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At least 307 records · Page 17

Toward an AI-Powered Software Pipeline for Real-Time Tracking and Analysis of Wildfire and Smoke

Real-time tracking of wildfires and smoke is crucial for effective response, minimizing damage, protecting lives, and efficiently managing resources during fire emergencies. We develop a web-based AI-powered pipeline that detects wildfires in aerial video and estimates deployment-relevant behavior metrics, including cumulative burned area, burned-area growth rate, fire spread direction, and smoke dispersion. The system combines a YOLO-based detector with YCbCr-based fire segmentation, HSV-based smoke segmentation, Farneback optical flow, and centroid-based spatiotemporal tracking. Using ground sampling distance (GSD), pixel-level fire masks are converted to physical burned-area measurements by correlating fire pixel counts with camera altitude and tilt angle. We benchmark YOLO variants and non-YOLO baselines (GoogLeNet, CNN, DBN, Autoencoder, U-Net, and AlexNet) on the IEEE FLAME dataset and a newly created aerial frame dataset, Wildfire-DB. Cross-dataset evaluation uses a strict threshold-transfer protocol: decision thresholds are selected on FLAME validation and transferred unchanged to Wildfire-DB to quantify generalization under domain shift. YOLOv6 achieves the strongest cross-dataset frame-level fire detection on Wildfire-DB (ROC-AUC 0.8200, PR-AUC 0.8044, and transferred-threshold F1 0.7596). For tracking-oriented deployment requiring oriented localization, YOLO11-OBB provides the most reliable cross-dataset behavior among OBB-capable models while remaining computationally feasible. To analyze the feasibility of UAV deployment, we further measure inference efficiency using synchronized GPU and CPU power logs on a fixed workload of 1569 frames. YOLO-family models process the video in 5.73–12.47 seconds with net energy of 1247.28–1775.39 J, substantially lower latency and energy than heavier classification and reconstruction baselines. Overall, model optimality depends on operational objectives: YOLOv6 is best for cross-dataset detection robustness, whereas YOL...

Color segmentation↗

Primary reaction control system/remote manipulator system interaction with loaded arm. Space shuttle engineering and operations support

A study of the interaction between the orbiter primary reaction control system (PRCS) and the remote manipulator system (RMS) with a loaded arm is documented. This analysis was performed with the Payload Deployment and Retrieval Systems Simulation (PDRSS) program with the passive arm bending option. The passive-arm model simulates the arm as massless elastic links with locked joints. The study was divided into two parts. The first part was the evaluation of the response of the arm to step inputs (i.e. constant jet torques) about each of the orbiter body axes. The second part of the study was the evaluation of the response of the arm to minimum impulse primary RCS jet firings with both single pulse and pulse train inputs.

Taylor, E. C.↗

Statistical Treatment of Earth Observing System Pyroshock Separation Test Data

The Earth Observing System (EOS) AM-1 spacecraft for NASA's Mission to Planet Earth is scheduled to be launched on an Atlas IIAS vehicle in June of 1998. One concern is that the instruments on the EOS spacecraft are sensitive to the shock-induced vibration produced when the spacecraft separates from the launch vehicle. By employing unique statistical analysis to the available ground test shock data, the NASA Lewis Research Center found that shock-induced vibrations would not be as great as the previously specified levels of Lockheed Martin. The EOS pyroshock separation testing, which was completed in 1997, produced a large quantity of accelerometer data to characterize the shock response levels at the launch vehicle/spacecraft interface. Thirteen pyroshock separation firings of the EOS and payload adapter configuration yielded 78 total measurements at the interface. The multiple firings were necessary to qualify the newly developed Lockheed Martin six-hardpoint separation system. Because of the unusually large amount of data acquired, Lewis developed a statistical methodology to predict the maximum expected shock levels at the interface between the EOS spacecraft and the launch vehicle. Then, this methodology, which is based on six shear plate accelerometer measurements per test firing at the spacecraft/launch vehicle interface, was used to determine the shock endurance specification for EOS. Each pyroshock separation test of the EOS spacecraft simulator produced its own set of interface accelerometer data. Probability distributions, histograms, the median, and higher order moments (skew and kurtosis) were analyzed. The data were found to be lognormally distributed, which is consistent with NASA pyroshock standards. Each set of lognormally transformed test data produced was analyzed to determine if the data should be combined statistically. Statistical testing of the data's standard deviations and means (F and t testing, respectively) determined if data sets were significantly different at a 95-percent confidence level. If two data sets were found to be significantly different, these families of data were not combined for statistical purposes. This methodology produced three separate statistical data families of shear plate data. For each population, a P99.1/50 (probability/confidence) per-separation-nut firing level was calculated. By using the binomial distribution, Lewis researchers determined that this pernut firing level was equivalent to a P95/50 per-flight confidence level. The overall envelope of the per-flight P95/50 levels led to Lewis' recommended EOS interface shock endurance specification. A similar methodology was used to develop Lewis' recommended EOS mission assurance levels. The available test data for the EOS mission are significantly larger than for a normal mission, thus increasing the confidence level in the calculated expected shock environment. Lewis significantly affected the EOS mission by properly employing statistical analysis to the data. This analysis prevented a costly requalification of the spacecraft's instruments, which otherwise would have been exposed to significantly higher test levels.

McNelis, Anne M.↗

Emergency Response Manual

Safety and security is very important at NASA. The Security Management and Safeguards Office goal is ensure safety and security for all NASA Lewis and Plum Brook Station visitors and workers. The office protects against theft, sabotage, malicious damage, espionage, and other threats or acts of violence. There are three types of security at NASA: physical, IT, and personnel. IT is concerned with sensitive and classified information and computers. Physical security includes the officers who check visitors and workers in and patrol the facility. Personnel security is concerned with background checks during hiring. During my internship, I met people from and gained knowledge about all three types of security. I primarily worked with Dr. Richard Soppet in physical security. During my experience with physical security, I observed and worked with many aspects of it. I attended various security meetings at both NASA Lewis and Plum Brook. The meetings were about homeland security and other improvements that will be made to both facilities. I also spent time with a locksmith. The locksmith makes copies of keys and unlocks doors for people who need them. I rode around in a security vehicle with an officer as he patrolled. I also observed the officer make a search of a visitor s vehicle. All visitors vehicles are searched upon entering NASA. I spent time and observed in the dispatch office. The officer answers calls and sends out officers when needed. The officer also monitors the security cameras. My primary task was completing an emergency response manual. This manual would assist local law enforcement and fire agencies in case of an emergency. The manual has pictures and descriptions of the buildings. It also contains the information about hazards inside of the buildings. This information will be very helpul to law enforcement so that when called upon during an emergency, they will not create an even bigger problem with collateral damage.

Barnett, Traci M.↗

A weather pattern responsible for increasing wildfires in the western United States

Abstract The western United States (U.S.) has been experiencing more severe wildfires, in part due to climate change, but the underlying synoptic patterns and their modulation in driving fire weather is unclear. Here we investigated the relationship between weather regimes (WRs) and fire weather indices, specifically vapor pressure deficit (VPD) and the Canadian Forest Fire Weather Index. By identifying five singular WRs using k-means clustering, we found that a particular regime (WR-2), one characterized by a distinct tripolar wave train pattern over the continental U.S., has exhibited an increased frequency since 1980. The ascribed WR-2 regime was found to be mainly responsible for rising trends in the fire weather indices, especially VPD. Further, the average fire indices of the WR-2 regime played a more important role than the frequency in shaping the rising trends in the fire weather indices. The increased frequency of the WR-2 WR was mainly attributed to anthropogenic forcing and, the year-to-year variation of the frequency was associated with sea surface temperature anomalies over the subtropical eastern Pacific. Human-induced climate change might have furthered the exacerbation of wildfire danger in the western U.S. by modulating the behaviors of WRs and fire weather indices.

Zhang, Wei (ORCID:0000000221698749)↗

Turbulence structure in clear and cloudy regions of the 7 July 1987 Electra mission

The 7 July mission of the 1987 FIRE Marine Stratocumulus Intensive Field Observations was chosen for analysis because of a well-defined transition from stratocumulus to clear conditions sampled by the aircraft on this day. It is hoped that by studying this case something can be learned about the processes responsible for the maintenance and breakup of stratocumulus layers, a primary objective of FIRE. The preliminary analysis is based on data from the Electra flight of this day. The properties of turbulence elements, i.e., updrafts and downdrafts, are examined to gain information on the nature of the turbulent exchanges through the boundary layer and across the inversion. Since such exchanges in large measure determine the stability and structure of cloud layers, a study of draft properties should be informative. The results will also be useful in the development of boundary layer models that are based on draft circulations (e.g., Randall, 1988; Hanson, 1988).

Khalsa, Siri Jodha Singh↗

International Space Station Environmental Control and Life Support Emergency Response Verification for Node 1

The International Space Station (ISS) Node 1 Environmental Control and Life Support (ECLS) System is comprised of five subsystems: Atmosphere Control and Supply (ACS), Atmosphere Revitalization (AR), Fire Detection and Suppression (FDS), Temperature and Humidity Control (THC), and Water Recovery and Management (WRM). This paper provides a summary of the Node 1 Emergency Response capability, which includes nominal and off-nominal FDS operation, off nominal ACS operation, and off-nominal THC operation. These subsystems provide the capability to help aid the crew members during an emergency cabin depressurization, a toxic spill, or a fire. The paper will also provide a discussion of the detailed Node 1 ECLS Element Verification methodologies for operation of the Node 1 Emergency Response hardware operations utilized during the Qualification phase.

Williams, David E.↗

Roadmap for the future of extreme wildfire events

Background Extreme wildfire events (EWEs) represent a growing threat globally, posing substantial risks to ecosystems, human communities, and infrastructure. Despite increased recognition of their ecological, social, and economic significance, current definitions of EWEs vary widely, reflecting disciplinary biases and regional contexts. This article emerges from an interdisciplinary workshop convened to reassess and refine the definition of EWEs, examine their impacts across ecological and social dimensions, and identify critical knowledge gaps impeding our understanding of these infrequent but important events. Results Our synthesis highlights significant limitations with existing definitions, particularly their reliance on subjective thresholds and their emphasis on extreme fire behavior alone. EWEs encompass a spectrum of complex, multi-dimensional phenomena that extend beyond immediate biophysical characteristics to include cumulative social, economic, and ecological impacts. These impacts often manifest over extended timeframes and include hazardous environmental contamination, severe geomorphic disturbances, ecosystem transformations, and unintended consequences of post-fire management actions. Current wildfire modeling frameworks inadequately capture these compounding factors, particularly the interactions among social systems, ecological conditions, and extreme fire behavior. To overcome these issues, we advocate for an interdisciplinary and context-sensitive approach to defining and studying EWEs. This revised definition emphasizes wildfires exhibiting anomalies in fire behavior, ecological outcomes, or social impacts relative to historically observed baselines, accommodating variability across different geographic regions and ecological settings. Conclusions Adopting an interdisciplinary framework that integrates biophysical and social sciences will enhance the predictive capability of wildfire models and improve resilience planning and response strategies. Filling identified knowledge gaps—such as limited high-quality empirical fire behavior data and insufficient integration of social dynamics into modeling—will better prepare communities and ecosystems to cope with and adapt to EWEs. This inclusive approach underscores the necessity for collaboration across disciplines and sectors, essential to managing extreme wildfires in an era of increasing climatic and ecological uncertainty.

54 ENVIRONMENTAL SCIENCES↗

Interactions between land use, fires, and dust as drivers of global climate change (Final Technical Report)

This award to UC Irvine and Cornell University led to the publication of 18 papers, three of which are highly cited. According to ISI Web of Science, the body of work from this grant has been cited over 476 times by May 2025. Several additional publications remain in review. This grant contributed to several significant science advances, including an improved understanding of the influence of fire aerosols on global photosynthesis (Xu et al., 2021), dust-driven teleconnections between Africa and South America (Li et al., 2021), the role of fire aerosols in triggering phytoplankton blooms in the Arctic (Ardyna et al., 2022), and wildfire responses to heat waves (Li et al., in review). Several other studies are being written up for publication, and will acknowledge funding support. These efforts include an analysis in which the magnitude of tropical fire emissions from land use change is constrained by comparing E3SMv3 simulations with atmospheric observations. This work has revealed that carbon cycle model estimates of land use change may considerably overestimate the global tropical deforestation flux. The project also contributed to several technical advances, including a new process-based and scale-aware desert dust emission scheme for global climate models (Leung et al., 2023), an improved representation of dust and its influence on radiation in E3SM (Feng et al., 2022), an improved representation of the dust parameterization in the Community Earth System Model (Li et al., 2022), and an improved coupling of wildfires with atmospheric chemistry in E3SM v3.

58 GEOSCIENCES↗

Functional Groups Based on Leaf Physiology: Are they Spatially and Temporally Robust?

The functional grouping hypothesis, which suggests that complexity in function can be simplified by grouping species with similar responses, was tested in the Florida scrub habitat. Functional groups were identified based on how species in fire maintained FL scrub function in terms of carbon, water and nitrogen dynamics. The suite of physiologic parameters measured to determine function included both instantaneous gas exchange measurements obtained from photosynthetic light response curves and integrated measures of function. Using cluster analysis, five distinct physiologically-based functional groups were identified. Using non-parametric multivariate analyses, it was determined that these five groupings were not altered by plot differences or by the three different management regimes; prescribed burn, mechanically treated and burn, and fire-suppressed. The physiological groupings also remained robust between the two years 1999 and 2000. In order for these groupings to be of use for scaling ecosystem processes, there needs to be an easy-to-measure morphological indicator of function. Life form classifications were able to depict the physiological groupings more adequately than either specific leaf area or leaf thickness. THe ability of life forms to depict the groupings was improved by separating the parasitic Ximenia americana from the shrub category.

Foster, Tammy E.↗

Low-intensity frequent fires in coniferous forests transform soil organic matter in ways that may offset ecosystem carbon losses

The impact of shifting disturbance regimes on soil carbon (C) storage is a key uncertainty in global change research. Wildfires in coniferous forests are becoming more frequent in many regions, potentially causing large C emissions. Repeated low-intensity prescribed fires can mitigate wildfire severity, but repeated combustion may decrease soil C unless compensatory responses stabilize soil organic matter. Here, we tested how 30 years of decadal prescribed burning affected C and nitrogen (N) in plants, detritus, and soils in coniferous forests in the Sierra Nevada mountains, USA. Tree basal area and litter stocks were resilient to fire, but fire reduced forest floor C by 77% (-36.4 Mg C/ha). In mineral soils, fire reduced C that was free from minerals by 41% (-4.4 Mg C/ha) but not C associated with minerals, and only in depths ≤ 5 cm. Fire also transformed the properties of remaining mineral soil organic matter by increasing the proportion of C in a pyrogenic form (from 3.2% to 7.5%) and associated with minerals (from 46% to 58%), suggesting the remaining soil C is more resistant to decomposition. Laboratory assays illustrated that fire reduced microbial CO2 respiration rates by 55% and the activity of eight extracellular enzymes that degrade cellulosic and aromatic compounds by 40–66%. Lower decomposition was correlated with lower inorganic N (-49%), especially ammonium, suggesting N availability is coupled with decomposition. The relative increase in forms of soil organic matter that are resistant to decay or stabilized onto mineral surfaces, and the associated decline in decomposition suggest that low-intensity fires may promote mineral soil C storage in pools with long mean residence times in coniferous forests.

54 ENVIRONMENTAL SCIENCES↗

Monitoring Disasters by Use of Instrumented Robotic Aircraft

Efforts are under way to develop data-acquisition, data-processing, and data-communication systems for monitoring disasters over large geographic areas by use of uninhabited aerial systems (UAS) robotic aircraft that are typically piloted by remote control. As integral parts of advanced, comprehensive disaster- management programs, these systems would provide (1) real-time data that would be used to coordinate responses to current disasters and (2) recorded data that would be used to model disasters for the purpose of mitigating the effects of future disasters and planning responses to them. The basic idea is to equip UAS with sensors (e.g., conventional video cameras and/or multispectral imaging instruments) and to fly them over disaster areas, where they could transmit data by radio to command centers. Transmission could occur along direct line-of-sight paths and/or along over-the-horizon paths by relay via spacecraft in orbit around the Earth. The initial focus is on demonstrating systems for monitoring wildfires; other disasters to which these developments are expected to be applicable include floods, hurricanes, tornadoes, earthquakes, volcanic eruptions, leaks of toxic chemicals, and military attacks. The figure depicts a typical system for monitoring a wildfire. In this case, instruments aboard a UAS would generate calibrated thermal-infrared digital image data of terrain affected by a wildfire. The data would be sent by radio via satellite to a data-archive server and image-processing computers. In the image-processing computers, the data would be rapidly geo-rectified for processing by one or more of a large variety of geographic-information- system (GIS) and/or image-analysis software packages. After processing by this software, the data would be both stored in the archive and distributed through standard Internet connections to a disaster-mitigation center, an investigator, and/or command center at the scene of the fire. Ground assets (in this case, firefighters and/or firefighting equipment) would also be monitored in real time by use of Global Positioning System (GPS) units and radio communication links between the assets and the UAS. In this scenario, the UAS would serve as a data-relay station in the sky, sending packets of information concerning the locations of assets to the image-processing computer, wherein this information would be incorporated into the geo-rectified images and maps. Hence, the images and maps would enable command-center personnel to monitor locations of assets in real time and in relation to locations affected by the disaster. Optionally, in case of a disaster that disrupted communications, the UAS could be used as an airborne communication relay station to partly restore communications to the affected area. A prototype of a system of this type was demonstrated in a project denoted the First Response Experiment (Project FiRE). In this project, a controlled outdoor fire was observed by use of a thermal multispectral scanning imager on a UAS that delivered image data to a ground station via a satellite uplink/ downlink telemetry system. At the ground station, the image data were geo-rectified in nearly real time for distribution via the Internet to firefighting managers. Project FiRE was deemed a success in demonstrating several advances essential to the eventual success of the continuing development effort.

Wegener, Steven S.↗

Design, Instrumentation, and Data Analysis for the SLS Core Stage Green Run Test Series

The Space Launch System (SLS) Core Stage (CS) Thrust Vector Control (TVC) system is comprised of eight mechanical feedback Shuttle heritage Type III TVC actuators and four RS-25 engines, each attached to a Shuttle heritage gimbal block/bearing. The actuators are powered by a Shuttle-derived hydraulic Core Auxiliary Power Unit (CAPU), and integrated with an all-new Core Stage thrust structure. The actuators are interfaced to the SLS Vehicle Management (VM) software via an all-new TVC Actuator Control (TAC) avionics subsystem. Despite the significant test and flight experience of the Shuttle hardware, the SLS Green Run ambient and hot fire test activities revealed a number of new findings associated with the dynamic response of the TVC integrated system. Test responses suggested that the TVC system did not meet its performance specifications and its step and frequency responses exhibited unexpected departures from prior lab tests and modeled behavior. This paper is the fifth installment in a seven-paper series surveying the design, engineering, test validation, and flight performance of the Core Stage Thrust Vector Control system. In this paper, the design of the TVC analyses conducted during the Core Stage Green Run test series are discussed in detail. Throughout the course of the test activities, the SLS flight control team worked diligently with the Core Stage contractor to revise test command profiles and ensure sufficient instrumentation was available to collect data. Post-test analysis combined the Green Run modal, ambient, and hot fire test data, MSFC 2- axis Core Stage TVC Inertial Load Simulator (ILS) data, Hardware-In-the-Loop (HWIL) Systems Integration Lab (SIL) results, and actuator Acceptance Testing Procedure (ATP) responses. These data were used to characterize the response, validate critical math models of the TVC subsystem, and isolate the probable cause of the unexpected responses. Through comprehensive analysis of the available test data sources, the integrated team identified the dominant contributors to the observed response and developed test-correlated rationale for vehicle flight control system performance, ultimately leading to a confident posture for the Artemis I mission.

John H. Wall↗

Future Pathways for Arctic Forest Fires

Wildfires are expected to become more common and more severe in the Arctic states due to climate change. Main cause for the fires is human activity, even in the boreal and Arctic forests. Therefore, activities such forest management and tourism, together with firefighting capacity and readiness, can have a significant impact on future wildfire risks and impacts. To assess the impacts of these factors we have created pathways for future wildfires up to 2050 for the Arctic states. We explore high and low fire activity and risk pathways for all the Arctic states and suggest most our best guess pathways for each state separately. The low activity and fire risk pathway assumes active fire suppression via population participation and official land management, efficient fuel treatments to reduce fire risk, and active firefighting. The high activity and fire risk pathway assumes the opposite due to lack of government and community response, with addition of lacking response to climate-driven changes to wildfire risks. In the Nordic countries, human ignition sources, such as timber extraction, tourism, summer cottages, and expanding wildland-urban intermix due to exurban growth may increase. In addition to these in Canada and Alaska, expansion of agriculture increases the likelihood of open burning of agricultural waste, increasing risk of the fire spreading to wildlands. Drier fuels due to climate change increase the risk of fires, and there is a growing risk of extreme heat conditions, creating favorable conditions for extreme wildfires from any ignition source. Throughout the Arctic lightning is expected to increase, increasing the risk of tundra (specifically grassland) fires, with potential to occur in hard-to-reach locations for firefighting. In short, policy actions and education play a crucial role in future wildfire management and adaptation.

Future↗

Fires and Smoke Observed from the Earth Observing System MODIS Instrument: Products, Validation, and Operational Use

The MODIS sensor, launched on NASA's Terra satellite at the end of 1999, was designed with 36 spectral channels for a wide array of land, ocean, and atmospheric investigations. MODIS has a unique ability to observe fires, smoke, and burn scars globally. Its main fire detection channels saturate at high brightness temperatures: 500 K at 4 microns and 400 K at 11 microns, which can only be attained in rare circumstances at the I kin fire detection spatial resolution. Thus, unlike other polar orbiting satellite sensors with similar thermal and spatial resolutions, but much lower saturation temperatures (e.g. AVHRR and ATSR), MODIS can distinguish between low intensity ground surface fires and high intensity crown forest fires. Smoke column concentration over land is for the first time being derived from the MOMS solar channels, extending from 0.41 microns to 2.1 microns. The smoke product has been provisionally validated both globally and regionally over southern Africa and central and south America. Burn scars are observed from MODIS even in the presence of smoke, using the 1.2 to 2.1 micron channels. MODIS burned area information is used to estimate pyrogenic emissions. A wide range of these fire and related products and validation are demonstrated for the wild fires that occurred in northwestern United States in the summer of 2000. The MODIS rapid response system and direct broadcast capability is being developed to enable users to obtain and generate data in near real time. It is expected that health and land management organizations will use these systems for monitoring the occurrence of fires and the dispersion of smoke within two to six hours after data acquisition.

Kaufman, Y. J.↗

A Conservation Strategy for the Florida Scrub-Jay on John F. Kennedy Space Center/Merritt Island National Wildlife Refuge: An Initial Scientific Basis for Recovery

The Florida Scrub-Jay (Aphelocoma coerulescens) is an indicator of ecosystem integrity of Florida scrub, an endangered ecosystem that requires frequent fire. One of the largest populations of this federally threatened species occurs on John F. Kennedy Space Center/Merritt Island National Wildlife Refuge. Population trends were predicted using population modeling and field data on reproduction and survival of Florida Scrub-Jays collected from 1988 - 1995. Analyses of historical photography indicated that habitat suitability has been declining for 30 years. Field data and computer simulations suggested that the population declined by at least 40% and will decline by another 40% in 1 0 years, if habitat management is not greatly intensified. Data and computer simulations suggest that habitat suitability cannot deviate greatly from optimal for the jay population to persist. Landscape trajectories of vegetation structure, responsible for declining habitat suitability, are associated with the disruption of natural fire regimes. Prescribed fire alone can not reverse the trajectories. A recovery strategy was developed, based on studies of Florida Scrub-Jays and scrub vegetation. A reserve design was formulated based on conservation science principles for scrub ecosystems. The strategy emphasizes frequent fire to restore habitat, but includes mechanical tree cutting for severely degraded areas. Pine thinning across large areas can produce rapid increases in habitat quality. Site-specific strategies will need to be developed, monitored, and modified to achieve conditions suitable for population persistence.

Breininger, D. R.↗

The Future of Arctic Fires: Leveraging Ongoing Activities, New Efforts, and International Cooperation

Fires in the Arctic region are gaining more attention and driving increased concern from the public, the scientific community, and policymakers. An increasing number of scientific projects, collaboration efforts, media coverage, and policy assessments have been and are being implemented and published regarding this emerging and important wildland fire phenomenon. In short, this increased activity comes from the recognition of increasing fire risk and activity close to, within, and impacting the Arctic. There is a need to integrate these numerous and expanding local, national, and international efforts to avoid redundant and overlapping efforts and to focus resources more efficiently. As a response, this report suggests short and long-term goals to respond to the growing fire risk and fire danger in the Arctic. All efforts call for more integrated international collaboration and greater recognition of the importance for Arctic communities to be collaborators and leaders.

Future↗

Synthesis and evaluation of polymers for use in early warning fire alarm devices

Conjugated polyacetylene polymers and one condensation polyene, all containing a high degree of conjugated unsaturation, were synthesized. These polymers were characterized by chemical analysis and by thermogravimetric analysis, as well as for their film-forming capability and gas/polymer interactions. It was found that those that had a high degree of conjugated unsaturation and had resonance - stabilizing groups were very thermally stable to 200 C, e.g., poly(dicyanoacetylene), poly(ethynylferrocene) and poly(phenylacetylene); while those with labile moieties, such as poly(p-formamidophenylacetylene), among others, suffered some degradation when heated in air. When subjected to gas/polymer interaction effects, the greatest change in electrical conductance was observed when ammonia was used as the gas and poly(p-nitrophenylacetylene) was the detector. Other polymers showed similar behavior. For example, poly(ethynylcarborane), considered to be an electron acceptor also showed a change in electrical conductance when exposed to ammonia, while poly(ethynylpyridine) and poly(ethylidenepyridazine) responded to carbon monoxide. However, for "fire gases" (gases from smoldering cotton), poly(ethynylferrocene) was the most responsive. Thus, the concept of polymers with different electronegativities forming charge-transfer complexes with different gases was found to be operable.

Byrd, N. R.↗