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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 307 records · Page 17

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NASA NTRS1986

Dry etching of beta-SiC in CF4 and CF4 + O2 mixtures

Dry etching of cubic (100) beta-SiC single-crystal thin films produced via chemical-vapor deposition (CVD) has been performed in CF4 and CF4 + O2 mixtures, in both the reactive-ion-etching (RIE) and plasma-etching modes. The latter process yielded measurable etch rates, but produced a dark surface layer which appears, from the results of secondary-ion mass spectrometry, to be residual SiC. The RIE samples had no residual layer, but Auger electron spectroscopy did reveal a C-rich surface. The optimal RIE conditions were obtained with 10 sccm of pure CF4 at 40 mtorr and a power density of 0.548 W/sq cm, giving an etch rate of 23.3 nm/min. Neither the increase of temperature between 293 and 573 K, nor the incremental addition of O2 to CF4 to 50 percent, produced any strong effect on the etch rates of SiC during RIE. Pictorial evidence of fine line structures produced by RIE of beta-SiC films are also presented.

Palmour, J. W.↗

NASA NTRS1986

Parametric tests of a 40-Ah bipolar nickel-hydrogen battery

A series of tests were performed to characterize battery performance relating to certain operating parameters which include charge current, discharge current, temperature, and pressure. The parameters were varied to confirm battery design concepts and to determine optimal operating conditions.

Cataldo, R. L.↗

NASA NTRS1986

On the polarization of Alpha Orionis

Much of the complex behavior of the polarization observed in the M2 supergiant Alpha Ori can be explained in terms of the combined effects of Rayleigh scattering in the photosphere and scattering by circumstellar dust in the presence of one or more photospheric hot spots. The ad hoc scattering layer of electrons which Schwarz and Clarke employed in their models reported in 1984 can be avoided, eliminating the conflict with the much lower column densities found in other studies of the extended chromosphere of this star. The transfer of polarized continuum radiation in cool model atmospheres has been treated fully. Under conditions of optimal spot area and location on the disk and large temperature differences (up to 1000 K) between the spot and normal photosphere, it is possible to get a net polarization up to about 0.3 percent in the blue in the direct starlight. The effects of spot limb darkening on the polarization of scattered spot light have been evaluated. Narrow-band observations that include molecular bands are encouraged for their diagnostic value.

Doherty, L. R.↗

NASA NTRS1986

Elevated temperature strengthening of a melt spun austenitic steel by TiB2

Mechanical properties of an iron-based alloy containing (by wt pct) 33Ni, 2Al, 6Ti, and 2B (resulting in an alloy containing 10 vol pct TiB2) were evaluated by hardness and tensile testing. The alloy was cast as a ribbon using a dual 'free-jet' variation of Jech et al. (1984) method of chill-block melt-spinning against a copper wheel; to simulate thermal cycles the alloy ribbon would experience during compaction into shapes, various segments of the ribbon were annealed under a vacuum at temperatures ranging from 500 to 1150 C. The results show that maximum strengths at 650 and 760 C were developed in ribbons annealed at 1100 C; in these ribbons an optimal combination of grain coarsening with minimum TiB2 particle growth was observed. However, the elevated-temperature strength of the TiB2-strengthened alloy under optimal annealing conditions was poorer than that of conventional iron-based superalloys strengthened by gamma-prime precipitates.

Michal, G. M.↗

NASA NTRS1987

Wheat production in controlled environments

Conditions are optimized for maximum yield and quality of wheat to be used in a controlled environment life support system (CELSS) in a Lunar or Martian base or a spacecraft. With yields of 23 to 57 g/sq m/d of edible biomass, a minimum size for a CELSS would be between 12 and 30 sq m per person, utilizing about 600 W/sq m of electrical energy for artificial light. Temperature, irradiance, photoperiod, carbon dioxide levels, humidity, and wind velocity are controlled in growth chambers. Nutrient solutions (adjusted for wheat) are supplied to the roots via a recirculating system that controls pH by adding HNO3 and controlling the NO3/NH4 ratio in solution. A rock-wool plant support allows direct seeding and densities up to 10,000 plants sq m. Densities up to 2000 plants/sq m appear to increase seed yield. Biomass production increases almost linearily with increasing irradiance from 400 to 1700 micromol/sq m/s of photosynthetic photon flux, but the efficiency of light utilization decreases over this range. Photoperiod and temperature both have a profound influence on floral initiation, spikelet formation, stem elongation, and fertilization.

Salisbury, Frank B.↗

NASA NTRS1987

Study of solid state photomultiplier

Available solid state photomultiplier (SSPM) detectors were tested under low-background, low temperature conditions to determine the conditions producing optimal sensitivity in a space-based astronomy system such as a liquid cooled helium telescope in orbit. Detector temperatures varied between 6 and 9 K, with background flux ranging from 10 to the 13th power to less than 10 to the 6th power photons/square cm-s. Measured parameters included quantum efficiency, noise, dark current, and spectral response. Experimental data were reduced, analyzed, and combined with existing data to build the SSPM data base included herein. The results were compared to analytical models of SSPM performance where appropriate models existed. Analytical models presented here were developed to be as consistent with the data base as practicable. Significant differences between the theory and data are described. Some models were developed or updated as a result of this study.

Hays, K. M.↗

NASA NTRS1988

Assessment and comparison of 100-MW coal gasification phosphoric acid fuel cell power plants

One of the advantages of fuel cell (FC) power plants is fuel versatility. With changes only in the fuel processor, the power plant will be able to accept a variety of fuels. This study was performed to design process diagrams, evaluate performance, and to estimate cost of 100 MW coal gasifier (CG)/phosphoric acid fuel cell (PAFC) power plant systems utilizing coal, which is the largest single potential source of alternate hydrocarbon liquids and gases in the United States, as the fuel. Results of this study will identify the most promising integrated CG/PAFC design and its near-optimal operating conditions. The comparison is based on the performance and cost of electricity which is calculated under consistent financial assumptions.

Lu, Cheng-Yi↗

NASA NTRS1989

Earth's early fossil record: Why not look for similar fossils on Mars?

The oldest evidence of life on Earth is discussed with attention being given to the structure and formation of stromatolites and microfossils. Fossilization of microbes in calcium carbonate or chert media is discussed. In searching for fossil remains on Mars, some lessons learned from the study of Earth's earliest fossil record can be applied. Certain sedimentary rock types and sedimentary rock configurations should be targeted for investigation and returned by the Martian rover and ultimately by human explorers. Domical, columnar to wavy laminated stratiform sedimentary rocks that resemble stromatolites should be actively sought. Limestone, other carbonates, and chert are the favored lithology. Being macroscopic, stromatolites might be recognized by an intelligent unmanned rover. In addition, black, waxy chert with conchoidal fracture should be sought. Chert is by far the preferred lithology for the preservation of microbes and chemical fossils. Even under optimal geological conditions (little or no metamorphism or tectonic alteration, excellent outcrops, and good black chert) and using experienced field biogeologists, the chances of finding well preserved microbial remains in chert are very low.

Awramik, Stanley M.↗

NASA NTRS1988

Metal with anomalously low Ni and Ge concentrations in the Allan Hills A77081 winonaite

The Ge content of metal in the Allan Hills A77081 winonaite was determined by high-sensitivity electron microprobe analysis. By optimizing analytical conditions for Ge determination, a detection limit of about 75 ppm could be achieved. In A77081 some small kamacite grains contain less Ni and Ge and more Co than coarse-grained metal. These small grains are always associated with sulfide, raising the possibility that anomalous metal is related to eutectic melting. However, when published partition coefficients for Ni and Ge in the Fe-Ni-S system are used to model fractionation of these elements during eutectic melting, one finds that secondary metal should be enriched in Ni and depleted in Ge. Thus, the positive Ni-Ge correlation found in this study is the opposite of the expected trend. No explanation for this discrepancy has yet been found. Nonetheless, the existence of anomalous metal is an indication that A77081, and probably other winonaites as well, have undergone some fractionation. This supports the notion that the high-temperature history of winonaites is related to the formation of IAB iron meteorites, whose silicate inclusions are very similar to winonaites.

Kracher, Alfred↗

NASA NTRS1990

H2, fixed architecture, control design for large scale systems

The H2, fixed architecture, control problem is a classic linear quadratic Gaussian (LQG) problem whose solution is constrained to be a linear time invariant compensator with a decentralized processing structure. The compensator can be made of p independent subcontrollers, each of which has a fixed order and connects selected sensors to selected actuators. The H2, fixed architecture, control problem allows the design of simplified feedback systems needed to control large scale systems. Its solution becomes more complicated, however, as more constraints are introduced. This work derives the necessary conditions for optimality for the problem and studies their properties. It is found that the filter and control problems couple when the architecture constraints are introduced, and that the different subcontrollers must be coordinated in order to achieve global system performance. The problem requires the simultaneous solution of highly coupled matrix equations. The use of homotopy is investigated as a numerical tool, and its convergence properties studied. It is found that the general constrained problem may have multiple stabilizing solutions, and that these solutions may be local minima or saddle points for the quadratic cost. The nature of the solution is not invariant when the parameters of the system are changed. Bifurcations occur, and a solution may continuously transform into a nonstabilizing compensator. Using a modified homotopy procedure, fixed architecture compensators are derived for models of large flexible structures to help understand the properties of the constrained solutions and compare them to the corresponding unconstrained ones.

Mercadal, Mathieu↗

NASA NTRS1989

Simulation and analysis of an intermediate frequency (IF) distribution system with applications for Space Station

Simulation and analysis results are described for a wideband fiber optic intermediate frequency distribution channel for a frequency division multiple access (FDMA) system where antenna equipment is remotely located from the signal processing equipment. The fiber optic distribution channel accommodates multiple signals received from a single antenna with differing power levels. Performance parameters addressed are intermodulation degradations, laser noise, and adjacent channel interference, as they impact the overall system design. Simulation results showed that the laser diode modulation level can be allowed to reach 100 percent without considerable degradation. The laser noise must be controlled as to provide a noise floor of less than -90 dBW/Hz. The fiber optic link increases the degradation due to power imbalance yet diminishes the effects of the transmit amplifier nonlinearity. Overall, optimal operation conditions can be found to yield a degradation level of about .1 dB caused by the fiber optic link.

Costello, Thomas A.↗

NASA NTRS1989

Correlation with a spatial light modulator having phase and amplitude cross coupling

In correlation filtering a spatial light modulators is traditionally modeled as affecting only the phase or only the amplitude of light. Usually, however, a single operating parameter affects both phase and amplitude. An integral constraint is developed that is a necessary condition for optimizing a correlation filter having single parameter coupling between phase and amplitude. The phase-only filter is shown to be a special case.

Juday, Richard D.↗

NASA NTRS1990

Soil bed reactor work of the Environmental Research Lab. of the University of Arizona in support of the research and development of Biosphere 2

Research at the Environmental Research Lab in support of Biosphere 2 was both basic and applied in nature. One aspect of the applied research involved the use of biological reactors for the scrubbing of trace atmospheric organic contaminants. The research involved a quantitative study of the efficiency of operation of Soil Bed Reactors (SBR) and the optimal operating conditions for contaminant removal. The basic configuration of a SBR is that air is moved through a living soil that supports a population of plants. Upon exposure to the soil, contaminants are either passively adsorbed onto the surface of soil particles, chemically transformed in the soil to usable compounds that are taken up by the plants or microbes as a metabolic energy source and converted to CO2 and water.

Frye, Robert↗

NASA NTRS1991

System characterization of positive real conditions

Necessary and sufficient conditions for positive realness in terms of state space matrices are presented under the assumption of complete controllability and complete observability of square systems with independent inputs. As an alternative to the positive real lemma and to the s-domain inequalities, these conditions provide a recursive algorithm for testing positive realness which result in a set of simple algebraic conditions. By relating the positive real property to the associated variational problem, a unified derivation of necessary and sufficient conditions for optimality of both singular and nonsingular problems is derived.

Wang, Q.↗

NASA NTRS1991

Charged particle LET-spectra measurements aboard LDEF

The linear energy transfer (LET) spectra of charged particles was measured in the 5 to 250 keV/micron (water) interval with CR-39 and in the 250 to 1000 keV/micron (water) interval with polycarbonate plastic nuclear track detectors (PNTDs) under different shielding depths in the P0006 experiment. The optimal processing conditions were determined for both PNTDs in relation to the relatively high track densities due to the long term exposure in space. The total track density was measured over the selected samples, and tracks in coincidence on the facing surfaces of two detector sheets were selected for measuring at the same position on each sheet. The Short Range (SR) and Galactic Cosmic Ray (GCR) components were measured separately. The integral dose and dose rate spectra of charged particles are also given. The high LET portion of the LET spectra was measured with high statistical accuracy. This is a unique result of this experiment due to the low flux of this type of particle under typical shielding conditions.

Csige, I.↗

NASA NTRS1990

Pt/SnO2-based CO-oxidation catalysts for CO2 lasers

The activity of Pt/SnO2-based CO-oxidation catalysts has been maximized by optimizing pretreatment conditions and catalyst formulation. The role of H2O in activating these catalysts and of CO2 retention in deactivating them has been determined as has the interaction of these catalysts with rare-isotope C(0-18) and (O-18)2.

Upchurch, Billy T.↗

NASA NTRS1991

The effect of microgravity on protein crystal growth

Based on the results of microgravity crystallization experiments using the protein canavalin aboard four separate U.S. Space Shuttle missions, visual observations and diffraction data are presented that support the contention that protein crystals of improved quality can be obtained in a microgravity environment. With canavalin, no significant increase in resolution was noted, but an overall improvement in diffraction quality, as judged by statistical analyses of the data, was clear. This improvement in quality may be due primarily to the elimination of defects and dislocations rather than an overall enhancement of order. The mechanism for this improvement may be microgravity-stabilized depletion zones that develop around growing crystals that establish and maintain optimal growth conditions more rapidly following nucleation. Such zones would be destroyed by convective flow effects in earth's gravity.

Mcpherson, Alexander↗

NASA NTRS1991

Toughening of PMR composites by semi-interpenetrating networks

Polymerization of monomer reactants (PMR-15) type polyimide and RP46 prepregs were drum wound using IM-7 fibers. Prepregging and processing conditions were optimized to yield good quality laminates with fiber volume fractions of 60 percent (+/- 2 percent). Samples were fabricated and tested to determine comprehensive engineering properties of both systems. These included 0 deg flexure, short beam shear, transverse flexure and tension, 0 deg tension and compression, intralaminar shear, short block compression, mode 1 and 2 fracture toughness, and compression after impact properties. Semi-2-IPN (interpenetrating polymer networks) toughened PMR-15 and RP46 laminates were also fabricated and tested for the same properties.

Tiwari, S. N.↗