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At least 307 records · Page 17

Real-Time Deposition Monitor for Ultrathin Conductive Films

A device has been developed that can be used for the real-time monitoring of ultrathin (2 or more) conductive films. The device responds in less than two microseconds, and can be used to monitor film depositions up to about 60 thick. Actual thickness monitoring capability will vary based on properties of the film being deposited. This is a single-use device, which, due to the very low device cost, can be disposable. Conventional quartz/crystal microbalance devices have proven inadequate to monitor the thickness of Pd films during deposition of ultrathin films for hydrogen sensor devices. When the deposited film is less than 100 , the QCM measurements are inadequate to allow monitoring of the ultrathin films being developed. Thus, an improved, high-sensitivity, real-time deposition monitor was needed to continue Pd film deposition development. The new deposition monitor utilizes a surface acoustic wave (SAW) device in a differential delay-line configuration to produce both a reference response and a response for the portion of the device on which the film is being deposited. Both responses are monitored simultaneously during deposition. The reference response remains unchanged, while the attenuation of the sensing path (where the film is being deposited) varies as the film thickness increases. This device utilizes the fact that on high-coupling piezoelectric substrates, the attenuation of an SAW undergoes a transition from low to very high, and back to low as the conductivity of a film on the device surface goes from nonconductive to highly conductive. Thus, the sensing path response starts with a low insertion loss, and as a conductive film is deposited, the film conductivity increases, causing the device insertion loss to increase dramatically (by up to 80 dB or more), and then with continued film thickness increases (and the corresponding conductivity increases), the device insertion loss goes back down to the low level at which it started. This provides a continuous, real-time monitoring of film deposition. For use with different films, the device would need to be calibrated to provide an understanding of how film thickness is related to film conductivity, as the device is responding primarily to conductivity effects (and not to mass loading effects) in this ultrathin film regime.

Hines, Jacqueline↗

Advancements in the Representation of Cloud-Aerosol Microphysics in the GEOS-5 AGCM

Despite numerous challenges, the physical parameterization of cloud-aerosol interactions in atmospheric GCMs has become a top priority for advancement because of our need to simulate and understand past, current, and future indirect effects of aerosols on clouds. The challenges stem from the involvement of wide range of cloud-scale dynamics and aerosol activation physical processes. Cloud dynamics modulate cloud areal extent and condensate, while aerosol activation depends on aerosol mass load, size distribution, internal mixing state, and nucleating properties, and ultimately determines cloud optical properties via particle sizes. Both macro- and micro-scale processes are obviously important for cloud-radiation interactions. We will present the main features of cloud microphysical properties in the GEOS- 5 Atmospheric GCM (AGCM) as simulated by the McRAS-AC (Microphysics of Clouds with Relaxed Arakawa-Schubert and Aerosol-Cloud interaction) scheme. McRAS-AC uses Fountoukis and Nenes (2005) aerosol activation for liquid clouds, and has an option for either Liu and Penner (2005) or Barahona and Nenes (2008, 2009) aerosol activation for ice clouds. Aerosol loading (on-line or climatological) comes from GOCART, with an assumed log-normal size distribution. Other features of McRAS-AC are level-by-level cloud-scale thermodynamics, and Seifert-Beheng (2001)-type precipitation microphysics, particularly from moist convection. Results from Single-Column Model simulations will be shown to demonstrate how cloud radiative properties, lifetimes, and precipitation are influenced by different parameterization assumptions. Corresponding fields from year-long simulations of the full AGCM will also be presented with geographical distributions of cloud effective particle sizes compared to satellite retrievals. While the primary emphasis will be on current climate, simulation results with perturbed aerosol loadings will also be shown to expose the radiative sensitivity of the microphysical parameterization.

Lee, D.↗

Rotation Rate of Saturn's Magnetosphere using CAPS Plasma Measurements

We present the present status of an investigation of the rotation rate of Saturn 's magnetosphere using a 3D velocity moment technique being developed at Goddard which is similar to the 2D version used by Sittler et al. (2005) [1] for SOI and similar to that used by Thomsen et al. (2010). This technique allows one to nearly cover the full energy range of the CAPS IMS from 1 V less than or equal to E/Q less than 50 kV. Since our technique maps the observations into a local inertial frame, it does work during roll manoeuvres. We have made comparisons with Wilson et al. (2008) [2] (2005-358 and 2005-284) who performs a bi-Maxwellian fit to the ion singles data and our results are nearly identical. We will also make comparisons with results by Thomsen et al. (2010) [3]. Our analysis uses ion composition data to weight the non-compositional data, referred to as singles data, to separate H+, H2+ and water group ions (W+) from each other. The ion data set is especially valuable for measuring flow velocities for protons, which are more difficult to derive using singles data within the inner magnetosphere, where the signal is dominated by heavy ions (i.e., proton peak merges with W+ peak as low energy shoulder). Our technique uses a flux function, which is zero in the proper plasma flow frame, to estimate fluid parameter uncertainties. The comparisons investigate the experimental errors and potential for systematic errors in the analyses, including ours. The rolls provide the best data set when it comes to getting 4PI coverage of the plasma but are more susceptible to time aliasing effects. Since our analysis is a velocity moments technique it will work within the inner magnetosphere where pickup ions are important and velocity distributions are non-Maxwellian. So, we will present results inside Enceladus' L shell and determine if mass loading is important. In the future we plan to make comparisons with magnetic field observations, use Saturn ionosphere conductivities as presently known and the field aligned currents necessary for the planet to enforce corotation of the rotating plasma.

Sittler, E.↗

The Plasmaspheric Plume and Magnetopause Reconnection

We present near-simultaneous measurements from two THEMIS spacecraft at the dayside magnetopause with a 1.5 h separation in local time. One spacecraft observes a high-density plasmaspheric plume while the other does not. Both spacecraft observe signatures of magnetic reconnection, providing a test for the changes to reconnection in local time along the magnetopause as well as the impact of high densities on the reconnection process. When the plume is present and the magnetospheric density exceeds that in the magnetosheath, the reconnection jet velocity decreases, the density within the jet increases, and the location of the faster jet is primarily on field lines with magnetosheath orientation. Slower jet velocities indicate that reconnection is occurring less efficiently. In the localized region where the plume contacts the magnetopause, the high-density plume may impede the solar wind-magnetosphere coupling by mass loading the reconnection site.

plumes↗

Modeling and Evaluation of the Global Sea-Salt Aerosol Distribution: Sensitivity to Emission Schemes and Resolution Effects at Coastal/Orographic Sites

One of the major sources of uncertainty in model estimates of the global sea-salt aerosol distribution is the emission parameterization. We evaluate a new sea-salt aerosol life cycle module coupled to the online multi-scale chemical transport model NMMB/BSC-CTM. We compare 5 year global simulations using five state-of-the-art sea-salt open-ocean emission schemes with monthly averaged coarse aerosol optical depth (AOD) from selected AERONET sun photometers, surface concentration measurements from the University of Miami's Ocean Aerosol Network, and measurements from two NOAA/PMEL cruises (AEROINDOEX and ACE1). Model results are highly sensitive to the introduction of sea-surface-temperature (SST)-dependent emissions and to the accounting of spume particles production. Emission ranges from 3888 teragrams per year to 8114 teragrams per year, lifetime varies between 7.3 hours and 11.3 hours, and the average column mass load is between 5.0 teragrams and 7.2 teragrams. Coarse AOD is reproduced with an overall correlation of around 0.5 and with normalized biases ranging from +8.8 percent to +38.8 percent. Surface concentration is simulated with normalized biases ranging from minus 9.5 percent to plus 28 percent and the overall correlation is around 0.5. Our results indicate that SST-dependent emission schemes improve the overall model performance in reproducing surface concentrations. On the other hand, they lead to an overestimation of the coarse AOD at tropical latitudes, although it may be affected by uncertainties in the comparison due to the use of all-sky model AOD, the treatment of water uptake, deposition and optical properties in the model and/or an inaccurate size distribution at emission.

Bias↗

Stratospheric Benzene and Hydrocarbon Aerosols Detected in Saturn's Auroral Regions

Context. Saturn's polar upper atmosphere exhibits significant auroral activity; however, its impact on stratospheric chemistry (i.e. the production of benzene and heavier hydrocarbons) and thermal structure remains poorly documented. Aims. We aim to bring new constraints on the benzene distribution in Saturn's stratosphere, to characterize polar aerosols (their vertical distribution, composition, thermal infrared optical properties), and to quantify the aerosols' radiative impact on the thermal structure. Methods. Infrared spectra acquired by the Composite Infrared Spectrometer (CIRS) on board Cassini in limb viewing geometry are analysed to derive benzene column abundances and aerosol opacity profiles over the 3 to 0.1 mbar pressure range. The spectral dependency of the haze opacity is assessed in the ranges 680-900 and 1360-1440 cm(exp −1). Then, a radiative climate model is used to compute equilibrium temperature profiles, with and without haze, given the haze properties derived from CIRS measurements. Results. On Saturn's auroral region (80 deg S), benzene is found to be slightly enhanced compared to its equatorial and mid-latitude values. This contrasts with the Moses & Greathouse (2005, J. Geophys. Res., 110, 9007) photochemical model, which predicts a benzene abundance 50 times lower at 80◦S than at the equator. This advocates for the inclusion of ion-related reactions in Saturn's chemical models. The polar stratosphere is also enriched in aerosols, with spectral signatures consistent with vibration modes assigned to aromatic and aliphatic hydrocarbons, and presenting similarities with the signatures observed in Titan's stratosphere. The aerosol mass loading at 80 deg S is estimated to be 1−4 × 10(exp −5) g cm(exp −2), an order of magnitude less than on Jupiter, which is consistent with the order of magnitude weaker auroral power at Saturn.We estimate that this polar haze warms the middle stratosphere by 6 K in summer and cools the upper stratosphere by 5 K in winter. Hence, aerosols linked with auroral activity can partly account for the warm polar hood observed in Saturn's summer stratosphere.

satellites↗

Global Effects of Transmitted Shock Wave Propagation Through the Earth's Inner Magnetosphere: First Results from 3-D Hybrid Kinetic Modeling

We use a new hybrid kinetic model to simulate the response of ring current, outer radiation belt, and plasmaspheric particle populations to impulsive interplanetary shocks. Since particle distributions attending the interplanetary shock waves and in the ring current and radiation belts are non-Maxwellian, waveparticle interactions play a crucial role in energy transport within the inner magnetosphere. Finite gyroradius effects become important in mass loading the shock waves with the background plasma in the presence of higher energy ring current and radiation belt ions and electrons. Initial results show that shocks cause strong deformations in the global structure of the ring current, radiation belt, and plasmasphere. The ion velocity distribution functions at the shock front, in the ring current, and in the radiation belt help us determine energy transport through the Earth's inner magnetosphere.

Lipatov, A. S.↗

Structure and Variability of the Martian Ion Composition Boundary Layer

A complex boundary layer with a variety of charged particle and electromagnetic field signatures, including a transition between plasma predominantly of solar wind origin and plasma of planetary origin, lies between the Martian bow shock and the ionosphere. In this paper, we develop and utilize algorithms to autonomously identify and characterize this ion composition boundary (ICB), using data from the Mars Atmosphere and Volatile EvolutioN (MAVEN) mission. We find an asymmetric ICB with a larger average thickness, lower altitude, and lower velocity shear in the hemisphere where the solar wind motional electric field points outward, as a result of the asymmetry of the mass loading process. The ICB thickness scales with the magnetosheath proton gyroradius at the top of the boundary layer but does not clearly vary with external drivers. The ICB location varies with solar wind ram pressure and crustal magnetic field strength, but does not clearly respond to solar wind Mach number or extreme ultraviolet irradiance. The ICB represents a distinct boundary for ion density and flow speed, but the magnetic field strength and direction typically do not vary significantly across the ICB. The plasma density and flow speed at the ICB vary seasonally, likely in response to variations in the neutral exosphere and/or atmosphere. However, the ICB on average remains at or below the altitude where pressure balance is achieved between the piled up magnetic field (MPB) and the solar wind ram pressure, regardless of season or crustal magnetic field strength.

Electromagnetic↗

A Joint Analysis of GPS Displacement and GRACE Geopotential Data for Simultaneous Estimation of Geocenter Motion and Gravitational Field

Gravitational potential data from GRACE are being used to study mass redistribution within and between the atmosphere, hydrosphere, cryosphere, and solid Earth. The GRACE data are made available in a reference frame with its origin at the center of mass of the Earth system (geocenter) while many other geophysical models and data sets refer to a reference frame attached to the Earth's surface. Changes in the offset between these reference frames (geocenter motion) must be accounted for when GRACE data are used to quantify surface mass changes. In this study, we developed a technique for co‐estimation of geocenter motion and gravitational potential field seamlessly from degree 1 to 90 by simultaneously inverting a set of globally‐distributed GPS displacement time series and the temporally‐varying GRACE gravity data. We found that the effect of geocenter motion was evident particularly in the GPS time series of horizontal displacements. Our estimates of geocenter motion are most consistent with the Satellite Laser Ranging (SLR) results within 1 mm in X and Z components and a submillimeter in Y component, when compared to monthly variability averaged over the period of 2003–2016. The overall magnitude of the degree‐1 (l = 1) surface mass load is estimated to be ~3 cm in equivalent water height annually migrating south‐westward from Europe (December–January) to the South Pacific (June–July). Our results also show that dense GPS network data improve water storage recovery in major river basins in the United States and Europe by contributing significantly to the recovery of higher‐degree (l ≥ ~20) geopotential coefficients.

Razeghi, Mahdiyeh↗

Solvent-Free Preparation of High Energy, Binder-Free Electrodes Enabled by Dry Compressible Holey Graphene

Graphene is an atomically thick sheet consisting of a graphitic carbon network with excellent mechanical strength, electrical and thermal conductivity, and chemical stability. Holey graphene, a structural derivative of graphene, has an array of through-the-thickness holes across the lateral surface of the nanosheet. The presence of these holes has minimal detrimental effect on the graphene properties and leads to enhanced performance in applications such as electronics, sensors, and energy storage. For example, these holes allow more facile cross-plane ion and gas transport than intact graphene, making holey graphene an ideal electrode material for electrochemical energy storage. This presentation will focus on the ability of holey graphene to be compression molded into robust articles or architectures under solvent-free conditions without the need for potentially parasitic binders. The unique dry compressibility of holey graphene has enabled facile fabrication of high mass loading electrodes with both high density and high porosity, which have found use in supercapacitors and various high-energy battery systems such as lithium-oxygen, lithium-sulfur, and lithium-selenium batteries.

Yi Lin↗

Coupling a Particle Trajectory Capability to the US3D CFD Flow Solver

The purpose of the current research effort is to incorporate particle trajectory equations into the US3D CFD flow solver. The integrated code will allow higher-fidelity modeling of particle-fluid interactions and allow for the simulation of physical effects such as surface heating augmentation due to particle impacts. The key elements underpinning the current work are a robust tracking algorithm that can identify the encompassing mesh elements for individual particles and a point to point MPI frame-work. These developments combined with accurate property models and high-order time-stepping deliver realistic simulations on larger computational grids for a wide range of particle mass loadings. The coupled US3D-particle code will be applied to the Schiarparelli capsule and Earth-based experimental test cases.

A Sahai↗

Nonstationary Quasiperpendicular Shock and Ion Reflection at Mars

Collisionless shocks in space plasma are regions of heating and acceleration of charged particles and dissipation of kinetic energy. These accelerated particles are the source of electromagnetic emissions from supernova remnants and other astrophysical structures.At high Mach numbers, shocks can be inherently nonstationary and exhibit modulated energy transfer and recurring plasma compression areas in the form of reformation. We use data from the Mars Atmosphere and Volatile Evolution (MAVEN) spacecraft to study reformation of the Martian bow shock which has a relatively high curvature compared to that at Earth and the upstream solar wind is often mass loaded with a population of pickup ions. We show evidence of ion reflection effects in reformation of a supercritical quasi-perpendicular shock.

Hadi Madanian↗

A Priori Subgrid Analysis of Temporal Mixing Layers with Evaporating Droplets

Subgrid analysis of a transitional temporal mixing layer with evaporating droplets has been performed using three sets of results from a Direct Numerical Simulation (DNS) database, with Reynolds numbers (based on initial vorticity thickness) as large as 600 and with droplet mass loadings as large as 0.5.

subgrid↗

Variability of the Solar Wind Flow Asymmetry in the Martian Magnetosheath Observed by MAVEN

We perform the first statistical analysis of effects that different external conditions20have on a solar wind (SW) flow asymmetry observed in the Martian magnetosheath due to mass loading, making use of∼5 years of Mars Atmosphere and Volatile EvolutioN22(MAVEN) observations. We find the difference between the mean magnetosheath SW velocity component along the SW convective electric field direction in regions in the positive and negative hemispheres displays a strong linear correlation with the ratio between the upstream Interplanetary Magnetic Field (IMF) cross-flow component (By) and the SW proton density (nsw). The asymmetry is maximized (∼25 - 35 kms−1) for low nsw(∼1 cm−3) and large IMF By(∼2 nT). These results suggest the SW flow asymmetry variability is due to a force arising from the differential streaming between SW protons and oxygen ions, with boundary conditions partly defined by the pristine SW properties.

N Romanelli↗

Concerning the Interaction of A Transmitted Interplanetary Impulse With A Plasmaspheric Drainage Plume: First Results From 3-D Hybrid Kinetic Modeling

We present a new hybrid kinetic model to simulate the response of plasmaspheric drainage plumes to impulsive interplanetary pressure pulses. Since particle distributions attending the interplanetary pulses and in the drainage plume are non-Maxwellian, wave-particle interactions play a crucial role in energy transport within and outside the plumes. Finite gyroradius effects become important in mass loading of the transmitted impulse with the drainage plume ions. A forward-reverse shock structure develops from the initial step-like transmitted shock. First results show that the impulse causes strong deformations in the global structure of the plume. The anisotropic ion velocity distribution functions at the impulse front and inside the plume help us determine energy transport via wave-particle interactions throughout the Earth’s inner magnetosphere.

A S Lipatov↗

Impacts of Cold Ionospheric Ions in Magnetic Reconnection at the Earth’s Magnetopause and Magnetotail

The Earth’s magnetosphere is filled by particles from two sources: the solar wind and the ionosphere. Ionospheric ions are initially cold and contain He+ and O+, in addition to to H+. Depending on their initial magnetic latitude and local time, and the state of the magnetosphere, they may contribute to the plasmasphere, the plasma sheet, the ring current, the warm plasma cloak etc. Depending on which path they follow in the magnetosphere, some of these ionospheric ions remain cold when they reach the two key reconnection regions: the Earth’s magnetopause and the plasma sheet in the tail. In this presentation, we will first review previous statistical works that quantify the number of cold/ionospheric ions near these two regions. Several works have attempted to quantify these populations, but they are inherently difficult to characterize due to their low energy, often below the spacecraft potential. We will also discuss the impacts they have on the magnetic reconnection process. Ionospheric ions mass-load the regions where reconnection takes place and change the characteristic Alfven speed, resulting in a smaller reconnection electric field. They also take a portion of the energy that is imparted to particles, affecting the energy budget of magnetic reconnection. Finally, they introduce new length and time scales, associated to their gyroradius and gyroperiod. We will discuss what are the implications of these impacts for the evolution of the magnetosphere – solar wind interactions.

Sergio Toledo Redondo↗

Modeling Evolvable Water Recovery Systems for Short and Long-Duration Missions in Partial Gravity

Water recovery technologies on the International Space Station (ISS) are designed and optimized for microgravity environments, thus creating a need for innovative systems optimized for mission operations in the presence of gravity. Alternative water recovery technologies under research by the Life Support Systems division were compiled into a series of Partial Gravity Water Recovery System (PGWRS) architectures. Individual unit processes were modeled via fundamental physical-chemical process equations to simulate their method of treatment, including chemical or biological oxidation, flash evaporation, filtration, or a combination of adsorption and ion exchange processes. Dimension and sizing data were then utilized to scale each architecture. Modeling was completed on an assortment of architectures assuming three scenarios in which treatment methods could take advantage of partial gravity: a short-duration mission with a temporary surface habitat, a longer duration mission with a more permanent habitat, and a long duration mission without resupply. Total system mass was estimated to quantitatively compare architectures within scenarios, but qualitative observations were also made regarding system robustness, flexibility, and capacity to meet more stringent demands. Technologies that traded most favorably between the scenarios were those that included a pre-oxidation stage to minimize mass loading to downstream absorption and ion exchange beds, exploited gravity in liquid-vapor separation processes, and reconstituted wastewater components into recyclable material streams.

Avery Carlson↗

Modeling Evolvable Water Recovery Systems for Short and Long-Duration Missions in Partial Gravity

Water recovery technologies on the International Space Station (ISS) are designed and optimized for microgravity environments, thus creating a need for innovative systems optimized for mission operations in the presence of gravity. Alternative water recovery technologies under research by the Life Support Systems division were compiled into a series of Partial Gravity Water Recovery System (PGWRS) architectures. Individual unit processes were modeled via fundamental physical-chemical process equations to simulate their method of treatment, including chemical or biological oxidation, flash evaporation, filtration, or a combination of adsorption and ion exchange processes. Dimension and sizing data were then utilized to scale each architecture. Modeling was completed on an assortment of architectures assuming three scenarios in which treatment methods could take advantage of partial gravity: a short-duration mission with a temporary surface habitat, a longer duration mission with a more permanent habitat, and a long duration mission without resupply. Total system mass was estimated to quantitatively compare architectures within scenarios, but qualitative observations were also made regarding system robustness, flexibility, and capacity to meet more stringent demands. Technologies that traded most favorably between the scenarios were those that included a pre-oxidation stage to minimize mass loading to downstream absorption and ion exchange beds, exploited gravity in liquid-vapor separation processes, and reconstituted wastewater components into recyclable material streams.

Avery L. Carlson↗