Search NASA⌕ Search

SEARCH · Search NASA

Results for “Modulational instability”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 307 records · Page 17
All sourcesNASA NTRSDOE OSTI
NASA NTRS2001

Microgravity Combustion Science and Fluid Physics Experiments and Facilities for the ISS

At the NASA Glenn Research Center, the Microgravity Science Program supports both ground-based and flight experiment research in the disciplines of Combustion Science and Fluid Physics. Combustion Science research includes the areas of gas jet diffusion flames, laminar flames, burning of droplets and misting fuels, solids and materials flammability, fire and fire suppressants, turbulent combustion, reaction kinetics, materials synthesis, and other combustion systems. The Fluid Physics discipline includes the areas of complex fluids (colloids, gels, foams, magneto-rheological fluids, non-Newtonian fluids, suspensions, granular materials), dynamics and instabilities (bubble and drop dynamics, magneto/electrohydrodynamics, electrochemical transport, geophysical flows), interfacial phenomena (wetting, capillarity, contact line hydrodynamics), and multiphase flows and phase changes (boiling and condensation, heat transfer, flow instabilities). A specialized International Space Station (ISS) facility that provides sophisticated research capabilities for these disciplines is the Fluids and Combustion Facility (FCF). The FCF consists of the Combustion Integrated Rack (CIR), the Fluids Integrated Rack (FIR) and the Shared Accommodations Rack and is designed to accomplish a large number of science investigations over the life of the ISS. The modular, multiuser facility is designed to optimize the science return within the available resources of on-orbit power, uplink/downlink capacity, crew time, upmass/downmass, volume, etc. A suite of diagnostics capabilities, with emphasis on optical techniques, will be provided to complement the capabilities of the subsystem multiuser or principal investigator-specific experiment modules. The paper will discuss the systems concept, technical capabilities, functionality, and the initial science investigations in each discipline.

Lauver, Richard W.↗
NASA NTRS1986

Observations of the Earth's magnetic field from the shuttle: Using the Spartan carrier as a magnetic survey tool

The shuttle-deployed and recovered Spartan shows promise as an inexpensive and simple support module for potential field measurements. The results of a preliminary engineering study on the applications of the Spartan carrier to magnetic measurements shows: (1) Extension of the mission duration to as long as 7 days is feasible but requires more reconfiguration of the internal systems; (2) On-board recording of Global Positioning System signals will provide position determination with an accuracy consistent with the most severe requirements; and (3) Making Spartan a magnetically clean spacecraft is straight forward but requires labor-intensive modifications to both the data and power systems. As a magnetic survey tool, Spartan would allow surveys at regularly spaced intervals and could make quick-reaction surveys at times of instability in the secular variation.

Webster, W. J., Jr.↗
NASA NTRS2006

Modeling the Observed QBO and Inter-Annual Variations of the Diurnal Tide in the Mesosphere

In the current version of the Numerical Spectral Model (NSM), the Quasi-biennial Oscillation (QBO) is generated primarily by small-scale gravity waves (GW) from Hines' Doppler Spread Parameterization (DSP). The model does not have topography, and the planetary waves are solely generated by instabilities. We discuss a 3D modeling study that describes the QBO extending from the stratosphere into the upper mesosphere, where the oscillation produces significant inter-annual variations in the diurnal tide. The numerical results are compared with temperature measurements from the SABER (TIMED) and MLS (UARS) instruments obtained by Huang et al. (2006). With a GW source that peaks at the Equator and is taken to be isotropic and independent of season, the NSM generates a QBO with variable periods around 26 months and zonal wind amplitudes of almost 25 m/s at 30 km. As reported earlier, the NSM reproduces the observed equinoctial maxima in the diurnal tide at altitudes around 95 km. The modeled QBO modulates the tide such that the seasonal amplitude maxima can vary from one year to another by as much as 30%. To shed light on the underlying mechanisms, the relative importance of the advection terms are discussed, and they are shown to be important in the stratosphere. At altitudes above 80 km, however, the QBO-related inter-annual variations of the tide are generated primarily by GW momentum deposition. In qualitative agreement with the SABER measurements, the model generates distinct zonal-mean QBO temperature variations in the stratosphere and mesosphere. In the stratosphere, the computed amplitudes are not much smaller than those observed, and the rate of downward propagation at the Equator is reproduced. The modeled temperature amplitudes in the mesosphere, however, are much smaller than those observed. The observed and computed temperature variations of the QBO peak at the Equator but extend with phase reversals to high latitudes, in contrast to the zonal winds that are confined to equatorial latitudes. Hemispherical asymmetries also appear in both the model results and the observations. The temperature amplitudes outside the equatorial region however tend to occur at lower latitudes in the model results. While there is qualitative agreement between the TIMED measurements and the model prediction, there are some areas of significant disagreement that require us to reexamine the present version of the NSM. The numerical results critically depend on the chosen parameters that determine the wave forcing, and there are a number of avenues to improve the performance of the model that had not been tuned to fit the observations. The GW spectrum and its latitude dependence in the troposphere are not well known, and numerical experiments are discussed that describe the related model response. While it appears that eastward propagating Kelvin waves and westward propagating Rossby gravity waves are not the primary source to generate the QBO, the GW forcing can seed the oscillation and act as a catalyst to enhance effectiveness of these planetary waves.

Mayr, Hans G.↗
NASA NTRS1994

Dynamics of the magnetic shearing instability and magnetohydrodynamic turbulence in accretion disks. 1: Vertical magnetic field

Recently, the magnetic shearing instability (MSI) has been proposed as a dynamical mechanism for angular momentum transport in accretion disks (Balbus & Hawley 1991; Hawley & Balbus 1991). In this paper, the nonlinear dynamics of MSI modes in the presence of a vertical magnetic field B(sub 0) is discussed. In particular, the saturation levels of the fluctuating fields, the angular momentum flux, and the energy dissipation mechanism, are examined in detail. It is shown that MSI induces strong magnetohydrodynamic (MHD) turbulence in a range of wavenumbers 1/H is less than K is less than or equal to Omega/V(sub A)(sub 0)), where H is the thickness, Omega is the rotation frequency of the disk, and V(sub A)(sub 0) is the Alfven velocity. Despite the fact that the linear growth rate of MSI is maximal at small-scale (i.e., k is approximately Omega/V(sub A(sub 0)), angular momentum transport due to MSI turbulence is dominated by the magnetic Reynolds stress driven by large-scale modes (k is approximately 1/H). It is shown that the amplitude of low k(sub r) MSI eddies is limited primarily by subscale shear flow instability. Thus, dominant MSI cells are quasi-isotropic. In a stationary state, the effective Shakura-Sunyaev 'alpha' value is predicted to be of order V(sub A)(sub 0)0/C(sub s). In addition, the veritcal magnetic-field-induced MSI cells convert vertical magnetic field B(sub 0) into azimuthal magnetic field B(sub theta) in the disk. The generation of azimuthal magnetic field in turn introduces new physical processes, such as dynamo activity and azimuthal MSI turbulence. We conclude that it is not possible to decouple vertical MSI saturation from azimuthal MSI evolution. Low-frequency MSI cells are shown to co-exist with high-frequency radial buoyancy or internal waves. We show that modulational interaction between waves on these two frequency ranges is usually weak in the case when mean magnetic field is vertical. Thus, MSI and internal wave dynamics must be treated on an equal footing.

Zhang, W.↗
NASA NTRS1986

Dwarf nova burst asymmetry and the physics of accretion disks

Far-ultraviolet observations of a burst of SS Cyg obtained with the Voyager spacecraft are presented along with optical observations. Representative V band and far-UV light curves are computed based on a thermal instability model, and the dependence of the far-UV delay and the shape of the outburst on the location in the disk where the outburst starts is examined. The results show that burst initiated at large radii produce asymmetric light curves for which the far-UV flux lags the optical flux by about half a day, as observed. For bursts starting at smaller radii, the delay is smaller and the outburst is more rounded and symmetric. For both burst types, the delay with respect to the optical is longer for larger accretion disks and at shorter wavelengths. The physical processes that will promote burst initiation in the outer disk are discussed, emphasizing that this can occur in principle with no modulation of the mass transfer rate from the companion.

Cannizzo, J. K.↗
DOE OSTI2025

Quasi-optical beam tracing module development for millimeter-wave high-wavenumber collective scattering on the NSTX-U and EAST tokamaks

A Python3-based beam tracing code utilizing Quasi-Optics has been developed to track both incident and receiving beams in high-k collective millimeter wave scattering systems within magnetic fusion plasmas. In contrast to existing ray tracing codes that solely consider refraction, this beam tracing code incorporates diffraction phenomena, providing a more comprehensive calculation. Here, this enhanced capability allows for a more accurate calculation of the scattering volume and spatial resolution in high-k collective scattering systems, crucial for evaluating system performance and facilitating data analysis. Unlike Geometrical Optics, Quasi-Optics employs the complex eikonal method, representing a Gaussian beam as a collection of coupled rays to accurately preserve diffraction characteristics. The developed code is intended for application in NSTX-Upgrade and EAST high-k beam tracing analyses, targeting frequencies of 693 GHz and 270 GHz, respectively. The high-k system's primary objective is the observation of electron-scale instabilities. Employing a symplectic integrator, the code ensures numerical accuracy, assessed through the conservation of the Hamiltonian. With its precision and efficiency, the code facilitates rapid inter-shot analyses.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
NASA NTRS2011

Early Oscillation Detection Technique for Hybrid DC/DC Converters

Oscillation or instability is a situation that must be avoided for reliable hybrid DC/DC converters. A real-time electronics measurement technique was developed to detect catastrophic oscillations at early stages for hybrid DC/DC converters. It is capable of identifying low-level oscillation and determining the degree of the oscillation at a unique frequency for every individual model of the converters without disturbing their normal operations. This technique is specially developed for space-used hybrid DC/DC converters, but it is also suitable for most of commercial and military switching-mode power supplies. This is a weak-electronic-signal detection technique to detect hybrid DC/DC converter oscillation presented as a specific noise signal at power input pins. It is based on principles of feedback control loop oscillation and RF signal modulations, and is realized by using signal power spectral analysis. On the power spectrum, a channel power amplitude at characteristic frequency (CPcf) and a channel power amplitude at switching frequency (CPsw) are chosen as oscillation level indicators. If the converter is stable, the CPcf is a very small pulse and the CPsw is a larger, clear, single pulse. At early stage of oscillation, the CPcf increases to a certain level and the CPsw shows a small pair of sideband pulses around it. If the converter oscillates, the CPcf reaches to a higher level and the CPsw shows more high-level sideband pulses. A comprehensive stability index (CSI) is adopted as a quantitative measure to accurately assign a degree of stability to a specific DC/DC converter. The CSI is a ratio of normal and abnormal power spectral density, and can be calculated using specified and measured CPcf and CPsw data. The novel and unique feature of this technique is the use of power channel amplitudes at characteristic frequency and switching frequency to evaluate stability and identify oscillations at an early stage without interfering with a DC/DC converter s normal operation. This technique eliminates the probing problem of a gain/phase margin method by connecting the power input to a spectral analyzer. Therefore, it is able to evaluate stability for all kinds of hybrid DC/DC converters with or without remote sense pins, and is suitable for real-time and in-circuit testing. This frequency-domain technique is more sensitive to detect oscillation at early stage than the time-domain method using an oscilloscope.

Wang, Bright L.↗
NASA NTRS1993

Optical beam forming techniques for phased array antennas

Conventional phased array antennas using waveguide or coax for signal distribution are impractical for large scale implementation on satellites or spacecraft because they exhibit prohibitively large system size, heavy weight, high attenuation loss, limited bandwidth, sensitivity to electromagnetic interference (EMI) temperature drifts and phase instability. However, optical beam forming systems are smaller, lighter, and more flexible. Three optical beam forming techniques are identified as applicable to large spaceborne phased array antennas. They are (1) the optical fiber replacement of conventional RF phased array distribution and control components, (2) spatial beam forming, and (3) optical beam splitting with integrated quasi-optical components. The optical fiber replacement and the spatial beam forming approaches were pursued by many organizations. Two new optical beam forming architectures are presented. Both architectures involve monolithic integration of the antenna radiating elements with quasi-optical grid detector arrays. The advantages of the grid detector array in the optical process are the higher power handling capability and the dynamic range. One architecture involves a modified version of the original spatial beam forming approach. The basic difference is the spatial light modulator (SLM) device for controlling the aperture field distribution. The original liquid crystal light valve SLM is replaced by an optical shuffling SLM, which was demonstrated for the 'smart pixel' technology. The advantages are the capability of generating the agile beams of a phased array antenna and to provide simultaneous transmit and receive functions. The second architecture considered is the optical beam splitting approach. This architecture involves an alternative amplitude control for each antenna element with an optical beam power divider comprised of mirrors and beam splitters. It also implements the quasi-optical grid phase shifter for phase control and grid amplifier for RF power. The advantages are no SLM is required for this approach, and the complete antenna system is capable of full monolithic integration.

Wu, Te-Kao↗
NASA NTRS1995

Observations in the vicinity of substorm onset: Implications for the substrom process

Multi-instrument data sets from the ground and satellites at both low and high altitude have provided new results concerning substorm onset and its source region in the magnetosphere. Twenty-six out of 37 substorm onset events showed evidence of azimuthally spaced auroral forms (AAFs) prior to the explosive poleward motion associated with optical substorm onset. AAFs can span 8 hours of local time prior to onset and generally propagate eastward in the morning sector. Onset itself is, however, more localized spanning only about 1 hour local time. AAF onset occur during time periods when the solar wind pressure is relatively high. AAFs brighten in conjunction with substorm onset leading to the conclusion that they are a growth phase activity casually related to substorm onset. Precursor activity associated with these AAFs is also seen near geosynchronous orbit altitude and examples show the relationship between the various instrumental definitions of substorm onset. The implied mode number (30 to 135) derived from this work is inconsistent with cavity mode resonances but is consistent with a modified flute/ballooning instability which requires azimuthal pressure gradients. The extended source region and the distance to the open-closed field line region constrain reconnection theory and local mechanisms for substorm onset. It is demonstrated that multiple onset substorms can exist for which localized dipolarizations and the Pi 2 occur simultaneously with tail stretching existing elsewhere. These pseudobreakups can be initiated by auroral streamers which originate at the most poleward set of arc systems and drift to the more equatorward main UV oval. Observations are presented of these AAFs in conjunction with low- and high-altitutde particle and magnetic field data. These place the activations at the interface between dipolar and taillike field lines probably near the peak in the cross-tail current. These onsets are put in the context of a new scenario for substorm morphology which employs individual modules which operate independently or couple together. This allows particular substorm events to be more accurately described and investigated.

Elphinstone, R. D.↗
NASA NTRS1999

Constitutive and Stability Behavior of Granular Materials Under Very Low Effective Stresses

The study of the behavior of granular materials such as sand is of great importance to the understanding of the response of foundations resting on surface and near-surface soil deposits. A clear understanding of the behavior of such materials can also provide insights into other related issues where low effective stresses are encountered such as liquefaction. The main sources of the constitutive and stability properties of cohesionless granular materials is interparticle friction, which in turn under low confinement stress levels is strongly affected by gravitational body forces under terrestrial (1 gravity) conditions. Under moderate-to-high stress levels, the influence of gravity on the behavior of experiments may not be pronounced and therefore the test results in a terrestrial environment may be acceptable for engineering purposes. However, the conduct of experiments on granular materials under very low stress levels and under quasi-static conditions can only be performed in a microgravity environment. A series of displacement-controlled cyclic triaxial compression experiments were performed in a SPACEHAB module on the Space Shuttle during the STS-79 mission to Mir in September, 1996, and the STS-89 mission in January, 1998. The experiments were conducted on six right cylindrical specimens 75 mm in diameter and 150 mm long at effective confining pressures of 0.05, 0.52 and 1.30 kPa. The results show very high peak strength friction angles in the range of 47.6 to 70.0 degrees, which are mainly due to overconsolidation and grain interlocking effects. It was observed that the residual strength levels were in the same range as that observed at higher confining stress levels. The dilatancy angles were unusually high in the range of 30 to 31 degrees. All specimens display substantial initial stiffnesses and elastic moduli during unloading and reloading events, which are nearly an order of magnitude higher than conventional theories predict. A periodic instability phenomenon which appears to result from buckling of multiple internal arches and columnar systems, augmented by stick-slips was observed in the experiments. Computed Tomography (CT) measurements revealed valuable data about the internal fabric and the specimens deformation patterns. Uniform diffuse bifurcation with multiple radial shear bands was observed in the specimens tested in a microgravity environment. In the axial direction, two major conical surfaces were developed. Spatial nonsymmetrical deformations were observed in specimens tested in terrestrial laboratory.

Alshibli, Khalid A.↗
DOE OSTI2024

Integration and validation of some modules for modelling of high-speed chemically reactive flows in two-phase gas-droplet mixtures

Three modules are integrated into the built-in OpenFOAM rhoCentralFoam solver towards accurate and efficient modelling of high-speed chemically reactive flows in two-phase gas-droplet mixtures within the OpenFOAM 10.0 framework. The first module is the mixture-averaged diffusion model. The second module is the built-in OpenFOAM Lagrangian solver coupled with optimised droplet drag coefficient and convective heat transfer coefficient sub-models. The last module is a sparse stiff chemistry solver based on dynamic adaptive hybrid integration (AHI-S). The optimised droplet sub-models are first verified in correct implementation for subsequent simulations in this work. Further, they show good accuracy against experimental and analytical data in the modelling of ammonia droplet acceleration and cooling in the flowing and/or low-temperature air. The accuracy and efficiency gains related to the mixture-averaged diffusion model and the AHI-S chemistry solver are examined by simulating 1-D detonation propagation in ammonia droplet-free/laden ammoniaoxygen mixtures. Numerical results of detonation propagation speed, gaseous temperature, density, and species distributions around the induction zone show good agreement with experimental data and analytical solutions. Compared to the built-in OpenFOAM diffusion model, the mixture-averaged diffusion model provides different numerical predictions of pulsating instabilities in detonation propagation. It shows better accuracy in depicting the detonation structure within the droplet-free section attributed to improved multi-component diffusion modelling. Compared to the built-in OpenFOAM solver EulerImplicit (backward Euler), the AHI-S chemistry solver reduces the computational cost by around 50%. It achieves satisfactory accuracy in calculating detonation propagation speed within the droplet-free section with the optimal efficiency when the safety factor, β, equals 0.5.

42 ENGINEERING↗
NASA NTRS2019

Extratropical Large-Scale Traveling Weather Systems in the Southern Hemisphere on Mars

From late-autumn through early-spring, the middle- and high-latitudes of both hemispheres of Mars and its predominantly carbon-dioxide atmosphere support mean equator-to-pole thermal contrasts, and then, support a strong mean westerly polar vortex. Observations from orbiting spacecraft indicate that this intense mean baroclinicity-barotropicity supports large-scale eastward traveling weather systems (i.e., transient, traveling synoptic-period waves, on the order of the Rossby deformation scale). On Earth, extratropical weather disturbances arise from wind-shear instabilities, and these are critical components of the terrestrial global circulation. So it is the case for Mars. Large-scale traveling weather systems on Mars serve as agents in the transport of heat, momentum and scalar and tracer quantities (e.g., atmospheric dust, watervapor, ice clouds, chemical species, etc). Such weather systems interact with other large-scale atmospheric circulation components, namely, quasi-stationary (i.e., forced Rossby) modes; global thermal tidal modes; and then, upon large-/continental- geographical scales, upslope/ down-slope flows amongst high relief, low relief, impact basins, and volcanic rises, and more. The character of Mars' traveling extratropical weather disturbances in its southern hemisphere during late winter through early spring is investigated using a high-resolution Mars global climate model (i.e., Mars GCM), and one from the Agency's Mars Climate Modeling Center (MCMC) based at the NASA Ames Research Center. The climate model includes several complex atmospheric physical packages. With such physics modules, our global climate simulations present comparatively well with observations of the planet's current water cycle (Haberle et al.,2019). The climate model is "forced" with an annual dust cycle (i.e., nudged based on MGS/TES observations). Compared to the northern-hemisphere counterparts, the southern synoptic-period weather disturbances and accompanying frontal waves have smaller meridional and zonal scales, and are less intense. Influences of the zonally asymmetric (i.e., east-west varying) topography on southern large-scale weather are investigated, in addition to large-scale up-slope/down-slope flows and the diurnal cycle. A southern storm zone in late winter and early spring presents in the western hemisphere via orographic influences from the Tharsis highlands, and the Argyre and Hellas impact basins. Geographically localized transient-wave activity diagnostics are constructed that illuminate dynamical differences amongst the simulations and these are presented.

Hollingsworth, Jeffery L.↗
NASA NTRS2020

Mechanisms of Stationary Crossflow Instability Growth and Breakdown Induced by Forward-Facing Steps

An experimental study is performed to determine the mechanisms by which a forward-facing step impacts the growth and breakdown to turbulence of the stationary cross-flow instability. Particle image velocimetry measurements are obtained in the boundary layer of a 30◦swept flat plate with a pressure body. Step heights range from 53 % to 71 % of the boundary-layer thickness. The critical step height is approximately 60 % of the boundary-layer thickness for the current study, although it is also shown that the critical step height depends on the initial amplitude of the stationary cross-flow vortices. For the critical cases, the stationary cross-flow amplitude grows sharply downstream of the step, decays for a short region and then grows again. The initial growth region is linear, and can be explained primarily through the impact of the step on the mean flow. Namely, the step causes abrupt changes to the mean flow, resulting in large values of wall-normal shear, as well as highly inflectional profiles, due to either cross-flow reversal, separation or both. These inflectional profiles are highly unstable for the stationary cross-flow. Additionally,the reversed flow regions are significantly modulated by the stationary cross-flow vortices. The second region of growth occurs due to the stationary-cross-flow-induced modulation of the shear layer, which leads to multiple smaller wavelength stream wise vortices. High-frequency fluctuations indicate that the unsteady transition mechanism for the critical cases relates to the shedding of vortices downstream of reattachment of the modulated separated regions.

boundary layer stability↗
NASA NTRS1994

Testing the gravitational instability hypothesis?

We challenge a widely accepted assumption of observational cosmology: that successful reconstruction of observed galaxy density fields from measured galaxy velocity fields (or vice versa), using the methods of gravitational instability theory, implies that the observed large-scale structures and large-scale flows were produced by the action of gravity. This assumption is false, in that there exist nongravitational theories that pass the reconstruction tests and gravitational theories with certain forms of biased galaxy formation that fail them. Gravitational instability theory predicts specific correlations between large-scale velocity and mass density fields, but the same correlations arise in any model where (a) structures in the galaxy distribution grow from homogeneous initial conditions in a way that satisfies the continuity equation, and (b) the present-day velocity field is irrotational and proportional to the time-averaged velocity field. We demonstrate these assertions using analytical arguments and N-body simulations. If large-scale structure is formed by gravitational instability, then the ratio of the galaxy density contrast to the divergence of the velocity field yields an estimate of the density parameter Omega (or, more generally, an estimate of beta identically equal to Omega(exp 0.6)/b, where b is an assumed constant of proportionality between galaxy and mass density fluctuations. In nongravitational scenarios, the values of Omega or beta estimated in this way may fail to represent the true cosmological values. However, even if nongravitational forces initiate and shape the growth of structure, gravitationally induced accelerations can dominate the velocity field at late times, long after the action of any nongravitational impulses. The estimated beta approaches the true value in such cases, and in our numerical simulations the estimated beta values are reasonably accurate for both gravitational and nongravitational models. Reconstruction tests that show correlations between galaxy density and velocity fields can rule out some physically interesting models of large-scale structure. In particular, successful reconstructions constrain the nature of any bias between the galaxy and mass distributions, since processes that modulate the efficiency of galaxy formation on large scales in a way that violates the continuity equation also produce a mismatch between the observed galaxy density and the density inferred from the peculiar velocity field. We obtain successful reconstructions for a gravitational model with peaks biasing, but we also show examples of gravitational and nongravitational models that fail reconstruction tests because of more complicated modulations of galaxy formation.

Babul, Arif↗
DOE OSTI2025

Electrolytic gold plating, stripping, and ion transport dynamics through a solid-state iodide perovskite

The pronounced electrochemical reactivity between halide perovskites and metal electrodes can introduce mobile extrinsic metal ions which can cause device instability or enable novel functionalities. Here we systematically investigate the kinetics of gold cation (Au + ) migration in indium tin oxide (ITO)/methylammonium lead triiodide (MAPbI 3 )/Au model devices under long-term potentiostatic biasing. Scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), and density functional theory (DFT) analyses reveal that Au + ions, electrochemically generated at the Au anode, traverse the perovskite layer with diffusion coefficients on the order of 10 −11 to 10 −10 cm 2 s −1 and are subsequently reduced at the cathode as Au 0 clusters, resembling metal plating behavior in electrolytic cells and solid-state batteries during charging. Furthermore, reversing the applied bias strips the plated Au 0 , revealing reversibility suitable for bipolar resistive switching devices and providing direct evidence of the electrochemical and ionic nature of Au transport within the perovskite matrix. Quantitatively determining diffusion coefficients and ion concentrations provides foundational inputs for future drift-diffusion modelling opportunities and allows us to relate our findings to implications on long term operation of devices like photovoltaic modules. These results clearly demonstrate the solid-state electrochemical nature of perovskite devices, highlight methods to be more quantitative about ion transport properties, provide and emphasize the importance of disentangling electro-, photo-, photoelectrochemical processes for understanding device performance and unlocking new functionalities.

14 SOLAR ENERGY↗
NASA NTRS1997

Identification of defective illegitimate recombinational repair of oxidatively-induced DNA double-strand breaks in ataxia-telangiectasia cells

Ataxia-telangiectasia (A-T) is an autosomal-recessive lethal human disease. Homozygotes suffer from a number of neurological disorders, as well as very high cancer incidence. Heterozygotes may also have a higher than normal risk of cancer, particularly for the breast. The gene responsible for the disease (ATM) has been cloned, but its role in mechanisms of the disease remain unknown. Cellular A-T phenotypes, such as radiosensitivity and genomic instability, suggest that a deficiency in the repair of DNA double-strand breaks (DSBs) may be the primary defect; however, overall levels of DSB rejoining appear normal. We used the shuttle vector, pZ189, containing an oxidatively-induced DSB, to compare the integrity of DSB rejoining in one normal and two A-T fibroblast cells lines. Mutation frequencies were two-fold higher in A-T cells, and the mutational spectrum was different. The majority of the mutations found in all three cell lines were deletions (44-63%). The DNA sequence analysis indicated that 17 of the 17 plasmids with deletion mutations in normal cells occurred between short direct-repeat sequences (removing one of the repeats plus the intervening sequences), implicating illegitimate recombination in DSB rejoining. The combined data from both A-T cell lines showed that 21 of 24 deletions did not involve direct-repeats sequences, implicating a defect in the illegitimate recombination pathway. These findings suggest that the A-T gene product may either directly participate in illegitimate recombination or modulate the pathway. Regardless, this defect is likely to be important to a mechanistic understanding of this lethal disease.

Non-NASA Center↗
NASA NTRS1995

Variability of accretion disks surrounding black holes: The role of inertial-acoustic mode instabilities

The global nonlinear time-dependent evolution of the inertial-acoustic mode instability in accretion disks surrounding black holes has been investigated. The viscous stress is assumed to be proportional to the gas pressure only, i.e., tau = alphap(sub g). It is found that an oscillatory nonsteady behavior exists in the inner regions of disks (r is less than 10r(sub g) where r(sub g) is the Schwarzschild radius) for sufficiently large alpha(greater than or approximately equal to 0.2) and for mass accretion rates less than about 0.3 times the Eddington value. The variations of the integrated bolometric luminosity from the disk, Delta L/L, are less than 3%. A power spectrum analysis of these variations reveals a power spectrum which can be fitted to a power-law function of the frequency Pis proportional to f(exp -gamma), with index gamma = 1.4-2.3 and a low-frequency feature at about 4 Hz in one case. In addition, a narrow peak centered at a frequency corresponding to the maximum epicyclic frequency of the disk at approximately 100-130 Hz and its first harmonic is also seen. The low-frequency modulations are remarkably similar to those observed in black hole candidate systems. The possible existence of a scattering corona in the inner region of the disk and/or other processes contributing to the power at high frequencies in the inner region of the accretion disk may make the detection of the high-frequency component difficult.

Chen, Xingming↗
DOE OSTI2026

Single-Particle Insights Into the Electronic Structure and Enhanced Stability of CsPbBr 3 /FAPbBr 3 Core/Crown Nanoplatelets at the Nanometer Scale

Colloidal perovskite nanoplatelets (NPLs), despite their exceptional optoelectronic properties, face significant challenges due to their intrinsic instability and trap-assisted non-radiative recombination. Although many studies employing surface engineering, such as selecting ligands or coating to passivate defects, have demonstrated improved optoelectronic properties, these enhancements are typically inferred from bulk-ensemble measurements; the effects at the single-particle level remain elusive. Here, we conduct single-particle-level studies using scanning tunneling spectroscopy (STS) on a unique core–crown system, CsPbBr 3 @FAPbBr 3 NPLs, where the lateral surfaces of the CsPbBr 3 core are coated with an FAPbBr 3 crown. Experimental density-of-states (DOS) analysis reveals a 47% reduction in deep-trap states in core-crown NPLs compared to core-only NPLs, consistent with nearly two-fold enhancements in photoluminescence quantum yields. Progressive I–V sweep measurements demonstrate superior electrical stability in core-crown NPLs, preserving band structure with minimal degradation, while core-only NPLs exhibit rapid bandgap shrinkage and trap formation. Density functional theory (DFT) calculations indicate that FA incorporation distorts Pb octahedral lattice, widening the bandgap. This study elucidates how surface engineering modulates charge localization, passivates defects, and enhances stability at the single-particle level. Moreover, by uncovering bias-induced trap states in single unpassivated NPLs, this study establishes a precise, robust approach for characterizing emerging perovskite nanocrystals.

77 NANOSCIENCE AND NANOTECHNOLOGY↗