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In microgravity combustion, heat loss due to radiation plays a large role. Combustion products are able to accumulate in the flame region and radiate heat, while the heat release from the flame remains relatively constant. This causes the flame temperature to decrease until combustion can no longer be sustained, a phenomenon known as radiative extinction.
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MS&T22, Pittsburgh PA, October 8-12, 2022
With the growing interest in ammonia as a carbon-free fuel, numerous recent research efforts on fundamental combustion characteristics of ammonia have been reported. Despite this attention, there remain fundamental aspects that lack experimental investigation or validated chemical kinetic models. Specifically, the understanding of ammonia flame structure and the quantification of extinction limits at elevated pressures are incomplete. Furthermore, the chemistry of NOx in relation to ammonia flames has not been thoroughly examined, especially at pressure, and it is useful to explore the operating conditions that exhibit favorable flame stability with minimal NOx formation. In the current work, key characteristics of ammonia/air combustion, including strain-induced extinction limits and NO* chemiluminescence, are experimentally investigated over a wide range of equivalence ratios and pressures. This paper presents initial results in a study directed to improved comprehension of ammonia combustion chemistry, and acquisition of new datasets under elevated pressure and temperature conditions, to better refine rate expressions for important reactions in ammonia combustion.
We have investigated the effect of pressure on Se-doped Eu{sub 2}SrBi{sub 2}S{sub 4}F{sub 4} and EuSr{sub 2}Bi{sub 2}S{sub 4}F{sub 4} at S sites. We report the electrical resistivity measurements under hydrostatic pressure (P) ~ 3 GPa and ~ 2.5 GPa on Eu{sub 2}SrBi{sub 2}S{sub 4−y}Se{sub y}F{sub 4} [dT{sub c}/dP ~ 1.68 K/GPa (x = 2)] and EuSr{sub 2}Bi{sub 2}S{sub 4−x}Se{sub x}F{sub 4} [dT{sub c}/dP ~ 1.57 K/GPa (x = 1.5) and 1.74 K/GPa (x = 2)] respectively. Pressure-induced superconductivity has been observed in EuSr{sub 2}Bi{sub 2}S{sub 2.5}Se{sub 1.5}F{sub 4} with T{sub c} of 2.42 K at 0.12 GPa and the T{sub c} increases with further application of P up to 3 GPa (dT{sub c}/dP ~ 1.12 K/GPa) and maximum T{sub c} of ~ 8 K is observed for EuSr{sub 2}Bi{sub 2}S{sub 2}Se{sub 2}F{sub 4.} These results corroborate the behavior of this material under high pressure magnetization studies. Further, the metallic nature is observed for EuSr{sub 2}Bi{sub 2}S{sub 2.5}Se{sub 1.5}F{sub 4}, EuSr{sub 2}Bi{sub 2}S{sub 2}Se{sub 2}F{sub 4}, and Eu{sub 2}SrBi{sub 2}S{sub 2}Se{sub 2}F{sub 4} compositions and it is slightly suppressed with the application of pressure. Pressure effect on upper critical field H{sub c2}(0) is estimated from magnetic field–dependent ρ(T) measurements and it is found to be higher for all compositions than parent compound. The field-dependent thermal activation energy (μ{sub 0}/k{sub B}) is calculated from Arrhenius plot using ρ(T) and designates a robust flux pinning potential which might be co-existing with applied magnetic field and pressure.
In recent years, investigations of the phase transition behavior of semiconducting nanoparticles under high pressure has attracted increasing attention due to their potential applications in sensors, electronics, and optics. However, current understanding of how the size of nanoparticles influences this pressure-dependent property is somewhat lacking. In particular, phase behaviors of semiconducting CdS nanoparticles under high pressure have not been extensively reported. Therefore, in this work, CdS nanoparticles of different sizes are used as a model system to investigate particle size effects on high-pressure-induced phase transition behaviors. In particular, 7.5, 10.6, and 39.7 nm spherical CdS nanoparticles are synthesized and subjected to controlled high pressures up to 15 GPa in a diamond anvil cell. Analysis of all three nanoparticles using in-situ synchrotron wide-angle X-ray scattering (WAXS) data shows that phase transitions from wurtzite to rocksalt occur at higher pressures than for bulk material. Bulk modulus calculations not only show that the wurtzite CdS nanomaterial is more compressible than rocksalt, but also that the compressibility of CdS nanoparticles depends on their particle size. Furthermore, sintering of spherical nanoparticles into nanorods was observed for the 7.5 nm CdS nanoparticles. Our results provide new insights into the fundamental properties of nanoparticles under high pressure that will inform designs of new nanomaterial structures for emerging applications.
The topic of atmospheric effects on crater formation is very complex because it includes not only pressure effects on excavation, but also drag effects on ejecta placement. Experiments have to be designed very carefully to allow isolation of the two phenomena. Historically, numerous investigators have shown an influence of atmospheric pressure. However, none have identified the scaling that correctly isolates pressure from drag effects. On-going work in explosive cratering has produced scaling paradigms for deeply buried explosive charges where drag effects are negligible. Here it was found that increased pressure caused significant induced strength effects that impeded crater excavation. The effect is more pronounced with increasing burial depth and less pronounced with increased yield.
Abstract not provided
Abstract Geothermal energy plays a vital role in decarbonizing electricity and heat supply. Effective utilization of geothermal resources hinges on identifying or generating permeable reservoir zones and understanding how effective pressure variations affect fluid circulation and reservoir properties by poroelastic deformation. Hydrothermal alteration can modify the petrophysical properties of geothermal reservoir rocks, which may increase or decrease its productivity. Understanding these alteration effects is essential to predict and optimize long‐term sustainable geothermal operations. Here, we investigate the impact of hydrothermal alteration on poroelastic and hydraulic properties of diverse lithologies in a series of deformation tests performed at several confining (0–80 MPa) and pore pressure (10–30 MPa) levels. Experimental results of hydrothermally altered dikes and phyllites obtained from the Blue Mountain geothermal field (Nevada, USA) are compared to thermally cracked La Peyratte granite (France) and correlated with petrophysical properties, mineral composition, and microstructures. Argillic alteration of dikes increases porosity and storage capacity but lowers thermal conductivity and increases pore compressibility. Conversely, silicate precipitation in phyllites increases stiffness and thermal conductivity but also reduces porosity and permeability. Experimentally determined effective pressure coefficients range from 0.1 to 0.9, differ for permeability and volumetric strain and decrease with increasing effective pressure. The presence of compliant microcracks and crack‐like pores significantly increases the stress sensitivity of La Peyratte granite and silicified phyllites. This study demonstrates how thermal and chemical alteration impacts poromechanical and petrophysical characteristics of geothermal targets, which ultimately govern reservoir stability and subsidence, induced seismicity as well as fluid and heat extraction efficiency during geothermal operations.
This paper presents the results of experimental and theoretical studies of the effects of pressure and thermal annealing on the photo-conversion efficiencies (PCEs) of polymer solar cells with active layers that consist of a mixture of poly(3-hexylthiophene-2,5-diyl) and fullerene derivative (6,6)-phenyl-C 61 -butyric acid methyl ester. The PCEs of the solar cells increased from ~2.3% (for the unannealed devices) to ~3.7% for devices annealed at ~150 °C. A further increase in thermal annealing temperatures (beyond 150 °C) resulted in lower PCEs. Further improvements in the PCEs (from ~3.7% to ~5.4%) were observed with pressure application between 0 and 8 MPa. However, a decrease in PCEs was observed for pressure application beyond 8 MPa. The improved performance associated with thermal annealing is attributed to changes in the active layer microstructure and texture, which also enhance the optical absorption, mobility, and lifetime of the optically excited charge carriers. The beneficial effects of applied pressure are attributed to the decreased interfacial surface contacts that are associated with pressure application. The implications of the results are then discussed for the design and fabrication of organic solar cells with improved PCEs.
The effects of pressure on the structure and electrical transport properties, including electrical resistance and critical magnetic field values for superconductivity in pristine and hydrogenated TiZr alloys, were investigated. As pressure increased from ambient to 55 GPa, the structure of the pristine TiZr alloys transformed from hcp to bcc via an intermediate ω phase. The superconducting transition temperature (T c ) significantly increased from 1.76 K at ambient pressure to 15.5 K at 52.2 GPa, accompanied by an extrapolated upper critical field of 24.5 T at T = 0 K. In contrast, the hydrogenated samples exhibited substantially lower T c values compared to the pristine ones, with a T c of 4.6 K at 50.5 GPa and an extrapolated upper critical field of 1.8 T at T = 0 K. Upon decompression, the superconductivity in the hydrogenated sample persisted down to 25 GPa, disappearing when the pressure was reduced to 19 GPa. Synchrotron X-ray diffractions (XRD) analysis revealed the formation of three hydrides: I4/mmm-(Ti, Zr)H 2 , P6 3 /mmc-(Ti, Zr)H 3 , and I4̅3d-(Ti,Zr) 4 H 15 . Finally, by combining XRD and electrical resistance data, we tentatively propose that the P6 3 /mmc-(Ti, Zr)H 3 predominantly induces superconductivity. In contrast to superhydrides, where electron–phonon interactions increase the superconducting temperature at high pressure, hydrogen atoms in hcp-(Ti, Zr)H 3 reduce T c .
The effects of pressure on single crystals of Cr-doped gallium oxide (β-Ga 2 O 3 :Cr 3+ ) and aluminum gallium oxide [(Al 0.1 Ga 0.9 ) 2 O 3 ] were examined by measuring the wavelength shift in the spectral R lines. Photoluminescence (PL) spectra of these materials were collected from samples in diamond anvil cells at pressures up to 9 GPa. The β-Ga 2 O 3 :Cr 3+ R lines were found to shift linearly under hydrostatic pressure. The (Al 0.1 Ga 0.9 ) 2 O 3 R lines also show a linear shift but the R 1 line shifted less than for β-Ga 2 O 3 :Cr 3+ . The ratio of R 2 to R 1 peak areas vs pressure is dominated by nonradiative recombination. X-ray diffraction measurements of (Al 0.1 Ga 0.9 ) 2 O 3 indicate that its equation of state is similar to that of β-Ga 2 O 3 . β-Ga 2 O 3 :Cr 3+ was examined under non-hydrostatic conditions by using mineral oil as a pressure transmitting medium. Similar to the case in ruby, the R 1 line is much more sensitive to non-hydrostatic stress than R 2 . Spatially resolved PL of a sample at 8 GPa in mineral oil showed significant variations in the R 1 emission wavelength. Furthermore, these results suggest that the R 1 line can serve as a sensitive probe of alloy composition and non-hydrostatic stress, while the R 2 line is insensitive to these perturbations.
Ignition analysis of condensed phase fuel suddenly exposed to stationary hot oxidizing gas, noting strong pressure effect due to feedback mechanism
Abstract not provided
High oxygen at reduced pressure effect on metabolism of radioactive acetate in rats
Expressions for thermal deflections of uniform thin beams and plates exposed to solar heating are obtained as a function of the properties of the material and the solar incidence angle. The major effect of the solar radiation pressure interacting with the thermally deformed structure is found to give rise to disturbance moments on the structure. The thermal deformations of the structures are assumed to be within 0.1 percent of the characteristic length of the structure. With the assumed thermal deformations, the resulting uncontrolled transient responses of these geosynchronous orbiting structures to the solar radiation pressure induced disturbances are simulated. The resulting rigid modal oscillations are found to be an order of magnitude larger than for those cases previously considered in which only the solar radiation pressure effect on vibrating structures was treated. Modifications of control laws and/or the feedback gain values are considered in order to improve the transient response characteristics under the thermally induced disturbances.
The method of laser photolysis/laser-induced fluorescence is used to obtain absolute rate constants for CN radical reactions with HCN and C2N2. The rate constants were found to be temperature-dependent in the range 300-740 K and pressure independent in the range 100-600 Torr. Rice-Remsperger-Kassel-Marcus theory for both reactions employing the transition state parameters obtained by the BAC-MP4 method are made. These calculations yielded reasonable results for the CN + HCN reaction, predicting both the temperature dependence and pressure independence. No pressure effect was observed in the pressure range 100-1000 Torr at temperatures below 900 K, confirming the experimental results.