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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 307 records · Page 17
All sourcesNASA NTRSDOE OSTI
DOE OSTI2015

SIGNATURES OF MRI-DRIVEN TURBULENCE IN PROTOPLANETARY DISKS: PREDICTIONS FOR ALMA OBSERVATIONS

Spatially resolved observations of molecular line emission have the potential to yield unique constraints on the nature of turbulence within protoplanetary disks. Using a combination of local non-ideal magnetohydrodynamics (MHD) simulations and radiative transfer calculations, tailored to properties of the disk around HD 163296, we assess the ability of ALMA to detect turbulence driven by the magnetorotational instability (MRI). Our local simulations show that the MRI produces small-scale turbulent velocity fluctuations that increase in strength with height above the mid-plane. For a set of simulations at different disk radii, we fit a Maxwell–Boltzmann distribution to the turbulent velocity and construct a turbulent broadening parameter as a function of radius and height. We input this broadening into radiative transfer calculations to quantify observational signatures of MRI-driven disk turbulence. We find that the ratio of the peak line flux to the flux at line center is a robust diagnostic of turbulence that is only mildly degenerate with systematic uncertainties in disk temperature. For the CO(3–2) line, which we expect to probe the most magnetically active slice of the disk column, variations in the predicted peak-to-trough ratio between our most and least turbulent models span a range of approximately 15%. Additional independent constraints can be derived from the morphology of spatially resolved line profiles, and we estimate the resolution required to detect turbulence on different spatial scales. We discuss the role of lower optical depth molecular tracers, which trace regions closer to the disk mid-plane where velocities in MRI-driven models are systematically lower.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2013

SYNOPTIC MAPPING OF CHROMOSPHERIC MAGNETIC FLUX

We used daily full-disk Ca II 854.2 nm magnetograms from the Synoptic Optical Long Term Investigations of the Sun (SOLIS) facility to study the chromospheric magnetic field from 2006 April through 2009 November. We determined and corrected previously unidentified zero offsets in the SOLIS magnetograms. By tracking the disk passages of stable unipolar regions, the measured net flux densities were found to systematically decrease from the disk center to the limb by a factor of about two. This decrease was modeled using a thin flux tube model with a difference in signal formation height between the center and limb sides. Comparison of photospheric and chromospheric observations shows that their differences are largely due to horizontal spreading of magnetic flux with increasing height. The north polar magnetic field decreased nearly linearly with time during our study period while the south polar field was nearly constant. We used the annual change in the viewing angle of the polar regions to estimate the radial and meridional components of the polar fields and found that the south polar fields were tilted away from the pole. Synoptic maps of the chromospheric radial flux density distribution were used as boundary conditions for extrapolation of the field from the chromosphere into the corona. A comparison of modeled and observed coronal hole boundaries and coronal streamer positions showed better agreement when using the chromospheric rather than the photospheric synoptic maps.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2013

COSMIC RAYS CAN DRIVE STRONG OUTFLOWS FROM GAS-RICH HIGH-REDSHIFT DISK GALAXIES

We present simulations of the magnetized interstellar medium (ISM) in models of massive star-forming (40 M {sub ☉} yr{sup –1}) disk galaxies with high gas surface densities (Σ{sub gas} ∼ 100 M {sub ☉} pc{sup –2}) similar to observed star-forming high-redshift disks. We assume that type II supernovae deposit 10% of their energy into the ISM as cosmic rays (CRs) and neglect the additional deposition of thermal energy or momentum. With a typical Galactic diffusion coefficient for CRs (3 × 10{sup 28} cm{sup 2} s{sup –1}), we demonstrate that this process alone can trigger the local formation of a strong low-density galactic wind maintaining vertically open field lines. Driven by the additional pressure gradient of the relativistic fluid, the wind speed can exceed 10{sup 3} km s{sup –1}, much higher than the escape velocity of the galaxy. The global mass loading, i.e., the ratio of the gas mass leaving the galactic disk in a wind to the star formation rate, becomes of order unity once the system has settled into an equilibrium. We conclude that relativistic particles accelerated in supernova remnants alone provide a natural and efficient mechanism to trigger winds similar to observed mass-loaded galactic winds in high-redshift galaxies. These winds also help in explaining the low efficiencies for the conversion of gas into stars in galaxies, as well as the early enrichment of the intergalactic medium with metals. This mechanism may be at least of similar importance to the traditionally considered momentum feedback from massive stars and thermal and kinetic feedback from supernova explosions.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2018

The Mochi LabJet Experiment for Measurements of Canonical Helicity Injection in a Laboratory Astrophysical Jet

The Mochi device is a new pulsed power plasma experiment designed to produce long, collimated, stable, magnetized plasma jets when set up in the LabJet configuration. The LabJet configuration aims to simulate an astrophysical jet in the laboratory by mimicking an accretion disk threaded by a poloidal magnetic field with concentric planar electrodes in front of a solenoidal coil. The unique setup consists of three electrodes, each with azimuthally symmetric gas slits. Two of the electrodes are biased independently with respect to the third electrode to control the radial electric field profile across the poloidal bias magnetic field. This design approximates a shear azimuthal rotation profile in an accretion disk. The azimuthally symmetric gas slits provide a continuously symmetric mass source at the footpoint of the plasma jet, so any azimuthal rotation of the plasma jet is not hindered by a discrete number of gas holes. The initial set of diagnostics consists of current Rogowski coils, voltage probes, magnetic field probe arrays, an interferometer and ion Doppler spectroscopy, supplemented by a fast ion gauge and a retarding grid energy analyzer. The measured parameters of the first plasmas are ~10 22 m -3 , ~0.4 T, and 5–25 eV, with velocities of ~20–80 km s -1 . Finally, the combination of a controllable electric field profile, a flared poloidal magnetic field, and azimuthally symmetric mass sources in the experiment successfully produces short-lived (~10 μs, ≳5 Alfvén times) collimated magnetic jets with a ~10:1 aspect ratio and long-lived (~100 μs, ≳40 Alfvén times) flow-stabilized, collimated, magnetic jets with a ~30:1 aspect ratio.

42 ENGINEERING↗
DOE OSTI2018

Fully Kinetic Large-scale Simulations of the Collisionless Magnetorotational Instability

We present two-dimensional particle-in-cell simulations of the fully kinetic collisionless magnetorotational instability (MRI) in weakly magnetized (high β) pair plasma. The central result of this numerical analysis is the emergence of a self-induced turbulent regime in the saturation state of the collisionless MRI, which can only be captured for large enough simulation domains. One of the underlying mechanisms for the development of this turbulent state is the drift-kink instability (DKI) of the current sheets resulting from the nonlinear evolution of the channel modes. The onset of the DKI can only be observed for simulation domain sizes exceeding several linear MRI wavelengths. The DKI and ensuing magnetic reconnection activate the turbulent motion of the plasma in the late stage of the nonlinear evolution of the MRI. At steady-state, the magnetic energy has an MHD-like spectrum with a slope of k –5/3 for kρ < 1 and k –3 for sub-Larmor scale (kρ > 1). We also examine the role of the collisionless MRI and associated magnetic reconnection in the development of pressure anisotropy. We study the stability of the system due to this pressure anisotropy, observing the development of mirror instability during the early-stage of the MRI. We further discuss the importance of magnetic reconnection for particle acceleration during the turbulence regime. Furthermore, consistent with reconnection studies, we show that at late times the kinetic energy presents a characteristic slope of ϵ –2 in the high-energy region.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2015

PHOTOMETRIC TRENDS IN THE VISIBLE SOLAR CONTINUUM AND THEIR SENSITIVITY TO THE CENTER-TO-LIMB PROFILE

Solar irradiance variations over solar rotational timescales are largely determined by the passage of magnetic structures across the visible solar disk. Variations on solar cycle timescales are thought to be similarly due to changes in surface magnetism with activity. Understanding the contribution of magnetic structures to total solar irradiance and solar spectral irradiance requires assessing their contributions as a function of disk position. Since only relative photometry is possible from the ground, the contrasts of image pixels are measured with respect to a center-to-limb intensity profile. Using nine years of full-disk red and blue continuum images from the Precision Solar Photometric Telescope at the Mauna Loa Solar Observatory, we examine the sensitivity of continuum contrast measurements to the center-to-limb profile definition. Profiles which differ only by the amount of magnetic activity allowed in the pixels used to determine them yield oppositely signed solar cycle length continuum contrast trends, either agreeing with previous results and showing negative correlation with solar cycle or disagreeing and showing positive correlation with solar cycle. Changes in the center-to-limb profile shape over the solar cycle are responsible for the contradictory contrast results, and we demonstrate that the lowest contrast structures, internetwork and network, are most sensitive to these. Thus the strengths of the full-disk, internetwork, and network photometric trends depend critically on the magnetic flux density used in the quiet-Sun definition. We conclude that the contributions of low contrast magnetic structures to variations in the solar continuum output, particularly to long-term variations, are difficult, if not impossible, to determine without the use of radiometric imaging.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2016

The magnetized galactic wind and synchrotron halo of the starburst dwarf galaxy IC 10

We aim to explore whether strong magnetic fields can be effectively generated in low-mass dwarf galaxies and, if so, whether such fields can be affected by galactic outflows and spread out into the intergalactic medium (IGM). We performed a radio continuum polarimetry study of IC 10, the nearest starbursting dwarf galaxy, using a combination of multifrequency interferometric (VLA) and single-dish (Effelsberg) observations. VLA observations at 1.43 GHz reveal an extensive and almost spherical radio halo of IC 10 in total intensity, extending twice more than the infrared-emitting galactic disk. The halo is magnetized with a magnetic field strength of 7 μG in the outermost parts. Locally, the magnetic field reaches about 29 μG in H ii complexes, becomes more ordered, and weakens to 22 μG in the synchrotron superbubble and to 7–10 μG within H i holes. At the higher frequency of 4.86 GHz, we found a large-scale magnetic field structure of X-shaped morphology, similar to that observed in several edge-on spiral galaxies. The X-shaped magnetic structure can be caused by the galactic wind, advecting magnetic fields injected into the interstellar medium by stellar winds and supernova explosions. The radio continuum scale heights at 1.43 GHz indicate the bulk speed of cosmic-ray electrons outflowing from H ii complexes of about 60 km s{sup −1}, exceeding the escape velocity of 40 km s{sup −1}. Hence, the magnetized galactic wind in IC 10 inflates the extensive radio halo visible at 1.43 GHz and can seed the IGM with both random and ordered magnetic fields. These are signatures of intense material feedback onto the IGM, expected to be prevalent in the protogalaxies of the early universe.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2016

A UNIFIED MODEL OF GRAIN ALIGNMENT: RADIATIVE ALIGNMENT OF INTERSTELLAR GRAINS WITH MAGNETIC INCLUSIONS

The radiative torque (RAT) alignment of interstellar grains with ordinary paramagnetic susceptibilities has been supported by earlier studies. The alignment of such grains depends on the so-called RAT parameter q {sup max}, which is determined by the grain shape. In this paper, we elaborate on our model of RAT alignment for grains with enhanced magnetic susceptibility due to iron inclusions, such that RAT alignment is magnetically enhanced, which we term the MRAT mechanism. Such grains can be aligned with high angular momentum at the so-called high- J attractor points, achieving a high degree of alignment. Using our analytical model of RATs, we derive the critical value of the magnetic relaxation parameter δ {sub m} to produce high- J attractor points as functions of q {sup max} and the anisotropic radiation angle relative to the magnetic field ψ . We find that if about 10% of the total iron abundance present in silicate grains is forming iron clusters, this is sufficient to produce high- J attractor points for all reasonable values of q {sup max}. To calculate the degree of grain alignment, we carry out numerical simulations of MRAT alignment by including stochastic excitations from gas collisions and magnetic fluctuations. We show that large grains can achieve perfect alignment when the high- J attractor point is present, regardless of the values of q {sup max}. Our obtained results pave the way for the physical modeling of polarized thermal dust emission as well as magnetic dipole emission. We also find that millimeter-sized grains in accretion disks may be aligned with the magnetic field if they are incorporated with iron nanoparticles.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2014

Hall-effect-controlled gas dynamics in protoplanetary disks. I. Wind solutions at the inner disk

The gas dynamics of protoplanetary disks (PPDs) is largely controlled by non-ideal magnetohydrodynamic (MHD) effects including Ohmic resistivity, the Hall effect, and ambipolar diffusion. Among these the role of the Hall effect is the least explored and most poorly understood. In this series, we have included, for the first time, all three non-ideal MHD effects in a self-consistent manner to investigate the role of the Hall effect on PPD gas dynamics using local shearing-box simulations. In this first paper, we focus on the inner region of PPDs, where previous studies (Bai and Stone 2013; Bai 2013) excluding the Hall effect have revealed that the inner disk up to ∼10 AU is largely laminar, with accretion driven by a magnetocentrifugal wind. We confirm this basic picture and show that the Hall effect modifies the wind solutions depending on the polarity of the large-scale poloidal magnetic field B{sub 0} threading the disk. When B{sub 0}⋅Ω>0, the horizontal magnetic field is strongly amplified toward the disk interior, leading to a stronger disk wind (by ∼50% or less in terms of the wind-driven accretion rate). The enhanced horizontal field also leads to much stronger large-scale Maxwell stress (magnetic braking) that contributes to a considerable fraction of the wind-driven accretion rate. When B{sub 0}⋅Ω<0, the horizontal magnetic field is reduced, leading to a weaker disk wind (by ≲ 20%) and negligible magnetic braking. Under fiducial parameters, we find that when B{sub 0}⋅Ω>0, the laminar region extends farther to ∼10-15 AU before the magnetorotational instability sets in, while for B{sub 0}⋅Ω<0, the laminar region extends only to ∼3-5 AU for a typical accretion rate of ∼10{sup –8} to10{sup –7} M {sub ☉} yr{sup –1}. Scaling relations for the wind properties, especially the wind-driven accretion rate, are provided for aligned and anti-aligned field geometries.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2016

Massive Gas Injection Valve Development for NSTX-U

NSTX-U research will offer new insight by studying gas assimilation efficiencies for MGI injection from different poloidal locations using identical gas injection systems. In support of this activity, an electromagnetic MGI valve has been built and tested. The valve operates by repelling two conductive disks due to eddy currents induced on them by a rapidly changing magnetic field created by a pancake disk solenoid positioned beneath the circular disk attached to a piston. The current is driven in opposite directions in the two solenoids, which creates a cancelling torque when the valve is operated in an ambient magnetic field, as would be required in a tokamak installation. The valve does not use ferromagnetic materials. Results from the operation of the valve, including tests conducted in 1 T external magnetic fields, are described. The pressure rise in the test chamber is measured directly using a fast time response baratron gauge. At a plenum pressure of just 1.38 MPa (~200 psig), the valve injects 27 Pa.m^3 (~200 Torr.L) of nitrogen with a pressure rise time of 3 ms.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2013

THE EXTENT OF MAGNETIC FIELDS AROUND GALAXIES OUT TO z {approx} 1

Radio quasar sightlines with strong Mg II absorption lines display statistically enhanced Faraday rotation measures (RMs), indicating the presence of additional magneto-active plasma with respect to sightlines free of such absorption. In this Letter, we use multi-color optical imaging to identify the galaxies likely hosting the magneto-active plasma, and to constrain the location of the latter with respect to the putative parent halo. We find that all of the sightlines with high |RM| pass within 50 kpc of a galaxy and that the |RM| distribution for low impact parameters, D < 50 kpc, is significantly different than for larger impact parameters. In addition, we find a decrease in the ratio of the polarization at 21 cm and 1.5 cm, p{sub 21}/p{sub 1.5}, toward lower D. These two effects are most likely related, strengthen the association of excess |RM| with intervening galaxies, and suggest that intervening galaxies operate as inhomogeneous Faraday screens. These results are difficult to reconcile with only a disk model for the magnetic field, but are consistent with highly magnetized winds associated with Mg II systems. We infer strong magnetic fields of a few tens of {mu}G, consistent with the values required by the lack of evolution of the FIR-radio correlation at high redshifts. Finally, these findings lend support to the idea that the small-scale helicity bottleneck of {alpha}-{Omega} galactic dynamos can be significantly alleviated via galactic winds.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2017

GLOBAL SIMULATIONS OF GALACTIC WINDS INCLUDING COSMIC-RAY STREAMING

Galactic outflows play an important role in galactic evolution. Despite their importance, a detailed understanding of the physical mechanisms responsible for the driving of these winds is lacking. In an effort to gain more insight into the nature of these flows, we perform global three-dimensional magnetohydrodynamical simulations of an isolated Milky Way-size starburst galaxy. We focus on the dynamical role of cosmic rays (CRs) injected by supernovae, and specifically on the impact of the streaming and anisotropic diffusion of CRs along the magnetic fields. We find that these microphysical effects can have a significant effect on the wind launching and mass loading factors, depending on the details of the plasma physics. Due to the CR streaming instability, CRs propagating in the interstellar medium scatter on self-excited Alfvén waves and couple to the gas. When the wave growth due to the streaming instability is inhibited by some damping process, such as turbulent damping, the coupling of CRs to the gas is weaker and their effective propagation speed faster than the Alfvén speed. Alternatively, CRs could scatter from “extrinsic turbulence” that is driven by another mechanism. We demonstrate that the presence of moderately super-Alfvénic CR streaming enhances the efficiency of galactic wind driving. Cosmic rays stream away from denser regions near the galactic disk along partially ordered magnetic fields and in the process accelerate more tenuous gas away from the galaxy. For CR acceleration efficiencies broadly consistent with the observational constraints, CRs reduce the galactic star formation rates and significantly aid in launching galactic winds.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2022

Hard disk drive dismantlement for critical material recovery

A system and method for recycling rare earth materials from dissimilar hard disk drives are provided. The system and method generally include scanning each hard disk drive, sorting and aligning each hard disk drive, rapid fastener removal or diversion to a metrology station, and the collection of separated value streams, optionally for formation into new magnetic stock. For each scanned hard disk drive having a match in an inventory database, the method includes the separation of an internal magnet from residual components. For each scanned hard disk drive lacking a match in the inventory database, the method includes generating a metrology data collection record containing the location of each fastener on multiple surfaces of the corresponding hard disk drive. The system and method are commercially scalable with the potential to generate between 600 and 700 metric tons of rare earth elements from a single processing facility annually, including neodymium for example.

McIntyre, Timothy J.↗
DOE OSTI2012

SUPERSONIC SHEAR INSTABILITIES IN ASTROPHYSICAL BOUNDARY LAYERS

Disk accretion onto weakly magnetized astrophysical objects often proceeds via a boundary layer (BL) that forms near the object's surface, in which the rotation speed of the accreted gas changes rapidly. Here, we study the initial stages of formation for such a BL around a white dwarf or a young star by examining the hydrodynamical shear instabilities that may initiate mixing and momentum transport between the two fluids of different densities moving supersonically with respect to each other. We find that an initially laminar BL is unstable to two different kinds of instabilities. One is an instability of a supersonic vortex sheet (implying a discontinuous initial profile of the angular speed of the gas) in the presence of gravity, which we find to have a growth rate of order (but less than) the orbital frequency. The other is a sonic instability of a finite width, supersonic shear layer, which is similar to the Papaloizou-Pringle instability. It has a growth rate proportional to the shear inside the transition layer, which is of order the orbital frequency times the ratio of stellar radius to the BL thickness. For a BL that is thin compared to the radius of the star, the shear rate is much larger than the orbital frequency. Thus, we conclude that sonic instabilities play a dominant role in the initial stages of nonmagnetic BL formation and give rise to very fast mixing between disk gas and stellar fluid in the supersonic regime.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2013

1 Hz FLARING IN THE ACCRETING MILLISECOND PULSAR NGC 6440 X-2: DISK TRAPPING AND ACCRETION CYCLES

The dynamics of the plasma in the inner regions of an accretion disk around accreting millisecond X-ray pulsars (AMXPs) is controlled by the magnetic field of the neutron star. The interaction between an accretion disk and a strong magnetic field is not well understood, particularly at low accretion rates (the so-called propeller regime). This is due in part to the lack of clear observational diagnostics to constrain the physics of the disk-field interaction. Here, we associate the strong {approx}1 Hz modulation seen in the AMXP NGC 6440 X-2 with an instability that arises when the inner edge of the accretion disk is close to the corotation radius (where the stellar rotation rate matches the Keplerian speed in the disk). A similar modulation has previously been observed in another AMXP (SAX J1808.4-3658) and we suggest that the two phenomena are related and that this may be a common phenomenon among other magnetized systems. Detailed comparisons with theoretical models suggest that when the instability is observed, the interaction region between the disk and the field is very narrow-of the order of 1 km. Modeling further suggests that there is a transition region ({approx}1-10 km) around the corotation radius where the disk-field torque changes sign from spin-up to spin-down. This is the first time that a direct observational constraint has been placed on the width of the disk-magnetosphere interaction region, in the frame of the trapped-disk instability model.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2021

Relaxation of a single defect spin by the low-frequency gyrotropic mode of a magnetic vortex

We excite the gyrotropic mode of a magnetic vortex and observe the resulting effect on the spin state of a nearby nitrogen-vacancy (NV) defect in diamond. Thin permalloy disks fabricated on a diamond sample are magnetized in a vortex state in which the magnetization curls around a central core. The magnetization dynamics of this configuration are described by a discrete spectrum of confined magnon modes as well as a low-frequency gyrotropic mode in which the vortex core precesses about its equilibrium position. Despite the spin transition frequencies being far-detuned from the modes of the ferromagnet, we observe enhanced relaxation of the NV spin when driving the gyrotropic mode. Moreover, we map the spatial dependence of the interaction between the vortex and the spin by translating the vortex core within the disk with an applied magnetic field, resulting in steplike motion as the vortex is pinned and de-pinned. Strong spin relaxation is observed when the vortex core is within approximately 250 nm of the NV center defect. We attribute this effect to the higher frequencies in the spectrum of the magnetic fringe field arising from the soliton-like nature of the gyrotropic mode when driven with sufficiently large amplitude.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2015

THE ORIGIN OF THE PUZZLING HARD X-RAY EMISSION OF γ CASSIOPEIAE

Massive B and Be stars produce X-rays from shocks in high-velocity winds with temperatures of a few million degrees and maximum X-ray luminosities of ≈10{sup 31} erg s{sup −1}. Surprisingly, a sub-group of early Be stars exhibits ≥20 times hotter X-ray temperatures and ≥10 times higher X-ray luminosities than normal. This group of Be stars, dubbed γ-Cas analogs, contains about 10 known objects. The origin of this bizarre behavior has been extensively debated in the past decades. Two mechanisms have been put forward: accretion of circumstellar disk matter onto an orbiting white dwarf, or magnetic field interaction between the star and the circumstellar disk. We show here that the X-ray and optical emissions of the prototype of the class, γ-Cas, are very well correlated on year timescales with no significant time delay. Since the expected migration time from internal disk regions that emit most of the optical flux to the orbit of the companion star is several years, the simultaneity of the high energy and optical flux variations indicates that X-ray emission arises from close to the star. The systematic lack of magnetic field detection reported in recent spectro-polarimetric surveys of Be stars is consistent with the absence of strong magnetic wind braking in these fast spinning stars but place strong constraints on the possible origin of the magnetic field. We propose that in γ-Cas, the magnetic field emerges from equatorially condensed subsurface convecting layers, the thickness of which steeply increases with rotation rate, and that γ-Cas and its analogs are the most massive and closest to critical rotation Be stars.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2025

Coupling Interfacial Redox‐Reactions with In Situ Proton Generation for the Photoelectrochemical Separation of Rare‐Earth Elements

Abstract A dual‐function photoelectrochemical (PEC) separation system is demonstrated for rare‐earth element (REE) recovery. The sustainable release of the captured REEs is promoted through the synergistic integration of a redox‐reaction for electrostatic repulsion, and in situ proton generation for ion‐exchange, all driven by photoelectrochemistry. The platform consists of a redox‐copolymer, poly(ferrocenylpropyl methacrylamide‐ co ‐methacrylic acid) (P(FPMAm‐ co ‐MAA)) (PFM), conjugated with carbon nanotubes (CNTs) and coated onto titanium dioxide nanorods (TNRs). The (PFM‐CNT)/TNR spontaneously adsorbs up to 214.2 mg of Yttrium/g PFM by ion‐exchange, and demonstrates broad applicability for other REEs. The adsorbed REEs are released through the PEC oxidation of ferrocene (Fc) to ferrocenium (Fc + ), and the simultaneous PEC water splitting reactions at the TNRs that protonate the carboxylate binding groups. This dual photoelectrochemically‐driven mechanism for REE release is investigated by in situ pH measurements, as well as vibrational and X‐ray photoelectron spectroscopy. Through PEC approaches, a 68.8% reduction in energy consumption during REE recovery has been achieved compared to purely electrochemical systems, with a regeneration efficiency close to 100%. For NdFeB magnets from waste hard disk drives, Nd and Dy recovery efficiencies of 59.2 and 61.1% are achieved. The dual‐functionality of these copolymer PEC systems offers a sustainable platform for modulating critical element recovery.

Cho, Ki‐Hyun [Department of Chemical and Biomolecu↗