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Lunar and Planetary Science XXXVI, Part 8

The following topics were discussed: Why Small is Beautiful, and How to Detect Another 10 Billion Small Main Belt Asteroids; Basalts in Mare Humorum and S.E. Procellarum; Basalts in Mare Serenitatis, Lacus Somniorum, Lacus Mortis and Part of Mare Tranquillitatis; Revised Thorium Abundances for Lunar Red Spots; Integrating Global-Scale Mission Datasets - Understanding the Martian Crust; Comparing Goldstone Solar System Radar Earth-based Observations of Mars with Orbital Datasets; Water Ice Clouds in the Martian Atmosphere: A View from MGS TES; Lunar Meteorite Northeast Africa 001: An Anorthositic Regolith Breccia with Mixed Highland/Mare Components; One Spectrometer, Two Spectra: Complementary Hemispherical Reflectance and Thermal Emission Spectroscopy Using a Single FTIR Instrument; Alteration Phases Associated with High Concentrations of Orthopyroxene and Olivine on Mars; Experimental Crystallization of Fe-rich Basalt: Application to Cooling Rate and Oxygen Fugacity of Nakhlite MIL-03346; Thermo-Chemical Convection in Europa s Icy Shell with Salinity; Tectonic Pressurization of Aquifers in the Formation of Mangala and Athabasca Valles on Mars; 3D Structural Interpretation of the Eagle Butte Impact Structure, Alberta, Canada; Ultraviolet Views of Enceladus, Tethys, and Dione; Crustal Plateaus as Ancient Large Impact Features: A Hypothesis; New Observations of Crustal Plateau Surface Histories, Venus: Implications for Crustal Plateau Hypotheses; Detailed Mineralogical Characterizations of Four S-Asteroids: 138 Tolosa, 306 Unitas, 346 Hermentaria, and 480 Hansa; Working with Planetary Coordinate Reference Systems; Bilingual Map of Mercury; and The Io Mountain Online Database.

Source record↗

Solar System Visualizations

Solar System Visualization products enable scientists to compare models and measurements in new ways that enhance the scientific discovery process, enhance the information content and understanding of the science results for both science colleagues and the public, and create.visually appealing and intellectually stimulating visualization products. Missions supported include MER, MRO, and Cassini. Image products produced include pan and zoom animations of large mosaics to reveal the details of surface features and topography, animations into registered multi-resolution mosaics to provide context for microscopic images, 3D anaglyphs from left and right stereo pairs, and screen captures from video footage. Specific products include a three-part context animation of the Cassini Enceladus encounter highlighting images from 350 to 4 meter per pixel resolution; Mars Reconnaissance Orbiter screen captures illustrating various instruments during assembly and testing at the Payload Hazardous Servicing Facility at Kennedy Space Center; and an animation of Mars Exploration Rover Opportunity's 'Rub al Khali' panorama where the rover was stuck in the deep fine sand for more than a month. This task creates new visualization products that enable new science results and enhance the public's understanding of the Solar System and NASA's missions of exploration.

Brown, Alison M.↗

Complex Organic Materials on Planetary Satellites and Other Small Bodies of the Solar System

The search for organic materials on small bodies of the Solar System is conducted spectroscopically from Earth-based telescopes and from spacecraft. Although the carbonaceous meteorites carry a significant inventory of complex organic solids, the sources of these meteorites have not been identified. Infrared spectra of a sample of the suspected sources, the C- and D-class asteroids, including new data from the Spitzer Space Telescope, show signatures of silicates, but none diagnostic of organic compounds. In the absence of discrete spectral features, the low albedos and colors in the visible and near-IR spectral regions are the principal links between the organic-bearing meteorites and the asteroids. While Pluto and a few trans-neptunian objects show spectral signatures of frozen CH4. Solid CH3OH has been identified on two Centaur objects in the outer Solar System. In some cases the red colors of those objects suggest the presence of tholins. The VIMS instrument aboard the Cassini spacecraft in orbit around Saturn has detected near-IR spectral features on at least three of Saturn's satellites that are indicative or suggestive of organic molecules. One entire hemisphere of the satellite Iapetus is covered with low-albedo material that shows a spectral signature of aromatic hydrocarbons (3.3 microns) and the -CH2 stretching mode bands of an aliphatic component. Organics absorbing at 3.44 microns are suspected in the region of the south pole of Enceladus, and also on the surface of Phoebe. Organic material may originate on icy bodies in the current epoch by various processes of energy deposition into native material, or they may fall to the surface from an external (probably cometary) source. Some organic material may be pre-solar, having originated in the interstellar medium before the formation of the Solar System. Using the techniques of remote sensing, its detection and analysis are slow and difficult.

Cruikshank, Dale P.↗

Comets, Asteroids, and the Origin of the Biosphere

During the past few decades, the role of comets in the delivery of water, organics, and prebiotic chemicals to the Biosphere of Earth during the Hadean (4.5-3.8 Ga) period of heavy bombardment has become more widely accepted. However comets are still largely regarded as frigid, pristine bodies of protosolar nebula material that are entirely devoid of liquid water and consequently unsuitable for life in any form. Complex organic compounds have been observed comets and on the water rich asteroid 1998 KY26, which has color and radar reflectivity similar to the carbonaceous meteorites. Near infrared observations have indicated the presence of crystalline water ice and ammonia hydrate on the large Kuiper Belt object (50000) Quaoar with resurfacing that may indicate cryovolcanic outgassing and the Cassini spacecraft has detected water-ice geysers on Saturn s moon Enceladus. Spacecraft observations of the chemical compositions and characteristics of the nuclei of several comets (Halley, Borrelly, Wild 2, and Tempel 1) have now firmly established that comets contain a suite of complex organic chemicals; water is the predominant volatile; and that extremely high temperatures (approx.350-400 K) can be reached on the surface of the very black (albedo-0.03) nuclei when the comets are with 1.5 AU from the Sun. Impact craters and pinnacles observed on comet Wild 2 suggest a thick crust and episodic outbursts and jets observed on the nuclei of several comets are interpreted as indications that localized regimes of liquid water and water vapor can periodically exist beneath the crust of some comets. The Deep Impact observations indicate that the temperature on the nucleus of of comet Tempel 1 at 1.5 AU varied from 330K on the sunlit side to a minimum of 280+/-8 K. It is interesting that even the coldest region of the comet surface was slightly above the ice/liquid water phase transition temperature. These results suggest that pools and films of liquid water can exist in a wide range of temperatures in cavities and voids at different depths just beneath the crust of a comet. The possibility that liquid water may exist over a wide range of temperatures on comets significantly enhances the possibility that these bodies may harbor niches suitable for microbial communities and ecosystems. Such niches would by ideal for the growth of psychrophilic, mesophilic, and possibly even thermophilic chemolithotrophs and photoautotrophs such as the motile filamentous cyanobacteria (e.g., Calothrix, Oscillatoria, Phormidium, and Spirulina) that can grow in geothermal springs and geysers at temperatures ranging from 320K to 345K and in cold polar desert soils. This paper reviews the observational data in support of the hypothesis that liquid water can exist in permafrost-like active regions just beneath the surface of comets when near perihelion and provides additional arguments in support of the hypothesis that comets, carbonaceous meteorites, and asteroids may have played a significant role in the origin and evolution of the Biosphere and in the distribution of microbial life throughout the Solar System.

Hoover, Richard B.↗

Titan Ion Composition at Magnetosphere-Ionosphere Transition Region

Using Cassini Plasma Spectrometer (CAPS) Ion Mass Spectrometer (IMS) ion composition data, we will investigate the compositional changes at the transition region between Saturn's magnetospheric flow and Titan's upper ionosphere. It is this region where scavenging of Titan's upper ionosphere can occur, where it is then dragged away by the magnetospheric flow as cold plasma for Saturn's magnetosphere. This cold plasma may form plumes as originally proposed by (1) during the Voyager 1 epoch. This source of cold plasma may have a unique compositional signature such as methane group ions. Water group ions that are observed in Saturn's outer magnetosphere (2,3) are relatively hot and probably come from the inner magnetosphere where they are born from fast neutrals escaping Enceladus (4) and picked up in the outer magnetosphere as hot plasma (5). This scenario will be complicated by pickup methane ions within Titan's mass loading region, as originally predicted by (6) based on Voyager 1 data and observationally confirmed by (3,7) using CAPS IMS data. But, CH4(+) ions or their fragments can only be produced as pickup ions from Titan's exosphere which can extend beyond the transition region of concern here, while CH5(+) ions can be scavenged from Titan's ionosphere. We will investigate these possibilities.

Sittler, Edward C.↗

Titan Orbiter with Aerorover Mission (TOAM)

We propose to develop a new mission to Titan called Titan Orbiter with Aerorover Mission (TOAM). This mission is motivated by the recent discoveries of Titan, its atmosphere and its surface by the Huygens Probe, and a combination of in situ, remote sensing and radar mapping measurements of Titan by the Cassini orbiter. Titan is a body for which Astrobiology (i.e., prebiotic chemistry) will be the primary science goal of any future missions to it. TOAM is planned to use an orbiter and balloon technology (i.e., aerorover). Aerobraking will be used to put payload into orbit around Titan. One could also use aerobraking to put spacecraft into orbit around Saturn first for an Enceladus phase of the mission and then later use aerocapture to put spacecraft into orbit around Titan. The Aerorover will probably use a hot air balloon concept using the waste heat from the MMRTG approx. 1000 watts. Orbiter support for the Aerorover is unique to our approach for Titan. Our strategy to use an orbiter is contrary to some studies using just a single probe with balloon. Autonomous operation and navigation of the Aerorover around Titan will be required, which will include descent near to the surface to collect surface samples for analysis (i.e., touch and go technique). The orbiter can provide both relay station and GPS roles for the Aerorover. The Aerorover will have all the instruments needed to sample Titan's atmosphere, surface, possible methane lakes-rivers, use multi-spectral imagers for surface reconnaissance; to take close up surface images; take core samples and deploy seismometers during landing phase. Both active and passive broadband remote sensing techniques will be used for surface topography, winds and composition measurements.

Sittler, E. C., Jr.↗

Microbial Extremophiles in Evolutionary Aspect

The microflora of the cryosphere of planet Earth provides the best analogs for life forms that might be found in the permafrost or polar ice caps of Mars, near the surface of the cometary nuclei, or in the liquid water beneath the ice crusts of icy moons of Jupiter and Saturn. For astrobiology the focus on the study alkaliphilic microorganisms was enhanced by the findings of abundant carbonates and carbonate globules rimmed with possibly biogenic magnetites in association with the putative microfossils in the ALH84001 meteorite. Although the ALH84001 "nanofossils" were to small and simple to be unambiguously recognized as biogenic, they stimulated Astrobiology research and studies of microbial extremophiles and biomarkers in ancient rocks and meteorites. Recent studies of CI and CM carbonaceous meteorites have resulted in the detection of the well-preserved mineralized remains of coccoidal and" filamentous microorganisms in cyanobacterial mats. Energy Dispersive X-ray Analysis has shown anomalous biogenic element ratios clearly indicating they are not recent biological contaminants. This paper reviews microbial extremophiles in context of their significance to Astrobiology and the evolution of life. Extremophilic microorganisms on Earth are models for life that might endure high radiation environments in the ice near the surface of comets or on the icy moons of Jupiter and Saturn and in the seafloor deep beneath the icy crusts of Europa and Enceladus.

Pikuta, Elena V.↗

Astrobiological Significance of Microbial Extremophiles

The microflora of the cryosphere of planet Earth provides the best analogs for life forms that might be found in the permafrost or polar ice caps of Mars, near the surface of the cometary nuclei, or in the liquid water beneath and the ice crusts of icy moons of Jupiter and Saturn. The importance of study alkaliphilic microorganisms for astrobiology was enhanced by the findings of abundant carbonates and carbonate globules rimmed with possibly biogenic magnetites in association with the putative microfossils in the ALH84001 meteorite. Although the ALH84001 "nanofossils" were to small and simple to be unambiguously recognized as biogenic, they stimulated Astrobiology research and studies of microbial extremophiles and biomarkers in ancient rocks and meteorites. Recent studies of CI and CM carbonaceous meteorites have resulted in the detection of the well-preserved mineralized remains of coccoidal and filamentous microorganisms in cyanobacterial mats. Energy Dispersive X-ray Analysis has shown anomalous biogenic element ratios clearly indicating they are not recent biological contaminants. This paper reviews microbial extremophiles in context of their significance to Astrobiology. The study of halophilic microorganisms was started from work with saline soils and lakes, and one of the record of good growth for Haloferax mediterranei was shown at 30 percent NaC1. Although alkali-tolerant nitrifying bacteria had previously been reported, the first described alkaliphilic microorganism was the bacterium Streptococcus faecalis. Halophilic and alkaliphilic forms are relevant to conditions that might be found in closed impact basins and craters on Mars filled with evaporite deposits. The first obligately acidophilic bacterium described was Acidithiobacillus ferrooxydans (formally Thiobacillus ferrooxidans). Later thermophilic lithotrophic acidophiles were found, and the hyperacidophilic moderately thermophilic species of the genus Picrophilus were found to grow at negative pH. The epoch of study of thermophilic microorganisms starts with the discovery of Thermus aquaticus, and presently the maximum temperature for growth at 113 C was found for Pyrolobus fumarii. The microorganisms capable of growth at high temperatures and in hyperacidic environments on Earth are good analogs for life that might be able to survive in hot acidic droplets in the upper regimes of the atmosphere of Venus. The study of barophiles was made possible by engineering achievements leading to the development of the submersible crafts used to study the Black Smokers of the Deep-sea Hydrothermal vents. The first described radioresistant bacterium Deinococcus radiodurans can survive ionizing irradiation and other DNA-damaging assaults at doses that are lethal to all other organisms. These microbes are models for life that might endure high radiation environments in the ice near the surface of comets or on the icy moons of Jupiter and Saturn and in the seafloor deep beneath icy crusts Europa and Enceladus. This paper presents ESEM and FESEM images showing intact microbes preserved in the deep ice cores extracted from just above Lake Vostok, Antarctica that are considered analogs for life forms that might survive on comets and icy moons.

Pikuta, Elena V.↗

NEXT Ion Propulsion System Configurations and Performance for Saturn System Exploration

The successes of the Cassini/Huygens mission have heightened interest to return to the Saturn system with focused robotic missions. The desire for a sustained presence at Titan, through a dedicated orbiter and in-situ vehicle, either a lander or aerobot, has resulted in definition of a Titan Explorer flagship mission as a high priority in the Solar System Exploration Roadmap. The discovery of active water vapor plumes erupting from the tiger stripes on the moon Enceladus has drawn the attention of the space science community. The NASA's Evolutionary Xenon Thruster (NEXT) ion propulsion system is well suited to future missions to the Saturn system. NEXT is used within the inner solar system, in combination with a Venus or Earth gravity assist, to establish a fast transfer to the Saturn system. The NEXT system elements are accommodated in a separable Solar Electric Propulsion (SEP) module, or are integrated into the main spacecraft bus, depending on the mission architecture and performance requirements. This paper defines a range of NEXT system configurations, from two to four thrusters, and the Saturn system performance capability provided. Delivered mass is assessed parametrically over total trip time to Saturn. Launch vehicle options, gravity assist options, and input power level are addressed to determine performance sensitivities. A simple two-thruster NEXT system, launched on an Atlas 551, can deliver a spacecraft mass of over 2400 kg on a transfer to Saturn. Similarly, a four-thruster system, launched on a Delta 4050 Heavy, delivers more than 4000 kg spacecraft mass. A SEP module conceptual design, for a two thruster string, 17 kW solar array, configuration is characterized.

Benson, Scott W.↗

Advanced Chemical Propulsion for Science Missions

The advanced chemical propulsion technology area of NASA's In-Space Technology Project is investing in systems and components for increased performance and reduced cost of chemical propulsion technologies applicable to near-term science missions. Presently the primary investment in the advanced chemical propulsion technology area is in the AMBR high temperature storable bipropellant rocket engine. Scheduled to be available for flight development starting in year 2008, AMBR engine shows a 60 kg payload gain in an analysis for the Titan-Enceladus orbiter mission and a 33 percent manufacturing cost reduction over its baseline, state-of-the-art counterpart. Other technologies invested include the reliable lightweight tanks for propellant and the precision propellant management and mixture ratio control. Both technologies show significant mission benefit, can be applied to any liquid propulsion system, and upon completion of the efforts described in this paper, are at least in parts ready for flight infusion. Details of the technologies are discussed.

Liou, Larry↗

Cassini/CIRS Observations of Water Vapor in Saturn's Stratosphere

The Composite Infrared Spectrometer (CIRS) on the Cassini spacecraft has obtained numerous spectra of Saturn at varying spectral and spatial resolutions since Saturn Orbit Insertion in 2004. Emission lines due to water vapor in Saturn's stratosphere were first detected using whole-disk observations from the Infrared Space Observatory (Feuchtgruber et al 1997) and subsequently confirmed by the Submillimeter Wave Astronomy Satellite (Rergin et al 2000). CIRS has detected water and the data permit the retrieval of the latitudinal variation of water on Saturn. Emission lines of H2O on Saturn are very weak in the CIRS data. Thus. large spectral averages as well as improvements in calibration are necessary to detect water vapor. Zonally averaged nadir spectra were produced every 10 degrees of latitude. Stratospheric temperatures in the 0.5 - 5.0 mbar range were obtained by inverting spectra of CH4 in the v4 band centered at 1304 cm(exp -1). The origin of water vapor is believed to be from the ablation of micrometeorites containing water ice, followed by photochemistry. This external source of oxygen originates either from the Saturn system (from the rings or perhaps from Enceladus) or from the interplanetary medium. Connerney (1986) proposed a mechanism to transport water from the inner edge of the B-ring along magnetic field lines to specific latitudes (50N and 44S) on Saturn. Prange et al (2006) interpreted a minimum in the abundance of acetylene from ultraviolet spectra near 41S on Saturn as possibly due to an enhanced influx of water. Existing CIRS far-IR spectra are at relatively low spatial resolution, but observations at closer range planned for the extended mission will be able to test the "ring rain" mechanism by searching for localized water vapor enhancement at midlatitudes.

Bjoraker, G. L.↗

Temperatures and Composition in the Saturn System from Cassini CIRS

We summarize recent observations by the Composite Infrared Spectrometer of Saturn, its rings, Titan, and the icy satellites. Limb observations of Saturn show vertical oscillations of temperatures and zonal-wind shears in the equatorial region that may be related to a temporal oscillation similar to the terrestrial QBO and Jupiter's QQO. There is also evidence of subsidence at mid-northern latitudes driven by the equatorial activity. Nadir-viewing observations show compact warm spots in the troposphere and stratosphere at both (summer and winter) poles, likely associated with subsidence. Observations of Titan have defined better the characteristics of the northern winter polar vortex, with 190 m/s winds surrounding a cold atmosphere at 1 microbar. The very warm polar stratopause at 10 microbar and the enhanced abundances of organic compounds suggest subsidence within the vortex. Analysis of the zonal structure in temperature indicates that the stratospheric zonal winds rotate about an axis that is displaced approximately 4.1 deg from the IAU pole. Additional flybys, including a close one in March 2008, continue to characterize the endogenic activity in Enceladus s south polar region. Temperature maps of bright and dark terrains on Iapetus indicate that its ice is approximately stable to sublimation in the bright regions and highly unstable in the dark regions. Thermal mapping of Saturn s rings continues to constrain their composition, and observations at different solar phase angles, spacecraft elevations, solar elevations, and local hour angles have elucidated the effects of ring-particle shadowing and vertical motions on the thermal structure, and revealed the presence of small-scale structure associated with self-gravity wakes.

Flasar, F. Michael↗

Simulation of a Miniature, Low-Power Time-of-Flight Mass Spectrometer for In Situ Analysis of Planetary Atmospheres

We are implementing nano- and micro-technologies to develop a miniaturized electron impact ionization mass spectrometer for planetary science. Microfabrication technology is used to fabricate the ion and electron optics, and a carbon nanotube (CNT) cathode is used to generate the ionizing electron beam. Future NASA planetary science missions demand miniaturized, low power mass spectrometers that exhibit high resolution and sensitivity to search for evidence of past and present habitability on the surface and in the atmosphere of priority targets such as Mars, Titan, Enceladus, Venus, Europa, and short-period comets. Toward this objective, we are developing a miniature, high resolution reflectron time-of-flight mass spectrometer (Mini TOF-MS) that features a low-power CNT field emission electron impact ionization source and microfabricated ion optics and reflectron mass analyzer in a parallel-plate geometry that is scalable. Charged particle electrodynamic modeling (SIMION 8.0.4) is employed to guide the iterative design of electron and ion optic components and to characterize the overall performance of the Mini TOF-MS device via simulation. Miniature (less than 1000 cubic centimeters) TOF-MS designs (ion source, mass analyzer, detector only) demonstrate simulated mass resolutions greater than 600 at sensitivity levels on the order of 10(exp -3) cps/molecule N2/cc while consuming 1.3 W of power and are comparable to current spaceflight mass spectrometers. Higher performance designs have also been simulated and indicate mass resolutions approximately 1000, though at the expense of sensitivity and instrument volume.

King, Todd T.↗

An Organic Decontamination Method for Sampling Devices used in Life-detection Studies

Organic decontamination of sampling and storage devices are crucial steps for life-detection, habitability, and ecological investigations of extremophiles living in the most inhospitable niches of Earth, Mars and elsewhere. However, one of the main stumbling blocks for Mars-analogue life-detection studies in terrestrial remote field-sites is the capability to clean instruments and sampling devices to organic levels consistent with null values. Here we present a new seven-step, multi-reagent cleaning and decontamination protocol that was adapted and tested on a glacial ice-coring device and on a rover-guided scoop used for sediment sampling both deployed multiple times during two field seasons of the Arctic Mars Analog Svalbard Expedition AMASE). The effectiveness of the protocols for both devices was tested by (1)in situ metabolic measurements via APT, (2)in situ lipopolysacchride (LPS) quantifications via low-level endotoxin assays, and(3) laboratory-based molecular detection via gas chromatography-mass spectrometry. Our results show that the combination and step-wise application of disinfectants with oxidative and solvation properties for sterilization are effective at removing cellular remnants and other organic traces to levels necessary for molecular organic- and life-detection studies. The validation of this seven-step protocol - specifically for ice sampling - allows us to proceed with confidence in kmskia4 analogue investigations of icy environments. However, results from a rover scoop test showed that this protocol is also suitable for null-level decontamination of sample acquisition devices. Thus, this protocol may be applicable to a variety of sampling devices and analytical instrumentation used for future astrobiology missions to Enceladus, and Europa, as well as for sample-return missions.

Eigenbrode, Jennifer↗

Heavy Ion Formation in Titan's Ionosphere: Magnetospheric Introduction of Free Oxygen and Source of Titan's Aerosols?

With the recent discovery of heavy ions, positive and negative, by the Cassini Plasma Spectrometer (CAPS) instrument in Titan's ionosphere, it reveals new possibilities for aerosol formation at Titan and the introduction of free oxygen to the aerosol chemistry from Saturn's magnetosphere with Enceladus as the primary oxygen source. One can estimate whether the heavy ions in the ionosphere are of sufficient number to account for all the aerosols, under what conditions are favorable for heavy ion formation and how they are introduced as seed particles deeper in Titan's atmosphere where the aerosols form and eventually find themselves on Titan's surface where unknown chemical processes can take place. Finally, what are the possibilities with regard to their chemistry on the surface with some free oxygen present in their seed particles?

Sittler, E. C., Jr.↗

Cassini/CIRS Observations of Water Vapor in Titan's Stratosphere

The Composite Infrared Spectrometer (CIRS) on the Cassini spacecraft has obtained spectra of Titan during most of the 44 flybys of the Cassini prime mission. Water vapor on Titan was first detected using whole-disk observations from the Infrared Space Observatory (Coustenis et al 1998, Astron. Astrophys. 336, L85-L89). CIRS data permlt the retrieval of the latitudinal variation of water on Titan and some limited information on its vertical profile. Emission lines of H2O on Titan are very weak in the CIRS data. Thus, large spectral averages as well as improvements in calibration are necessary to detect water vapor. Water abundances were retrieved in nadir spectra at 55 South, the Equator, and at 19 North. Limb spectra of the Equator were also modeled to constrain the vertical distribution of water. Stratospheric temperatures in the 0.5 - 4.0 mbar range were obtained by inverting spectra of CH4 in the v4 band centered at 1304/cm. The temperature in the lower stratosphere (4 - 20 mbar) was derived from fitting pure rotation lines of CH4 between 80 and 160/cm. The origin of H2O and CO2 is believed to be from the ablation of micrometeorites containing water ice, followed by photochemistry. This external source of water originates either within the Saturn system or from the interplanetary medium. Recently, Horst et al (J. Geophys. Res. 2008, in press) developed a photochemical model of Titan in which there are two external sources of oxygen. Oxygen ions (probably from Enceladus) precipitate into Titan's atmosphere to form CO at very high altitudes (1100 km). Water ice ablation at lower altitudes (700 km) forms H2O and subsequent chemistry produces CO2. CIRS measurements of CO, CO2, and now of H2O will provide valuable constraints to these photochemical models and - improve our understanding of oxygen chemistry on Titan.

Bjoraker, Gordon L.↗

Cassini Orbit Determination Performance during Saturn Satellite Tour: August 2005 - January 2006

During the period spanning the second Enceladus flyby in July 2005 through the eleventh Titan encounter in January 2006, the Cassini spacecraft was successfully navigated through eight close-targeted satellite encounters. Three of these encounters included the 500 km flybys of the icy satellites Hyperion, Dione and Rhea and five targeted flybys of Saturn's largest moon, Titan. This paper will show how our refinements to Saturn's satellite ephemerides have improved orbit determination predictions. These refinements include the mass estimates of Saturn and its satellites by better than 0.5%. Also, it will be shown how this better orbit determination performance has helped to eliminate several statistical maneuvers that were scheduled to clean-up orbit determination and/or maneuver-execution errors.

Rhea↗

Advanced Chemical Propulsion System Study

A detailed; mission-level systems study has been performed to show the benefit resulting from engine performance gains that will result from NASA's In-Space Propulsion ROSS Cycle 3A NRA, Advanced Chemical Technology sub-topic. The technology development roadmap to accomplish the NRA goals are also detailed in this paper. NASA-Marshall and NASA-JPL have conducted mission-level studies to define engine requirements, operating conditions, and interfaces. Five reference missions have been chosen for this analysis based on scientific interest, current launch vehicle capability and trends in space craft size: a) GTO to GEO, 4800 kg, delta-V for GEO insertion only approx.1830 m/s; b) Titan Orbiter with aerocapture, 6620 kg, total delta V approx.210 m/s, mostly for periapsis raise after aerocapture; c) Enceladus Orbiter (Titan aerocapture) 6620 kg, delta V approx.2400 m/s; d) Europa Orbiter, 2170 kg, total delta V approx.2600 m/s; and e) Mars Orbiter, 2250 kg, total delta V approx.1860 m/s. The figures of merit used to define the benefit of increased propulsion efficiency at the spacecraft level include propulsion subsystem wet mass, volume and overall cost. The objective of the NRA is to increase the specific impulse of pressure-fed earth storable bipropellant rocket engines to greater than 330 seconds with nitrogen tetroxide and monomothylhydrazine propellants and greater than 335 , seconds with nitrogen tetroxide and hydrazine. Achievement of the NRA goals will significantly benefit NASA interplanetary missions and other government and commercial opportunities by enabling reduced launch weight and/or increased payload. The study also constitutes a crucial stepping stone to future development, such as pump-fed storable engines.

Portz, Ron↗