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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 307 records · Page 17
All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

Functional metal–organic frameworks as effective sensors of gases and volatile compounds

Developing efficient sensor materials with superior performance for selective, fast and sensitive detection of gases and volatile organic compounds (VOCs) is essential for human health and environmental protection, through monitoring indoor and outdoor air pollutions, managing industrial processes, controlling food quality and assisting early diagnosis of diseases. Metal–organic frameworks (MOFs) are a unique type of crystalline and porous solid material constructed from metal nodes (metal ions or clusters) and functional organic ligands. They have been investigated extensively for possible use as high performance sensors for the detection of many different gases and VOCs in recent years, due to their large surface area, tunable pore size, functionalizable sites and intriguing properties, such as electrical conductivity, magnetism, ferroelectricity, luminescence and chromism. The high porosity of MOFs allows them to interact strongly with various analytes, including gases and VOCs, thus resulting in easily measurable responses to different physicochemical parameters. Although much of the recent work on MOF-based luminescent sensors have been summarized in several excellent reviews (up to 2018), a comprehensive overview of these materials for sensing gases and VOCs based on chemiresistive, magnetic, ferroelectric, and colorimertic mechanisms is missing. In this review, we highlight the most recent progress in developing MOF sensing and switching materials with an emphasis on sensing mechanisms based on electricity, magnetism, ferroelectricity and chromism. We provide a comprehensive analysis on the MOF–analyte interactions in these processes, which play a key role in the sensing performance of the MOF-based sensors and switches. We discuss in detail possible applications of MOF-based sensing and switching materials in detecting oxygen, water vapor, toxic industrial gases (such as hydrogen sulfide, ammonia, sulfur dioxide, nitrous oxide, carbon oxides and carbon disulfide) and VOCs (such as aromatic and aliphatic hydrocarbons, ketones, alcohols, aldehydes, chlorinated hydrocarbons and N,N'-dimethylformamide). Altogether, this review serves as a timely source of information and provides insight for the future development of advanced MOF materials as next-generation gas and VOC sensors.

36 MATERIALS SCIENCE↗
NASA NTRS2002

Development and Application of Novel Diagnostics for Arc-Jet Characterization

This NASA-Ames University Consortium Project has focused on the design and demonstration of optical absorption sensors using tunable diode laser to target atomic copper impurities from electrode erosion in thc arc-heater metastable electronic excited states of molecular nitrogen, atomic argon, aid atomic oxygen in the arcjet plume. Accomplishments during this project include: 1. Design, construction, and assembly of optical access to the arc-heater gas flow. 2. Design of diode laser sensor for copper impurities in the arc-heater flow. 3 . Diode laser sensor design and test in laboratory plasmas for metastable Ar(3P), O(5S), N(4P), and N2(A). 4. Diode laser sensor demonstration measurements in the test cell to monitor species in the arc-jet plume.

Hanson, R. K.↗
DOE OSTI2025

Transformation of TiN to TiNO Films via In-Situ Temperature-Dependent Oxygen Diffusion Process and Their Electrochemical Behavior

Titanium oxynitride (TiNO) thin films represent a multifaceted material system applicable in diverse fields, including energy storage, solar cells, sensors, protective coatings, and electrocatalysis. This study reports the synthesis of TiNO thin films grown at different substrate temperatures using pulsed laser deposition. A comprehensive structural investigation was conducted by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), Non-Rutherford backscattering spectrometry (N-RBS), and X-ray absorption spectroscopy (XAS), which facilitated a detailed analysis that determined the phase, composition, and crystallinity of the films. Structural control was achieved via temperature-dependent oxygen in-diffusion, nitrogen out-diffusion, and the nucleation growth process related to adatom mobility. The XPS analysis indicates that the TiNO films consist of heterogeneous mixtures of TiN, TiNO, and TiO2 phases with temperature-dependent relative abundances. The correlation between the structure and electrochemical behavior of the thin films was examined. The TiNO films with relatively higher N/O ratio, meaning less oxidized, were more electrochemically active than the films with lower N/O ratio, i.e., more oxidized films. Films with higher oxidation levels demonstrated enhanced crystallinity and greater stability under electrochemical polarization. These findings demonstrate the importance of substrate temperature control in tailoring the properties of TiNO film, which is a fundamental part of designing and optimizing an efficient electrode material.

Cherono, Sheilah↗
DOE OSTI2023

Dissolved Oxygen and Temperature Data from the Hyporheic Zone of the East River Watershed July 2017 to October 2018

Dissolved oxygen (DO) is critical for aquatic ecosystems. Our focus is on the long-term DO dynamics in hyporheic zone of rivers, which are a function of both transport (hydrologic exchange between river and hyporheic zone) and uptake by biogeochemical reactions or respiration. The study site is the alpine East River watershed in Colorado, USA, meander A downstream from the pump house. Opti O2 probes were deployed in the water column and directly within the river-bed at 10, 20, and 35 cm depth (38°55'23.38"N, 106°57'4.21"W, 9046.88m) to monitor DO and temperature. A continuous data stream from July 24, 2017 to Oct 24, 2018 was autonomously telemetered to the cloud. This 14-month DO and temperature time series were obtained without any servicing for maintenance or data downloads; additionally the ability to remotely verify probe performance during field deployment was essential to confirm data validity during winter freeze-in and hydrological/weather events, such as spring melt and summer monsoons. We investigate the variations in dissolved oxygen dynamics of this snow-pack dominated watershed during a comparatively low flow water year (2018) and a relatively normal water year (2017), enabled by distinctive, in-situ, high frequency (∆t = 5min) sensors that provided a continuous time-series from the undisturbed study site over multiple seasons.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS2023

Disruptive Chemical Approach to Modify Perovskites for Chemical and Biological Sensors

We have been investigating CaCu3Ti4O12 class of perovskites for variety of applications due to its very large dielectric constant. Several mechanisms have been proposed for the existence of the high dielectric constant based on grain boundaries and oxygen deficiencies. We will report the results of the effects of monovalent substitution to replace calcium. This will alter the size to distort the perovskite structure. In addition, we used this system as a sensor for organic agents. There were very large changes in dielectric constant and resistivity indicating this system as a very good sensor material.

Perovskites↗
DOE OSTI2025

Subnanometer Thick Native sp 2 Carbon on Oxidized Diamond Surfaces

Oxygen-terminated diamond has a wide breadth of applications, which include stabilizing near-surface color centers, semiconductor devices, and biological sensors. Despite the vast literature on characterizing functionalization groups on diamond, the chemical composition of the shallowest portion of the surface (<1 nm) is challenging to probe with conventional techniques like XPS and FTIR. In this work, we demonstrate the use of angleresolved XPS to probe the first ten nanometers of both oxygen and hydrogen terminated (100) single-crystalline diamond grown via chemical vapor deposition (CVD). With the use of consistent peakfitting methods, the peak identities and relative peak binding energies were identified for sp 2 carbon, ether, hydroxyl, carbonyl, and C−H groups for both of these diamond surface terminations. For the oxygen-terminated sample, we also quantified the thickness of the sp 2 carbon layer situated on top of the bulk sp 3 diamond bonded carbon to be 0.3 ± 0.1 nm, based on the analysis of the Auger electron spectra and D-parameter calculations. These results indicate that the majority of the oxygen is bonded to the sp 2 carbon layer on the diamond, and not directly to the sp 3 diamond bonded carbon.

Carbon↗
NASA NTRS1987

Probabilistic risk analysis of flying the space shuttle with and without fuel turbine discharge temperature redline protection

An exact mathematical model is presented of the Space Shuttle Main Engine computer voting logic in the presence of High Pressure Fuel Turbine (HPFT) overtemperature events and fuel turbine temperature sensor failures. The model provides estimates of the probability of erroneous engine shutdown and the probability of not detecting a HPFT overtemperature event. Because it is believed that the likelihood of sensor failures and overtemperature events in the HPFT greatly overshadows those in the High Pressure Oxygen Turbine (HPOT), this modeling effort focused on the HPFT. However, because the redline protection logic is the same for both turbines, estimation of the model parameters using relevant HPOT data would provide estimates of the risk of erroneous engine shutdown and an undetected overtemperature event in the HPOT. Because of the complexity of the model, it was necessary to program the solution which thus makes it feasible to accommodate a changing data base. This is considered to be of great interest because of the subjective nature in determining the relevancy of certain failures and the fact that the data base is constantly changing as a result of the frequent engine tests.

Howell, Leonard↗
NASA NTRS2017

Vehicle-Level Oxygen/Methane Propulsion System Hotfire Testing at Thermal Vacuum Conditions

A prototype integrated liquid oxygen/liquid methane propulsion system was hot-fire tested at a variety of simulated altitude and thermal conditions in the NASA Glenn Research Center Plum Brook Station In-Space Propulsion Thermal Vacuum Chamber (formerly B2). This test campaign served two purposes: 1) Characterize the performance of the Plum Brook facility in vacuum accumulator mode and 2) Collect the unique data set of an integrated LOX/Methane propulsion system operating in high altitude and thermal vacuum environments (a first). Data from this propulsion system prototype could inform the design of future spacecraft in-space propulsion systems, including landers. The test vehicle for this campaign was the Integrated Cryogenic Propulsion Test Article (ICPTA), which was constructed for this project using assets from the former Morpheus Project rebuilt and outfitted with additional new hardware. The ICPTA utilizes one 2,800 lbf main engine, two 28 lbf and two 7 lbf reaction control engines mounted in two pods, four 48-inch propellant tanks (two each for liquid oxygen and liquid methane), and a cold helium system for propellant tank pressurization. Several hundred sensors on the ICPTA and many more in the test cell collected data to characterize the operation of the vehicle and facility. Multiple notable experiments were performed during this test campaign, many for the first time, including pressure-fed cryogenic reaction control system characterization over a wide range of conditions, coil-on-plug ignition system demonstration at the vehicle level, integrated main engine/RCS operation, and a non-intrusive propellant mass gauging system. The test data includes water-hammer and thermal heat leak data critical to validating models for use in future vehicle design activities. This successful test campaign demonstrated the performance of the updated Plum Brook In-Space Propulsion thermal vacuum chamber and incrementally advanced the state of LOX/Methane propulsion technology through numerous system-level and subsystem experiments.

Morehead, Robert L.↗
NASA NTRSDate not supplied

Lunar Surface Cargo Offloading Concepts

A sustainable presence on the lunar surface will serve as a vital training ground and technology demonstration test site in preparation for future human missions to Mars. Robotic lunar surface campaigns will focus on the exploration of resources providing information on the availability and extraction of usable resources, such as oxygen and water, and prepare the surface for a sustained human presence. Landers, outfitted with sensor packages, will be used to conduct risk-reduction activities and aid in the development of technologies prior to the crewed lunar missions that drive the need to for a logistics supply chain that requires offloading. A series of landers will be required on other planetary surfaces to build up the capabilities, capitalizing on those resources, required for sustained human presence. In each of those landers will be cargo including ascent vehicles, habitats, supplies, science packages, spare parts, fluids commodities for fuel and life support, and others varying in volume and ranging from mass in hundreds of kilograms to an estimated 6-14 metric tons to support Human Landing Systems and surface logistics requirements. This paper will examine the challenge of offloading examples of these cargo elements from different categories of landers on the lunar surface using a variety of methodologies. Challenges on the lunar surface arise with the conditions present (thermal, lighting, communications, regolith consistency), the desire to minimize mass of all landed systems, the desire to perform much of the activities with limited to minimal human interaction, and the overall configuration of the landers that are responsible for landing the cargo.

Lunar↗
NASA NTRSDate not supplied

Lunar Surface Cargo Offloading Concepts

A sustainable presence on the lunar surface will serve as a vital training ground and technology demonstration test site in preparation for future human missions to Mars. Robotic lunar surface campaigns will focus on the exploration of resources providing information on the availability and extraction of usable resources, such as oxygen and water, and prepare the surface for a sustained human presence. Landers, outfitted with sensor packages, will be used to conduct risk-reduction activities and aid in the development of technologies prior to the crewed lunar missions that drive the need to for a logistics supply chain that requires offloading. A series of landers will be required on other planetary surfaces to build up the capabilities, capitalizing on those resources, required for sustained human presence. In each of those landers will be cargo including ascent vehicles, habitats, supplies, science packages, spare parts, fluids commodities for fuel and life support, and others varying in volume and ranging from mass in hundreds of kilograms to an estimated 6-14 metric tons to support Human Landing Systems and surface logistics requirements. This paper will examine the challenge of offloading examples of these cargo elements from different categories of landers on the lunar surface using a variety of methodologies. Challenges on the lunar surface arise with the conditions present (thermal, lighting, communications, regolith consistency), the desire to minimize mass of all landed systems, the desire to perform much of the activities with limited to minimal human interaction, and the overall configuration of the landers that are responsible for landing the cargo.

Lunar↗
NASA NTRSDate not supplied

Modification of Oxygen Regulator Functionality Tester for X-59 Regulator Testing

NASA Armstrong Flight Research Center currently has possession of an oxygen regulator functionality tester. This device was used for ensuring that the oxygen regulators for aircraft life support systems are functional and safe for flight and/or other testing. This tester has been in storage for about 25 years, with occasional adjustment to sensors and instruments. Due to the aging structure, there are components and instruments that may be broken, unstable, worn-out, and thus inhibits safe and accurate future testing on other oxygen regulators. This tester is also limited in the types of regulators it may test, limited to ones that only have one line to deliver oxygen in and out of the regulator, to the pilots mask. It has been requested for this tester to be modified to test the X-59 oxygen regulator.

Mirin Morris-ward↗
NASA NTRS1975

Skylab analysis of San Francisco Bay

The distribution and volume of sediment present in suspension during the Skylab 4 overpass for San Pablo Bay and the Carquinez Strait is studied along with the movement and eventual distribution of both natural and dredged sediment in San Francisco Bay. The most useful Skylab sensor film is found to be the S-190B color photography. Changes in temperature, dissolved oxygen, pH, salinity, and pollutants information simultaneously collected are correlated with the spectral differences observed in the various Skylab data. The techniques outlined should be applicable for coastal and estuarine process studies in other areas. A suspensate concentration of about 2 mg/liter is quite sufficient to tag a surface current system, and the surface structure of currents with over 250 mg/liter can be imaged by using progressively longer wavelength filters.

Steller, D. D.↗
NASA NTRS2009

Biosensors for EVA: Muscle Oxygen and pH During Walking, Running and Simulated Reduced Gravity

During lunar excursions in the EVA suit, real-time measurement of metabolic rate is required to manage consumables and guide activities to ensure safe return to the base. Metabolic rate, or oxygen consumption (VO2), is normally measured from pulmonary parameters but cannot be determined with standard techniques in the oxygen-rich environment of a spacesuit. Our group developed novel near infrared spectroscopic (NIRS) methods to calculate muscle oxygen saturation (SmO2), hematocrit, and pH, and we recently demonstrated that we can use our NIRS sensor to measure VO2 on the leg during cycling. Our NSBRI-funded project is looking to extend this methodology to examine activities which more appropriately represent EVA activities, such as walking and running and to better understand factors that determine the metabolic cost of exercise in both normal and lunar gravity. Our 4 year project specifically addresses risk: ExMC 4.18: Lack of adequate biomedical monitoring capability for Constellation EVA Suits and EPSP risk: Risk of compromised EVA performance and crew health due to inadequate EVA suit systems.

Lee, S. M. C.↗
NASA NTRS2018

Space Environmental Effects on Additively Manufactured Materials

Space simulations including thermal vacuum, atomic oxygen, and ultraviolet radiation were performed to study the durability of various additively manufactured materials. In addition to ground simulations, additively manufactured materials were selected for a one-year flight on the Materials on International Space Station Experiment (MISSE) Flight Facility. The space environment is composed of atomic oxygen, ultraviolet radiation, protons, electrons, meteoroid/space debris impacts, thermal cycling, and hard vacuum. An improved UV sensor is also discussed.

Finckenor, M. M.↗
NASA NTRS2001

Lyapunov-Based Sensor Failure Detection And Recovery For The Reverse Water Gas Shift Process

Livingstone, a model-based AI software system, is planned for use in the autonomous fault diagnosis, reconfiguration, and control of the oxygen-producing reverse water gas shift (RWGS) process test-bed located in the Applied Chemistry Laboratory at KSC. In this report the RWGS process is first briefly described and an overview of Livingstone is given. Next, a Lyapunov-based approach for detecting and recovering from sensor failures, differing significantly from that used by Livingstone, is presented. In this new method, models used are in terms of the defining differential equations of system components, thus differing from the qualitative, static models used by Livingstone. An easily computed scalar inequality constraint, expressed in terms of sensed system variables, is used to determine the existence of sensor failures. In the event of sensor failure, an observer/estimator is used for determining which sensors have failed. The theory underlying the new approach is developed. Finally, a recommendation is made to use the Lyapunov-based approach to complement the capability of Livingstone and to use this combination in the RWGS process.

Haralambous, Michael G.↗
NASA NTRS2002

LYAPUNOV-Based Sensor Failure Detection and Recovery for the Reverse Water Gas Shift Process

Livingstone, a model-based AI software system, is planned for use in the autonomous fault diagnosis, reconfiguration, and control of the oxygen-producing reverse water gas shift (RWGS) process test-bed located in the Applied Chemistry Laboratory at KSC. In this report the RWGS process is first briefly described and an overview of Livingstone is given. Next, a Lyapunov-based approach for detecting and recovering from sensor failures, differing significantly from that used by Livingstone, is presented. In this new method, models used are in t e m of the defining differential equations of system components, thus differing from the qualitative, static models used by Livingstone. An easily computed scalar inequality constraint, expressed in terms of sensed system variables, is used to determine the existence of sensor failures. In the event of sensor failure, an observer/estimator is used for determining which sensors have failed. The theory underlying the new approach is developed. Finally, a recommendation is made to use the Lyapunov-based approach to complement the capability of Livingstone and to use this combination in the RWGS process.

Haralambous, Michael G.↗
NASA NTRS1995

SeaWiFS technical report series. Volume 27: Case studies for SeaWiFS calibration and validation, part 3

This document provides brief reports, or case studies, on a number of investigations sponsored by the Calibration and Validation Team (CVT) within the Sea-viewing Wide Field-of-view Sensor (SeaWiFS) Project. Chapter I describes a comparison of the irradiance immersion coefficients determined for several different marine environmental radiometers (MERs). Chapter 2 presents an analysis of how light absorption by atmospheric oxygen will influence the radiance measurements in band 7 of the SeaWiFS instrument. Chapter 3 gives the results of the second ground-based solar calibration of the instrument, which was undertaken after the sensor was modified to reduce the effects of internal stray light. (The first ground-based solar calibration of SeaWiFS is described in Volume 19 in the SeaWiFS Technical Report Series.) Chapter 4 evaluates the effects of ship shadow on subsurface irradiance and radiance measurements deployed from the deck of the R/V Weatherbird 11 in the Atlantic Ocean near Bermuda. Chapter 5 illustrates the various ways in which a single data day of SeaWiFS observations can be defined, and why the spatial definition is superior to the temporal definition for operational usage.

Hooker, Stanford B.↗
NASA NTRS2013

Optical Breath Gas Sensor for Extravehicular Activity Application

The function of the infrared gas transducer used during extravehicular activity in the current space suit is to measure and report the concentration of carbon dioxide (CO2) in the ventilation loop. The next generation portable life support system (PLSS) requires next generation CO2 sensing technology with performance beyond that presently in use on the Space Shuttle/International Space Station extravehicular mobility unit (EMU). Accommodation within space suits demands that optical sensors meet stringent size, weight, and power requirements. A laser diode spectrometer based on wavelength modulation spectroscopy is being developed for this purpose by Vista Photonics, Inc. Two prototype devices were delivered to NASA Johnson Space Center (JSC) in September 2011. The sensors incorporate a laser diode-based CO2 channel that also includes an incidental water vapor (humidity) measurement and a separate oxygen channel using a vertical cavity surface emitting laser. Both prototypes are controlled digitally with a field-programmable gate array/microcontroller architecture. The present development extends and upgrades the earlier hardware to the Advanced PLSS 2.0 test article being constructed and tested at JSC. Various improvements to the electronics and gas sampling are being advanced by this project. The combination of low power electronics with the performance of a long wavelength laser spectrometer enables multi-gas sensors with significantly increased performance over that presently offered in the EMU.

Wood, William R.↗