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NASA NTRS2008

Select Methodology for Validating Advanced Satellite Measurement Systems

Advanced satellite sensors are tasked with improving global measurements of the Earth's atmosphere, clouds, and surface to enable enhancements in weather prediction, climate monitoring capability, and environmental change detection. Measurement system validation is crucial to achieving this goal and maximizing research and operational utility of resultant data. Field campaigns including satellite under-flights with well calibrated FTS sensors aboard high-altitude aircraft are an essential part of the validation task. This presentation focuses on an overview of validation methodology developed for assessment of high spectral resolution infrared systems, and includes results of preliminary studies performed to investigate the performance of the Infrared Atmospheric Sounding Interferometer (IASI) instrument aboard the MetOp-A satellite.

Larar, Allen M.↗
NASA NTRS2010

Hazard Detection Analysis for a Forward-Looking Interferometer

The Forward-Looking Interferometer (FLI) is a new instrument concept for obtaining the measurements required to alert flight crews to potential weather hazards to safe flight. To meet the needs of the commercial fleet, such a sensor should address multiple hazards to warrant the costs of development, certification, installation, training, and maintenance. The FLI concept is based on high-resolution Infrared Fourier Transform Spectrometry (FTS) technologies that have been developed for satellite remote sensing. These technologies have also been applied to the detection of aerosols and gases for other purposes. The FLI concept is being evaluated for its potential to address multiple hazards including clear air turbulence (CAT), volcanic ash, wake vortices, low slant range visibility, dry wind shear, and icing during all phases of flight (takeoff, cruise, and landing). The research accomplished in this second phase of the FLI project was in three major areas: further sensitivity studies to better understand the potential capabilities and requirements for an airborne FLI instrument, field measurements that were conducted in an effort to provide empirical demonstrations of radiometric hazard detection, and theoretical work to support the development of algorithms to determine the severity of detected hazards

West, Leanne↗
NASA NTRS2010

Carbon Dioxide (CO2) Retrievals from Atmospheric Chemistry Experiment (ACE) Solar Occultation Measurements

The Atmospheric Chemistry Experiment ACE satellite (SCISAT-1) was launched into an inclined orbit on 12 August 2003 and is now recording high signal-to-noise 0.02 per centimeter resolution solar absorption spectra covering 750-4400 per centimeter (2.3-13 micrometers). A procedure has been developed for retrieving average dry air CO2 mole fractions (X(sub CO2)) in the altitude range 7-10 kilometers from the SCISAT-1 spectra. Using the N2 continuum absorption in a window region near 2500 per centimeter, altitude shifts are applied to the tangent heights retrieved in version 2.2 SCISAT-1 processing, while cloudy or aerosol-impacted measurements are eliminated. Monthly-mean XCO2 covering 60 S to 60 N latitude for February 2004 to March 2008 has been analyzed with consistent trends inferred in both hemispheres. The ACE XCO2 time series have been compared with previously-reported surface network measurements, predictions based on upper tropospheric aircraft measurements, and space-based measurements. The retrieved X(sub CO2) from the ACE-FTS spectra are higher on average by a factor of 1.07 plus or minus 0.025 in the northern hemisphere and by a factor of 1.09 plus or minus 0.019 on average in the southern hemisphere compared to surface station measurements covering the same time span. The ACE derived trend is approximately 0.2% per year higher than measured at surface stations during the same observation period.

Rinsland, Curtis P.↗
NASA NTRS2011

First Stage Solid Propellant Multi Debris Thermal Analysis

The crew launch vehicle considered for the Constellation (Cx) Program utilizes a first stage solid rocket motor. If an abort is initiated in first stage flight the Crew Module (CM) will separate and be pulled away from the launch vehicle via a Launch Abort System (LAS) in order to safely and quickly carry the crew away from the malfunction launch vehicle. Having aborted the mission, the launch vehicle will likely be destroyed via a Flight Termination System (FTS) in order to prevent it from errantly traversing back over land and posing a risk to the public. The resulting launch vehicle debris field, composed primarily of first stage solid propellant, poses a threat to the CM. The harsh radiative thermal environment induced by surrounding burning propellant debris may lead to CM parachute failure. A methodology, detailed herein, has been developed to address this concern and quantify the risk of first stage propellant debris leading to radiative thermal demise of the CM parachutes. Utilizing basic thermal radiation principles, a software program was developed to calculate parachute temperature as a function of time for a given abort trajectory and debris piece trajectory set. Two test cases, considered worst-case aborts with regard to launch vehicle debris environments, were analyzed using the simulation: an abort declared at Mach 1 and an abort declared at maximum dynamic pressure (Max Q). For both cases, the resulting temperature profiles indicated that thermal limits for the parachutes were not exceeded. However, short duration close encounters by single debris pieces did have a significant effect on parachute temperature, with magnitudes on the order of 10 s of degrees Fahrenheit. Therefore while these two test cases did not indicate exceedance of thermal limits, in order to quantify the risk of parachute failure due to radiative effects from the abort environment, a more thorough probability-based analysis using the methodology demonstrated herein must be performed.

Toleman, Benjamin M.↗
NASA NTRS2011

Northern Hemisphere Atmospheric Influence of the Solar Proton Events and Ground Level Enhancement in January 2005

Solar eruptions in early 2005 led substantial barrage of charged particles on the Earth's atmosphere during the January 16-21 period. Proton fluxes were greatly increased during these several days and led to the production ofHO(x)(H, OH, BO2)and NO(x)(N, NO, NO2), which then caused the destruction of ozone. We focus on the Northern polar region, where satellite measurements and simulations with the Whole Atmosphere Community Climate Model (WACCM3) showed large enhancements in mesospheric HO(x) and NO(x) constituents, and associated ozone reductions, due 10 these solar proton events (SPEs). The WACCM3 simulations show enhanced short-lived OH throughout the mesosphere in the 60-82.5degN latitude band due to the SPEs for most days in the Jan.16-2l,2005 period, in reasonable agreement with the Aura Microwave Limb Sounder (MLS) measurements. Mesospheric HO2 is also predicted to be increased by the SPEs, however, the modeled HO2 results are somewhat larger than the MLS measurements. These HO(x) enhancements led to huge predicted and MLS-measured ozone decreases of greater than 40% throughout most of the Northern polar mesosphere during the SPE period. Envisat Michelson Interferometer for Passive Atmospheric Sounding (MIPAS) measurements of hydrogen peroxide (H2O2) show increases throughout the stratosphere with highest enhancements of about 60 ppt y in the lowermost mesosphere over the Jan. 16-18, 2005 period due to the solar protons. WACCM3 predictions indicate H2O2 enhancements over the same time period of more than twice that amount. Measurements of nitric acid (HNO3) by both MLS and MIPAS show an increase of about 1 ppbv above background levels in the upper stratosphere during January 16-29, 2005. WACCM3 simulations show only minuscule HNO3 changes in the upper stratosphere during this time period. However due to the small loss rates during winter, polar mesospheric enhancements of NO(x) are computed to be greater than 50 ppbv during the SPE period. Computed NO(x)increases, which were statistically significant at the 95% level, lasted about a month past the SPEs. The SCISAT-I Atmospheric Chemistry Experiment Fourier Transform Spectrometer (ACE-FTS) NO(x) measurements and MIPAS NO, measurements for the polar Northern Hemisphere are in reasonable agreement with these predictions. An extremely large ground level enhancement (GLE) occurred during the SPE period on January 20, 2005. We find that protons of energies 300 to 20,000 MeV, not normally included in our computations, led to enhanced lower stratospheric odd nitrogen concentrations of less than 0.1% as a result of this GLE.

Jackman, C. H.↗
NASA NTRS2011

First Stage Solid Propellant Multiply Debris Thermal Analysis

Destruction of a solid rocket stage of a launch vehicle can create a thermal radiation hazard for an aborting crew module. This hazard was assessed for the Constellation Program (Cx) crew and launch vehicle concept. For this concept, if an abort was initiated in first stage flight, the Crew Module (CM) will separate and be pulled away from the malfunctioning launch vehicle via a Launch Abort System (LAS). Having aborted the mission, the launch vehicle will likely be destroyed via a Flight Termination System (FTS) in order to prevent it from errantly traversing back over land and posing a risk to the public. The resulting launch vehicle debris field, composed primarily of first stage solid propellant, poses a threat to the CM. The harsh radiative thermal environment, caused by surrounding burning propellant debris, may lead to CM parachute failure. A methodology, detailed herein, has been developed to address this concern and to quantify the risk of first stage propellant debris leading to the thermal demise of the CM parachutes. Utilizing basic thermal radiation principles, a software program was developed to calculate parachute temperature as a function of time for a given abort trajectory and debris piece trajectory set. Two test cases, considered worst case aborts with regard to launch vehicle debris environments, were analyzed using the simulation: an abort declared at Mach 1 and an abort declared at maximum dynamic pressure (Max Q). For both cases, the resulting temperature profiles indicated that thermal limits for the parachutes were not exceeded. However, short duration close encounters by single debris pieces did have a significant effect on parachute temperature. Therefore while these two test cases did not indicate exceedance of thermal limits, in order to quantify the risk of parachute failure due to radiative effects from the abort environment, a more thorough probability-based analysis using the methodology demonstrated herein must be performed.

Toleman, Benjamin M.↗
NASA NTRS2011

Direct EPP Affects on the Middle Atmosphere

Energetic precipitating particles (EPPs) can cause significant direct constituent changes in the mesosphere and stratosphere (middle atmosphere) during certain periods. Both protons and electrons can influence the polar middle atmosphere through ionization and dissociation processes. EPPs can enhance HOx (H, OH, HO2) through the formation of positive ions followed by complex ion chemistry and NOx (N, NO, NO2) through the dissociation of molecular nitrogen. The HOx increases result in direct ozone destruction in the mesosphere and upper stratosphere via several catalytic loss cycles. Such middle atmospheric HOx-caused ozone loss is rather short-lived due to the relatively short lifetime (hours) of the HOx constituents. The NOx family has a considerably longer lifetime than the HOx family and can also lead to catalytic ozone destruction. EPP-caused enhancements of the NOx family can affect ozone directly, if produced in the stratosphere. Ozone decreases from the EPPs lead to a reduction in atmospheric heating and, subsequent atmospheric cooling. Conversely, EPPs can cause direct atmospheric heating through Joule heating. Measured HOx constituents OH and HO2 showed increases due to solar protons. Observed NOx constituents NO and NO2 were enhanced due to both solar protons and precipitating electrons. Other hydrogen- and nitrogen-ocntaining constituents were also measured to be directly influenced by EPPs, including N2O, HNO3, HO2NO2, N2OS, H2O2, ClONO2, HCl, and HOCl. Observed constituents ClO and CO were directly affected by EPPs as well. Many measurements indicated significant direct ozone decreases. A significant number of satellites housed instruments, which observed direct EPP-caused atmospheric effects, including Nimbus 4 (BUV), Nimbus 7 (SBUV), several NOAA platforms (SBUV/2), SME, UARS (HALOE, CLAES), SCISAT-1 (ACE-FTS), Odin (OSIRIS), Envisat-l (GOMOS, MIPAS, SCIAMACHY), and Aura (MLS). Measurements by rockets and ground-based radar also indicated EPP direct impacts. Atmospheric models have been used with some success in predicting the direct EPP impacts on the mesosphere and stratosphere. A review of the observed direct effects of EPP on the middle atmosphere will be given in this presentation.

Jackman, Charles H.↗
NASA NTRS2011

The Primordial Inflation Explorer (PIXIE) Mission

The Primordial Inflation Explorer (PIXIE) is an Explorer-class mission to map the absolute intensity and linear polarization of the cosmic microwave background and diffuse astrophysical foregrounds over the full sky from frequencies 30 GHz to 6 THz (I cm to 50 I-tm wavelength). PIXIE uses a polarizing Michelson interferometer with 2.7 K optics to measure the difference spectrum between two orthogonal linear polarizations from two co-aligned beams. Either input can view either the sky or a temperature-controlled absolute reference blackbody calibrator. The multimoded optics and high etendu provide sensitivity comparable to kilo-pixel focal plane arrays, but with greatly expanded frequency coverage while using only 4 detectors total. PIXIE builds on the highly successful COBEIFIRAS design by adding large-area polarization-sensitive detectors whose fully symmetric optics are maintained in thermal equilibrium with the CMB. The highly symmetric nulled design provides redundant rejection of major sources of systematic uncertainty. The principal science goal is the detection and characterization of linear polarization from an inflationary epoch in the early universe, with tensor-to-scalar ratio r much less than 10(exp -3). PIXIE will also return a rich data set constraining physical processes ranging from Big Bang cosmology, reionization, and large-scale structure to the local interstellar medium. Keywords: cosmic microwave background, polarization, FTS, bolometer

Kogut, Alan J.↗
NASA NTRS2011

Optical-Path-Difference Linear Mechanism for the Panchromatic Fourier Transform Spectrometer

A document discusses a mechanism that uses flex-pivots in a parallelogram arrangement to provide frictionless motion with an unlimited lifetime. A voicecoil actuator drives the parallelogram over the required 5-cm travel. An optical position sensor provides feedback for a servo loop that keeps the velocity within 1 percent of expected value. Residual tip/tilt error is compensated for by a piezo actuator that drives the interferometer mirror. This mechanism builds on previous work that targeted ground-based measurements. The main novelty aspects include cryogenic and vacuum operation, high reliability for spaceflight, compactness of the design, optical layout compatible with the needs of an imaging FTS (i.e. wide overall field-of-view), and mirror optical coatings to cover very broad wavelength range (i.e., 0.26 to 15 m).

Blavier, Jean-Francois L.↗
NASA NTRS2012

Miniaturized Laser Heterodyne Radiometer (LHR) for Measurements of Greenhouse Gases in the Atmospheric Column

This passive laser heterodyne radiometer (LHR) instrument simultaneously measures multiple trace gases in the atmospheric column including carbon dioxide (CO2) and methane (CH4), and resolves their concentrations at different altitudes. This instrument has been designed to operate in tandem with the passive aerosol sensor currently used in AERONET (an established network of more than 450 ground aerosol monitoring instruments worldwide). Because aerosols induce a radiative effect that influences terrestrial carbon exchange, simultaneous detection of aerosols with these key carbon cycle gases offers a uniquely comprehensive measurement approach. Laser heterodyne radiometry is a technique for detecting weak signals that was adapted from radio receiver technology. In a radio receiver, a weak input signal from a radio antenna is mixed with a stronger local oscillator signal. The mixed signal (beat note, or intermediate frequency) has a frequency equal to the difference between the input signal and the local oscillator. The intermediate frequency is amplified and sent to a detector that extracts the audio from the signal. In the LHR instrument described here, sunlight that has undergone absorption by the trace gas is mixed with laser light at a frequency matched to a trace gas absorption feature in the infrared (IR). Mixing results in a beat signal in the RF (radio frequency) region that can be related to the atmospheric concentration. For a one-second integration, the estimated column sensitivities are 0.1 ppmv for CO2, and <1 ppbv for CH4. In addition to producing a standalone ground measurement product, this instrument could be used to calibrate/validate four Earth observing missions: ASCENDS (Active Sensing of CO2 Emissions over Nights, Days, and Seasons), OCO-2 (Orbiting Carbon Observatory), OCO-3, and GOSAT (Greenhouse gases Observational SATellite). The only network that currently measures CO2 and CH4 in the atmospheric column is TCCON (Total Carbon Column Observing Network), and only two of its 16 operational sites are in the United States. TCCON data is used for validation of GOSAT data, and will be used for OCO-2 validation. While these Fourier-transform spectrometers (FTS) can measure the largest range of trace gases, the network is severely limited due to the high cost and extreme size of these instruments (these occupy small buildings and require personnel for operation). The LHR/AERONET instrument offers a significantly smaller (carry-on luggage size) autonomous instrument that can be incorporated into AERONET s much larger (450 instruments) global network.

Steel, Emily↗
NASA NTRS2012

Preliminary Modeling of CH3D From 4000 to 4550 cm (exp-1)

A new study of 12CH3D line positions and intensities was performed for the upper portion of the Enneadecad polyad between 4000 and 4550/cm. For this, FTIR spectra were recorded with D-enriched methane samples (at 80 K with a Bruker 125 IFS at 0.005/cm resolution and at 291 K with the McMath-Pierce FTS at 0.011/cm resolution, respectively). Line positions and intensities were retrieved by least square curve-fitting procedures and analyzed using the effective Hamiltonian and the effective dipole moment expressed in terms of irreducible tensor operators adapted to symmetric top molecules. Initially, only the cold spectrum was used to identify quantum assignments and predict 12CH3D relative intensities in this region. To assign higher quanta up to J equal 14, additional line positions and intensities were obtained from two room temperature spectra. In the final stage, measured intensities from both the cold and the room temperature data were normalized to corresponding values at 296 K and then averaged. Combining the two temperature datasets confirmed the assumed quantum assignments and also demonstrated the relative accuracies to be better than 70.0002/cm for line positions and at least +/-6% for intensities so that approx.1160 features were selected. Including additional assignments from the room temperature spectra alone permitted 1362 line intensities of 11 bands (involving 23 vibrational symmetry components) to be reproduced with an RMS of 9%. Over 4085 selected positions for 12 bands were modeled to 0.008/cm. Nevertheless a number of known assignments could not be modeled to within our experimental precisions. More work is needed to obtain a complete characterization of this complex polyad.

Nikitin, A. V.↗
NASA NTRS2013

Thermal Stability of RP-2 for Hydrocarbon Boost Regenerative Cooling

A series of tests were performed in the NASA Glenn Research Centers Heated Tube Facility to study the heat transfer and thermal stability behavior of RP-2 under conditions similar to those found in rocket engine cooling channels. It has long been known that hydrocarbon fuels, such as RP-2, can decompose at high temperature to form deposits (coke) which can adversely impact rocket engine cooling channel performance. The heated tube facility provides a simple means to study these effects. Using resistively heated copper tubes in a vacuum chamber, flowing RP-2 was heated to explore thermal effects at a range of test conditions. Wall temperature (850-1050F) and bulk fluid temperature (300-500F) were varied to define thermal decomposition and stability at each condition. Flow velocity and pressure were fixed at 75 fts and 1000 psia, respectively. Additionally, five different batches of RP-2 were tested at identical conditions to examine any thermal stability differences resulting from batch to batch compositional variation. Among these tests was one with a potential coke reducing additive known as 1,2,3,4-Tetrahydroquinoline (THQ). While copper tubes were used for the majority of tests, two exploratory tests were performed with a copper alloy known as GRCop-42. Each tube was instrumented with 15 thermocouples to examine the temperature profile, and carbon deposition at each thermocouple location was determined post-test in an oxidation furnace. In many tests, intermittent local temperature increases were observed visually and in the thermocouple data. These hot spots did not appear to correspond with a higher carbon deposition.

Kleinhenz, Julie E.↗
NASA NTRS2013

The Relation Between Atmospheric Humidity and Temperature Trends for Stratospheric Water

We analyze the relation between atmospheric temperature and water vapor-a fundamental component of the global climate system-for stratospheric water vapor (SWV). We compare measurements of SWV (and methane where available) over the period 1980-2011 from NOAA balloon-borne frostpoint hygrometer (NOAA-FPH), SAGE II, Halogen Occultation Experiment (HALOE), Microwave Limb Sounder (MLS)/Aura, and Atmospheric Chemistry Experiment Fourier Transform Spectrometer (ACE-FTS) to model predictions based on troposphere-to-stratosphere transport from ERA-Interim, and temperatures from ERA-Interim, Modern Era Retrospective-Analysis (MERRA), Climate Forecast System Reanalysis (CFSR), Radiosonde Atmospheric Temperature Products for Assessing Climate (RATPAC), HadAT2, and RICHv1.5. All model predictions are dry biased. The interannual anomalies of the model predictions show periods of fairly regular oscillations, alternating with more quiescent periods and a few large-amplitude oscillations. They all agree well (correlation coefficients 0.9 and larger) with observations for higherfrequency variations (periods up to 2-3 years). Differences between SWV observations, and temperature data, respectively, render analysis of the model minus observation residual difficult. However, we find fairly well-defined periods of drifts in the residuals. For the 1980s, model predictions differ most, and only the calculation with ERA-Interim temperatures is roughly within observational uncertainties. All model predictions show a drying relative to HALOE in the 1990s, followed by a moistening in the early 2000s. Drifts to NOAA-FPH are similar (but stronger), whereas no drift is present against SAGE II. As a result, the model calculations have a less pronounced drop in SWV in 2000 than HALOE. From the mid-2000s onward, models and observations agree reasonably, and some differences can be traced to problems in the temperature data. These results indicate that both SWV and temperature data may still suffer from artifacts that need to be resolved in order to answer the question whether the large-scale flow and temperature field is sufficient to explain water entering the stratosphere.

Fueglistaler, S.↗
NASA NTRS2013

Optical Properties of Iron Silicates in the Infrared to Millimeter as a Function of Wavelength and Temperature

The Optical Properties of Astronomical Silicates with Infrared Techniques (OPASI-T) program utilizes multiple instruments to provide spectral data over a wide range of temperature and wavelengths. Experimental methods include Vector Network Analyzer (VNA) and Fourier Transform Spectroscopy (FTS) transmission, and reflection/scattering measurements. From this data, we can determine the optical parameters for the index of refraction, n, and the absorption coefficient, k. The analysis of the laboratory transmittance data for each sample type is based upon different mathematical models, which are applied to each data set according to their degree of coherence. Presented here are results from iron silicate dust grain analogs, in several sample preparations and at temperatures ranging from 5-300 K, across the infrared and millimeter portion of the spectrum (from 2.5-10,000 μm or 4,000-1 cm(exp −1).

Optical↗
NASA NTRS2012

Validation of MIPAS IMK-IAA Temperature, Water Vapor, and Ozone Profiles with MOHAVE-2009 Campaign Measurements

MIPAS observations of temperature, water vapor, and ozone in October 2009 as derived with the scientific level-2 processor run by Karlsruhe Institute of Technology (KIT), Institute for Meteorology and Climate Research (IMK) and CSIC, Instituto de Astrofısica de Andalucıa (IAA) and retrieved from version 4.67 level-1b data have been compared to co-located field campaign observations obtained during the MOHAVE-2009 campaign at the Table Mountain Facility near Pasadena, California in October 2009. The MIPAS measurements were validated regarding any potential biases of the profiles, and with respect to their precision estimates. The MOHAVE-2009 measurement campaign provided measurements of atmospheric profiles of temperature, water vapor/relative humidity, and ozone from the ground to the mesosphere by a suite of instruments including radiosondes, ozonesondes, frost point hygrometers, lidars, microwave radiometers and Fourier transform infrared (FTIR) spectrometers. For MIPAS temperatures (version V4O_T_204), no significant bias was detected in the middle stratosphere; between 22 km and the tropopause MIPAS temperatures were found to be biased low by up to 2 K, while below the tropopause, they were found to be too high by the same amount. These findings confirm earlier comparisons of MIPAS temperatures to ECMWF data which revealed similar differences. Above 12 km up to 45 km, MIPAS water vapor (version V4O_H2O_203) is well within 10% of the data of all correlative instruments. The well-known dry bias of MIPAS water vapor above 50 km due to neglect of non-LTE effects in the current retrievals has been confirmed. Some instruments indicate that MIPAS water vapor might be biased high by 20 to 40% around 10 km (or 5 km below the tropopause), but a consistent picture from all comparisons could not be derived. MIPAS ozone (version V4O_O3_202) has a high bias of up to +0.9 ppmv around 37 km which is due to a non-identified continuum like radiance contribution. No further significant biases have been detected. Cross-comparison to co-located observations of other satellite instruments (Aura/MLS, ACE-FTS, AIRS) is provided as well.

MIPAS validation↗
NASA NTRS2013

Optical Properties of Iron Silicates in the Infrared to Millimeter as a Function of Wavelength and Temperature

The Optical Properties of Astronomical Silicates with Infrared Techniques (OPASI-T) program utilizes multiple instruments to provide spectral data over a wide range of temperature and wavelengths. Experimental methods include Vector Network Analyzer (VNA) and Fourier Transform Spectroscopy (FTS) transmission, and reflection/scattering measurements. From this data, we can determine the optical parameters for the index of refraction, n, and the absorption coefficient, k. The analysis of the laboratory transmittance data for each sample type is based upon different mathematical models, which are applied to each data set according to their degree of coherence. Presented here are results from iron silicate dust grain analogs, in several sample preparations and at temperatures ranging from 5-300 K, across the infrared and millimeter portion of the spectrum (from 2.5-10,000 m or 4,000-1 cm(exp−1).

Methods: laboratory↗
NASA NTRS2013

Air- and Self-Broadened Half Widths, Pressure-Induced Shifts, and Line Mixing in the Nu(sub 2) Band of (12)CH4

Lorentz self- and air-broadened half width and pressure-induced shift coefficients and their dependences on temperature have been measured from laboratory absorption spectra for nearly 130 transitions in the nu(sub 2) band of (12)CH4. In addition line mixing coefficients (using the relaxation matrix element formalism) for both self- and airbroadening were experimentally determined for the first time for a small number of transitions in this band. Accurate line positions and absolute line intensities were also determined. These parameters were obtained by analyzing high-resolution (approx. 0.003 to 0.01 per cm) laboratory spectra of high-purity natural CH4 and air-broadened CH4 recorded at temperatures between 226 and 297 K using the McMath-Pierce Fourier transform spectrometer (FTS) located at the National Solar Observatory on Kitt Peak, Arizona. A multispectrum nonlinear least squares technique was used to fit short (5-15 per cm) spectral intervals in 24-29 spectra simultaneously. Parameters were determined for nu(sub 2) transitions up to J" = 16. The variations of the measured broadening and shift parameters with the rotational quantum number index and tetrahedral symmetry species are examined. The present results are also compared with previous measurements available in the literature.

Smith, M. A. H.↗