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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 307 records · Page 17
All sourcesNASA NTRSDOE OSTI
DOE OSTI2025

Large enhancement of ferroelectric properties of perovskite oxides via nitrogen incorporation

Perovskite oxides have a wide variety of physical properties that make them promising candidates for versatile technological applications including nonvolatile memory and logic devices. Chemical tuning of those properties has been achieved, to the greatest extent, by cation-site substitution, while anion substitution is much less explored due to the difficulty in synthesizing high-quality, mixed-anion compounds. Here, nitrogen-incorporated BaTiO3 thin films have been synthesized by reactive pulsed-laser deposition in a nitrogen growth atmosphere. The enhanced hybridization between titanium and nitrogen induces a large ferroelectric polarization of 70 μC/cm2 and high Curie temperature of ~1213 K, which are ~2.8 times larger and ~810 K higher than in bulk BaTiO3, respectively. These results suggest great potential for anion-substituted perovskite oxides in producing emergent functionalities and device applications.

Wang, Tao↗
DOE OSTI2026

High-entropy 1D halide perovskite piezoelectrics found by megalibrary synthesis and rapid nonlinear optical screening

Piezoelectric molecular crystals offer excellent compositional and structural tunability and sustainable processability. However, their discovery is slow, primarily due to the serial synthesis and screening processes used. Here, we report an approach that combines massively parallel megalibrary synthesis with scanning second harmonic generation (SHG) microscopy for rapid screening of piezoelectric molecular crystals. Megalibraries consisting of more than 1,000,000 compositionally distinct but positionally encoded TMCM x TMA (1–x) Cd y Pb (1–y) ClzBr (3–z) (TMCM: trimethylchloromethylammonium, TMA: tetramethylammonium; 0 ≤ x ≤ 1, 0 ≤ y ≤ 1, 0 ≤ z ≤ 3) nanocrystals were synthesized. The megalibraries were rapidly screened by SHG microscopy to identify notable noncentrosymmetric structures, which were then tested for piezoelectricity, facilitating discovery of a high-entropy noncentrosymmetric material with a large d 33 (TMCM 0.75 TMA 0.25 Cd 0.75 Pb 0.25 Cl 1.5 Br 1.5 , 42.8 picocoulombs per newton). Furthermore, this approach enabled systematic investigation of the Curie temperature (T C )–composition relationship in the TMCMCdCl z Br (3–z) system, facilitating reverse design of materials with targeted T C . Our work establishes a powerful approach to accelerate the discovery and design of unusual piezoelectrics for next-generation electronics and optics.

Li, Jun [Northwestern University, Evanston, IL (Un↗
DOE OSTI2020

Giant piezoelectricity in oxide thin films with nanopillar structure

High-performance piezoelectric materials are critical components for electromechanical sensors and actuators. For more than 60 years, the main strategy for obtaining large piezoelectric response has been to construct multiphase boundaries, where nanoscale domains with local structural and polar heterogeneity are formed, by tuning complex chemical compositions. We used a different strategy to emulate such local heterogeneity by forming nanopillar regions in perovskite oxide thin films. We obtained a giant effective piezoelectric coefficient d 33 , f * of ~1098 picometers per volt with a high Curie temperature of ~450°C. Our lead-free composition of sodium-deficient sodium niobate contains only three elements (Na, Nb, and O). The formation of local heterogeneity with nanopillars in the perovskite structure could be the basis for a general approach to designing and optimizing various functional materials.

Science & Technology - Other Topics↗
DOE OSTI2023

Programming correlated magnetic states with gate-controlled moiré geometry

The ability to control the underlying lattice geometry of a system may enable transitions between emergent quantum ground states. We report in situ gate switching between honeycomb and triangular lattice geometries of an electron many-body Hamiltonian in rhombohedral (R)–stacked molybdenum ditelluride (MoTe 2 ) moiré bilayers, resulting in switchable magnetic exchange interactions. At zero electric field, we observed a correlated ferromagnetic insulator near one hole per moiré unit cell with a widely tunable Curie temperature up to 14 K. Applying an electric field switched the system into a half-filled triangular lattice with antiferromagnetic interactions; further doping this layer-polarized superlattice tuned the antiferromagnetic exchange interaction back to ferromagnetic. Our work demonstrates R-stacked MoTe 2 moirés to be a laboratory for engineering correlated states with nontrivial topology.

Science & Technology - Other Topics↗
DOE OSTI2024

Magnetic properties of Lutetium and Yttrium doped Ce 2 Fe 14 B magnets

The increasing demand for Nd-Dy and Sm-Co based permanent magnets is exacerbating the current critical materials shortage, therefore improving and optimizing current candidate critical element free permanent magnets is necessary to develop future clean energy technologies. In this work, we aim to increase the thermal stability and magnetic performance of Ce 2 Fe 14 B based permanent magnets through the substitution of Ce ions with noncritical rare earth elements Lu and Y. The substitution of Lu (x=0; 0.05; 0.1; 0.15) for Ce ions in (LuxCe 2-x )Fe 14 B was unsuccessful, likely due to disparities in ionic size and valencies, and failed to exhibit improved thermal stability or magnetic performance. In contrast, Y substitution for Ce ions in (Y x Ce 2-x )Fe14B (x= 0.1; 0.2; 0.3; 0.4; 0.5) alloys was successful. Notably, these alloys demonstrated enhanced thermal stability, as evidenced by an increase in the Curie temperature, reaching a peak of 443 K at x= 0.5. Y substitution also helped to suppress the CeFe2 Laves phase. Without loss of the anisotropy field Y substitution increased the saturation magnetization, MS, peaking at MS = 125 emu/g for a Y concentration of x= 0:4, demonstrating (Y 0.4 Ce 1.6 )Fe 14 B as a potential critical element free permanent magnet with an energy product as high as 29 MGOe. This work is advantageous in developing low cost high performance permanent magnets with reduced or little to no critical rare earth elements.

Rai, Binod K.↗
DOE OSTI2022

Electronic Structure and Quantum Spin Correlations in Novel Magnetic Compounds

This project has studied the development of new magnetic materials with high magnetocrystalline anisotropy, magnetization, and high Curie temperatures, novel magnetic nanostructures that show skyrmions in the length scale of the range of 10 nm, and Heusler compounds with noncoplanar and noncollinear spin structures with topological Hall effect. The materials investigated towards this project are promising for next-generation energy and information devices. Most importantly, this project has provided fundamental understanding of science and technology behind the above-mentioned materials and insights for future strategies to satisfy the rapidly growing demands of magnetic materials in many applications.

36 MATERIALS SCIENCE↗
DOE OSTI2023

Magnetic properties of Lu and Y doped Ce-Fe-B magnets

The growing demand for Nd2Fe14B magnets is exacerbating the current critical materials shortage. To reduce the amount of critical material in Nd2Fe14B magnets, chemical substitutions have been used and shown to improve the magnetic behavior, such as the Curie Temperature TC, anisotropy field Ha, and saturation magnetization MS.

Bretana, Alex↗
DOE OSTI2025

Polymer-assisted transfer of MBE-grown van der Waals materials

Molecular beam epitaxy (MBE) has been used to create high-quality, large-scale two-dimensional van der Waals (2D vdW) materials. However, due to the strong adhesion between the substrate and deposited materials, the peel-off and dry transfer of MBE-grown vdW films onto other substrates has been challenging. This limits the study and use of MBE films for heterogeneous integration including stacked and twisted heterostructures. In this work, we develop a polymer-assisted dry transfer method and successfully perform full-film transfer of various MBE-grown 2D vdW materials including transition metal dichalcogenides (TMD), topological insulators (TI) and 2D magnets. In particular, we transfer air-sensitive 2D magnets, characterize their magnetic properties, and compare them with as-grown materials. The results show that the transfer technique does not degrade the magnetic properties, with the Curie temperature and hysteresis loops exhibiting similar behaviors after the transfer. Our results enable further development of heterogeneous integration of 2D vdW materials based on MBE growth.

Li, Ziling [The Ohio State University]↗
DOE OSTI2024

Site Occupancy Preference and Magnetic Properties in Nd 2 (Fe,Co) 14 B

Partial replacement of Fe by Co is an effective method to increase Curie temperature (T C ) , which improves the thermal stability of magnetic properties in Nd 2 Fe 14 B-based permanent magnets. The correlation between Fe substitution and magnetic properties has been studied in Nd 2 (Fe,Co) 14 B via a first-principles calculation. The calculated Fe substitution energies indicate that the Co atoms avoid the 8 j 2 site, which agrees with the experiments. The Co atoms are ferromagnetically coupled with Fe sublattice and show magnetic moments of about 1.2 to 1.7 μ B at different crystallographic sites, less than that of Fe (2.1–2.7 μ B ), resulting in the decrease in total magnetization at ground state (0 K) with increasing Co content. The effective exchange interaction parameter, derived from the energy difference between varied magnetic structures, increases from 7.8 meV to 17.0 meV with increasing Co content from x = 0 to x = 14 in Nd 2 Fe 14–x Co x B. This change in the effective exchange interaction parameter is responsible for the enhancement of T C in Nd 2 (Fe,Co) 14 B. The total magnetization at 300 K, derived from mean-field theory, shows a peak maximum value at x = 1 in Nd 2 Fe 14–x Co x B. The phenomenon results from the interplay between the reduction of the magnetic moment in the Fe(Co) sublattice and the enhancement of T C with increasing Co content.

36 MATERIALS SCIENCE↗
DOE OSTI2024

Coercivity of (Fe 0.7 Co 0.3 ) 2 B Nanowire and Its Bonded Magnet

(Fe 0.7 Co 0.3 ) 2 B are potential permanent magnets material due to its large saturation magnetization and high Curie temperature. However, it has moderate magnetocrystalline anisotropy (MCA) and low coercivity. One way to improve its coercivity is to combine the contributions from magnetocrystalline- and magnetic-shape anisotropy by preparing (Fe 0.7 Co 0.3 ) 2 B nanowires. We study the effects of size, morphology, and surface defects on the hard magnetic properties of nanowires using micromagnetic simulation. The hard magnetic properties of (Fe 0.7 Co 0.3 ) 2 B nanowire-bonded magnets are estimated, including the role of inter-wire magnetostatic interaction. By considering the existence of local reductions in MCA energy of up to 30% on the surface layer of nanowires, the anisotropic bonded magnet with a 65% vol. of (Fe 0.7 Co 0.3 ) 2 B nanowires would have typical remanence, B r = 7.6–8.4 kG, coercivity, H ci = 9.6–9.9 kOe, and maximum energy product, (BH) m = 14–17.8 MGOe. Developing effective technology for synthesizing nanowires and fabricating corresponding bonded magnets is promising for manufacturing practical magnets based on the magnetic phase with a relatively low or moderate MCA, such as (Fe 0.7 Co 0.3 ) 2 B.

36 MATERIALS SCIENCE↗
NASA NTRS1973

Theory of disordered Heisenberg ferromagnets

A Green's function technique is used to calculate the magnetic properties of Heisenberg ferromagnets in which the exchange interactions deviate randomly in strength from the mean interaction. Systems of sc, bcc, and fcc topologies and of general spin values are treated. Disorder produces marked effects in the density of spin wave states, in the form of enhancement of the low-energy density and extension of the energy band to higher values. The spontaneous magnetization and the Curie temperature decrease with increasing disorder. The effects of disorder are shown to be more pronounced in the ferromagnetic than in the paramagnetic phase.

Stubbs, R. M.↗
NASA NTRS1974

Unique properties of SBN and their use in a layered optical memory

Holographic storage experiments using crystal Sr(0.75)Ba(0.25)Nb2O6 (SBN 75/25) as a volume-phase holographic medium show that this material is the most sensitive crystalline storage medium yet discovered. An exposure level of 0.003 J/sq cm at 0.488 micron produces a 1% diffraction efficiency in a 5-mm length of crystal. In addition to high recording sensitivity, SBN 75/25 exhibits interesting electric-field induced effects that include electric-field enhanced recording sensitivity and voltage-switchable latent-to-active holographic reconstruction efficiency. These effects are explained in terms of drift and diffusion of photoionized carriers coupled with the nonlinear electrooptic behavior characteristic of this low Curie temperature ferroelectric crystal. A mechanism is proposed that correlates the observed electrically controlled holographic response with the dielectric behavior of the crystal. These interesting effects are used to implement a novel, layered optical memory having no moving parts and having electrical access for writing or reading selected layers.

Thaxter, J. B.↗
NASA NTRS1977

Global lunar crust - Electrical conductivity and thermoelectric origin of remanent magnetism

An upper limit is placed on the average crustal conductivity from an investigation of toroidal (V x B) induction in the moon, using ten-minute data intervals of simultaneous lunar orbiting and surface magnetometer data. Crustal conductivity is determined as a function of crust thickness. For an average global crust thickness of about 80 km, the crust surface electrical conductivity is of the order of 1 hundred millionth mho/m. The toroidal-induction results lower the surface-conductivity limit obtained from poloidal-induction results by approximately four orders of magnitude. In addition, a thermoelectric (Seebeck effect) generator model is presented as a magnetic-field source for thermoremanent magnetization of the lunar crust during its solidification and cooling. Magnetic fields from 1000 to 10,000 gammas are calculated for various crater and crustal geometries. Solidified crustal material cooling through the iron Curie temperature in the presence of such ancient lunar fields could have received thermoremanent magnetization consistent with that measured in most returned lunar samples.

Dyal, P.↗
NASA NTRS1978

Critical phenomena in a low gravity environment

Various types of critical point phenomena are discussed including the gas-liquid phase transition of a fluid, the spontaneous magnetization of a ferromagnet below the Curie temperature, and structural phase transitions of solid materials. The interrelation of thermodynamic properties by scaling laws is considered noting theories for the validity of scaling laws and the principle of universality. Gravity effects are reviewed noting that in earth-based experiments the phenomena are significantly influenced by the earth's gravitational field and that fluid samples that are spatially homogeneous cannot be realized near the gas-liquid critical point.

Sengers, J. V.↗
NASA NTRS1981

Use of MAGSAT anomaly data for crustal structure and mineral resources in the US Midcontinent

The analysis and preliminary interpretation of investigator-B MAGSAT data are addressed. The data processing included: (1) removal of spurious data points; (2) statistical smoothing along individual data tracks, to reduce the effect of geomagnetic transient disturbances; (3) comparison of data profiles spatially coincident in track location but acquired at different times; (4) reduction of data by weighted averaging to a grid with 1 deg xl deg latitude/longitude spacing, and with elevations interpolated and weighted to a common datum of 400 km; (5) wavelength filtering; and (6) reduction of the anomaly map to the magnetic pole. Agreement was found between a magnitude data anomaly map and a reduce-to-the-pole map supporting the general assumption that, on a large scale (long wavelength), it is induced crustal magnetization which is responsible for major anamalies. Anomalous features are identified and explanations are suggested with regard to crustal structure, petrologic characteristics, and Curie temperature isotherms.

Carmichael, R. S.↗
NASA NTRS1983

Use of MAGSAT anomaly data for crustal structure and mineral resources in the US midcontinent

Magnetic field data acquired by NASA's MAGSAT satellite is used to construct a long-wavelength magnetic anomaly map for the U.S. midcontinent. This aids in interpretation of gross crustal geology (structure, lithologic composition, resource potential) of the region. Magnetic properties of minerals and rocks are investigated and assessed, to help in evaluation and modelling of crustal magnetization sources and depth to the Curie-temperature isotherm.

Carmichael, R. S.↗
NASA NTRS1984

Magnetic cristobalite (?) - A possible new magnetic phase produced by the thermal decomposition of nontronite

The effect of heat treatment for 1 h or more at 900-1000 C on the magnetic properties of nontronite, an iron-rich smectite clay thought to be an important component of Martian regolith, is investigated experimentally, extending the findings of Moskowitz and Hargraves (1982). The results are presented in graphs and tables and discussed. A phase with Curie temperature 200-220 C, remanent coercivity greater than 800 mT, and a type-2 room-temperature-coercivity response to thermomagnetic cycling is observed and attributed to an iron-substituted cristobalite which may form by topotactic growth from a smectite precursor.

Moskowitz, B. M.↗