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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 307 records · Page 17
All sourcesNASA NTRSDOE OSTI
NASA NTRS1996

Clusters of DNA induced by ionizing radiation: formation of short DNA fragments. I. Theoretical modeling

We have developed a general theoretical model for the interaction of ionizing radiation with chromatin. Chromatin is modeled as a 30-nm-diameter solenoidal fiber comprised of 20 turns of nucleosomes, 6 nucleosomes per turn. Charged-particle tracks are modeled by partitioning the energy deposition between primary track core, resulting from glancing collisions with 100 eV or less per event, and delta rays due to knock-on collisions involving energy transfers >100 eV. A Monte Carlo simulation incorporates damages due to the following molecular mechanisms: (1) ionization of water molecules leading to the formation of OH, H, eaq, etc.; (2) OH attack on sugar molecules leading to strand breaks: (3) OH attack on bases; (4) direct ionization of the sugar molecules leading to strand breaks; (5) direct ionization of the bases. Our calculations predict significant clustering of damage both locally, over regions up to 40 bp and over regions extending to several kilobase pairs. A characteristic feature of the regional damage predicted by our model is the production of short fragments of DNA associated with multiple nearby strand breaks. The shapes of the spectra of DNA fragment lengths depend on the symmetries or approximate symmetries of the chromatin structure. Such fragments have subsequently been detected experimentally and are reported in an accompanying paper (B. Rydberg, Radiat, Res. 145, 200-209, 1996) after exposure to both high- and low-LET radiation. The overall measured yields agree well quantitatively with the theoretical predictions. Our theoretical results predict the existence of a strong peak at about 85 bp, which represents the revolution period about the nucleosome. Other peaks at multiples of about 1,000 bp correspond to the periodicity of the particular solenoid model of chromatin used in these calculations. Theoretical results in combination with experimental data on fragmentation spectra may help determine the consensus or average structure of the chromatin fibers in mammalian DNA.

Non-NASA Center↗
NASA NTRS1976

Researches on interactions of satellite-speed helium atoms with aluminum and quartz surfaces

Three major areas were experimentally studied: (1) energy transfer in collisions of satellite-speed (700 m/sec) helium atoms with a cleaned satellite-type aluminum surface was investigated using the molecular-beam technique. Spatial and energy distributions of reflected helium atoms were measured and analyzed, (2) The gross accommodation coefficient for a satellite-speed (7000 m/sec) helium beam entering a 2-inch-diameter aluminum spherical cavity was determined by measuring the exit velocity distribution of the leaving helium atoms using a metastable time-of-flight method. Results indicate that the 7000-m/sec satellite-speed helium atoms entering the cavity gain full accommodation with the room-temperature inner surface of the sphere through a large number of collisions before leaving the spherical cavity; and (3) the feasibility of producing a satellite-speed atomic hydrogen beam by arc-heating, for use in studies of interactions of satellite-surfaces with hydrogen atoms under laboratory conditions, was investigated. It was found that a stable arc-heated molecular hydrogen beam can be obtained using the arc-heater, and that a partially dissociated hydrogen beam can be produced. Photographs of laboratory equipment are shown.

Liu, S. M.↗
NASA NTRS1979

Quantum-mechanical calculation of three-dimensional atom-diatom collisions in the presence of intense laser radiation

A formalism is presented for describing the collision of fluorine with the hydrogen molecule in the presence of intense radiation. For a laser frequency on the order of the spin-orbit splitting of fluorine, the interaction of the molecular system with the radiation occurs at relatively long range where, for this system, the electric dipole is vanishingly small. Hence the interaction occurs due to the magnetic dipole coupling. Even so, at low collision energies a substantial enhancement of the quenching cross section is found for a radiation intensity of 10 to the 11th W/sq cm.

Devries, P. L.↗
NASA NTRS1983

Calculation of the polarization potential for e-N2 collisions

A polarization potential V(pol) for e-N2 collisions is calculated by the generalization of the static part of the method of polarized orbitals to molecular targets. Partial differential equations (PDE) are derived for polarized orbitals, which are functions of the distance (r) from the molecular center and angle (theta) from the molecular axis. The equations are solved with the use of the noniterative PDE technique. From the polarized orbitals a polarization potential can be constructed whose r and theta dependence is found to be significantly different from the well-known phenomenological one. The two potentials are further compared by carrying out limited hybrid-theory scattering calculations. Only those scattering results based on the calculated V(pol) are in satisfactory accord with experiment.

Onda, K.↗
NASA NTRS1995

Heavy ion track-structure calculations for radial dose in arbitrary materials

The delta-ray theory of track structure is compared with experimental data for the radial dose from heavy ion irradiation. The effects of electron transmission and the angular dependence of secondary electron ejection are included in the calculations. Several empirical formulas for electron range and energy are compared in a wide variety of materials in order to extend the application of the track-structure theory. The model of Rudd for the secondary electron-spectrum in proton collisions, which is based on a modified classical kinematics binary encounter model at high energies and a molecular promotion model at low energies, is employed. For heavier projectiles, the secondary electron spectrum is found by scaling the effective charge. Radial dose calculations for carbon, water, silicon, and gold are discussed. The theoretical data agreed well with the experimental data.

Cucinotta, Francis A.↗
NASA NTRS1987

Heterogeneous chemical reaction of chlorine nitrate and water on sulfuric-acid surfaces at room temperature

The use of H2SO4 as a catalyst for aerosol production of chlorine compounds in the chemistry of the antarctic stratosphere was investigated in laboratory trials. The experiments involved the gas surface collision rate of a molecule on a given surface during its residence time in a Knudsen cell in molecular flow conditions. Chlorine nitrate gas was made to flow through a chamber exposed to a container holding a 95.6 pct H2SO4 solution. Gas leaving the cell was scanned with a mass spectrometer. A sticking coefficient of 0.00032 was found for the chlorine nitrate, a value five times that previously reported.

Rossi, Michel J.↗
NASA NTRS2014

Molecular Gas Clumps from the Destruction of Icy Bodies in the beta Pictoris Debris Disk

Many stars are surrounded by disks of dusty debris formed in the collisions of asteroids, comets and dwarf planets. But is gas also released in such events? Observations at sub-mm wavelengths of the archetypal debris disk around β Pictoris show that 0.3% of a Moon mass of carbon monoxide orbits in its debris belt. The gas distribution is highly asymmetric, with 30% found in a single clump 85 AU from the star, in a plane closely aligned with the orbit of the inner planet, beta Pic b. This gas clump delineates a region of enhanced collisions, either from a mean motion resonance with an unseen giant planet, or from the remnants of a collision of Mars-mass planets.

wavelengths↗
NASA NTRS1979

Magnetic diffusion and ionization fractions in dense molecular clouds - The role of charged grains

The physics of magnetic diffusion in dense molecular clouds is examined, with particular attention given to the role of charged grains in controlling the process. The ionization fraction of dense molecular clouds in the presence of grains is determined from considerations of charge exchange, dissociative recombination, radiative recombination and collisions between grains and charged species, and it is found that the inclusion of grains tends to lower the ionization fraction for a given cosmic-ray ionization rate and metal depletion. The kinematics of grain motion is discussed and it is shown that at temperatures less than 30 K, each grain alternates rapidly in charge between -1 and 0 and thus executes periodic motion in a self-gravitating cloud containing a magnetic field. The full kinematics of magnetic diffusion including the motions of ions and electrons are then examined, taking into account the additional viscous force from charged grains, and numerical calculations of the diffusion time scales of uniform, magnetically supported clouds or cloud cores are presented.

Elmegreen, B. G.↗
NASA NTRS2000

Sputtering Erosion in the Ion Thruster

During the first phase of this research, the sputtering yields of molybdenum by low energy (100 eV and higher) xenon ions were measured by using the methods of secondary neutral mass spectrometry (SNMS) and Rutherford backscattering spectrometry (RBS). However, the measured sputtering yields were found to be far too low to explain the sputtering erosions observed in the long-duration tests of ion thrusters. The only difference between the sputtering yield measurement experiments and the ion thruster tests was that the later are conducted at high ion fluences. Hence, a study was initiated to investigate if any linkage exists between high ion fluence and an enhanced sputtering yield. The objective of this research is to gain an understanding of the causes of the discrepancies between the sputtering rates of molybdenum grids in an ion thruster and those measured from our experiments. We are developing a molecular dynamics simulation technique for studying low-energy xenon ion interactions with molybdenum. It is difficult to determine collision sequences analytically for primary ions below the 200 eV energy range where the ion energy is too low to be able to employ a random cascade model with confidence and it is too high to have to consider only single collision at or near the surface. At these low energies, the range of primary ions is about 1 to 2 nm from the surface and it takes less than 4 collisions on the average to get an ion to degrade to such an energy that it can no longer migrate. The fine details of atomic motion during the sputtering process are revealed through computer simulation schemes. By using an appropriate interatomic potential, the positions and velocities of the incident ion together with a sufficient number of target atoms are determined in small time steps. Hence, it allows one to study the evolution of damages in the target and its effect on the sputtering yield. We are at the preliminary stages of setting up the simulation program.

Ray, Pradosh K.↗
NASA NTRS1972

Linear momentum transfer effects in molecular dissociation produced by electron impact.

In this study of molecular dissociation produced by electron impact, diatomic systems and polyatomic molecules are considered, and attention is given to the effects of thermal motion and of momentum transfer in the collision process. A procedure is described which makes it possible to 'construct' both the laboratory angular distribution and velocity distribution of the atomic fragments (or, alternatively, the time-of-flight distribution). The calculation assumes that s-wave electron scattering predominates, i.e., that excitation occurs near threshold. The computational procedure may also be reversed to allow construction of possible molecular models to fit given experimental angular and velocity distribution data.

Misakian, M.↗
NASA NTRS1998

Molecular Processes in Comets

The research focused on molecular hydrogen and its response to ultraviolet radiation, photoelectron impact excitation and X-ray radiation and on the interpretation of the ultraviolet spectra of the Jupiter dayglow and auroras. A systematic effort was made to obtain reliable rate coefficients for rovibrational energy transfer of H2, particularly in collisions with hydrogen atoms. We carried out elaborate quantum-mechanical calculations of the scattering of H and H2 on what had been characterized as a reliable potential energy surface of the H3 molecular system. These calculations took into account reactive channels and rate coefficients for ortho-para transitions were obtained. Quantal calculations are too complex to be applied to all the possible rovibrational transitions and we turned to a semi-classical method. With it we calculated rate coefficients for transitions, reactive and non-reactive, for all the rovibrational levels. We carried out the calculations for three of the available H3 potential energy surfaces. We discovered an unexpected sensitivity of the rate coefficients for the non-reactive channels to the potential energy surface. This discovery stimulated more thorough investigations of the potential energy surface elsewhere and to the construction of a new surface. We have used it in further semi-classical calculations in work that will shortly be 2 completed and which, together with new quantum-mechanical calculations should comprise a set of reliable rate coefficients that can be used in discussions of H2 on the Jovian planets. We carried out a detailed study of the Jovian ultraviolet dayglow. There has been a long-running argument about the dayglow on Jupiter. There are two sources of excitation: fluorescence and photoelectron impact excitation. It had been argued that a third source "the electron glow" was needed to bring theory and observation into agreement. We believe we have shown conclusively that the third source is unnecessary. We have achieved a close quantitative agreement between the predicted spectrum arising from fluorescence and photoelectrons and the measured spectrum. We also demonstrated a method by which the presence of HD could be established observationary. Similar calculations were carried out of the ultraviolet spectra of the Jovian auroras. We again found close agreement. Indeed, the agreement was so detailed we were able to derive the temperature of the atmosphere. We found, contrary to the standard model of the time, a high temperature between 400 K and 600 K and established the presence of a significant temperature gradient. A large temperature gradient was indeed found by direct sampling with the Jupiter probe.

Dalgarno, A.↗
NASA NTRS1984

Spiral structure and star formation. II - Stellar lifetimes and cloud kinematics

The reliability studies using continuum gas dynamical calculations becomes questionable in connection with the apparent clumpiness of the Galaxy's interstellar medium (ISM). Roberts and Hausman (1984) have, therefore, presented a detailed model of a disk galaxy in which the ISM consists entirely of 'cloud particles', which orbit ballistically in the galaxy's gravitational field, collide inelastically with one another, and give birth to and subsequently interact with young star associations. The effects of changing the clouds's collisional mean free path have been examined, and the variations in the young star system's spiral morphology have been explored. The present investigation is concerned with a further study of this clumpy, cloudy ISM model, taking into account longer mean free path models likely to be appropriate for systems of molecular clouds. Attention is also given to the kinematics of clouds as they orbit under the influence of galactic gravity, collisions, and supernova remnants.

Hausman, M. A.↗
NASA NTRS1984

Atomic hydrogen maser measurements with wall surfaces of carbon tetrafluoride

The principal objectives of the Smithsonian Astrophysical Observatory cold maser research programs are given. This work is aimed principally at understanding more about the interaction of hydrogen atoms with wall coatings of fluorinated ethylene propylene (Dupont Teflon FEP-120 co-polymer) and of carbon tetrafluoride (CE4). The principal measured quantity in these experiments is the wall shift of the maser's output frequency. The wall shift per atomic collision was calculated from the measured wall frequency shift. This assumes that the wall surface area is smooth on a molecular scale.

Vessot, R. F. C.↗
NASA NTRS1984

Experimental techniques for cross-section measurements

Attention is given to electron collision phenomena which can be studied under single-collision conditions at low and intermediate electron impact energies, ranging from threshold to a few hundred eV, using gas phase molecular targets. Several of the experimental methods discussed were first developed and applied to atoms, but are equally applicable to molecules with minor modifications in the interpretation of the data, due to the greater complexity of molecular systems.

Trajmar, S.↗
NASA NTRS1990

Novel laser gain and time-resolved FTIR studies of photochemistry

Several techniques are discussed which can be used to explore laboratory photochemical processes and kinetics relevant to planetary atmospheres; these include time-resolved laser gain-versus-absorption spectroscopy and time-resolved Fourier transform infrared (FTIR) emission studies. The laser gain-versus-absorption method employed tunable diode and F-center lasers to determine the yields of excited photofragments and their kinetics. The time-resolved FTIR technique synchronizes the sweep of a commercial FTIR with a pulsed source of light to obtain emission spectra of novel transient species in the infrared. These methods are presently being employed to investigate molecular photodissociation, the yields of excited states of fragments, their subsequent reaction kinetics, Doppler velocity distributions, and velocity-changing collisions of translationally fast atoms. Such techniques may be employed in future investigations of planetary atmospheres, for example to study polycyclic aromatic hydrocarbons related to cometary emissions, to analyze acetylene decomposition products and reactions, and to determine spectral features in the near infrared and infrared wavelength regions for planetary molecules and clusters.

Leone, Stephen R.↗
NASA NTRS1990

Thermal structure of neutral winds from young stellar objects

The physical processes that control the thermal structure of lightly ionized winds from cool protostars are discussed. Attention is concentrated on the hydrogen gas, and the heating, cooling, and chemical processes that affect the neutral and ionic species of atomic and molecular hydrogen are examined. Warm silicate dust may condense out of the cooling wind and may heat the gas through collisions. Singly ionized sodium atoms, which do not recombine for the mass-loss rates considered, set a lower limit to the ionization fraction in the wind. Magnetic fields, which are presumed to accelerate the wind, couple directly to the ionic component of the gas and transfer momentum and energy to the neutral component through collisions. This process of ambipolar diffusion is found to be the dominant source of heat input to the gas.

Ruden, Steven P.↗
NASA NTRS1993

Momentum loss in proton-nucleus and nucleus-nucleus collisions

An optical model description, based on multiple scattering theory, of longitudinal momentum loss in proton-nucleus and nucleus-nucleus collisions is presented. The crucial role of the imaginary component of the nucleon-nucleon transition matrix in accounting for longitudinal momentum transfer is demonstrated. Results obtained with this model are compared with Intranuclear Cascade (INC) calculations, as well as with predictions from Vlasov-Uehling-Uhlenbeck (VUU) and quantum molecular dynamics (QMD) simulations. Comparisons are also made with experimental data where available. These indicate that the present model is adequate to account for longitudinal momentum transfer in both proton-nucleus and nucleus-nucleus collisions over a wide range of energies.

Khan, Ferdous↗