed that best management practices have the potential to mitigate 13 years of regional emissions (330 Tg C in 100 years) or 105 years of agriculture, forestry and livestock emissions (40 Tg C in 100 years) making the agriculture sector a net carbon (C) sink and promoting ecosystem services.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2023

Dual origin of ferropericlase inclusions within super-deep diamonds

Ferropericlase [(Mg,Fe)O] is one of the major constituents of Earth's lower mantle and the most abundant mineral inclusion in sub-lithospheric diamonds. Although a lower mantle origin for ferropericlase inclusions has often been suggested, some studies have proposed that many of these inclusions may instead form at much shallower depths, in the deep upper mantle or transition zone. No straightforward method exists to discriminate ferropericlase of lower-mantle origin without characteristic mineral associations, such as co-existing former bridgmanite. To explore ferropericlase-diamond growth relationships, we have investigated the crystallographic orientation relationships (CORs), determined by single-crystal X-ray diffraction, between 57 ferropericlase inclusions and 37 diamonds from Juina (Brazil) and Kankan (Guinea). We show that ferropericlase inclusions can develop specific (16 inclusions in 12 diamonds), rotational statistical (9 inclusions in 7 diamonds) and random (32 inclusions in 25 diamond) CORs with respect to their diamond hosts. All measured inclusions showing a specific COR were found to be Fe-rich (X FeO > 0.30). Coexistence of non-randomly and randomly oriented ferropericlase inclusions within the same diamond indicates that their CORs may be variably affected by local growth conditions. However, the occurrence of specific CORs only for Fe-rich inclusions indicates that Fe-rich ferropericlases have a distinct genesis and are syngenetic with their host diamonds. In conclusion, this result provides strong support for a dual origin for ferropericlase in Earth's mantle, with Fe-rich compositions likely indicating redox growth in the upper mantle, while more Mg-rich compositions with random COR mostly representing ambient lower mantle trapped as protogenetic inclusions.

58 GEOSCIENCES↗
DOE OSTI2023

Exploring sustainable electricity system development pathways in South America’s MERCOSUR sub-region

South America has abundant natural water and energy resources, and exploiting these resources to achieve a clean energy future is central to the continent’s economic and sustainable development objectives for the next several decades. Designing pathways to achieving this clean energy future requires better understanding the structural, techno-economic, and policy forces that may influence the future development of the electricity sector in the region. Here, we focus on an interconnected electricity system of five South American countries – Argentina, Brazil, Chile, Paraguay, and Uruguay – which represent major electricity generation, consumption, and trade dynamics in the region. We explore the implications of various forces that could shape the future composition of the power sector in the sub-region, including: evolving renewable energy cost and performance, natural gas prices, cross-border interconnection facilities, early retirement of installed hydropower, and different decarbonization goals. We use a model framework based on a power system planning platform (GridPath) to co-optimize investment and operations of generation, storage, and transmission facilities out to 2050. Our results in a Reference scenario indicate that the electricity system can maintain a relatively clean energy portfolio by leveraging existing hydropower capacity and integrating increasingly cost-competitive wind and solar power. However, dependence on natural gas in the region is likely to remain high. A low-carbon electricity system can cost-effectively be achieved through policy interventions (e.g., renewable portfolio standards) and by diversifying investments in wind, solar, battery storage, and some new hydropower capacity. We also find that existing hydropower is critical for maintaining reliable future grid operations. Enhanced regional electricity trade, mostly based on existing interconnection capacities with nominal investment in new transmission, can significantly benefit the clean energy transition in the region.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗
DOE OSTI2021

Relative effect of anthropogenic warming and natural climate variability to changes in Compound drought and heatwaves

Compound drought and heatwave (CDHW) events can be influenced by large scale teleconnections and anthropogenic warming, leading to severe socio-economic impacts across various climate regions. Here, the relative influence of six different teleconnection patterns and anthropogenic global warming on the global CDHW occurrences is quantified systematically using the instrumental data period, 1982–2016. The results from the study suggest a substantial increase in the CDHW events (1–5 events per year) across various parts of the globe at the beginning of 21st century (2000–2016). A Bayesian approach is implemented to identify the most vulnerable climate regions based on the degree of susceptibility of heatwaves (DSHW) towards drought. As such, top ten most vulnerable regions are selected based on the DSHW magnitude, and a partial correlation analysis is performed to select the natural and anthropogenic drivers of CDHW in those regions, separately. A logistic regression model is then used to determine significant changes in the odds of CDHW due to changes in the selected drivers that suggest a significantly positive, and multiplicative effect of anthropogenic global warming in the top ten most vulnerable climate regions. Finally, the same logistic regression model, integrated with an analytical framework, is applied to determine the relative influence of anthropogenic global warming on the changes in odds of CDHW for the future, 1.5 °C and 2 °C warming limits. Finally, the results suggest that relative to the 2 °C global warming, constraining to the 1.5 °C global warming limit may conduce about 17-fold reduction in the odds of CDHW in the most vulnerable climate region, East Asia, 5–8-fold reduction in Western North America, Northern Australia, Central North America, Central Europe, South Asia, and the Mediterranean region, and 3–4-fold reduction in Northeastern Brazil, Eastern North America, and West Asia.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2019

Comparison of biofuel life-cycle GHG emissions assessment tools: The case studies of ethanol produced from sugarcane, corn, and wheat

The use of alternative fuels, particularly bio-based fuels, has been an important strategy to achieve greenhouse gas (GHG) emission reductions compared to petroleum-based fuels. However, discrepancies between results obtained by using different attributional life-cycle assessment (LCA) tools have challenged the credibility of the individual assessments, and as result, the progress towards or compliance with GHG mitigation targets. The objective of this study was to identify the main differences and commonalities in methodological structures, calculation procedures, and assumptions for the major commercial biofuel, ethanol, across three public LCA tools, BioGrace (EU), GHGenius (Canada), and GREET (U.S.), and a research-oriented fourth, the Virtual Sugarcane Biorefinery (VSB), a Brazilian platform for sugarcane ethanol assessments. The calculated emissions across models ranged from 16 to 45 for sugarcane, 43-62 for corn, and 45-68 g CO 2 eq MJ -1 for wheat ethanol. Harmonizing the three public models with VSB assumptions for sugarcane ethanol produced in Brazil, the range was reduced to 16-17 g CO 2 eq MJ -1 for sugarcane ethanol. Agricultural production (e.g., N 2 O emissions from fertilizers; energy and fuel use; straw field-burning; and limestone application) and ethanol shipping were found to be the major causes for variations for differences calculated for sugarcane ethanol. Similarly, harmonizing BioGrace and GHGenius calculations using GREET assumptions for U.S. corn ethanol generated nearly identical results (models varied within a 3% range). The coproduct treatment method was found to be the most influential parameter in the variations calculated for both corn and wheat ethanol. The application of the tools as part of GHG emissions accounting requirements is often defined via regulations and differences and/or conflicting assumptions set-forth in these models lead to most differences observed. Our study provides recommendations for promoting transparency in LCA calculations and assumptions across the tools used in research and development or for regulatory tools regarding biofuels.

09 BIOMASS FUELS↗
DOE OSTI2022

Zinc speciation and desorption kinetics in a mining waste impacted tropical soil amended with phosphate

Mining is an important component of the Brazilian economy. However, it may also contribute to environmental problems such as the pollution of soils with zinc and other potentially toxic metals. Our objective was to evaluate changes in the chemical speciation and mobility of Zn in a soil amended with phosphate. Soil samples were collected from a deactivated mining area in the state of Minas Gerais, Brazil, and amended with NH 4 H 2 PO 4 saturated with deionized water to 70 % of maximum water retention and incubated at 25 ± 2 °C in open containers for 60 days. The soil was chemically and mineralogically characterized, and sequential extraction, desorption kinetics, and speciation were carried out using synchrotron bulk-sample and micro–X-ray Absorption Near-Edge Structure (XANES/μ-XANES) spectroscopy at the Zn K-edge, and X-ray fluorescence microprobe analysis (μ-XRF). The combination of μ-XRF and μ-XANES techniques made it possible to identify Zn hotspots in the main species formed after phosphate remediation. The best fit combination for bulk XANES and μ-XANES was observed in Zn-montmorillonite, Zn-kerolite, Zn-ferrihydrite, and gahnite. In the course of phosphate treatment, gahnite, Zn layered double hydroxides (Zn-LDH), Zn3(PO4), and ZnO were identified by bulk XANES, while Zn-ferrihydrite, Zn-montmorillonite, and scholzite were identified by μ-XANES. Zinc in the phosphate-amended soil had the strongest partial correlations (r' > 0.05) with Ni, Co, Fe, Cr, Mn, Si, P, Cd, Pb, and Cd, while the unamended soil showed the strongest correlation with Cu, Pb, Fe, and Si. The application of NH 4 H 2 PO 4 altered Zn speciation and favored an increase in Zn desorption. Here, the most available Zn contents after phosphate amendment were correlated with the release of exchangeable Zn fractions, associated with carbonate and organic matter.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2022

Efficacy of an inactivated Senecavirus A vaccine in weaned pigs and mature sows

Senecavirus A (SVA), commonly known as Seneca Valley virus (SVV) is a causative agent for vesicular disease in swine. It has been found across the globe including the United States, Brazil, and China. Clinical disease caused by this virus is identical to foot-and-mouth disease virus (FMDV). Since FMDV has the potential to cause severe economic consequences in FMDV-free countries, those countries are on high alert for signs of vesicles in swine and an investigation is performed to rule out the presence of FMDV if observed. In countries where SVA cases have continued to occur, investigations and testing can cause a burden on personnel and resources. The objectives of this study were to test the efficacy of a whole-virus inactivated SVA vaccine against challenge in nursery-aged pigs, mature sows, and to assess the protection of passive maternal immunity generated by immunized dams. Animals were given two doses of the vaccine intramuscularly three weeks apart and challenged intranasally two weeks after the second dose. Non-vaccinated animals challenged with SVA developed clinical signs of disease, replicated virus, and developed a neutralizing antibody response. Vaccinated animals had robust neutralizing titers after two doses; and after challenge, did not develop vesicular disease and had limited rectal shedding. Piglets suckling immunized dams and challenged with SVA at 3–6 days-of-age had neutralizing titers prior to challenge and did not replicate or shed virus. An efficacious vaccine could improve swine welfare and reduce the economic consequences of continued foreign animal disease investigations.

60 APPLIED LIFE SCIENCES↗
DOE OSTI2020

Eudicot Nutshells: Cell-Wall Composition and Biofuel Feedstock Potential

Nutshells are the recalcitrant and membranous layers that encompass and provide protection to the seed of a fruit. Rich in lignin, these are often waste products of the food industry and are a potential energy-dense feedstock for biorefineries to convert to biofuels. Here, assessing their potential requires an understanding of the relative amounts of cellulose, hemicelluloses, and lignin, the composition and structure of the lignin, and a saccharifiability assessment, all provided here. In the context of understanding the general character of phylogenetically diverse eudicot species, we provide a chemical analysis of the lignin in the shells of commonly eaten nuts and detail the chemical composition of their lignins. Particularly striking observations include the >40% levels of Klason lignins in the nutshells from macadamia, pecan, and Brazil nut and lignin compositions ranging from <1% syringyl (S) in macadamia to 77% S in pistachio and essentially 0% p-hydroxyphenyl (H) in mango to as high as 7.5% H in walnut. Novel units in the lignin polymer (such as the hydroxystilbenes recently discovered in macaúba and coconut shell lignins) were not evident in any of the samples, but the series provided such a range of compositions that it aided more detailed assignment.

NMR↗
DOE OSTI2025

Kinetic Modeling of Secondary Organic Aerosol in a Weather-Chemistry Model: Parameterizations, Processes, and Predictions for GOAmazon

Secondary organic aerosol (SOA) forms and evolves in the atmosphere through many pathways and processes, over diverse spatial and time scales. Hence, there is a need to represent these widely-varying kinetic processes in large-scale atmospheric models to allow for accurate predictions of the abundance, properties, and impacts of SOA. In this work, we integrated a kinetic, process-level model (simpleSOM-MOSAIC) into a weather-chemistry model (WRF-Chem) to simulate the oxidation chemistry and microphysics of atmospheric SOA. simpleSOM-MOSAIC simulates multigenerational gas-phase chemistry, autoxidation reactions, heterogeneous oxidation, oligomerization, and phase-state-influenced gas/particle partitioning of SOA. As a case study, the integrated WRF-Chem-simpleSOM-MOSAIC (WC-SSM) model was used to simulate the photochemical evolution downwind of a large city (Manaus, Brazil) in the Amazon and, in turn, study the anthropogenic and biogenic interactions in an otherwise pristine environment. Consistent with previous work, we found that OA was enhanced by up to a factor of four in the urban plume due to elevated hydroxyl radical (OH) concentrations, relative to the background, and that this OA was dominated by SOA from biogenic precursors (80%). Further, in addition to accurately simulating the OA enhancement in the urban plume, the model reproduced the magnitude of the OA oxygen-to-carbon (O:C) ratio and broadly tracked the evolution of the aerosol size distribution. Our work highlights the importance of including an integrated, kinetic representation of SOA processes in an atmospheric model

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2025

Impacts of Precipitation Events on Concentrations of Oxygenated Gas- and Particle-Phase Compounds Observed in the Amazon

Removal of gases and particles by precipitation (wet deposition) is a critical process that significantly influences the transport and chemical transformation of atmospheric compounds. However, there are few studies that directly measure or constrain the rates of this process under real-world conditions. This work quantifies the net change in ambient concentrations during precipitation events (removal rates) of gas- and particle-phase organic compounds at a surface site near Manaus, Brazil, during the GoAmazon2014/5 campaign. Removal rates of identified and unknown compounds that have been previously classified into source-based clusters are measured during rain events and categorized based on estimated properties of compounds and clusters. Highly oxygenated gases, such as isoprene oxidation products, are removed during precipitation events with a median removal rate of 0.09 h –1 and the fastest analyte is removed at a rate of 0.22 h –1 . Removal rates of particle-phase compounds are observed at roughly this median rate, while less soluble gases, such as terpenes, exhibit low removal rates. These results are roughly in agreement with prior theoretical estimates of wet deposition rates for comparable compounds, providing an empirical point of comparison while noting that our metric reflects the net influence of precipitation events rather than wet deposition alone.

atmospheric chemistry↗
DOE OSTI2018

Low Phosphorus Availability Decreases Susceptibility of Tropical Primary Productivity to Droughts

Large uncertainties in the susceptibility of tropical forest productivity to precipitation changes hamper climate change projection. Interactions between the availabilities of water and phosphorus could theoretically either increase or decrease the susceptibility of tropical gas exchange to variation of precipitation. The inclusion of phosphorus-water interactions in a land surface model reduces the coefficient of variance, a measure of variability, of biweekly gross primary productivity by a factor of 1.5–2.3 at three tropical forest sites in Brazil, bringing it closer to estimates from eddy covariance measurements and remote sensing. Soil drought conditions are attenuated due to 8–30% lower water consumption during wet periods in presence of phosphorus limitation. When soils are dry, plant phosphorus acquisition is impaired by reduced ion mobility, despite an increase in net phosphorus mineralization. We conclude that water-phosphorus interactions cannot be omitted in analysis of the resilience of tropical ecosystems to precipitation changes.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2019

Sampling in the Dark: Challenges in Fine-Root Research

Plant roots play an essential role in the global carbon cycle, but they are often underinvestigated and underrepresented in Earth system models (ESMs). Fine roots are estimated to contribute up to 33% of terrestrial plant production, evidence of their key role in the cycling of carbon, water, and nutrients. Few root-sampling methods are nondestructive, however, and even those methods come with their own set of challenges. This January, root researchers met at Oak Ridge National Laboratory to discuss current challenges in root research. They also discussed some possible solutions that may encourage more researchers to undertake belowground projects. Meeting participants have been using minirhizotrons—instruments that use a transparent tube driven into the soil to collect visible wavelength color imagery of plant roots in situ—in tropical forests in Brazil, Panama, and Puerto Rico; in a deciduous woodland; and in a northern peatland.

54 ENVIRONMENTAL SCIENCES↗