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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 307 records · Page 17
All sourcesNASA NTRSDOE OSTI
DOE OSTI2024

Complete resolution across the neodymium/samarium isotopic envelope with a liquid sampling‐atmospheric pressure glow discharge — Orbitrap mass spectrometer

Rationale Nd and Sm isotope ratios play an important role in geological dating and as nuclear forensic signatures; however, the overlap of the respective 144, 148, 150 Nd/Sm isobars requires prior separations to be performed before analysis on typical MS platforms. The work presented here overcomes these isobaric interferences using ultrahigh‐mass resolution to alleviate interference without prior chemical separations. Methods A liquid sampling‐atmospheric pressure glow discharge ion source was coupled to a standard, QExactive Focus Orbitrap mass spectrometer, providing a mass resolution of ~80 k. A Spectroswiss FTMS booster X2 data acquisition package was used to collect extended transients, providing much higher mass resolution; ~230 k and ~600 k are employed here for Nd and Sm isotopes. Results While the standard Orbitrap resolution is far greater than typical “atomic” MS platforms, it was insufficient to alleviate all isobars. The use of a resolution of ~230 k resulted in baseline separation across the entire isotopic envelope for both Nd and Sm. Isotope ratios obtained from Nd:Sm mixtures using high‐resolution were equivalent to those found for individual‐element solutions, while isotope ratios obtained at a resolution of ~80 k (standard for the OEM data system) showed large deviations. Conclusions Use of ultrahigh‐resolution is an attractive alternative to extensive chemical separations to alleviate severe isobaric interferences. Sufficient mass resolution greatly reduces/eliminates the need for sample manipulations (separations) before analysis while reducing costs and total analysis times.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1972

Lunar orbital mass spectrometer experiment.

One of the Orbital Science experiments on Apollo 15 was a mass spectrometer designed to measure the composition and distribution of the lunar atmosphere. It operated for nearly 90 hours, producing spectra of an unexpectedly complex nature, indicating that many complex gas molecules exist in the vicinity of the spacecraft. The most plausible explanation is that there was continual vaporization of frozen or liquid drops of water, fuel, or other matter that had been ejected from the spacecraft with small relative velocity so that these particles remained in nearby orbits. The search for naturally occurring gases in these spectra involves a statistical analysis of the data which has not been completed to date. A theoretical prediction regarding the possibilities of detecting lunar volcanism from orbit is included.

Hoffman, J. H.↗
NASA NTRS1978

A technique for mass spectrometer measurements of atomic and molecular oxygen in the lower thermosphere

A neutral mass spectrometer with a quasi-open ion source was flown on each of the Atmosphere Explorer (AE) C, D, and E satellites. The three instruments provided an opportunity to study the effects of different source insert materials on the source surface chemistry. It was found that, after a period of conditioning in space, the recombination coefficient of atomic oxygen on gold appears to be substantially lower than it is on Nichrome V. The lower recombination coefficient on gold allows the spectrometer to directly measure a significant fraction of the incident atomic oxygen, making it possible to distinguish between ambient O and O2. Equations are developed to calculate the atomic and molecular oxygen densities. Preliminary measurements of molecular oxygen densities obtained by this technique agree well with measurements taken in the fly-through mode of operation.

Kayser, D. C.↗
NASA NTRS1993

Neutral composition measurements by the Pioneer Venus Neutral Mass Spectrometer during orbiter re-entry

Measurements by the Pioneer Venus Orbiter Neutral Mass Spectrometer (ONMS) instrument during Orbiter re-entry have been made from 18-24 hours local solar time, above 170 km, of He, and from midnight to 4.5 hours below 200 km of He, N, O, CO, N2, and CO2. Preliminary results indicate that in the post-midnight sector He is the dominant species above 170 km, O the dominant species from 140-170 km and CO2 the dominant species below 140 km. Estimated scale height temperatures for He, O, and CO2 of about 105-120 K are similar to those observed in 1978-1980 at higher solar activity. The densities at 1 am local solar time and at 150 km are within 35% of those measured earlier. The He bulge is also similar to that observed in 1978-1980 confirming that thermosphere superrotation is still present. Comparison with the results of a Venus Thermosphere General Circulation Model suggests the nightside is not sensitive to changes in solar activity due to the isolation of the day and night thermospheres. apparently, the relatively small changes in the dayside thermosphere with solar activity have little impact on the nightside thermosphere.

Kasprzak, W. T.↗
NASA NTRS1993

Neutral Composition Measurements by the Pioneer Venus Neutral Mass Spectrometer During Orbiter Re-Entry

Measurements by the Pioneer Venus Orbiter Neutral Mass Spectrometer (ONMS) instrument during Orbiter re-entry have been made from 18-24 hours local solar time, above 170 km, of He, and from midnight to 4.5 hours below 200 km of He, N, O, CO, N2, and CO2. Preliminary results indicate that in the post-midnight sector He is the dominant species above 170 km, O the dominant species from 140-170 km and CO2 the dominant species below 140 km. Estimated scale height temperatures for He, O and CO2 of about 105-120 K are similar to those observed in 1978-80 at higher solar activity. The densities at 1 am local solar time and at 150 km are within 35% of those measured earlier. The He bulge is also similar to that observed in 1978-80 confirming that thermosphere superrotation is still present. Comparison with the results of a Venus Thermosphere General Circulation Model suggests the nightside is not sensitive to changes in solar activity due to the isolation of the day and night thermospheres. Apparently, the relatively small changes in the dayside thermosphere with solar activity have little impact on the nightside thermosphere.

Kasprzak, W. T.↗
NASA NTRS1976

Electro-optical detector for use in a wide mass range mass spectrometer

An electro-optical detector is disclosed for use in a wide mass range mass spectrometer (MS), in the latter the focal plane is at or very near the exit end of the magnetic analyzer, so that a strong magnetic field of the order of 1000G or more is present at the focal plane location. The novel detector includes a microchannel electron multiplier array (MCA) which is positioned at the focal plane to convert ion beams which are focused by the MS at the focal plane into corresponding electron beams which are then accelerated to form visual images on a conductive phosphored surface. These visual images are then converted into images on the target of a vidicon camera or the like for electronic processing. Due to the strong magnetic field at the focal plane, in one embodiment of the invention, the MCA with front and back parallel ends is placed so that its front end forms an angle of not less than several degrees, preferably on the order of 10.degree.-20.degree., with respect to the focal plane, with the center line of the front end preferably located in the focal plane. In another embodiment the MCA is wedge-shaped, with its back end at an angle of about 10.degree.-20.degree. with respect to the front end. In this embodiment the MCA is placed so that its front end is located at the focal plane.

Giffin, Charles E.↗
NASA NTRS1980

Bennett ion mass spectrometers on the Pioneer Venus Bus and Orbiter

Identical Bennett radio-frequency ion mass spectrometer instruments on the Pioneer Venus Bus and Orbiter have provided the first in-situ measurements of the detailed composition of the planet's ionosphere. The sensitivity, resolution, and dynamic range are sufficient to provide measurements of the solar-wind-induced bow-shock, the ionopause, and highly structured distributions of up to 16 thermal ion species within the ionosphere. The use of adaptive scan and detection circuits and servo-controlled logic for ion mass and energy analysis permits detection of ion concentrations as low as 5 ions/cu cm and ion flow velocities as large as 9 km/sec for O(+). A variety of commandable modes provides ion sampling rates ranging from 0.1 to 1.6 sec between measurements of a single constituent. A lightweight sensor and electronics housing are features of a compact instrument package.

Taylor, H. A., Jr.↗
NASA NTRS2014

The Neutral Gas and Ion Mass Spectrometer on the Mars Atmosphere and Volatile Evolution Mission

The Neutral Gas and Ion Mass Spectrometer (NGIMS) of the Mars Atmosphere and Volatile Evolution Mission (MAVEN) is designed to measure the composition, structure, and variability of the upper atmosphere of Mars. The NGIMS complements two other instrument packages on the MAVEN spacecraft designed to characterize the neutral upper atmosphere and ionosphere of Mars and the solar wind input to this region of the atmosphere. The combined measurement set is designed to quantify atmosphere escape rates and provide input to models of the evolution of the martian atmosphere. The NGIMS is designed to measure both surface reactive and inert neutral species and ambient ions along the spacecraft track over the 125-500 km altitude region utilizing a dual ion source and a quadrupole analyzer.

Gas↗
NASA NTRS1974

Fast scan control for deflection type mass spectrometers

A high speed scan device is reported that allows most any scanning sector mass spectrometer to measure preselected gases at a very high sampling rate. The device generates a rapidly changing staircase output which is applied to the accelerator of the spectrometer and it also generates defocusing pulses that are applied to one of the deflecting plates of the spectrometer which when shorted to ground deflects the ion beam away from the collector. A defocusing pulse occurs each time there is a change in the staircase output.

Yeager, P. R.↗
NASA NTRS1986

Quadrupole mass spectrometer for Space Shuttle applications - Flight capabilities and ground calibration

The AFGL Quadrupole Ion/Neutral Mass Spectrometer (QINMS), its flight capabilities, and a few examples of QINMS data from the STS-4 flight are discussed in addition to the beam facility and calibration procedures used at the Los Alamos National Laboratory facility. A 5-eV atomic oxygen beam is produced using a continuous optical discharge technique, and the resulting pumped beam has sufficient high flux and velocity to simulate orbital conditions. The calibrated instrument will be used in the NASA Johnson Space Center Evaluation of Oxygen Interactions with Materials experiment to measure the density of ambient oxygen and to identify the products of oxygen-surface reactions.

Hunton, D. E.↗
NASA NTRS2002

Evaluation of Small Mass Spectrometer Systems

This work is aimed at understanding the aspects of designing a miniature mass spectrometer (MS) system. A multitude of commercial and government sectors, such as the military, environmental agencies and industrial manufacturers of semiconductors, refrigerants, and petroleum products, would find a small, portable, rugged and reliable MS system beneficial. Several types of small MS systems are evaluated and discussed, including linear quadrupole, quadrupole ion trap, time of flight and sector. The performance of each system in terms of accuracy, precision, limits of detection, response time, recovery time, scan rate, volume and weight is assessed. A performance scale is setup to rank each systems and an overall performance score is given to each system. All experiments involved the analysis of hydrogen, helium, oxygen and argon in a nitrogen background with the concentrations of the components of interest ranging from 0-5000 part-per-million (ppm). The relative accuracies of the systems vary from < 1% to approx. 40% with an average below 10%. Relative precisions varied from 1% to 20%, with an average below 5%. The detection limits had a large distribution, ranging from 0.2 to 170 ppm. The systems had a diverse response time ranging from 4 s to 210 s as did the recovery time with a 6 s to 210 s distribution. Most instruments had scan times near, 1 s, however one instrument exceeded 13 s. System weights varied from 9 to 52 kg and sizes from 15 x 10(exp 3)cu cm to 110 x 10(exp 3) cu cm.

Arkin, C. Richard↗