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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 307 records · Page 17
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NASA NTRS1998

Effects of 1997-1998 El Nino on Tropospheric Ozone and Water Vapor

This paper analyzes the impact of the 1997-1998 El Nino on tropospheric column ozone and tropospheric water vapor derived respectively from the Total Ozone Mapping Spectrometer (TOMS) on Earth Probe and the Microwave Limb Scanning instrument on the Upper Atmosphere Research Satellite. The 1997-1998 El Nino, characterized by an anomalous increase in sea-surface temperature (SST) across the eastern and central tropical Pacific Ocean, is one of the strongest El Nino Southern Oscillation (ENSO) events of the century, comparable in magnitude to the 1982-1983 episode. The major impact of the SST change has been the shift in the convection pattern from the western to the eastern Pacific affecting the response of rain-producing cumulonimbus. As a result, there has been a significant increase in rainfall over the eastern Pacific and a decrease over the western Pacific and Indonesia. The dryness in the Indonesian region has contributed to large-scale burning by uncontrolled wildfires in the tropical rainforests of Sumatra and Borneo. Our study shows that tropospheric column ozone decreased by 4-8 Dobson units (DU) in the eastern Pacific and increased by about 10-20 DU in the western Pacific largely as a result of the eastward shift of the tropical convective activity as inferred from National Oceanic and Atmospheric Administration (NOAA) outgoing longwave radiation (OLR) data. The effect of this shift is also evident in the upper tropospheric water vapor mixing ratio which varies inversely as ozone (O3). These conclusions are qualitatively consistent with the changes in atmospheric circulation derived from zonal and vertical wind data obtained from the Goddard Earth Observing System data assimilation analyses. The changes in tropospheric column O3 during the course of the 1997-1998 El Nino appear to be caused by a combination of large-scale circulation processes associated with the shift in the tropical convection pattern and surface/boundary layer processes associated with forest fires in the Indonesian region.

Chandra, S.↗
NASA NTRS1994

TOMS total ozone data compared with northern latitude Dobson ground stations

Ozone measurements from the Total Ozone Mapping Spectrometer on the Nimbus 7 satellite are compared with ground-based measurements from five Dobson stations at northern latitudes to evaluate the accuracy of the TOMS data, particularly in regions north of 50 deg N. The measurements from the individual stations show mean differences from -2.5 percent up to plus 8.3 percent relative to TOMS measurements and two of the ground stations, Oslo and Longyearbyen, show a significant drift of plus 1.2 percent and plus 3.7 percent per year, respectively. It can be shown from nearly simultaneous measurements in two different wavelength double pairs at Oslo that at least 2 percent of the differences result from the use of the CC' wavelength double pair instead of the standard AD wavelength double pair. Since all Norwegian stations used the CC' wavelength double pair exclusively a similar error can be assumed for Tromso and Longyearbyren. A comparison between the tropospheric ozone content in TOMS data and from ECC ozonesonde measurements at Ny-Alesund and Bear Island shows that the amount of tropospheric ozone in the standard profiles used in the TOMS algorithm is too low, which leads to an error of about 2 percent in total ozone. Particularly at high solar zenith angles (greater than 80 deg), Dobson measurements become unreliable. They are up to 20 percent lower than TOMS measurements averaged over solar zenith angles of 88 deg to 89 deg.

Heese, B.↗
NASA NTRS2017

Altitude Registration of Limb-Scattered Radiation

One of the largest constraints to the retrieval of accurate ozone profiles from UV backscatter limb sounding sensors is altitude registration. Two methods, the Rayleigh scattering attitude sensing (RSAS) and absolute radiance residual method (ARRM), are able to determine altitude registration to the accuracy necessary for long-term ozone monitoring. The methods compare model calculations of radiances to measured radiances and are independent of onboard tracking devices. RSAS determines absolute altitude errors, but, because the method is susceptible to aerosol interference, it is limited to latitudes and time periods with minimal aerosol contamination. ARRM, a new technique introduced in this paper, can be applied across all seasons and altitudes. However, it is only appropriate for relative altitude error estimates. The application of RSAS to Limb Profiler (LP) measurements from the Ozone Mapping and Profiler Suite (OMPS) on board the Suomi NPP (SNPP) satellite indicates tangent height (TH) errors greater than 1 km with an absolute accuracy of +/-200 m. Results using ARRM indicate a approx. 300 to 400m intra-orbital TH change varying seasonally +/-100 m, likely due to either errors in the spacecraft pointing or in the geopotential height (GPH) data that we use in our analysis. ARRM shows a change of approx. 200m over 5 years with a relative accuracy (a long-term accuracy) of 100m outside the polar regions.

Ozone profiles↗
NASA NTRS2000

Merged Long-Term Data Sets from TOMS and SBUV Total Ozone Measurements

Total ozone has been measured by a series of nadir-viewing satellite instruments. These measurements begin with the Total Ozone Mapping Spectrometer (TOMS) and Solar Backscatter UltraViolet (SBUV) instruments on Nimbus 7, launched in late 1978. The measurements have continued with the Meteor 3 TOMS, Earth Probe TOMS, and NOAA 9,11,14 SBUV/2 instruments. The problem for producing a long-term data set is establishing the relative calibration of the various instruments to better than 1%. There was a nearly two year gap between the Meteor 3 TOMS and the Earth Probe TOMS. This gap is filled by the NOAA 9 and 11 SBUV/2 instruments, but they were in drifting orbits that result in effective gaps in the record when the equator crossing time occurs at large solar zenith angle. We have used recently re-derived calibrations of the SBUV instruments using the D-pair (306/313 nm wavelengths) data at the equator. These equatorial D-pair measurements should maintain the internal calibration of each instrument better than previous approaches. We then use the comparisons between instruments during their overlap periods to establish a consistent calibration over the entire data set. The resulting merged ozone data set is independent of the ground-based Dobson/Brewer network.

Stolarski, Richard↗
NASA NTRS2002

Chemistry-Transport Modeling of the Satellite Observed Distribution of Tropical Tropospheric Ozone

We have compared the 14-year record of satellite derived tropical tropospheric ozone columns (TTOC) from the NIMBUS-7 Total Ozone Mapping Spectrometer (TOMS) to TTOC calculated by a chemistry-transport model (CTM). An objective measure of error, based on the zonal distribution of TTOC in the tropics, is applied to perform this comparison systematically. In addition, the sensitivity of the model to several key processes in the tropics is quantified to select directions for future improvements. The comparisons indicate a widespread, systematic (20%) discrepancy over the tropical Atlantic Ocean, which maximizes during austral Spring. Although independent evidence from ozonesondes shows that some of the disagreement is due to satellite over-estimate of TTOC, the Atlantic mismatch is largely due to a misrepresentation of seasonally recurring processes in the model. Only minor differences between the model and observations over the Pacific occur, mostly due to interannual variability not captured by the model. Although chemical processes determine the TTOC extent, dynamical processes dominate the TTOC distribution, as the use of actual meteorology pertaining to the year of observations always leads to a better agreement with TTOC observations than using a random year or a climatology. The modeled TTOC is remarkably insensitive to many model parameters due to efficient feedbacks in the ozone budget. Nevertheless, the simulations would profit from an improved biomass burning calendar, as well as from an increase in NOX abundances in free tropospheric biomass burning plumes. The model showed the largest response to lightning NOX emissions, but systematic improvements could not be found. The use of multi-year satellite derived tropospheric data to systematically test and improve a CTM is a promising new addition to existing methods of model validation, and is a first step to integrating tropospheric satellite observations into global ozone modeling studies. Conversely,the CTM may suggest improvements to evolving satellite retrievals for tropospheric ozone.

Peters, Wouter↗
NASA NTRS2000

On the Long-Term Calibration of the TOMS Total Ozone Record

Comparison of Total Ozone Mapping Spectrometer (TOMS) data to the network of ground-based Dobson/Brewer measurements reveals difference in the time dependence of the calibration of the two systems. We have been searching for a method to determine the time dependence of the TOMS calibrations that is independent of the Dobson/Brewer network. In a separate paper by DeLand et al., calibrations of the Solar Backscatter UV Spectrometer (SBUV) instruments have been rederived using the D-pair (306/313 nm wavelengths) data at the equator. These calibrations have been applied to the data from the Nimbus 7 SBUV and the NOAA 9 and 11 SBUV/2 data to derive a new version 7 data set for each instrument. We have used these data to do a detailed comparison to the Nimbus 7 and Earth Probe TOMS data. Assuming that the D-pair establishes the correct calibration, these comparisons reveal some small calibration drifts (approximately 1%) in the TOMS data. They also reveal an offset in the D-pair calibration with respect to the Dobson network of approximately 8 Dobson units with the Dobson being lower than the D-pair. The D-pair calibration offsets have been used to create a merged ozone data set from TOMS with a calibration that has been determined independent of the Dobson/Brewer network. Trend analyses of these data will be presented and compared to trend analyses using the ground-based data.

Stolarski, Richard S.↗
NASA NTRSDate not supplied

Improved Assessment of Recent Trends in NOx and VOC Emissions and Ozone Production Sensitivity Regimes Using Satellite Data

This presentation highlights results from a NASA Aura Science Team and Atmospheric Composition Modeling and Analysis Program (ACMAP) project which study the capability to observe and model trends in ozone (O3) production regimes using spaceborne sensors. Ultraviolet– visible (UV–Vis) tropospheric column satellite retrievals of formaldehyde (HCHO) (a proxy for volatile organic compound [VOC] reactivity) and nitrogen dioxide (NO2) (a proxy for nitrogen oxides [NOx]) are frequently used to investigate the sensitivity of O3 production to emissions of NOx and VOCs. There are challenges that come from using satellite-derived ratios of HCHO and NO2 (FNR) to study O3 production sensitivity with the largest uncertainties associated with specific spaceborne sensor’s retrieval biases and errors. This study quantifies the differences and improvements in satellite retrievals of O3 production sensitivity regimes using FNRs when moving from legacy polar orbiting satellites such as the Ozone Monitoring Instrument (OMI) onboard NASA’s Aura satellite and Ozone Mapping and Profiler Suite Nadir Mapper (OMPS-NM) onboard the NASA/NOAA Suomi-NPP platform to newer, higher spatiotemporal resolution satellite sensors TROPOspheric Monitoring Instrument (TROPOMI) and eventually the recently launched NASA geostationary sensor Tropospheric Emissions: Monitoring of Pollution (TEMPO). Furthermore, we investigate how using retrievals of NO2 and HCHO from these different satellites to constrain model predictions impacts the ability to accurately simulate O3 chemistry including chemical production regimes. To this end, we have conducted inverse model simulations, using the WRF-CMAQ-DDM data assimilation system at 12 km × 12 km, to constrain emissions of NOx and VOCs over the contiguous United States (CONUS) when assimilating OMI and TROPOMI retrievals of NO2 and HCHO. Two advantages of this are that we a) account for each satellite’s errors/biases in the emission estimation and b) update the prior profile to ensure that only radiance information is used for optimizing the emissions. This presentation will demonstrate: a) the varying accuracy of different satellite retrieved FNRs and ability to capture known sub-annual emission trends (e.g., seasonal, weekend/weekday) and emission anomalies during the COVID-19 lockdown of 2020, b) the differences and improvements in top-down emission estimates of NOx and VOCs when constrained by newer satellite sensors compared to legacy systems, and c) multi-sensor optimized emission estimates of summer-time NOx and VOCs between 2019-2021.

Data↗
NASA NTRS1975

Satellite global monitoring of environmental quality

The missions of two NASA satellites for the monitoring of environmental quality are described: Nimbus G, the Air Pollution and Oceanographic Observing Satellite, and the Applications Explorer Mission (AEM) satellite to be used in the Stratospheric Aerosol and Gas Experiment (SAGE). The scientific payload of Nimbus G is described in detail with a discussion of limb infrared monitoring of the stratosphere, the stratospheric and mesospheric sounder, stratospheric aerosol measurement, the solar and backscatter UV spectrometer for ozone mapping, the earth radiation budget experiment, the scanning multichannel microwave radiometer, the coastal zone color scanner and the temperature-humidity infrared radiometer. A brief description is given of the SAGE program and future NASA plans relating to the global monitoring of environmental quality are outlined.

Schiffer, R. A.↗
NASA NTRS1975

Optical design of the SBUV/TOMS experiment on Nimbus G

The paper examines the tradeoffs performed in optimizing the optical design of the solar backscatter ultraviolet/total ozone mapping spectrometer (SBUV/TOMS) experiment on Nimbus G to stringent performance requirements within the limitations of the spacecraft interface. The SBUV portion of the experiment incorporates a double monochromator optimized for better than 1.0 A spectral resolution over the wavelength range 1600-4000 A. The TOMS portion of the experiment is a stepped line scanning system with a 105-deg total field of view. Special techniques are used to reduce the polarization sensitivity of the instrument to less than 5% for 100% linearly polarized incident radiation and to keep the spectral stray light to less than 0.000001 of the incident solar spectrum. Optical material selection is imperative in order to minimize the effects of fluorescence and phosphorescence arising from the bombardment of particulate radiation in space.

Henderson, B. D.↗
NASA NTRS1983

Exospheric cleaning of the Earth Radiation Budget solar radiometer during solar maximum

Anomalous behavior of the Earth Sensor Assemblies (ESA) had been observed on the Defense Meteorological Satellite Program (DMSP) 5D/1 satellites and the Tiros-N satellite. The present investigation is concerned with the reasons for the observed phenomena. Degradation of the Earth Radiation Budget (ERB) solar channels and the Solar Backscatter Ultraviolet and Total Ozone Mapping Spectrometer (SBUV/TOMS) diffuser plate is attributed to transmission or reflection loss originating from the growth of an organic film by photolytic polymerization. Simultaneous degradation of the ESA interference filter coated lenses facing the flight direction and the recovery of the ERB solar channels on Nimbus 6 and 7 is caused by a reaction with the increase in the exospheric atmospheric density caused by solar maximum.

Predmore, R. E.↗
NASA NTRS1983

Application of ultraviolet reflectivity measurements from Nimbus-7 to determine cloud amount

A technique is described that uses scene reflectivity derived from the Total Ozone Mapping Spectrometer (TOMS) measurements from aboard the Nimbus-7 satellite to improve the estimation of cloud amounts from the data taken by the Temperature Humidity IR Radiometer (THIR) onboard the same satellite. TOMS operates in six 1 nm wide spectral bands in the UV (380, 360, 340, 331, 318, and 313 nm) and provides information for inference of directional albedos. Moreover, the features of the TOMS images are paralleled with those obtained by the Geostationary Operational Environmental Satellite (GEOS) visible images. It is noted that by use of such a multisensor approach relatively thin or broken low clouds (below 2 km) can be detected with an rms error of about 10 percent when compared to the GOES visible and IR images.

Bhartia, P. K.↗
NASA NTRS1983

Nimbus-7 total ozone algorithm

The total ozone algorithm used for the processing of Nimbus-4 BUV measurements is modified to account for off-nadir viewing of the Total Ozone Mapping Spectrometer onboard Nimbus-7 satellite. TOMS is a cross-track scanning instrument with a 50 x 50-km field of view, increasing to 150 x 150 km at the extreme off-nadir angle of 51 deg and six spectral bands in the 310-380-nm region. Consideration is given to the determination of the pressure at the reflecting surface and profile selection scheme at very high solar zenith angles. The algorithm is also applicable to the Solar Backscattered UV Experiment aboard the same satellite. The modifications provide for a better cloud height, snow correction, and improved retrievals near the terminator.

Bhartia, P. K.↗
NASA NTRS1983

Cloud observations with Nimbus-7 satellite data

A Nimbus-7 Cloud Data Processing Team was established in 1982 in order to implement cloud-related studies for as long as the spacecraft's Temperature Humidity IR radiometer and Total Ozone Mapping Spectrometer continue to operate. It will soon be possible to correlate the Nimbus-7 cloud cover information with International Satellite Cloud Climatology results. The production of validated Nimbus-7 cloud products was scheduled to begin in November, 1983; each year of Nimbus-7 cloud data should take about four months to produce.

Stowe, L. L.↗
NASA NTRS1986

UV albedo of clouds from TOMS data

The Pilot Climate Data System (PCDS) was found to be useful in examining a subset of data from the Nimbus-7 Total Ozone Mapping Spectrometer (TOMS). The TOMS instrument scans with six channels between .3 and .4 micrometers. It was suggested that by analyzing albedo values from the longer wavelength channels of the TOMS, the effects of increasing optical depth could be determined. It is spectral relationship of albedo-to-optical depth that is investigated here. The question can be stated: Is there spectral differentiation in albedo with changes in the optical depth of clouds? Nimbus-7 TOMS data were obtained through the PCDS for an area and time period for which correlative NOAA AVHRR data were available. The AVHRR data were important in determining the existing cloud patterns. As expected, no spectral differentiation was observed at very high albedos (associated with high optical depths). However, at lower optical depths, evidence of spectral dependence on albedo was observed. Mapping the results geographically was deemed highly desirable but was not possible through the PCDS at the time. The PCDS can be viewed as an effective research tool to access selected portions of data. Without being intimately familiar with a data set, a PCDS user can successfully manipulate data in a scientific study.

Short, D.↗
NASA NTRS1986

Spatial and temporal characteristics of global cloud cover as observed from the Nimbus-7 satellite

The spatial and temporal characteristics of the total cloud amount (TCA) were determined on the bases of 2 yr of data collected by Nimbus-7. The instruments used were the 11.5 microns channel of the Temperature Humidity IR radiometer and the 0.38 micron channel of the Total Ozone Mapping Spectrometer. Comparisons were made between long-term averages and large variations during the El Nino/Southern Oscillation event of 1982/83. Separate attention was also given to the TCA for the Northern and Southern Hemispheres, and to TCA averages over specific large-scale global features such as deserts.

Stowe, L. L.↗
NASA NTRS1986

October Antarctic temperature and total ozone trends from 1979-1985

The morphology of temperature trends in the south polar stratosphere from 1979-1985 is detailed. A significant cooling has occurred in the stratosphere over this period. South polar October mean temperatures have declined 18 K at 24 km over the seven-year period. A large fraction of this decline occurs as a result of including 1979 temperatures in the trend. The years 1979 and 1982 differ from other years in that they include large mid-October wave events which produce significantly warmer polar temperatures. Nevertheless, a significant temperature decline has still occurred in the stratosphere even when the dynamically active years are not included. Comparing two relatively dynamically quiet years, 1980 and 1985, the largest temperature decrease in the 30 mb temperature field occurs not at the pole but in the subpolar temperature maximum centered near 60 deg S. The changes in temperature of both the maximum and the polar low regions correlate fairly well with total ozone changes observed by the Total Ozone Mapping Spectrophotometer.

Newman, Paul A.↗
NASA NTRS1987

Reflectivity of earth's surface and clouds in ultraviolet from satellite observations

The Total Ozone Mapping Spectrometer on board Nimbus 7 is used to infer the UV surface and cloud reflectance at 370 nm. Cloudless surface reflectivity was analyzed on a global basis for all surface types for several months. The UV surface reflectivity varies from 2 percent for some forest and grassland regions to 14 percent for some sandy desert areas. A notable exception is the large salt flats of Bolivia, which have a reflectivity of about 60 percent. Cloud reflectivity was also analyzed for clouds located at three levels in the atmosphere, as determined by the 11.5 micron channel of the Temperature Humidity Infrared Radiometer. Average cloud reflectivity at 370 nm ranges from 52 percent for low clouds (tops less than 2 km) to 76 percent for high clouds (tops greater than 7 km at the equator, decreasing to greater than 4 km at poles).

Eck, T. F.↗
NASA NTRS1987

Scientific and Operational Requirements for TOMS Data

Global total ozone and sulfur dioxide data from the Nimbus 7 Total Ozone Mapping Spectrometer (TOMS) instrument have applications in a broad range of disciplines. The presentations of 29 speakers who are using the data in research or who have operational needs for the data are summarized. Five sessions addressed topics in stratospheric processes, tropospheric dynamics and chemistry, remote sensing, volcanology, and future instrument requirements. Stratospheric and some volcanology requirements can be met by a continuation of polar orbit satellites using a slightly modified TOMS but weather related research, tropospheric sulfur budget studies, and most operational needs require the time resolution of a geostationary instrument.

Krueger, Arlin J.↗