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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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All sourcesNASA NTRSDOE OSTI
NASA NTRS1987

O-16 excesses in Murchison and Murray hibonites - A case against a late supernova injection origin of isotopic anomalies in O, Mg, Ca, and Ti

Ion probe measurements of the oxygen isotopic composition of seven hibonite samples from the CM chondrites Murchison and Murray are reported. All samples show large O-16 excesses relative to terrestrial oxygen. The data for all samples plot along the carbonaceous chondrite O-16-rich mixing line and show no evidence for isotopic mass fractionation effects characteristic of FUN inclusions. These hibonites have the largest Ca-48 and Ti-50 isotopic anomalies found to date; thus there is no intrinsic relationship between anomalies of a nucleosynthetic origin and isotopic mass fractionation effects. The large O-16 excess seen in the sample with the largest measured Ca-48 and Ti-50 depletions argues against a late injection of exotic material from a nearby supernova as a source for the isotopic anomalies.

Fahey, A. J.↗
NASA NTRS1983

Eclipse-related measurements of middle-atmosphere electrical parameters

Measurements of electrical conductivity and its constituent parameters, charge density and ion mobility, are presented for the solar eclipse rocket campaign conducted at Red Lake, Ontario, Canada. Three parachute-borne probes (two Gerdien condensers and a blunt probe) were flown during the eclipse which occurred on 26 February 1979. Additional payloads launched at other times provided important supplemental background measurements. The entire launch series occurred during aurorally active conditions, as indicated by the probe measurements. Specifically, positive conductivity enhancements above 45 km demonstrate the dominance of auroral ionization as a source for positive ions in the region. Such effects evidenced during the eclipse make it difficult to determine the extent to which the decrease in positive conductivity above 60 km is eclipse-related. The negative conductivity component associated with free electrons displays solar dependence both during the eclipse and for the other measurement periods. In spite of the aurorally active conditions, rapid electron loss was observed during totality, thus indicating the importance of non-ionizing solar effects on electrons in the region.

Mitchell, J. D.↗
NASA NTRS1977

Atomic nitrogen measurements in the upper thermosphere

The open source neutral mass spectrometer on board the Atmosphere Explorer satellites measures, besides other neutral constituents, atomic nitrogen densities in the upper thermosphere. Atomic nitrogen combines with atomic oxygen on the walls of the mass spectrometer ion source to form NO. From the measured NO concentration atomic nitrogen is deduced. Studies of the diurnal variation show that the maximum atomic nitrogen densities occur near 1600 local solar time (LST) and minimum densities near 0400 LST. The diurnal amplitude at 300 km is about a factor of 8, which is lower than predicted in present models. Atomic nitrogen also exhibits a pronounced seasonal variation with an amplitude similar to that of the diurnal variation; summer values are considerably higher than winter ones.

Mauersberger, K.↗
NASA NTRS2002

The Gas Production Rate and Coma Structure of Comet C/1995 01 (Hale-Bopp)

The University of Wisconsin-Madison and NASA-Goddard conducted a comprehensive multi-wavelength observing campaign of coma emissions from comet Hale-Bopp, including OH 3080 A, [O I] 6300 A, H2O(+) 6158 A, H Balmer-alpha 6563 A, NH2 6330 A, [C I] 9850 A CN 3879 A, C2 5141 A, C3 4062 A, C I 1657 A, and the UV and optical continua. In this work, we concentrate on the results of the H2O daughter studies. Our wide-field OH 3080 A measured flux agrees with other, similar observations and the expected value calculated from published water production rates using standard H2O and OH photochemistry. However, the total [O I] 6300 A flux determined spectroscopically over a similar field-of-view was a factor of 3 - 4 higher than expected. Narrow-band [O I] images show this excess came from beyond the H2O scale length, suggesting either a previously unknown source of [O I] or an error in the standard OH + upsilon to O((sup I)D) + H branching ratio. The Hale-Bopp OH and [O I] distributions, both of which were imaged to cometocentric distances greater than 1 x 10(exp 6) km, were more spatially extended than those of comet Halley (after correcting for brightness differences), suggesting a higher bulk outflow velocity. Evidence of the driving mechanism for this outflow is found in the H(alpha) line profile, which was narrower than in comet Halley (though likely because of opacity effects, not as narrow as predicted by Monte-Carlo models). This is consistent with greater collisional coupling between the suprathermal H photodissociation products and Hale-Bopp's dense coma. Presumably because of mass loading of the solar wind by ions and ions by the neutrals, the measured acceleration of H2O(+) down the ion tail was much smaller than in comet Halley. Tailward extensions in the azimuthal distributions of OH 3080 A, [O I], and [C I], as well as a Doppler asymmetry in the [O I] line profile, suggest ion-neutral coupling. While the tailward extension in the OH can be explained by increased neutral acceleration, the [O I] 6300 A and [C I] 9850 A emissions show 13% and less than 200% excesses in this direction (respectively), suggesting a non-negligible contribution from dissociative recombination of CO(+) and/or electron collisional excitation. Thus, models including the effects of photo-and collisional chemistry are necessary for the full interpretation of these data.

Morgenthaler, Jeffrey P.↗
NASA NTRS2000

Isotope Geochemistry of Possible Terrestrial Analogue for Martian Meteorite ALH84001

We have studied the microdomain oxygen and carbon isotopic compositions by SIMS of complex carbonate rosettes from spinel therzolite xenoliths, hosted by nepheline basanite, from the island of Spitsbergen (Norway). The Quaternary volcanic rocks containing the xenoliths erupted into a high Arctic environment and through relatively thick continental crust containing carbonate rocks. We have attempted to constrain the sources of the carbonates in these rocks by combined O-18/O-16 and C-13/C-12 ratio measurements in 25 micron diameter spots of the carbonate and compare them to previous work based primarily on trace-element distributions. The origin of these carbonates can be interpreted in terms of either contamination by carbonate country rock during ascent of the xenoliths in the host basalt, or more probably by hydrothermal processes after emplacement. The isotopic composition of these carbonates from a combined delta.18O(sub SMOW) and delta.13C(sub PDB) standpoint precludes a primary origin of these minerals from the mantle. Here a description is given of the analysis procedure, standardization of the carbonates, major element compositions of the carbonates measured by electron microprobe, and their correlated C and O isotope compositions as measured by ion microprobe. Since these carbonate rosettes may represent a terrestrial analogue to the carbonate "globules" found in the martian meteorite ALH84001 interpretations for the origin of the features found in the Spitsbergen may be of interest in constraining the origin of these carbonate minerals on Mars.

Mojzsis, Stephen J.↗
NASA NTRS2018

Origin of Molecular Oxygen in Comets: Current Knowledge and Perspectives

The Rosetta Orbiter Spectrometer for Ion and Neutral Analysis (ROSINA) instrument onboard the Rosetta spacecraft has measured molecular oxygen (O 2 ) in the coma of comet 67P/Churyumov-Gerasimenko (67P/C-G) in surprisingly high abundances. These measurements mark the first unequivocal detection of O 2 in a cometary environment. The large relative abundance of O 2 in 67P/C-G despite its high reactivity and low interstellar abundance poses a puzzle for its origin in comet 67P/C-G, and potentially other comets. Since its detection, there have been a number of hypotheses put forward to explain the production and origin of O 2 in the comet. These hypotheses cover a wide range of possibilities from various in situ production mechanisms to protosolar nebula and primordial origins. Here, we review the O2 formation mechanisms from the literature, and provide a comprehensive summary of the current state of knowledge of the sources and origin of cometary O 2 .

Molecular oxygen↗
NASA NTRS1995

Solar wind composition

Advances in instrumentation have resulted in the determination of the average abundances of He, C, N, O, Ne, Mg, Si, S, and Fe in the solar wind to approximately 10%. Comparisons with solar energetic particle (SEP) abundances and galactic cosmic ray abundances have revealed many similarities, especially when compared with solar photospheric abundances. It is now well established that fractionation in the corona results in an overabundance (with respect to the photosphere) of elements with first ionization potentials less than 10 eV. These observations have in turn led to the development of fractionation models that are reasonably successful in reproducing the first ionization (FIP) effect. Under some circumstances it has been possible to relate solar wind observations to particular source regions in the corona. The magnetic topologies of the source regions appear to have a strong influence on the fractionation of elements. Comparisons with spectroscopic data are particularly useful in classifying the different topologies. Ions produced from interstellar neutral atoms are also found in the solar wind. These ions are picked up by the solar wind after ionization by solar radiation or charge exchange and can be identified by their velocity in the solar wind. The pick-up ions provide most of the pressure in the interplanetary medium at large distances. Interstellar abundances can be derived from the observed fluxes of solar wind pick-up ions.

Ogilvie, K. W.↗
NASA NTRS1982

The X-ray binary, UW CMa

The UW CMa is a close, eclipsing binary composed of an O7f primary with a stron wind and a less luminous O-type companion. It was found that UW CMa a variable X-ray source, whose X-ray variations are in phase with its optical light curve. Since both components of the binary system are O stars, accretion by a compact object is ruled out as a mechanism for generating X-rays. The UW CMa represents a new class of X-ray binaries, in which X-rays result from the collision of a wind from one star with the surface or wind of the other star. It is hypothesised that the impact of a wind against a star generates a shock wave about 0.25 stellar radii above the stellar surface, and material behind the shock front, heated to bout 10 million degrees, radiates the X-ray apparent X-ray variability is due to its location between the two stars, where it undergoes eclipses. The high temperature region maintains an ionization cavity in the wind, as detected with IUE. The ionization cavity is the source of depletion of absorbing ions in the wind between the two stars.

Heap, S. R.↗
NASA NTRS1991

Carbohydrates as a source of energy and matter for the origin of life

Recently, we proposed a new model of early glycolysis in which the oxidation of glyceraldehyde self-hemiacetals yielded energy rich polyglyceric acid instead of energy rich thioesters. In this model, polyglyceric acid not only acts as an energy source for phosphoanhydride synthesis, but also as an autocatalyst that can replicate the sequence of D and L residues in its structure. We began our investigation of this new hypothesis - the triose model - by developing a thermal method for the racemization-free synthesis of polyglyceric acid. The hydrolytic stability and the role of chirality in interactions of polyglyceric acid were studied using this thermal polymer. Next, we established that the 2- and 3-glycerol esters of polyglyceric acid are energy rich by measuring the Gibbs free energy change of hydrolysis of the 2- and 3-glycerol esters of 2 and 3-O-L glyceroyl-glyceric acid methyl ester - a model of polyglyceric acid. Recently, we discovered that glyceraldehyde is bound and oxidized to glyceric acid on the surface of ferric hydroxide and that soluble ferric ion catalyzes the rearrangement of glyceraldehyde to lactic acid. We are exploring the possibility that these reactions could yield polyglyceric acid and polylactic acid under plausible prebiotic conditions.

Weber, A. L.↗
NASA NTRS1988

Formic and acetic acid over the central Amazon region, Brazil. I - Dry season

The concentrations of formic and acetic acids in the gas phase, atmospheric aerosol, and rainwater samples collected in Amazonia at ground level and in the atmosphere during the Amazon Boundary Layer Experiment in July/August 1985 were analyzed by ion exchange chromatography. The diurnal behavior of both acids at ground level and their vertical distribution in the forest canopy point to the existence of vegetative sources as well as to production by chemical reactions in the atmosphere. The concentrations of formic and acetic acids in the gas phase were about 2 orders of magnitude higher than the corresponding concentrations in the atmospheric aerosol. In rainwater, the total formate and acetate represented about one half of the anion equivalents, in contrast to less than 10 percent of the soluble anionic equivalents contributed by these acids in the atmospheric aerosol. The observed levels of these ions in rainwater are considered to be the result of a combination of chemical reactions in hydrometeors and the scavenging of the gaseous acids by cloud droplets.

Andreae, M. O.↗
NASA NTRS1974

Exospheric temperature and composition from satellite beacon measurements

Routine measurements of the slab thickness of the ionosphere, from 1965 to 1971, are used to infer the changes in neutral temperature and ion composition at a mean latitude of 40 S. Values of neutral temperature at solar maximum are 5 to 10% above Northern Hemisphere backscatter results. The diurnal and seasonal changes agree closely with satellite drag and backscatter measurements, except that the maximum temperature occurs after sunset in winter. Winter night-time values of the O(+)/H(+) transition height were 500 km in 1965-1966, 800 km in 1968-1969, and 700 km in 1971. Changes in the transition height lag about six months behind the changes in solar flux. Diurnal variations have a minimum just before sunrise and a maximum 1 to 3 hr after noon. On winter nights the transition height descends to the level set by chemical equilibrium. On summer nights the transition height is always above this level, giving a continual production of H(+) which serves as an additional source for maintaining the night-time ionosphere in the winter hemisphere.

Titheridge, J. E.↗
NASA NTRS2011

O-6 Optical Property Degradation of the Hubble Space Telescope's Wide Field Camera-2 Pick Off Mirror

Degradation in the performance of optical components can be greatly affected by exposure to the space environment. Many factors can contribute to such degradation including surface contaminants; outgassing; vacuum, UV, and atomic oxygen exposure; temperature cycling; or combinations of parameters. In-situ observations give important clues to degradation processes, but there are relatively few opportunities to correlate those observations with post-flight ground analyses. The return of instruments from the Hubble Space Telescope (HST) after its final servicing mission in May 2009 provided such an opportunity. Among the instruments returned from HST was the Wide-Field Planetary Camera-2 (WFPC-2), which had been exposed to the space environment for 16 years. This work focuses on the identifying the sources of degradation in the performance of the Pick-off mirror (POM) from WFPC-2. Techniques including surface reflectivity measurements, spectroscopic ellipsometry, FTIR (and ATR-FTIR) analyses, SEM/EDS, X-ray photoelectron spectroscopy (XPS) with and without ion milling, and wet and dry physical surface sampling were performed. Destructive and contact analyses took place only after completion of the non-destructive measurements. Spectroscopic ellipsometry was then repeated to determine the extent of contaminant removal by the destructive techniques, providing insight into the nature and extent of polymerization of the contaminant layer.

McNamara, Karen M.↗
NASA NTRS1999

Helicon Plasma Source Optimization Studies for VASIMR

A helicon plasma source at Oak Ridge National Laboratory is being used to investigate operating scenarios relevant to the VASIMR (VAriable Specific Impulse Magnetoplasma Rocket). These include operation at high magnetic field (> = 0.4 T), high frequency (<= 30 MHz), high power (< = 3 kW), and with light ions (He+, H+). To date, He plasmas have been produced with n(sub e0) = 1.7 x 10(exp 19)/cu m (measured with an axially movable 4mm microwave interferometer), with Pin = I kW at f = 13.56 MHz and absolute value of B(sub 0) = 0.16 T. In the near future, diagnostics including a mass flow meter and a gridded energy analyzer array will be added to investigate fueling efficiency and the source power balance. The latest results, together with modeling results using the EMIR rf code, will be presented.

Goulding, R. H.↗
NASA NTRS1976

Recombination of O2/+/ in the ionosphere

In spite of the excellent agreement between various laboratory measurements of the recombination rate of O2(+) with electrons, it is still questionable whether the laboratory results apply in the ionosphere, because although the radiative lifetime of vibrating O2(+) is not well known, indications are that it may be very long. Whether the laboratory results apply in the atmosphere depends on whether the recombination rate is dependent on the vibrational state of the O2(+) ion and on whether the ions are deactivated (or not) in both the laboratory experiments and the atmosphere prior to recombination. To obtain reliable answers to these questions, the present study was carried out to determine the recombination of O2(+) in the ionosphere from in situ measurements of the relevant temperatures and densities made by the open source mass spectrometer carried by the AE-C satellite. The photochemistry involved is discussed. The results show that the ionospheric determination of the recombination rate of O2(+) with electrons agrees with the laboratory measurements of Walls and Dunn (1974) for electron temperatures between 1200 and 2000 K.

Torr, D. G.↗
NASA NTRS1993

Evolutionary implications of a steady-state water abundance on Venus

In 1987, Grinspoon proposed that the data on hydrogen abundance, isotopic composition, and escape rate were consistent with the hypothesis that water on Venus might be in steady-state rather than monotonic decline since the dawn of time. This conclusion was partially based on a derived water lifetime against nonthermal escape of approximately 10(exp 8) years. Others have questioned this conclusion. De Bergh et al. found H2O lifetimes of greater than 10(exp 9) years. Donahue and Hodges derived H2O lifetimes of 0.4 - 5 x 10(exp 9) years. The most sophisticated analysis to date of near-IR radiation from Venus' nightside reveals a water mixing ratio of approximately 30 ppm. Recent re-analysis of Pioneer Venus Mass Spectrometer Data are consistent with a water abundance of 30 ppm. Hodges and Tinsley found an escape flux due to charge exchange with hot H(+) of 2.8 x 10(exp 7) cm(exp -2) s(exp -1). Gurwell and Yung estimated an escape flux of 3.5 x 10(exp 6) cm(exp -2) s(exp -1) from collisions with hot O produced by dissociative recombination of O2(+). Brace et al. estimated an escape flux of 5 x 10(exp 6) cm(exp -2) s(exp -1) from ion escape from the ionotail of Venus. The combined estimated escape flux from all of these processes is 3.7 x 10(exp 7) cm(exp -2) s(exp -1), suggesting a lifetime against escape for water of less than 10(exp 8) years. A recent estimate of H escape flux employing a different ionospheric model and using Pioneer Venus reentry data to estimate the response of the escape flux to the solar cycle finds a somewhat lower escape flux of 1.4 x 10(exp 7) cm(exp -2) s(exp -1), suggesting a water lifetime closer to 2 x 10(exp 8) years, significantly less than the age of the planet. Large uncertainties remain in these quantities, yet the data suggest that a source of water more recent than primordial sources is required and that a steady-state is likely. To obvious candidates for this source water are cometary impact and volcanic outgassing. Other aspects of this investigation are discussed.

Grinspoon, David H.↗
NASA NTRS2006

Grain Surface Chemistry and the Composition of Interstellar Ices

Submicron sized dust grains are an important component of the interstellar medium. In particular they provide surface where active chemistry can take place. At the low temperatures (-10 K) of the interstellar medium, colliding gas phase species will stick, diffuse, react, and form an icy mantle on these dust grains. This talk will review the principles of grain surface chemistry and delineate important grain surface routes, focusing on reactions involving H, D, and O among each other and with molecules such as CO. Interstellar ice mantles can be studied through the fundamental vibrations of molecular species in the mid-infrared spectra of sources embedded in or located behind dense molecular clouds. Analysis of this type of data has provided a complex view of the composition of these ices and the processes involved. Specifically, besides grain surface chemistry, the composition of interstellar ices is also affected by thermal processing due to nearby newly formed stars. This leads to segregation between different ice components as well as outgassing. The latter results in the formation of a so-called Hot Core region with a gas phase composition dominated by evaporated mantle species. Studies of such regions provide thus a different view on the ice composition and the chemical processes involved. Interstellar ices can also be processed by FUV photons and high energy cosmic ray ions. Cosmic ray processing likely dominates the return of accreted species to the gas phase where further gas phase reactions can take place. These different chemical routes towards molecular complexity in molecular clouds and particularly regions of star formation will be discussed.

Tielens, A. G. G. M.↗
NASA NTRS2012

Coordinated STEM/FIB/NanoSIMS Analyses of Presolar Silicates in Comet Dust and Primitive Meteorites

Silicate grains were among the most abundant mineralogical building blocks of our Solar System. These grains were the detritus from earlier generations of stars that have been recycled in the early solar nebula. Rare sub-micrometer survivors of this processing have been identified in meteorites, micrometeorites and interplanetary dust particles (IDPs). These silicate grains are recognized as presolar in origin because of their extremely anomalous isotopic compositions that reflect nucleosynthetic processes in their stellar sources (evolved stars, novae and supernovae). We perform coordinated chemical, mineralogical and isotopic studies of these grains to determine their origins and histories. We examine the complex mineralogy and petrography of presolar silicates using imaging, diffraction and chemical data obtained from thin sections with the JSC JEOL 2500 field-emission STEM equipped with a Noran thin window energy dispersive x-ray (EDX) spectrometer and a Gatan Tridiem GIF. Quantitative element x-ray maps (spectrum images) are acquired by rastering a 4 nm incident probe whose dwell time is minimized to avoid beam damage and element diffusion during mapping. Successive image layers are acquired and combined in order to achieve approx 1% counting statistics for major elements. The IDP samples are prepared by ultramicrotomy of particles embedded in epoxy or elemental sulfur. After EDX mapping, the sections are subjected to C, N, and O isotopic imaging with the JSC NanoSIMS 50L ion microprobe. We prepare sections of some meteorite grains using the JSC FEI Quanta 3D focused ion beam (FIB) instrument. The specimen surface is protected from the FIB milling process by layers of electron beam-deposited C and Pt followed by an ion-deposited Pt layer. We also use the FIB to preferentially remove surrounding grains to reduce the background in subsequent NanoSIMS measurements. For mineralogical studies, we again employ the FIB instrument to deposit a protective cap over the grain of interest and then extract the grain and thin it to electron transparency for TEM analysis.

Keller, Lindsay↗
NASA NTRS1991

Identification and characterization of extraterrestrial non-chondritic interplanetary dust

Interplanetary dust particles (IDPs) are among the most pristine and primitive extraterrestrial materials available for direct study. Most of the stratospheric particles selected for study from the JSC Curatorial Collection were chondritic in composition (major element abundances within a factor of two of chondritic meteorites) because this composition virtually ensures that the particle is from an extraterrestrial source. It is likely that some of the most interesting classes of IDP's have not been recognized simply because they are not chondritic or do not fit established criteria for extraterrestrial origin. Indeed, mass spectroscopy data from the Giotto Flyby of comet Halley indicate that a substantial fraction of the dust is in the submicron size range and that a majority of these particles contain C, H, O, and/or N as major elements. The preponderance of CHON particles in the coma of Halley implies that similar particles may exist in the JSC stratospheric dust collection. However, the JSC collection also contains a variety of stratospheric contaminants from terrestrial sources which have these same characteristics. Because established criteria for extraterrestrial origin may not apply to such particles in individual cases, and integrated approach is required in which a variety of analysis techniques are applied to the same particle. Non-chondritic IDP's, like their chondritic counterparts, can be used to elucidate pre- and early solar system processes and conditions. The study of non-chondritic IDP's may additionally yield unique information which bears on the nature of cometary bodies and the processing of carbonaceous and other low atomic number materials. A suite of complementary techniques, including Low Voltage Scanning Electron Microscopy (LVSEM), Energy-Dispersive X-ray Microanalysis (EDX), Secondary Ion Mass Spectrometry (SIMS) isotope-ratio imaging and Analytical Electron Microscopy (AEM), were utilized to accomplish the following two objectives: (1) to develop criteria for the unequivocal identification of extraterrestrial non-chondritic IDP's; and (2) to infer IDP parent body, solar nebula, and pre-solar conditions through the study of phases, textures, and components contained within non-chondritic IDP's. The general approach taken is designed to maximize the total information obtained from each particle. Techniques will be applied in order from least destructive to most destructive.

Blake, D. F.↗