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At least 307 records · Page 17

Dynamic mechanical analysis of polymeric materials

Polymeric materials exhibit mechanical behavior which is dependent on temperature. Dynamic mechanical analysis measures the mechanical damping and resonant frequency of a material over a temperature range. Values of the dynamic loss modulus, storage modulus, and loss tangent can be calculated from these data. The glass transition temperature and onset temperature are obtained from curves of the dynamic moduli versus temperature.

Kern, Kristen T.↗

On the Retrieval and Analysis of Multilevel Clouds

An accurate satellite retrieval of cloud properties depends upon the detection and analysis of multilayered, overlapping cloud systems that surface observations show to be common. Multiple cloud layers are often found, for instance, in frontal situations, where cirrus overlays boundary layer convective cloud or low-to mid-level stratus cloud. Surface observers (Hahan et al., 1982) indicate that over ocean in the Northern Hemisphere between 30 deg. N and 60 deg. N, 51 percent of observations are of multilevel clouds. A satellite analysis by Coakley (1983) over the Pacific Ocean finds that more than 50 percent of 500 (250 sq km) frames exhibit evidence of multilayered cloud systems. The questions addressed in this study are the following: What error is introduced when inferring the cloud pressure from a Field-Of-View (FOV) that contains some arbitrary amount of transparent cloud overlaying a lower-level black cloud, such as stratus, by making the assumption that there is only a single cloud layer in the FOV, and what may be done to improve the cloud retrieval? The CO2 slicing methods (e.g. McCleese and Wilson, 1976; Smith and Platt, 1978; Chahine, 1974) have been shown to provide accurate means of inferring cirrus cloud altitude from passive infrared radiance measurements. The CO2 techniques have been applied to radiometric data from several instruments, notably the High Resolution Infrared Radiometric Sounder (HIRS/2, hereafter referred to as HIRS), the VISSR Atmospheric Sounder (VAS) (e.g., Menzel et al., 1983; Wylie and Menzel, 1989), and most recently to the High Resolution Interferometer Sounder (HIS) (Smith and Frey, 1990). The methods take advantage of the fact that infrared CO2 sounding channels spaced closely in wavenumber each have varying opacity to CO2, thereby causing each channel to be sensitive to a different level in the atmosphere. The techniques have been shown to be effective for single-layered, nonblack, mid- to high-level clouds such as cirrus, but are generally applied operationally to any given cloud occurrence. The CO2 slicing algorithms are most accurate for clouds than occur in a single, well-defined layer, or for multi-layered cloud cases in which the uppermost cloud layer is nearly black. Significant cloud height retrieval errors may ensue if the HIRS Field-Of-View (FOV) is cotaminated with low cloud. McCleese and Wilson (1976) have shown that the retrieved cloud height for the case of multiple cloud layers is a weighted average of the cloud heights actually present. The weight is approximately proportional to the product of the cloud heigt and the effective cloud amount. The effect of their result is that the uppermost cloud layer dominates the cloud pressure retrieval. Beyond stating that the higher cloud dominates the cloud pressure retrieval, there is no quantitative information to provide a way of estimating the errors in cloud pressure retrieval one should expect for certain common multilevel cloud situations or any suggestions on how to reduce the errors. In this paper we estimate the magnitude of the errors and use a simple algorithm to reduce the errors in optically thin cloud height retrival.

Baum, Bryan A.↗

Jet Noise Reduction by Microjets - A Parametric Study

The effect of injecting tiny secondary jets (microjets ) on the radiated noise from a subsonic primary jet is studied experimentally. The microjets are injected on to the primary jet near the nozzle exit with variable port geometry, working fluid and driving pressure. A clear noise reduction is observed that improves with increasing jet pressure. It is found that smaller diameter ports with higher driving pressure, but involving less thrust and mass fraction, can produce better noise reduction. A collection of data from the present as well as past experiments is examined in an attempt to correlate the noise reduction with the operating parameters. The results indicate that turbulent mixing noise reduction, as monitored by OASPL at a shallow angle, correlates with the ratio of jet to primary jet driving pressures normalized by the ratio of corresponding diameters (p d /pjD). With gaseous injection, the spectral amplitudes decrease at lower frequencies while an increase is noted at higher frequencies. It is apparent that this amplitude crossover is at least partly due to shock-associated noise from the underexpanded jets themselves. Such crossover is not seen with water injection since the flow in that case is incompressible and there is no shock-associated noise. Centerline velocity data show that larger noise reduction is accompanied by faster jet decay as well as significant reduction in turbulence intensities. While a physical understanding of the dependence of noise reduction on p d /pjD remains unclear, given this correlation, an analysis explains the observed dependence of the effect on various other parameters.

Zaman, K. B. M. Q.↗

Modern insights into the mechanisms of neptunium oxalate decomposition

Neptunium oxalate (Np(C 2 O 4 ) 2 ·6H 2 O) is a historically relevant solid phase used in nuclear processing as a precursor for neptunium dioxide (NpO 2 ). Although Np oxalate has been synthesized and used for NpO 2 production for decades, the thermal decomposition mechanism of this phase remains poorly understood and has not been evaluated in over 30 years. Conflicting reports in historical literature suggest either a direct conversion from anhydrous oxalate to NpO 2 or a decomposition that includes the formation of Np carbonate or oxidized Np intermediate phases. In this work, we reexamine the decomposition pathway of Np(C 2 O 4 ) 2 ·6H 2 O using thermal analysis coupled with evolved gas analysis and temperature-dependent Raman spectroscopy to elucidate decomposition mechanisms and intermediate phases using modern analytical techniques. Thermal analysis revealed a three-stage decomposition process, including dehydration below 200 °C, oxalate breakdown between 170 and 370 °C, and NpO 2 formation by 500 °C. However, an unidentified plateau in the thermal data was observed during measurements. Raman spectroscopy confirmed the stages of decomposition, and in the analysis of potential intermediate phases, no carbonate phases or Np 2 O 5 were identified. Raman data suggest that residual oxalate or nonstoichiometric oxide are present during decomposition before pure NpO 2 is formed. These findings clarify aspects of the Np oxalate decomposition mechanism and address longstanding discrepancies in the literature, with a specific focus on Np-specific materials chemistry.

Lawson, Kathryn M. [Oak Ridge National Laboratory ↗

Isospin dependence of the nuclear EMC effect from a global QCD analysis

We perform a new global QCD analysis of unpolarized parton distribution functions (PDFs) in the nucleon from proton, deuteron, and A = 3 data, including recent measurements of He 3 / D and H 3 / D cross section ratios from the MARATHON experiment at Jefferson Lab. Simultaneously inferring the PDFs and nucleon off-shell corrections allows both to be determined consistently, without theoretical assumptions about the isospin dependence of nuclear effects. The analysis provides strong evidence for the need of nucleon off-shell corrections to describe the A = 3 data, with large isoscalar and a suggestion of nonzero isovector contributions in A ≤ 3 nuclei. We find that the extracted EMC ratios of nuclear to nucleon structure functions for A = 2 and 3 differ from those naively extrapolated from heavy nuclei down to low A .

Cocuzza, C. [William & Mary] (ORCID:00000003492292↗

Astrocyte Reactivity by Alcohol Dependence in the Central Amygdala

Astrocytes play essential roles in the brain, but prolonged insult can result in the loss or diminishment of homeostatic functions and increased neuroinflammatory response. The central amygdala (CeA) is an important limbic region in reward and stress responsivity as well as in the development of alcohol dependence. Using a multi-omics approach with Aldh1l1-EGFP/Rpl10a mice and the chronic intermittent ethanol – two-bottle choice exposure model, we have characterized the translational response of CeA astrocytes, as well as the proteomic and phosphoproteomic changes in dependent, non-dependent, and naïve mice. We identified astrocyte-specific alterations in neuroimmune functions and antioxidant/oxidative stress pathways in dependent animals while non-dependent EtOH drinking altered cytoskeletal plasticity related pathways. Proteomic analysis showed down-regulation of astrocyte physiological functions in dependent animals while phosphoproteomic analysis identified cytoskeleton remodeling in both dependent and non-dependent animals suggesting the development of a reactive astrocyte phenotype. Astrocyte morphological reconstruction showed increased CeA astrocyte complexity in dependent and non-dependent groups compared to naïve mice. The astrocyte-specific increase in neuroimmune functions, down-regulation of astrocyte homeostatic functions, alteration in protein phosphorylation-mediated cytoskeleton remodeling, and increased astrocyte complexity demonstrate EtOH induced astrocyte activation in the CeA and suggest the presence of both adaptive and maladaptive reactive astrocytes. These findings highlight the roles CeA astrocytes play in the progression of alcohol intake to dependence and are the first step in the identification of novel astrocyte-specific therapeutic approaches for alcohol use disorder through the potentiation of adaptive changes and inhibition of maladaptive changes in astrocytes.

Hashimoto, Joel↗

Analysis of shell type structures subjected to time dependent mechanical and thermal loading

A general mathematical model and solution methodologies for analyzing structural response of thin, metallic shell-type structures under large transient, cyclic or static thermomechanical loads is considered. Among the system responses, which are associated with these load conditions, are thermal buckling, creep buckling and ratchetting. Thus, geometric as well as material-type nonlinearities (of high order) can be anticipated and must be considered in the development of the mathematical model.

Simitses, G. J.↗

Dynamic Creep Buckling: Analysis of Shell Structures Subjected to Time-dependent Mechanical and Thermal Loading

The objective of the present research is to develop a general mathematical model and solution methodologies for analyzing the structural response of thin, metallic shell structures under large transient, cyclic, or static thermomechanical loads. Among the system responses associated with these loads and conditions are thermal buckling, creep buckling, and ratcheting. Thus geometric and material nonlinearities (of high order) can be anticipated and must be considered in developing the mathematical model. A complete, true ab-initio rate theory of kinematics and kinetics for continuum and curved thin structures, without any restriction on the magnitude of the strains or the deformations, was formulated. The time dependence and large strain behavior are incorporated through the introduction of the time rates of metric and curvature in two coordinate systems: fixed (spatial) and convected (material). The relations between the time derivative and the covariant derivative (gradient) were developed for curved space and motion, so the velocity components supply the connection between the equations of motion and the time rates of change of the metric and curvature tensors.

Simitses, G. J.↗

Pathways of proton release in the bacteriorhodopsin photocycle

The pH dependencies of the rate constants in the photocycles of recombinant D96N and D115N/D96N bacteriorhodopsins were determined from time-resolved difference spectra between 70 ns and 420 ms after photoexcitation. The results were consistent with the model suggested earlier for proteins containing D96N substitution: BR hv----K----L----M1----M2----BR. Only the M2----M1 back-reaction was pH-dependent: its rate increased with increasing [H+] between pH 5 and 8. We conclude from quantitative analysis of this pH dependency that its reverse, the M1----M2 reaction, is linked to the release of a proton from a group with a pKa = 5.8. This suggests a model for wild-type bacteriorhodopsin in which at pH greater than 5.8 the transported proton is released on the extracellular side from this as yet unknown group and on the 100-microseconds time scale, but at pH less than 5.8, the proton release occurs from another residue and later in the photocycle most likely directly from D85 during the O----BR reaction. We postulate, on the other hand, that proton uptake on the cytoplasmic side will be by D96 and during the N----O reaction regardless of pH. The proton kinetics as measured with indicator dyes confirmed the unique prediction of this model: at pH greater than 6, proton release preceded proton uptake, but at pH less than 6, the release was delayed until after the uptake. The results indicated further that the overall M1----M2 reaction includes a second kinetic step in addition to proton release; this is probably the earlier postulated extracellular-to-cytoplasmic reorientation switch in the proton pump.

NASA Discipline Exobiology↗

Towards Stability Analysis of Jump Linear Systems with State-Dependent and Stochastic Switching

This paper analyzes the stability of hierarchical jump linear systems where the supervisor is driven by a Markovian stochastic process and by the values of the supervised jump linear system s states. The stability framework for this class of systems is developed over infinite and finite time horizons. The framework is then used to derive sufficient stability conditions for a specific class of hybrid jump linear systems with performance supervision. New sufficient stochastic stability conditions for discrete-time jump linear systems are also presented.

Tejada, Arturo↗

Stresses and deformations in angle-ply composite tubes

The stress and deformations in angle-ply composite tubes subjected to axisymmetric thermal loading were investigated both experimentally and analytically. For the theoretical portion a generalized plane strain elasticity analysis was developed. The analysis included mechanical and thermal loading, and temperature-dependent material properties. The elasticity analysis was also used to study the effect of including a thin metallic coating on a graphite-epoxy tube. The stresses in the coatings were found to be quite high, exceeding the yield stress of aluminum. An important finding in the analytical studies was the fact that even tubes with a balanced-symmetric lamination sequence exhibit shear deformation, or twist. For the experimental portion an apparatus was developed to measure torsional and axial response in the temperature range of 140 to 360 K. Eighteen specimens were tested, combining three material systems, eight lamination sequences, and three off-axis ply orientation angles. For the twist response, agreement between analysis and experiment was found to be good. The axial response of the tubes tested was found to be greater than predicted by a factor of three. As a result, it is recommended that the thermally induced axial deformations be investigated, both experimentally and analytically.

Rousseau, Carl Q.↗

What Could Be Causing Global Ozone Depletion

The reported decline trend in global ozone between 1970 and 1986 may be in part an artifact of the analysis; the trend value appears to depend on the time interval selected for analysis--in relation to the 11-year solar cycle. If so, then the decline should diminish as one approaches solar maximum and includes data from 1987 to 1990. If the decline is real, its cause could be the result of natural and human factors other than just chlorofluorocarbons.

Singer, S. Fred↗

Time-dependent deformation of titanium metal matrix composites

A three-dimensional finite element program called VISCOPAC was developed and used to conduct a micromechanics analysis of titanium metal matrix composites. The VISCOPAC program uses a modified Eisenberg-Yen thermo-viscoplastic constitutive model to predict matrix behavior under thermomechanical fatigue loading. The analysis incorporated temperature-dependent elastic properties in the fiber and temperature-dependent viscoplastic properties in the matrix. The material model was described and the necessary material constants were determined experimentally. Fiber-matrix interfacial behavior was analyzed using a discrete fiber-matrix model. The thermal residual stresses due to the fabrication cycle were predicted with a failed interface, The failed interface resulted in lower thermal residual stresses in the matrix and fiber. Stresses due to a uniform transverse load were calculated at two temperatures, room temperature and an elevated temperature of 650 C. At both temperatures, a large stress concentration was calculated when the interface had failed. The results indicate the importance of accuracy accounting for fiber-matrix interface failure and the need for a micromechanics-based analytical technique to understand and predict the behavior of titanium metal matrix composites.

Bigelow, C. A.↗

NASA's Software Safety Standard

NASA relies more and more on software to control, monitor, and verify its safety critical systems, facilities and operations. Since the 1960's there has hardly been a spacecraft launched that does not have a computer on board that will provide command and control services. There have been recent incidents where software has played a role in high-profile mission failures and hazardous incidents. For example, the Mars Orbiter, Mars Polar Lander, the DART (Demonstration of Autonomous Rendezvous Technology), and MER (Mars Exploration Rover) Spirit anomalies were all caused or contributed to by software. The Mission Control Centers for the Shuttle, ISS, and unmanned programs are highly dependant on software for data displays, analysis, and mission planning. Despite this growing dependence on software control and monitoring, there has been little to no consistent application of software safety practices and methodology to NASA's projects with safety critical software. Meanwhile, academia and private industry have been stepping forward with procedures and standards for safety critical systems and software, for example Dr. Nancy Leveson's book Safeware: System Safety and Computers. The NASA Software Safety Standard, originally published in 1997, was widely ignored due to its complexity and poor organization. It also focused on concepts rather than definite procedural requirements organized around a software project lifecycle. Led by NASA Headquarters Office of Safety and Mission Assurance, the NASA Software Safety Standard has recently undergone a significant update. This new standard provides the procedures and guidelines for evaluating a project for safety criticality and then lays out the minimum project lifecycle requirements to assure the software is created, operated, and maintained in the safest possible manner. This update of the standard clearly delineates the minimum set of software safety requirements for a project without detailing the implementation for those requirements. This allows the projects leeway to meet these requirements in many forms that best suit a particular project's needs and safety risk. In other words, it tells the project what to do, not how to do it. This update also incorporated advances in the state of the practice of software safety from academia and private industry. It addresses some of the more common issues now facing software developers in the NASA environment such as the use of Commercial-Off-the-Shelf Software (COTS), Modified OTS (MOTS), Government OTS (GOTS), and reused software. A team from across NASA developed the update and it has had both NASA-wide internal reviews by software engineering, quality, safety, and project management. It has also had expert external review. This presentation and paper will discuss the new NASA Software Safety Standard, its organization, and key features. It will start with a brief discussion of some NASA mission failures and incidents that had software as one of their root causes. It will then give a brief overview of the NASA Software Safety Process. This will include an overview of the key personnel responsibilities and functions that must be performed for safety-critical software.

Ramsay, Christopher M.↗

Space radiator simulation system analysis

A transient heat transfer analysis was carried out on a space radiator heat rejection system exposed to an arbitrarily prescribed combination of aerodynamic heating, solar, albedo, and planetary radiation. A rigorous analysis was carried out for the radiation panel and tubes lying in one plane and an approximate analysis was used to extend the rigorous analysis to the case of a curved panel. The analysis permits the consideration of both gaseous and liquid coolant fluids, including liquid metals, under prescribed, time dependent inlet conditions. The analysis provided a method for predicting: (1) transient and steady-state, two dimensional temperature profiles, (2) local and total heat rejection rates, (3) coolant flow pressure in the flow channel, and (4) total system weight and protection layer thickness.

Black, W. Z.↗

Vanishing rainbows near orbiting and the energy dependence of rainbow scattering - Relation to properties of the potential

The energy threshold behavior of elastic rainbow scattering near the transition to orbiting is derived. Analysis of the energy dependence of the rainbow angle shows that the full range from high energies down to orbiting can be fitted with two parameters. Thus, measurements of the rainbow angle can give essentially only two pieces of information about the potential. For potentials of common shapes, such measurements are sensitive to regions of the potential just beyond the minimum and give information about the shape of the potential in this range. However, neither a minimum nor a point of inflection in the potential is necessary for rainbow scattering.

Greene, E. F.↗

Importance of Sample Handling and Preparation for Surface Analysis: A Summary of ISO Standard 20579 Part 1, Documenting and Reporting the Handling of Specimens Prior to Analysis

Reliable and reproducible analysis of surfaces is critically dependent on how samples have been collected, handled, and prepared before analysis. Although there are important, well-established general guidelines to minimize unintended alteration of the surfaces to be analyzed, specific handling steps depend on the nature of the samples and information desired. Assessments of the validity and reliability of the results require adequate information about sampling, handling, and processing. ISO standard 20579 part 1 describes the information to be recorded and reported for samples that are prepared or submitted for surface analysis. This paper summarizes elements of the standard, which includes annexes that justify and inform the sample handling processes. Also included is a checklist of information that needs to be recorded and reported and an appendix containing an example of a form that might be used to report the information.

AES↗