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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 307 records · Page 17
All sourcesNASA NTRSDOE OSTI
NASA NTRS2004

Low Earth Orbital Atomic Oxygen Interactions With Materials

Atomic oxygen is formed in the low Earth orbital environment (LEO) by photo dissociation of diatomic oxygen by short wavelength (< 243 nm) solar radiation which has sufficient energy to break the 5.12 eV O2 diatomic bond in an environment where the mean free path is sufficiently long (~ 108 meters) that the probability of reassociation or the formation of ozone (O3) is small. As a consequence, between the altitudes of 180 and 650 km, atomic oxygen is the most abundant species. Spacecraft impact the atomic oxygen resident in LEO with sufficient energy to break hydrocarbon polymer bonds, causing oxidation and thinning of the polymers due to loss of volatile oxidation products. Mitigation techniques, such as the development of materials with improved durability to atomic oxygen attack, as well as atomic oxygen protective coatings, have been employed with varying degrees of success to improve durability of polymers in the LEO environment. Atomic oxygen can also oxidize silicones and silicone contamination to produce non-volatile silica deposits. Such contaminants are present on most LEO missions and can be a threat to performance of optical surfaces. The LEO atomic oxygen environment, its interactions with materials, results of space testing, computational modeling, mitigation techniques, and ground laboratory simulation procedures and issues are presented.

Banks, Bruce A.↗
NASA NTRS1988

Analysis of lipophilic pigments from a phototrophic microbial mat community by high performance liquid chromatography

As assay for lipophilic pigments in phototrophic microbial mat communities using reverse phase-high performance liquid chromatography was developed which allows the separation of 15 carotenoids and chloropigments in a single 30 min program. Lipophilic pigments in a laminated mat from a commercial salina near Laguna Guerrero Negro, Baja California Sur, Mexico reflected their source organisms. Myxoxanthophyll, echinenone, canthaxanthin, and zeaxanthin were derived from cyanobacteria; chlorophyll c, and fucoxanthin from diatoms; chlorophyll a from cyanobacteria and diatoms; bacteriochlorophylls a and c, bacteriophaeophytin a, and gamma-carotene from Chloroflexus spp.; and beta-carotene from a variety of phototrophs. Sensitivity of detection was 0.6-6.1 ng for carotenoids and 1.7-12 ng for most chloropigments. This assay represents a significant improvement over previous analyses of lipophilic pigments in microbial mats and promises to have a wider application to other types of phototrophic communities.

NASA Discipline Exobiology↗
NASA NTRS2004

The Response of the North Atlantic Bloom to NAO Forcing

Results from the climatologically forced coupled ice/ocean/biogeochemical model that covers the Arctic and North Atlantic Oceans are presented and compared to the chlorophyll fields of satellite-derived ocean color measurements. Biogeochemical processes in the model are determined from the interactions among four phytoplankton functional groups (diatoms, chlorophytes, cyanobacteria and coccolithophores) and four nutrients (nitrate, ammonium, silicate and dissolved iron). The model simulates the general large-scale pattern in April, May and June, when compared to both satellite-derived and in situ observations. The subpolar North Atlantic was cool in the 1980s and warm in the latter 1990s, corresponding to the CZCS and SeaWiFS satellite observing periods, respectively. The oceanographic conditions during these periods resemble the typical subpolar upper ocean response to the NAO+ and NAO-phases, respectively. Thus, we use the atmospheric forcing composites from the two NAO phases to simulate the variability of the mid-ocean bloom during the satellite observing periods. The model results show that when the subpolar North Atlantic is cool, the NAO+ case, more nutrients are available in early spring than when the North Atlantic is warm, the NAO-case. However, the NAO+ simulation produces a later bloom than the NAO-simulation. This difference in the bloom times is also identified in SeaWiFS and CZCS satellite measurements. In the model results, we can trace the difference to the early diatom bloom due to a warmer upper ocean. The higher nutrient abundance in the NAO+ case did not provide larger total production than in the NAO- case, instead the two cases had a comparable area averaged amplitude. This leads us to conclude that in the subpolar North Atlantic, the timing of the spring phytoplankton bloom depends on surface temperature and the magnitude of the bloom is not significantly impacted by the nutrient abundance.

Mizoguchi, Ken-Ichi↗
NASA NTRS2012

Modeling the Flow of Rarefied Gases at NASA

At modest temperatures, the thermal energy of atmospheric diatomic gases such as nitrogen is primarily distributed between only translational and rotational energy modes. Furthermore, these energy modes are fully excited such that the specific heat at constant volume is well approximated by the simple expression C(sub v) = 5/2 R. As a result, classical mechanics provides a suitable approximation at such temperatures of the true quantum mechanical behavior of the inter-molecular collisions of such molecules. Using classical mechanics, the transfer of energy between rotational and translation energy modes is studied. The approach of Lordi and Mates is adopted to compute the trajectories and time dependent rotational orientations and energies during the collision of two non-polar diatomic molecules. A Monte-Carlo analysis is performed collecting data from the results of many such simulations in order to estimate the rotational relaxation time. A Graphical Processing Unit (GPU) is employed to improve the performance of the Monte-Carlo analysis. A comparison of the performance of the GPU implementation to an implementation on traditional computer architecture is made. Effects of the assumed inter-molecular potential on the relaxation time are studied. The seminar will also present highlights of computational analyses performed at NASA Johnson Space Center of heat transfer in rarefied gases.

Forrest E. Lumpkin, III↗
NASA NTRS2014

Interannual Variation in Phytoplankton Class-Specific Primary Production at a Global Scale

We used the NASA Ocean Biogeochemical Model (NOBM) combined with remote sensing data via assimilation to evaluate the contribution of 4 phytoplankton groups to the total primary production. First we assessed the contribution of each phytoplankton groups to the total primary production at a global scale for the period 1998-2011. Globally, diatoms were the group that contributed the most to the total phytoplankton production (50, the equivalent of 20 PgC y-1. Coccolithophores and chlorophytes each contributed to 20 (7 PgC y-1 of the total primary production and cyanobacteria represented about 10 (4 PgC y(sub-1) of the total primary production. Primary production by diatoms was highest in high latitude (45) and in major upwelling systems (Equatorial Pacific and Benguela system). We then assessed interannual variability of this group-specific primary production over the period 1998-2011. Globally the annual relative contribution of each phytoplankton groups to the total primary production varied by maximum 4 (1-2 PgC y-1. We assessed the effects of climate variability on the class-specific primary production using global (i.e. Multivariate El Nio Index, MEI) and regional climate indices (e.g. Southern Annular Mode (SAM), Pacific Decadal Oscillation (PDO) and North Atlantic Oscillation (NAO)). Most interannual variability occurred in the Equatorial Pacific and was associated with climate variability as indicated by significant correlation (p 0.05) between the MEI and the class-specific primary production from all groups except coccolithophores. In the Atlantic, climate variability as indicated by NAO was significantly correlated to the primary production of 2 out of the 4 groups in the North Central Atlantic (diatomscyanobacteria) and in the North Atlantic (chlorophytes and coccolithophores). We found that climate variability as indicated by SAM had only a limited effect on the class-specific primary production in the Southern Ocean. These results provide a modeling and data assimilation perspective to phytoplankton partitioning of primary production and contribute to our understanding of the dynamics of the carbon cycle in the oceans at a global scale.

Chl-a↗
NASA NTRS2014

Interannual Variation in Phytoplankton Class-specific Primary Production at a Global Scale

Phytoplankton is responsible for over half of the net primary production on earth. The knowledge on the contribution of various phytoplankton groups to the total primary production is still poorly understood. Data from satellite observations suggest that for upwelling regions, photosynthetic rates by microplankton is higher than that of nanoplankton but that when the spatial extent is considered, the production by nanoplankton is comparable or even larger than microplankton. Here, we used the NASA Ocean Biogeochemical Model (NOBM) combined with remote sensing data via assimilation to evaluate the contribution of 4 phytoplankton groups to the total primary production. Globally, diatoms were the group that contributed the most to the total phytoplankton production (approx. 50%) followed by coccolithophores and chlorophytes. Primary production by diatoms was highest in high latitude (>45 deg) and in major upwelling systems (Equatorial Pacific and Benguela system). We assessed the effects of climate variability on the class-specific primary production using global (i.e. Multivariate El Nino Index, MEI) and 'regional' climate indices (e.g. Southern Annular Mode (SAM), Pacific Decadal Oscillation (PDO) and North Atlantic Oscillation (NAO)). Most interannual variability occurred in the Equatorial Pacific and was associated with climate variability. These results provide a modeling and data assimilation perspective to phytoplankton partitioning of primary production and contribute to our understanding of the dynamics of the carbon cycle in the oceans at a global scale.

OBM↗
NASA NTRS2014

Locating Noctiluca Miliaris in the Arabian Sea: An Optical Proxy Approach

Coincident with shifting monsoon weather patterns over India, the phytoplankter Noctiluca miliaris has recently been observed to be dominating phytoplankton blooms in the northeastern Arabian Sea during the winter monsoons. Identifying the exact environmental and/or ecological conditions that favor this species has been hampered by the lack of concurrent environmental and biological observations on time and space scales relevant to ecologic and physiologic processes. We present a bio-optical proxy for N. miliaris measured on highly resolved depth scales coincident with hydrographic observations with the goal to identify conducive hydrographic conditions for the bloom. The proxy is derived from multichannel excitation chlorophyll a fluorescence and is validated with microscopy, pigment composition, and spectral absorption. Phytoplankton populations dominated by either diatoms or other dinoflagellates were additionally discerned. N. miliaris populations in full bloom were identified offshore in low-nutrient and low-N : P ratio surface waters within a narrow temperature and salinity range. These populations transitioned to high-biomass diatom-dominated coastal upwelling populations. A week later, the N. miliaris blooms were observed in declining phase, transitioning to very-low-biomass populations of non-N. miliaris dinoflagellates. There were no clear hydrographic conditions uniquely associated with the N. miliaris populations, although N. miliaris was not found in the upwelling or extremely oligotrophic waters. Taxonomic transitions were not discernible in the spatial structure of the bloom as identified by the ocean color Chl imagery, indicating that in situ observations may be necessary to resolve community structure, particularly for populations below the surface.

Arabian Sea↗
NASA NTRS2013

Interannual Variation in Phytoplankton Primary Production at a Global Scale

We used the NASA Ocean Biogeochemical Model (NOBM) combined with remote sensing data via assimilation to evaluate the contribution of four phytoplankton groups to the total primary production. First, we assessed the contribution of each phytoplankton groups to the total primary production at a global scale for the period 1998-2011. Globally, diatoms contributed the most to the total phytoplankton production ((is)approximately 50%, the equivalent of 20 PgC·y1). Coccolithophores and chlorophytes each contributed approximately 20% ((is) approximately 7 PgC·y1) of the total primary production and cyanobacteria represented about 10% ((is) approximately 4 PgC·y1) of the total primary production. Primary production by diatoms was highest in the high latitudes ((is) greater than 40 deg) and in major upwelling systems (Equatorial Pacific and Benguela system). We then assessed interannual variability of this group-specific primary production over the period 1998-2011. Globally the annual relative contribution of each phytoplankton groups to the total primary production varied by maximum 4% (1-2 PgC·y1). We assessed the effects of climate variability on group-specific primary production using global (i.e., Multivariate El Niño Index, MEI) and "regional" climate indices (e.g., Southern Annular Mode (SAM), Pacific Decadal Oscillation (PDO) and North Atlantic Oscillation (NAO)). Most interannual variability occurred in the Equatorial Pacific and was associated with climate variability as indicated by significant correlation (p (is) less than 0.05) between the MEI and the group-specific primary production from all groups except coccolithophores. In the Atlantic, climate variability as indicated by NAO was significantly correlated to the primary production of 2 out of the 4 groups in the North Central Atlantic (diatoms/cyanobacteria) and in the North Atlantic (chlorophytes and coccolithophores). We found that climate variability as indicated by SAM had only a limited effect on group-specific primary production in the Southern Ocean. These results provide a modeling and data assimilation perspective to phytoplankton partitioning of primary production and contribute to our understanding of the dynamics of the carbon cycle in the oceans at a global scale.

Coccolithophores↗
NASA NTRS2018

Biologically Inspired Radiation Reflector

A thermal protection system (TPS) comprising a mixture of silicon carbide and SiOx that has been converted from Si that is present in a collection of diatom frustules and at least one diatom has quasi-periodic pore-to-pore separation distance d(p-p) in a selected range. Where a heat shield comprising the converted SiC/SiOx frustules receives radiation, associated with atmospheric (re)entry, a portion of this radiation is reflected so that radiation loading of the heat shield is reduced.

Johnson, Sylvia M.↗
NASA NTRS2019

Laser Rayleigh Scattering for Flow Density and Condensation Measurements in the Supercooled Mach-14 Free-Stream at AEDC Wind Tunnel No. 9

Laser Rayleigh scattering was used to investigate clusters in the free-stream flow at Arnold Engineering Development Center’s Tunnel 9 (T9). The facility was run at Mach-14, with a pure-N2 flow medium, and at several total pressures and temperatures. Using an excimer laser operating at 248 nm, the Rayleigh instrument imaged scattering from the focused laser beam in the free-stream. As a wind-tunnel flow is accelerated, it cools and approaches the condensation boundary. As a precursor to condensation, small clusters of molecules are first formed, but the individual clusters are too small to be spatially resolved in typical images of the beam. Thus clusters effectively add a spatially smooth background signal to the pure diatomic-molecule Rayleigh signal. The main result of the present work is that clustering was not significant. After correcting for interference by small particles imbedded in the T9 flow, cluster scattering was unobservable or smaller than one standard deviation (1-sigma) of the uncertainties for almost all tunnel runs. The total light scattering level was measured to be 1.05 +/- 0.15 (1-sigma) of the expected diatomic scattering, when averaged over the entire usable data set. This result included flow conditions that were supercooled to temperatures of ~ 20 K, about 25 K below the condensation limit of ~ 45 K. Thus the Mach-14 nozzle flow is essentially cluster-free for many supercooled conditions that might be used to extend the facility operating range to larger Reynolds numbers.

Herring, Gregory C.↗
NASA NTRS2021

Diagnosing Seasonal to Multi-decadal Phytoplankton Group Dynamics in a Highly Productive Coastal Ecosystem

The Santa Barbara Channel, CA (SBC) is a biodiverse marine ecosystem fueled largely by phytoplankton productivity, and the composition of the phytoplankton community influences the magnitude and fates of this productivity. Here, we create a 22-year monthly time series of phytoplankton biomarker pigment concentrations in the SBC by combining 12 years of high performance liquid chromatography phytoplankton pigment concentrations with bio-optical models and 10 additional years of bio-optical observations. The bio-optical models skillfully predict biomarker pigment concentrations representative of five distinct phytoplankton groups (PGs; diatoms, dinoflagellates, chlorophytes, prymnesiophytes, and picophytoplankton) and resolve seasonal responses to the annual upwelling-relaxation cycle for all PGs except the dinoflagellates. Our observations indicate that nanophytoplankton groups respond most rapidly to seasonal upwelling, followed by diatoms, and then by picophytoplankton as the water column stratifies in the summer. A Regional Ocean Modeling System (ROMS) solution is used to relate advection of different source waters to the observed PG dynamics. The ROMS simulation results suggest that, on seasonal time scales, pronounced cross-SBC differences in PG seasonality are related to cross-SBC differences in source waters. El Niño Southern Oscillation events drive interannual variability in the upwelling response of most PGs. On decadal time scales, dinoflagellate blooms are associated with the warm phase of the North Pacific Gyre Oscillation and anomalous advection of Southern California Bight source waters into the SBC. Taken together, our results provide a novel view of phytoplankton community succession in response to seasonal upwelling by considering the dynamics of pico- and nano-phytoplankton and suggest that regional surface ocean advection plays a substantial role in driving phytoplankton composition in the SBC.

Phytoplankton↗
NASA NTRS2023

Impact of Pacific Ocean Heatwaves on Phytoplankton Community Composition

Since 2013, marine heatwaves have become recurrent throughout the equatorial and northeastern Pacific Ocean and are expected to increase in intensity relative to historic norms. Among the ecological ramifications associated with these high temperature anomalies are increased mortality of higher trophic organisms such as marine mammals and seabirds, which are likely triggered by changes in the composition of phytoplankton, the base of the marine trophic food web. Here, we assimilated satellite ocean color data into an ocean biogeochemical model to describe changes in the abundance of phytoplankton functional types (PFTs) during the last decade's (2010s) warm anomalies in the equatorial and northeastern Pacific Ocean. We find important changes associated with the "Blob" warm anomaly in the Gulf of Alaska, where reduced silica supply led to a switch in community composition from diatoms to dinoagellates, resulting in an increase in surface ocean chlorophyll during the Summer-Fall of 2014. A more dramatic change was observed in the equatorial Pacific, where the extreme warm conditions of the 2016 El Niño resulted in a major decline of about 40 % in surface chlorophyll, which was associated with a nearly total collapse in diatoms.

Pacific Ocean↗
NASA NTRS2023

Phytoplankton Diversity and Chemotaxonomy in Contrasting North Pacific Ecosystems

Background. Phytoplankton is the base of majority of ocean ecosystems. It is responsible for half of the global primary production, and different phytoplankton taxa have a unique role in global biogeochemical cycles. In addition, phytoplankton abundance and diversity are highly susceptible to climate induced changes, hence monitoring of phytoplankton and its diversity is important and necessary. Methods. Water samples for phytoplankton and photosynthetic pigment analyses were collected in boreal winter 2017, along transect in the North Pacific Subtropical Gyre (NPSG) and the California Current System (CCS). Phytoplankton community was analyzed using light and scanning electron microscopy and photosynthetic pigments by high-performance liquid chromatography. To describe distinct ecosystems, monthly average satellite data of MODIS Aqua Sea Surface temperature and Chlorophyll a concentration, as well as Apparent Visible Wavelength were used. Results. A total of 207 taxa have been determined, mostly comprised of coccolithophores (35.5%), diatoms (25.2%) and dinoflagellates (19.5%) while cryptophytes, phytoflagellates and silicoflagellates were included in the group ``others" (19.8%). Phytoplankton spatial distribution was distinct, indicating variable planktonic dispersal rates and specific adaptation to ecosystems. Dinoflagellates, and nano-scale coccolithophores dominated NPSG, while micro-scale diatoms, and cryptophytes prevailed in CCS. A clear split between CCS and NPSG is evident in dendogram visualising LINKTREE constrained binary divisive clustering analysis done on phytoplankton counts and pigment oncentrations. Of all pigments determined, alloxanthin, zeaxanthin, divinyl chlorophyll b and lutein have highest correlation to phytoplankton counts. Conclusion. Combining chemotaxonomy and microscopy is an optimal method to determine phytoplankton diversity on a large-scale transect. Distinct communities between the two contrasting ecosystems of North Pacific reveal phytoplankton groups specific adaptations to trophic state, and support the hypothesis of shift from microto nano-scale taxa due to sea surface temperatures rising, favoring stratification and oligotrophic conditions.

oceanography↗
NASA NTRSDate not supplied

Impact of Pacific Ocean Heatwaves on Phytoplankton Community Composition

Since 2013, marine heatwaves have become recurrent throughout the equatorial and northeastern Pacific Ocean and are expected to increase in intensity relative to historic norms. Among the ecological ramifications associated with these high temperature anomalies are increased mortality of higher trophic organisms such as marine mammals and seabirds, which are likely triggered by changes in the composition of phytoplankton, the base of the marine trophic food web. Here, we assimilated satellite ocean color data into an ocean biogeochemical model to describe changes in the abundance of phytoplankton functional types (PFTs) during the last decade’s (2010s) warm anomalies in the equatorial and northeastern Pacific Ocean. We find important changes associated with the “Blob” warm anomaly in the Gulf of Alaska, where reduced silica supply led to a switch in community composition from diatoms to dinoflagellates, resulting in an increase in surface ocean chlorophyll during the Summer–Fall of 2014. A more dramatic change was observed in the equatorial Pacific, where the extreme warm conditions of the 2016 El Niño resulted in a major decline of about 40% in surface chlorophyll, which was associated with a nearly total collapse in diatoms.

Lionel A Quintero↗
NASA NTRSDate not supplied

Impact of Pacific Ocean Heatwaves on Phytoplankton Community Composition

Since 2013, marine heatwaves have become recurrent throughout the equatorial and northeastern Pacific Ocean and are expected to increase in intensity relative to historic norms. Among the ecological ramifications associated with these high temperature anoma- lies are increased mortality of higher trophic organisms such as marine mammals and sea- birds, which are likely triggered by changes in the composition of phytoplankton, the base of the marine trophic food web. Here, we assimilated satellite ocean color data into an ocean biogeochemical model to describe changes in the abundance of phytoplankton functional types (PFTs) during the last decade’s (2010s) warm anomalies in the equatorial and northeastern Pacific Ocean. We find important changes associated with the “Blob” warm anomaly in the Gulf of Alaska, where reduced silica supply led to a switch in community composition from diatoms to dinoflagellates, resulting in an increase in surface ocean chlorophyll during the Summer–Fall of 2014. A more dramatic change was observed in the equatorial Pacific, where the extreme warm conditions of the 2016 El Niño resulted in a major decline of about 40% in surface chlorophyll, which was associated with a nearly total collapse in diatoms.

Lionel A. Arteaga↗
DOE OSTI2020

Late Holocene history of Tokotan Lake (Kuril Archipelago, Russian Far East): The use of lacustrine records for paleoclimatic reconstructions from geologically dynamic settings

A high-resolution, multiproxy analysis of a core from Tokotan Lake, Urup Island, illustrates the complex paleoenvironmental signals that can be preserved in sedimentary deposits from geologically active areas, such as the Kuril Archipelago. Diatom and geochemical analyses of the Tokotan core suggest a shallowing and lessening of the lake area over the last ~3450 cal BP. Without other proxies, the record could be interpreted as showing a general decrease in precipitation over the Late Holocene. However, palynological data indicate no change in vegetation, thereby implying no significant climatic variation. Neither of these paleoclimatic interpretations agrees with Late Holocene reconstructions from the Kuril Archipelago or the Russian mainland. Paleomagnetic data imply variable sediment sources during the lake's history, indicating alterations within the Tokotan catchment (e.g., shifts in gradients or sediment loads in the inflowing streams). Such changes would be particularly important in the Shabalina River, which today has formed a partial dam across the lake's outlet. Here, the results of the Tokotan study indicate that other factors (e.g., volcanism, seismic activity, sea-level changes) rather than climate were more probable determinants of the Late Holocene lake record. Given the geologic dynamism of the region, it is perhaps not surprising that paleo-records from the Kuril Islands display an inconsistency in the numbers and/or duration of proposed Holocene climatic oscillations, underscoring the importance of multiproxy investigations in areas that are or have been geologically dynamic.

58 GEOSCIENCES↗
DOE OSTI2020

Prediction of chlorine and fluorine crystal structures at high pressure using symmetry driven structure search with geometric constraints

The high-pressure properties of fluorine and chlorine are not yet well understood because both are highly reactive and volatile elements, which have made conducting diamond anvil cell and x-ray diffraction experiments a challenge. Here, we use ab initio methods to search for stable crystal structures of both elements at megabar pressures. We demonstrate how symmetry and geometric constraints can be combined to efficiently generate crystal structures that are composed of diatomic molecules. Furthermore, our algorithm extends the symmetry driven structure search method by adding constraints for the bond length and the number of atoms in a molecule while still maintaining generality. As a method of validation, we have tested our approach for dense hydrogen and reproduced the known molecular structures of Cmca-12 and Cmca-4. We apply our algorithm to study chlorine and fluorine in the pressure range of 10 GPa–4000 GPa while considering crystal structures with up to 40 atoms per unit cell. We predict chlorine to follow the same series of phase transformations as elemental iodine from Cmca to Immm to Fm3¯m, but at substantially higher pressures. We predict fluorine to transition from a C2/c to Cmca structure at 70 GPa, to a novel orthorhombic and metallic structure with P42/mmc symmetry at 2500 GPa, and finally to its cubic analog form with Pm3¯n symmetry at 3000 GPa.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗