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At least 307 records · Page 17

Developing Lightning Prediction Tools for the CCAFS Dual-Polarimetric Radar

NASA Marshall Space Flight Center and the University of Alabama Huntsville are collaborating with the 45th Weather Squadron (45WS) to develop improved lightning prediction capabilities for the new C-band dual-polarimetric weather radar being acquired for use by 45WS and launch weather forecasters at Cape Canaveral Air Force Station (CCAFS). In particular, these algorithms will focus on lightning onset, cessation and combined lightning-radar applications for convective winds assessment. Research using radar reflectivity (Z) data for prediction of lightning onset has been extensively discussed in the literature and subsequently applied by launch weather forecasters as it pertains to lightning nowcasting. Currently the forecasters apply a relatively straight forward but effective temperature-Z threshold algorithm for assessing the likelihood of lightning onset in a given storm. In addition, a layered VIL above the freezing level product is used as automated guidance for the onset of lightning. Only limited research and field work has been conducted on lightning cessation using Z and vertically-integrated Z for determining cessation. Though not used operationally vertically-integrated Z (basis for VIL) has recently shown promise as a tool for use in nowcasting lightning cessation. The work discussed herein leverages and expands upon these and similar reflectivity-threshold approaches via the application/addition of over two decades of polarimetric radar research focused on distinct multi-parameter radar signatures of ice/mixed-phase initiation and ice-crystal orientation in highly electrified convective clouds. Specifically, our approach is based on numerous previous studies that have observed repeatable patterns in the behavior of the vertical hydrometeor column as it relates to the temporal evolution of differential reflectivity and depolarization (manifested in either LDR or p(sub hv)), development of in-situ mixed and ice phase microphysics, electric fields, and ensuing lightning in the sub-tropical/tropical convection typical of the southeastern U.S., Maritime Continent, and southwestern Amazon. The polarimetric signatures detected in this setting provide a basis for automated 3-D detection of hydrometeor types in fuzzy logic hydrometeor identification algorithms (HID). Our working hypothesis is that improvement in lightning onset warning lead time and specificity for a given storm, relative to application of a Z-threshold algorithm, should arise as a consequence of the ability of dual-polarimetric radar to unambiguously detect and identify (through HID algorithms) the updraft elevation of rain-water cores above the freezing level and subsequent onset of drop freezing, riming, and robust mixed phase processes leading to significant charge separation and lightning. This type of algorithm, though dependent on the quality of the polarimetric data should be less susceptible to variable Z-calibration that can impact a given Z-threshold approach. To facilitate development of the algorithm while the 45WS dual-pol radar is in its current test stages and to evaluate the impact of polarimetric data quality (e.g., modified scan parameters and sampling) on the ensuing algorithms, we are using the ARMOR C-band dual-pol radar in Huntsville combined with N. Alabama LMA data and ARMOR HID algorithms [NCAR algorithm modified for application at C-band] in a testbed fashion. For lightning cessation we are revisiting the application of differential propagation phase variables for the monitoring of ice crystal alignment driven by in-cloud electric fields combined with metrics of ice water path (i.e., vertically integrated reflectivity). Importantly it should be noted that this approach is still very much a research topic and as such, we will explore operational applications that involve radar frequencies other than C-Band by using the UAH MAX X-band dual-pol radar in slow staring modes.

Petersen, W. A.↗

Pulsed Lidar for Measurement of C02 Concentrations for the ASCENDS Mission - Update

We have been developing a laser-based sounding technique for the remote measurement of the tropospheric CO2 concentrations from orbit for NASA is ASCENDS mission. The mission's goals are to provide measurements of tropospheric CO2 abundance with global-coverage, a few hundred km spatial and monthly temporal resolution. These are needed to better understand CO2 fluxes and the processes that regulate CO2 storage by the land and oceans. For the lIP, we are developing and demonstrating the lidar techniques and key lidar technology that will permit measurements of the CO2 column abundance in the lower troposphere from aircraft. Our final goal is to demonstrate the key capabilities needed for a space lidar and mission approach for the ASCENDS mission. We use a pulsed lidar technique, which is much less sensitive to errors from cloud and atmospheric scattering and to noise from solar background. It allows continuous measurements of CO2 mixing ratio in the lower troposphere during day and night. Our approach uses the 1570nm CO2 band and a two-wavelength laser absorption spectrometer, which continuously measures at nadir from a circular polar orbit. It directs the narrow co-aligned laser beams from the instrument's lasers toward nadir, and measures the energy of the laser echoes reflected from land and water surfaces. It uses a pair of tunable laser transmitters, which allowing measurement of the extinction from a single selected CO2 absorption line in the 1570 nm band and from a line pair in the Oxygen A-band near 765 nm. These regions have temperature insensitive absorption lines are free from interference from other gases. The lasers pulse at 10KHz, use tunable diode seed lasers followed by laser amplifiers, and have MHz spectral widths. During the measurement the lasers are stepped across the selected lines at a kHz rate. The receiver uses a 1-m class telescope and photon sensitive detectors and measures the background light and energies of the laser echoes from the surface. The extinction and column densities for the CO2 and O2 gases are estimated from the ratio of the on and off line echo pulse energies via the integrated path differential absorption (IPDA) technique. Our technique exploits the atmospheric pressure broadening of the lines to weight the measurement sensitivity to the atmospheric column below 5 km. Pulsed laser signals, time gated receiver are used to isolate the surface laser echo signals and to exclude photons scattered from clouds and aerosols. We have successfully demonstrated many key aspects of the approach and lidar technology in the laboratory. We have demonstrated CO2 column measurements in airborne flights during the summers of 2009 and 2010. These included measurements from 3-l3 km altitudes made over a variety of surfaces and through thin and broken clouds. We demonstrated initial airborne measurements of O2 column density to 10 km altitudes during the summer 2010 flights. More details approach, key technologies, and demonstration measurements will be given in the presentation.

Abshire, James↗

Tunable Electronic Energy Level Alignment and Exciton Diversity in Organic–Inorganic van der Waals Heterostructures

van der Waals stacking of two-dimensional (2D) materials offers a powerful platform for engineering material interfaces with tailored electronic and optical properties. While most van der Waals multilayers have featured inorganic monolayers, incorporating molecular monolayers introduces additional degrees of tunability and functionality. Here, in this study, we investigate hybrid bilayers composed of atomically thin perylene-based molecular crystals interfaced with monolayer transition metal dichalcogenides (TMDs), specifically MoS 2 and WS 2 . Using the ab initio many-body perturbation theory within the GW approximation and the Bethe-Salpeter equation approach, we predict emergent properties beyond those of the isolated constituent systems. Notably, we find substantial renormalization of monolayer molecular crystal band gap due to TMD-induced polarization. Furthermore, by varying the TMD monolayer, we demonstrate tuning of the energy level alignment of the bilayer and subsequent control over a diversity of lowest-energy excitons, which include strongly bound hybrid excitons and long-lived charge-transfer excitons. These findings establish organic-inorganic van der Waals heterostructures as a promising class of materials for tunable optoelectronic devices and quantum excitonic phenomena, expanding the design space for low-dimensional systems.

GW-BSE calculations↗

Development of a diode laser heterodyne spectrometer and observations of silicon monoxide in sunspots

A state of the art, tunable diode laser infrared heterodyne spectrometer was designed and constructed for ground based observations throughout the 8 to 12 micron atmospheric window. The instrument was optimized for use with presently available tunable diode lasers, and was designed as a flexible field system for use with large reflecting telescopes. The instrument was aligned and calibrated using laboratory and astronomical sources. Observations of SiO fundamental (v = 1-0) and hot band (v = 2-1) absorption features were made in sunspots near 8 microns using the spectrometer. The data permit an unambiguous determination of the temperature pressure relation in the upper layers of the umbral atmosphere, and support the sunspot model suggested by Stellmacher and Wiehr.

Glenar, D. A.↗

Metal thin-film optical polarizers for space applications, phase 2

A light polarizing material was developed for wavelengths in the visible and near infrared spectral band (400 to 3,000 nm). The material is comprised of ellipsoidal silver particles uniformly distributed and aligned on the surface of an optical material. A method is set forth for making polarizing material by evaporatively coating a smooth glass surface with ellipsoidal silver particles. The wavelength of peak absorption is chosen by selecting the aspect ratio of the ellipsoidal metal particles and the refractive index of the material surrounding the metal particles. The wavelength of peak absorption can be selected to fall at a desired wavelength in the range from 400 to 3,000 nm by control of the deposition process. This method is demonstrated by evaporative deposition of silver particles directly on to a smooth optical surface. By applying a multilayer silver coating of a glass disc, a contrast of greater than 40,000 was achieved at 590 nm. A polarizing filter was designed, fabricated, and assembled which achieved contrast of 100,00 at 59 nm and can serve as a replacement for crystal polarizers.

Slocum, Robert E.↗

Rapid Chemometric Filtering of Spectral Data

A method of rapid, programmable filtering of spectral transmittance, reflectance, or fluorescence data to measure the concentrations of chemical species has been proposed. By programmable is meant that a variety of spectral analyses can readily be performed and modified in software, firmware, and/or electronic hardware, without need to change optical filters or other optical hardware of the associated spectrometers. The method is intended to enable real-time identification of single or multiple target chemical species in applications that involve high-throughput screening of multiple samples. Examples of such applications include (but are not limited to) combinatorial chemistry, flow cytometry, bead assays, testing drugs, remote sensing, and identification of targets. The basic concept of the proposed method is to perform real-time crosscorrelations of a measured spectrum with one or more analytical function(s) of wavelength that could be, for example, the known spectra of target species. Assuming that measured spectral intensities are proportional to concentrations of target species plus background spectral intensities, then after subtraction of background levels, it should be possible to determine target species concentrations from cross-correlation values. Of course, the problem of determining the concentrations is more complex when spectra of different species overlap, but the problem can be solved by use of multiple analytical functions in combination with computational techniques that have been developed previously for analyses of this type. The method is applicable to the design and operation of a spectrometer in which spectrally dispersed light is measured by means of an active-pixel sensor (APS) array. The row or column dimension of such an array is generally chosen to be aligned along the spectral-dispersion dimension, so that each pixel intercepts light in a narrow spectral band centered on a wavelength that is a known function of the pixel position. The proposed method admits of two hardware implementations for computing cross-correlations in real time.

Beaman, Gregory↗

Exploring the potential of using L-Band InSAR for the mapping of flooded vegetation in tropical wetlands

Wetlands play a critical role in global water and carbon cycles, yet monitoring their water extent remains difficult, particularly beneath dense vegetation. SAR-based techniques such as backscatter thresholding are limited by complex scattering mechanisms, while fully polarimetric SAR (PolSAR) data capable of detecting doublebounce scattering remain scarce. To address these challenges, this study evaluates the potential of Interferometric SAR (InSAR) for mapping water surfaces beneath vegetation, termed flooded vegetation, using the Atrato floodplain in Colombia as a case study. We develop an automated workflow combining InSAR fringe detection with local phase homogeneity analysis and random sampling of processing parameters to generate probabilistic flooded vegetation maps. Applied to ALOS PALSAR-1 L-band image pairs from 2007–2011, the workflow captures seasonal fluctuations in flooded extent ranging from 500 to 1,500 km2. Compared to other L-band SAR inundation products, the InSAR-based maps identify broader flooded areas, with ~70% agreement in pairwise comparisons. Around 84% of detections align with existing wetland inventories and seasonal changes correspond with regional hydrological indicators, including terrestrial water storage anomalies and water gauge measurements. PolSAR analysis shows that InSAR complements backscatter-based methods by detecting inundation in areas with weak double-bounce signals. These findings suggest that combining InSAR with backscatter-based methods can improve detection of flooded vegetation, which is especially relevant for the upcoming NISAR mission that will offer frequent global L-band observations.

Coastal inundation↗

Photodetector Arrays for Multicolor Visible/Infrared Imaging

Monolithic focal-plane arrays of photodetectors capable of imaging the same scenes simultaneously in multiple wavelength bands in the visible and infrared spectral regions have been proposed. In prior visible/infrared imaging systems, it has been standard practice to use separate optical trains to form images in visible and infrared wavelength bands on separate visibleand infrared-photodetector arrays. Because the proposal would enable the detection of images in multiple wavelength bands on the same focal plane, the proposal would make it unnecessary to use multiple optical trains. Hence, multispectral imaging systems could be made more compact and the difficulties of aligning multiple optical trains would be eliminated. Each pixel in an array according to the proposal would contain stacks of several photodetectors. The proposal is a logical extension of prior concepts of arrays of stacked photodetectors for imaging in two or three wavelength bands. For example, such an array was described in Three-Color Focal-Plane Array of Infrared QWIPs (NPO-20683), NASA Tech Briefs, Vol. 24, No. 5 (May 2000), page 26a. In one proposed design, (see figure), each pixel would be divided into four subpixels, one being dedicated to a visible- and-near-infrared (V) band, one to a combination of the V band and a verylong- wavelength infrared (VLWIR) band, one to a combination of the V band and a long-wavelength infrared (LWIR) band, and one to a combination of the V band and a medium-wavelength infrared (MWIR) band. For this purpose, each subpixel would include a GaAs-based positive/intrinsic/negative (PIN) photodiode for detection in the V band stacked with three quantum-well infrared photodetectors (QWIPs), each optimized for one of the aforementioned infrared bands. The stacks of photodetectors in all the subpixels would be identical except for the electrical connections, which would be configured to activate the various wavelengthband combinations.

Gunapala, Sarath↗

Photoluminescence mapping of laser-damaged β-Ga 2 O 3

Here, photoluminescence (PL) mapping was utilized to investigate damage in β-Ga 2 O 3 epilayers induced by 1064 nm laser pulses. The intensity and position of the intrinsic UV band were determined and plotted as a false-color image. Two types of damage were identified: circular damage and damage cracks. Circular damage shows lower UV PL intensity than the surrounding material with color centers in a “halo” around the damaged region. Damage cracks are aligned with the a and c axes and show higher PL intensity than undamaged material. Defects in the as-grown material were revealed by shifts in the UV band energy.

36 MATERIALS SCIENCE↗

Demonstration of a Monolithic Micro-Spectrometer System

The starting design of a spectrometer based on a modified Czerny-Turner configuration containing five precision surfaces encapsulated in a monolithic structure is described. Since the purpose at the early stages of the development was to demonstrate the feasibility of the technology and not an attempt to address a specific sensing problem, the first substrate material chosen was optical quality polymethyl methacrylate (PMMA). The final system design decision was narrowed down to two possible configurations containing five and six precision surfaces. The five surface design was chosen since it contained one less precision optical surface, yet included multiple off-axis spheres. In this particular design and material system, the mass was kept below 7 g. The wavelength range (bandpass) design goal was 1 micrometer (0.6 - 1.6 micrometers). The PMMA is particularly transparent in this wavelength region and there are interesting effects to monitor within this band. The optical system was designed and optimized using the ZEMAX optical design software program to be entirely alignment free (self aligning).

Rajic, S.↗

Performance of the QWIP Focal Plane Arrays for NASA's Landsat Data Continuity Mission

The focal plane assembly for the Thermal Infrared Sensor (TIRS) instrument on NASA's Landsat Data Continuity Mission (LDCM) consists of three 512 x 640 GaAs Quantum Well Infrared Photodetector (QWIP) arrays. The three arrays are precisely mounted and aligned on a silicon carrier substrate to provide a continuous viewing swath of 1850 pixels in two spectral bands defined by filters placed in close proximity to the detector surfaces. The QWIP arrays are hybridized to Indigo ISC9803 readout integrated circuits (ROICs). QWIP arrays were evaluated from four laboratories; QmagiQ, (Nashua, NH), Army Research Laboratory, (Adelphi, MD}, NASA/ Goddard Space Flight Center, (Greenbelt, MD) and Thales, (Palaiseau, France). All were found to be suitable. The final discriminating parameter was the spectral uniformity of individual pixels relative to each other. The performance of the QWIP arrays and the fully assembled, NASA flight-qualified, focal plane assembly will be reviewed. An overview of the focal plane assembly including the construction and test requirements of the focal plane will also be described.

Jhabvala, M.↗

Design and Performance of a 40W Uplink Laser Transmitter for NASA's O2O Laser Communications Mission

NASA’s Orion Artemis II Optical Communications System (O2O) will provide operational laser communications between the ground and lunar orbit for the Artemis II crewed mission. In this work we describe a 40W ground-based laser transmitter for the O2O system. The uplink transmitter operates in the optical C-band and uses an energy-efficient 32-PPM modulation format. Four spatial diversity channels are time-aligned and combined in the far field. Each channel produces up to 10 W of output power and contains both the communications signal and the 7kHz modulated beacon signal required for acquisition. The transmitter delivers data at 10 Mbits/s and 20 Mbits/s channel rates, corresponding to the 250 MHz and 500 MHz slot rates respectively.

free-space optical communications↗

Transmission Telescope Optical Dynamic Alignment

The Integrated Radio Optical Communication System (iROC) is designed to transmit data between Mars and Earth by means of radio waves at 32.67 GHz (Ka Band) and laser beam at 1550 nm, both transmitted via a combined teletenna. The iROC terminal will provide ‘beaconless’ operations to allow full function from the outer planets. In order to point without the aid of an uplink beacon, the proof of concept presented here is addressing the need for an accurate determination and control of the relative position of the laser beam with respect to a reference star. The experiment presented simulates a surrogate transmission telescope system in laboratory setting and presents the model used in the correction of the outgoing beam. The results of the model show a nonlinear dependence between the outgoing and the reference beam, indicating the necessity of a minimum of two metrology instruments placed along the optical system for increased pointing precision.

optical communication↗

A survey of pedestal magnetic fluctuations using gyrokinetics and a global reduced model for microtearing stability

This article presents a global reduced model for slab-like microtearing modes (MTMs) in the H-mode pedestal, which reproduces distinctive features of experimentally observed magnetic fluctuations, such as chirping and discrete frequency bands at noncontiguous mode numbers. Our model, importantly, includes the global variation of the diamagnetic frequencies, which is necessary to reproduce the experimental observations. The key insight underlying this model is that MTM instability is enabled by the alignment of a rational surface with the peak in the profile of the diamagnetic frequency. Conversely, MTMs are strongly stabilized for toroidal mode numbers for which these quantities are misaligned. This property explains the discrete fluctuation bands in several DIII-D and JET discharges, which we survey using our reduced model in conjunction with global gyrokinetic simulations. A fast yet accurate reduced model for MTMs enables rapid interpretation of magnetic fluctuation data from a wide range of experimental conditions to help assess the role of MTM in the pedestal.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Pressure‐Dependent “Insulator–Metal–Insulator” Behavior in Sr‐Doped La 3 Ni 2 O 7

Abstract Recently, superconductivity at high temperatures is observed in bulk La 3 Ni 2 O 7−δ under high pressure. However, the attainment of high‐purity La 3 Ni 2 O 7−δ single crystals remains a formidable challenge. Here, the crystal structure and physical properties of single crystals of Sr‐doped La 3 Ni 2 O 7 synthesized at high pressure (20 GPa) and high temperature (1400 °C) are reported. Through single crystal X‐ray diffraction, it is shown that high‐pressure‐synthesized paramagnetic Sr‐doped La 3 Ni 2 O 7 crystallizes in an orthorhombic structure with Ni─O─Ni bond angles of 173.4(2)° out‐of‐plane and 175.0(2)°and 176.7(2)°in plane. The substitution of Sr alters in band filling and the ratio of Ni 2+ /Ni 3+ in Sr‐doped La 3 Ni 2 O 7 , aligning them with those of “La 3 Ni 2 O 7.05” , thereby leading to significant modifications in properties under high pressure relative to the unsubstituted parent phase. At ambient pressure, Sr‐doped La 3 Ni 2 O 7 exhibits insulating properties, and the conductivity increases as pressure goes up to 10 GPa. However, upon further increasing pressure beyond 10.7 GPa, Sr‐doped La 3 Ni 2 O 7 transits back from a metal‐like behavior to an insulator. The insulator–metal–insulator trend under high pressure dramatically differs from the behavior of the parent compound La 3 Ni 2 O 7−δ , despite their similar behavior in the low‐pressure regime. These experimental results underscore the considerable challenge in achieving superconductivity in nickelates.

36 MATERIALS SCIENCE↗

Laser Sounder for Measuring Atmospheric CO2 Concentrations: Progress Toward Ascends

The next generation of space-based, active remote sensing instruments for measurement of tropospheric CO2 promises a capability to quantify global carbon sources and sinks at regional scales. Active (laser) methods will extend CO2 measurement coverage in time, space, and perhaps precision such that the underlying mechanisms for carbon exchange at the surface can be understood with .sufficient detail to confidently project the future of carbon-climate interaction and the influence of remediative policy actions. The recent Decadal Survey for Earth Science by the US National Research Council has recommended such a mission called the Active Sensing of CO2 Emissions over Nights, Days, and Seasons (ASCENDS) for launch in 2013-2016. We have been developing a laser technique for measurement of tropospheric CO2 for a number of years. Our immediate goal is to develop and demonstrate the method and instrument technology that will permit measurements of the CO2 column abundance over a horizontal path and from aircraft at the few-ppmv level. Our longer-term goal is to demonstrate the required capabilities of the technique, develop a space mission approach, and design the instrument for an ASCENDS-type mission. Our approach is to use a dual channel laser absorption spectrometer (i.e., differential absorption in altimeter mode), which continuously measures from a near-polar circular orbit. We use several co-aligned tunable fiber laser transmitters allowing simultaneous measurement of the absorption from a CO2 line in the 1570 nm band, O2 extinction in the oxygen A-band (near 765 nm), and aerosol backscatter in the same measurement path. We measure the energy of the laser echoes at nadir reflected from land and water surfaces, day and night. The lasers have spectral widths much narrower than the gas absorption lines and are turned on and off the selected CO2 and O2 lines at kHz rates. The gas extinction and column densities for the CO2 and O2 gases are estimated from the ratio of the on and off-line singnals via the DIAL technique. We used pulsed laser signals, photon counting detectors, and time gating to isolate the laser returns from the surface, and to reject photons scattered from thin clouds and aerosols. High signal-to-noise ratios are required and the CO2 estimates can be sensitive to small drifts or other errors in the instrument, so the absorption estimates need to be quite stable for hours. We have constructed a breadboard version of the CO2 sensor that uses a low power fiber laser and a 20 cm diameter telescope. We have used it to make measurements of CO2 absorption in the laboratory and over 200-m to 2-km long open horizontal paths. These have been done in several sessions extending over multiple days, which allows us to assess the measurement stability and to compare absorption variations to readings from an external in situ CO2 sensor. We have also calculated characteristics of the technique for space including its expected measurement performance for different modulation types, and have performed an initial space mission accommodation study. We sill describe these results in the presentation.

Abshire, J. B.↗

NASA Tech Briefs, December 2012

The topics include: Pattern Generator for Bench Test of Digital Boards; 670-GHz Down- and Up-Converting HEMT-Based Mixers; Lidar Electro-Optic Beam Switch with a Liquid Crystal Variable Retarder; Feedback Augmented Sub-Ranging (FASR) Quantizer; Real-Time Distributed Embedded Oscillator Operating Frequency Monitoring; Software Modules for the Proximity-1 Space Link Interleaved Time Synchronization (PITS) Protocol; Description and User Instructions for the Quaternion to Orbit v3 Software; AdapChem; Mars Relay Lander and Orbiter Overflight Profile Estimation; Extended Testability Analysis Tool; Interactive 3D Mars Visualization; Rapid Diagnostics of Onboard Sequences; MER Telemetry Processor; pyam: Python Implementation of YaM; Process for Patterning Indium for Bump Bonding; Archway for Radiation and Micrometeorite Occurrence Resistance; 4D Light Field Imaging System Using Programmable Aperture; Device and Container for Reheating and Sterilization; Radio Frequency Plasma Discharge Lamps for Use as Stable Calibration Light Sources; Membrane Shell Reflector Segment Antenna; High-Speed Transport of Fluid Drops and Solid Particles via Surface Acoustic Waves; Compact Autonomous Hemispheric Vision System; A Distributive, Non-Destructive, Real-Time Approach to Snowpack Monitoring; Wideband Single-Crystal Transducer for Bone Characterization; Numerical Simulation of Rocket Exhaust Interaction With Lunar Soil; Motion Imagery and Robotics Application (MIRA): Standards-Based Robotics; Particle Filtering for Model-Based Anomaly Detection in Sensor Networks; Ka-band Digitally Beamformed Airborne Radar Using SweepSAR Technique; Composite With In Situ Plenums; Multi-Beam Approach for Accelerating Alignment and Calibration of HyspIRI-Like Imaging Spectrometers; JWST Lifting System; Next-Generation Tumbleweed Rover; Pneumatic System for Concentration of Micrometer-Size Lunar Soil.

Source record↗

Laser Sounder for Global Measurement of CO2 Concentrations in the Troposphere from Space

Measurements of tropospheric CO2 abundance with global-coverage, a few hundred km spatial and monthly temporal resolution are needed to quantify processes that regulate CO2 storage by the land and oceans. The Orbiting Carbon Observatory (OCO) is the first space mission focused on atmospheric CO2 for measuring total column CO, and O2 by detecting the spectral absorption in reflected sunlight. The OCO mission is an essential step, and will yield important new information about atmospheric CO2 distributions. However there are unavoidable limitations imposed by its measurement approach. These include best accuracy only during daytime at moderate to high sun angles, interference by cloud and aerosol scattering, and limited signal from CO2 variability in the lower tropospheric CO2 column. We have been developing a new laser-based technique for the remote measurement of the tropospheric CO2 concentrations from orbit. Our initial goal is to demonstrate a lidar technique and instrument technology that will permit measurements of the CO2 column abundance in the lower troposphere from aircraft. Our final goal is to develop a space instrument and mission approach for active measurements of the CO2 mixing ratio at the 1-2 ppmv level. Our technique is much less sensitive to cloud and atmospheric scattering conditions and would allow continuous measurements of CO2 mixing ratio in the lower troposphere from orbit over land and ocean surfaces during day and night. Our approach is to use the 1570nm CO2 band and a 3-channel laser absorption spectrometer (i.e. lidar used an altimeter mode), which continuously measures at nadir from a near polar circular orbit. The approach directs the narrow co-aligned laser beams from the instrument's lasers toward nadir, and measures the energy of the laser echoes reflected from land and water surfaces. It uses several tunable fiber laser transmitters which allowing measurement of the extinction from a single selected CO2 absorption line in the 1570 nm band. This band is free from interference from other gases and has temperature insensitive absorption lines. During the measurement the lasers are tuned on- and off- a selected CO2 line near 1572 nm and a selected O2 line near 768 nm in the Oxygen A band at kHz rates. The lasers use tunable diode seed lasers followed by fiber amplifiers, and have spectral widths much narrower than the gas absorption lines. The receiver uses a 1-m diameter telescope and photon counting detectors and measures the background light and energies of the laser echoes from the surface. The extinction and column densities for the CO2 and O2 gases are estimated from the ratio of the on and offline surface echo via the differential optical absorption technique. Our technique rapidly alternates between several on-line wavelengths set to the sides of the selected gas absorption lines. It exploits the atmospheric pressure broadening of the lines to weight the measurement sensitivity to the atmospheric column below 5 km. This maximizes sensitivity to CO2 in the boundary layer, where variations caused by surface sources and sinks are largest. Simultaneous measurements of O2 column will use an identical approach with an O2 line. Thee laser frequencies are tunable and have narrow (MHz) line widths. In combination with sensitive photon counting detectors these enables much higher spectral resolution and precision than is possible with passive spectrometer. 1aser backscatter profiles are also measured, which permits identifying measurements made to cloud tops and through aerosol layers. The measurement approach using lasers in common-nadir-zenith path allows retrieving CO2 column mixing ratios in the lower troposphere irrespective of sun angle. Pulsed laser signals, time gated receiver and a narrow receiver field-of-view are used to isolate the surface laser echo signals and to exclude photons scattered from clouds and aerosols. Nonetheless, the optical absorption change due to a change of a few ppO2 is small, <1 % which makes achieving the needed measurement sensitivities and stabilities quite challenging. Measurement SNRs and stabilities of >600:1 are needed to estimate CO2 mixing ratio at the 1-2 ppm level. We have calculated characteristics of the technique and have demonstrated aspects of the laser, detector and receiver approaches in th e laboratory We have also measured O2 in an absorption cell, and made C02 measurements over a 400 m long (one way) horizontal path using a sensor breadboard. We will describe these and more details of our approach in the paper.

Abshire, James B.↗