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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 307 records · Page 17
All sourcesNASA NTRSDOE OSTI
DOE OSTI2019

A computational model for nanosecond pulse laser-plasma interactions

A multi-physics numerical model for laser-induced optical breakdown and laser-plasma interaction in a non-equilibrium gas is presented, accounting for: production of priming electrons via multi-photon ionization, energy absorption, cascade ionization, induced hydrodynamic response, and shock formation and propagation. The gas is governed by the Navier-Stokes equations, with non-equilibrium effects taken into account by means of a two-temperature model. The space-time dependence of the laser beam is modeled with a flux-tube formulation for the Radiative Transfer Equation. The flow governing equations are discretized in space using a second-order finite volume method. The semi-discrete equations are marched in time using an implicit-explicit (IMEX) dual time-stepping strategy, where diffusion and chemistry are solved implicitly, whereas convection is explicit. Application to a 20 ns long 50 mJ pulse laser-induced breakdown in quiescent O 2 shows the advantages of this temporal discretization during and just after the laser pulse, while a less-expensive symmetric Strang splitting (with implicit chemistry) is sufficient for the post-breakdown gas dynamics after ≃ 0.1 μs. The integrated model is shown to reproduce key features of corresponding experiments.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2023

Plasmon Mediated Near–Field Energy Transfer From Solid–State, Electrically Injected Excitons to Solution Phase Chromophores

An organic diode is demonstrated that near-field energy transfers to molecules in solution via surface plasmon polaritons, in contrast to typical far-field excitation via absorption of traveling photons. Electrically generated excitons couple to surface plasmon modes in the cathode; the plasmons subsequently excite chromophore molecules on top of the cathode. External quantum efficiency and time resolved photoluminescence measurements are used to characterize the diode and the near-field energy transfer process. In addition, it is shown that excited chromophores can charge-transfer to quencher molecules, illustrating the potential of this device to be used for photochemical applications.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2024

Unveiling the Structural Origins of Dynamic Diversity in Pd-Based Metallic Glasses

The β -relaxation is one of the major dynamic behaviors in metallic glasses (MGs) and exhibits diverse features. Despite decades of efforts, the understanding of its structural origin and contribution to the overall dynamics of MG systems is still unclear. Here two palladium-based Pd—Cu—P and Pd—Ni—P MGs are reported with distinct different β -relaxation behaviors and reveal the structural origins for the difference using the advanced X-ray photon correlation spectroscopy and absorption fine structure techniques together with the first-principles calculations. The pronounced β -relaxation and fast atomic dynamics in the Pd—Cu—P MG mainly come from the strong mobility of Cu atoms and their locally favored structures. In contrast, the motion of Ni atoms is constrained by P atoms in the Pd—Ni—P MG, leading to the weakened β -relaxation peak and sluggish dynamics. Finally, the correlation of atomic dynamics with microscopic structures provides a way to understand the structural origins of different dynamic behaviors as well as the nature of aging in disordered materials.

36 MATERIALS SCIENCE↗
DOE OSTI2025

Growth of tetragonal PtO by molecular-beam epitaxy and its integration into β-Ga 2 O 3 Schottky diodes

We demonstrate the epitaxial growth of tetragonal platinum monoxide (PtO) on MgO, TiO 2 , and β-Ga 2 O 3 single-crystalline substrates by ozone molecular-beam epitaxy. We provide synthesis routes and derive a growth diagram under which PtO films can be synthesized by physical vapor deposition. A combination of electrical transport and photoemission spectroscopy measurements, in conjunction with density functional theory calculations, reveal PtO to be a degenerately doped p-type semiconductor with a bandgap of E g ≈ 1.6 eV. Spectroscopic ellipsometry measurements are used to extract the complex dielectric function spectra, indicating a transition from free-carrier absorption to higher photon energy transitions at E ≈ 1.6 eV. Using tetragonal PtO as an anode contact, we fabricate prototype Schottky diodes on n-type Sn-doped β-Ga 2 O 3 substrates and extract Schottky barrier heights of ϕ B > 2.2 eV.

Hensling, Felix V. E. [Cornell Univ., Ithaca, NY (↗
DOE OSTI2020

Mixed-strategy approach to band-edge analysis and modeling in semiconductors

In semiconductor physics, the Urbach rule describes an exponential dependence of the UV-Vis absorption coefficient on photon energy at the band edge. The rule is so ubiquitously applied that a single common mechanism, variability in the local potential, is generally considered to be the cause of exponential band edges. Variability in the local potential may be caused by alloy inhomogeneity, structural defects, impurities, thermal excitation, or any other mechanism that interrupts ideal crystallinity and creates disorder. A crucial point of the Urbach rule is its development for band edges which approach linearity when plotted on a logarithmic scale. The rule was not developed in the context of nonlinear band edges with complex fine structure. Even so, this model has been applied extensively to band edges with such features. Using differential analysis and deconvolution, we develop an analytical technique capable of separating the components responsible for the fine structure observed. This approach reduces challenging signal-artifact convolution problems to a simple linear combination. Furthermore, we develop a model that can be applied to the nonlinear band-edge signals extracted. In this work, we show that in the limiting case of linearity, our model is consistent with and produces the same results as the linear Urbach model. Our model is capable of bypassing “tailing” as an indirect measure of the spread in the local potential and gives a direct measure of this quantity.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
NASA NTRS1972

Bremsstrahlung in the atmosphere.

Results of calculations concerning the emission of bremsstrahlung by electrons in the upper atmosphere and the penetration of this radiation to atmospheric depths of 3 to 10 g/sq cm, where it can be measured by balloon-borne detectors. The calculations take into account the multiple scattering and slowing down of electrons, and the multiple Compton scattering and photoelectric absorption of bremsstrahlung photons. Numerical data have been generated for electron beams incident onto the atmosphere with energies between 20 keV and 2 MeV, assuming wide-area precipitation and an incident angular distribution isotropic over the downward hemisphere. The results relate the number and energy spectrum of the incident electrons to the bremsstrahlung flux spectrum at balloon heights. The interpretation of some observed bremsstrahlung flux spectra is attempted.

Berger, M. J.↗
NASA NTRS1974

Two new physical processes in the far-ultraviolet spectrum of zeta Tauri

We have detected absorption features in the far-ultraviolet spectrum of zeta Tau (B3pe), one of which corresponds to a new transition involving quasi-H/-/, and the other to a transition involving quasi-H2/+/. The former transition produces a broad absorption feature on the red wing of L-alpha. It is the result of the absorption of a photon by a ground-state hydrogen atom and colliding electron, and it leads to the excitation of both electrons to the 2p2 3Pe state of H/-/.

Heap, S. R.↗
NASA NTRS1976

Components in interstellar molecular hydrogen

Results are reported for precise spectrophotometric measurements of the profiles of selected Lyman absorption lines produced by hydrogen molecules in various rotational levels along the line of sight to 13 stars which have shown some evidence for an increase in line width with increasing rotational quantum number (J). The line profiles were measured by multiple scans with the Copernicus satellite telescope. Based on analysis of the radial velocities, derivations of the column densities, and line-profile fitting, the following conclusions are made: (1) the increase in interstellar H2 line width with increasing J results from the presence of the most shortward component, which is relatively weak at low J but becomes more important at higher J; (2) the relative column densities found for the different J levels in each component may be fitted by a theoretical model in which rotational excitation is due to absorption of UV photons followed by radiative quadrupole spontaneous transitions or collisionally induced downward transitions between different J levels; (3) the atomic hydrogen density is between 300 and 1000 per cu cm in the most shortward component for each of three stars; (4) the approaching gas which produces each shortward component must be in the form of thin sheets; and (5) the sheets are the compressed gas behind a shock front moving through the interstellar medium.

Spitzer, L., Jr.↗
NASA NTRS1981

Far wing depolarization of light - Generalized absorption profiles

An absorption (and/or emission) event which takes place during a strong collision is called a 'correlated event'. It is discussed how correlated events affect the far red wing depolarization of fluorescence. Attention is given to an atomic vapor which is irradiated by linearly polarized light of a frequency on the red side of the resonance line. Two limiting cases are considered, corresponding to excitation in the impact region and in the quasi-static wing. In the quasi-static wing, absorption of a photon followed by fluorescence (rather than Rayleigh scattering), occurs mostly during a collision. Correlated events dominate the scattering process. Expressions derived for the polarization of the fluorescent light are applied to far red wing depolarization. It is found that the polarization of the fluorescent light does not go to zero in the far wing, but depends crucially on the detailed nature of the anisotropy in the long-range part of the interatomic potential.

Thomann, P.↗
NASA NTRS1982

Shuttle lidar resonance fluorescence investigations. I - Analysis of Na and K measurements. II - Analysis of thermospheric Mg/+/ measurements

Optical radar systems (lidar) have a number of advantages compared to passive techniques with respect to applications involving the measurement of alkali atoms (Na and K) in the atmosphere. By using Shuttle-borne optical radar systems, analytical capabilities can be extended to cover wider geographic areas. One of the objectives of the present investigation is to assess the performance and application of a recently defined Shuttle optical radar system for the measurements of sodium and potassium in the 80-110-km region. A second objective is related to a study of the effects of high-intensity laser beams on the optical radar measurements, giving particular attention to the saturation in the atomic absorption of laser photons. A numerical simulation is conducted of the measurements of magnesium ions (Mg/+/) over the 80-500-km altitude range using recently defined Shuttle optical radar system parameters to study the performance of such a system.

Yeh, S.-D.↗
NASA NTRS1984

Evidence for an infrared disk in the core of the extraordinary planetary nebula Abell 30

High spatial resolution infrared maps of the core of the evolved planetary nebula Abell 30, which has been shown to be composed of heavily processed material, are presented. These maps reveal an elongated, disklike structure that is not evident on optical pictures. Multicolor photometry at several positions in this disk shows that this emission is due to dust, some of which is near the evaporation temperature of graphite. Lyman-alpha trapping is shown to be inadequate as a heating source for these grains, but direct absorption of stellar photons is sufficient. In view of the unusual chemical composition, A30 represents a late stage in the evolution of a planetary nebula progenitor. The observed infrared structure may provide clues to the ejection mechanism at this stage of development.

Lester, D. F.↗
NASA NTRS1984

The nitrogen cycle: Atmosphere interactions

Atmospheric interactions involving the nitrogen species are varied and complex. These interactions include photochemical reactions, initiated by the absorption of solar photons and chemical kinetic reactions, which involve both homogeneous (gas-to-gas reactions) and heterogeneous (gas-to-particle) reactions. Another important atmospheric interaction is the production of nitrogen oxides by atmospheric lightning. The nitrogen cycle strongly couples the biosphere and atmosphere. Many nitrogen species are produced by biogenic processes. Once in the atmosphere nitrogen oxides are photochemically and chemically transformed to nitrates, which are returned to the biosphere via precipitation, dry deposition and aerosols to close the biosphere-atmosphere nitrogen cycle. The sources, sinks and photochemistry/chemistry of the nitrogen species; atmospheric nitrogen species; souces and sinks of nitrous oxide; sources; sinks and photochemistry/chemistry of ammonia; seasonal variation of the vertical distribution of ammonia in the troposphere; surface and atmospheric sources of the nitrogen species, and seasonal variation of ground level ammonia are summarized.

Levine, J. S.↗
NASA NTRS1985

The solar spectral irradiance between 150 and 200 nm

The absorption of solar photons controls the composition of the middle atmosphere. Concern about the effects of man's industrial activities on his environment has led to a number of long-term programs related to stratospheric photochemistry. An important part of these programs represents studies of the variability of the sun's solar spectral irradiance. A program to measure the solar ultraviolet flux, both within and outside the earth's atmosphere, has been in progress for a number of years. This program has the objective to develop techniques which would provide an absolute accuracy of at least 5 percent. The amount of satellite instrument degradation is determined on the basis of a comparison of data provided by these instruments with data obtained in connection with rocket flights. It was found that a significant decrease in the solar irradiance below 190 nm occurred between 1980 and 1981.

Mentall, J. E.↗
NASA NTRS1983

Kinetic modeling of an IBr solar pumped laser

The possibility of using an IBr laser as a solar-energy converter is examined theoretically, and reasons for its choice are given. Broadband absorption results in dissociation with the formation of excited metastable Br atoms, some of which then lase to the ground state Br. The ground state is depopulated by three-body recombination and, more importantly, by exchange reactions which more than compensate for the high quenching in heteronuclear halogen systems. Kinetic modeling indicates lasing is possible in the pulsed mode and possibly in the steady state with a cooled gas flow system. Temperature effects are discussed. The efficiency of the laser approaches 1.2 percent at optical thicknesses large enough for complete absorption of the photons.

Harries, W. L.↗
NASA NTRS1986

Saturation and beaming in astrophysical masers. III - Asymmetrically pumped masers

There is reason to believe that the physical conditions in many astrophysical masers are far from homogeneous. In particular, if the maser pump involves the absorption of infrared photons, the pump rate may vary rapidly (perhaps exponentially) across the cloud. The consequences of such variation of the pump rate for the maser radiation are calculated, and it is shown that there are substantial asymmetries in the output of the maser. A general result is that the maser radiation is preferentially emitted back toward the source of pump radiation. The implication of this result for the interpretation of the circumstellar 1612 MHz OH masers is briefly discussed.

Alcock, C.↗
NASA NTRS1987

Infrared emission and excitation in LMC HII regions

The infrared excess (IRE) of the Large Magellanic Cloud (LMC) HII nebulae is found to correlate positively with the temperature of the ambient radiation field or with the He(+)/H(+) abundance ratio. This result is discussed in terms of a selective absorption of the photons in the range 504 to 912 A relative to the He ionizing photons. This interpretation may explain the paradox of finding highly excited nebulae with only relatively moderate equivalent width of their Balmer lines.

Ungerer, V.↗