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At least 307 records · Page 17

Nanoscopic strain evolution in single-crystal battery positive electrodes

Single-crystal Ni-rich layered oxides (SC-NMC) with a grain-boundary-free configuration have effectively addressed the long-standing cracking issue of conventional polycrystalline Ni-rich materials (PC-NMC) in lithium-ion batteries, prompting a shift in optimization strategies. However, continued reliance on anisotropic lattice volume change—a well-established failure indicator in PC-NMC—as a metric for understanding strain and guiding compositional design for SC-NMC becomes controversial. Here, in this study, by leveraging multiscale diagnostic techniques, we unravelled the distinct nanoscopic strain evolution in SC-NMC during battery operation, challenging the conventional composition-driven strategies and mechanical degradation indicators used for PC-NMC. Through particle-level chemomechanical analysis, we reveal a decoupling between mechanical stability and lattice volume change in SC-NMC, identifying that structural instability in SC materials is primarily driven by multidimensional lattice distortions induced by kinetics-driven reaction heterogeneity and progressively deactivating chemical phases. Using this mechanical failure mode, we redefine the roles of cobalt and manganese in maintaining mechanical stability. Unlike cobalt’s detrimental role in PC-NMC, we find cobalt to be critical in enhancing the longevity of SC-NMC by mitigating localized strain along the extended diffusion pathway, whereas manganese exacerbates mechanical degradation.

36 MATERIALS SCIENCE↗

Arabidopsis trigalactosyldiacylglycerol1 mutants reveal a critical role for phosphtidylcholine remodeling in lipid homeostasis

Lipid remodeling plays a critical role in plant response to abiotic stress and metabolic perturbations. Key steps in this process involve modifications of phosphatidylcholine (PC) acyl chains mediated by lysophosphatidylcholine: acyl-CoA acyltransferases (LPCATs) and phosphatidylcholine: diacylglycerol cholinephosphotransferase (ROD1). To assess their importance in lipid homeostasis, we took advantage of the trigalactosyldiacylglycerol1 (tgd1) mutant that exhibits marked increases in fatty acid synthesis and fatty acid flux through PC due to a block in inter-organelle lipid trafficking. Here, we showed that the increased fatty acid synthesis in tgd1 is due to posttranslational activation of the plastidic acetyl-coenzyme A carboxylase. Genetic analysis showed that knockout of LPCAT1 and 2 resulted in a lethal phenotype in tgd1. In addition, plants homozygous for lpcat2 and heterozygous for lpcat1 in the tgd1 background showed reduced levels of PC and triacylglycerols (TAG) and alterations in their fatty acid profiles. We further showed that disruption of ROD1 in tgd1 resulted in changes in fatty acid composition of PC and TAG, decreased leaf TAG content and reduced seedling growth. Combined, our results reveal a critical role of LPCATs and ROD1 in maintaining cellular lipid homeostasis under conditions, in which fatty acid production largely exceeds the cellular demand for membrane lipid synthesis.

59 BASIC BIOLOGICAL SCIENCES↗

The effect of dietary supplementation of Lycium barbarum leaves on the growth performance, organ indexes and intestinal microflora of rats

This study was conducted to investigate both fruit and different levels of leaf supplementation on the growth performance, organ indices and intestinal microflora of rats. Twenty-five healthy male Sprague–Dawley rats were randomly divided into five groups. The rats in the control (NC) and positive control (PC) groups were fed by gavage a basal diet and a basal diet with 4 g/kg of L. barbarum fruit homogenate, respectively. The test (LD, MD, and HD) groups were fed basal diets with additional 2, 4, and 8 g/kg of L. barbarum leaf homogenate, respectively. The feeding period was 35 d. The result revealed that the rats in the LD group had the highest average weight gain ( p < 0.05). The cardiac and renal indexes in the LD and MD groups were significantly higher than in NC group, respectively ( p < 0.05). Diversity analysis revealed that adding low concentrations of L. barbarum leaf homogenates markedly reduced the Shannon index of the rats cecum ( p < 0.05). The relative abundance of Verrucomicrobiota was higher in the LD group than those in other groups ( p < 0.05). The relative abundance of Actinobacteriota was found significantly higher in PC group than others ( p < 0.05). The relative abundance of Akkermansia in LD group was the highest ( p < 0.05). The relative abundance of Romboutsia in the PC group was considerably higher than that in other groups. The relative abundance of Candidatus_Saccharimonas in the supplementation groups was appreciably lower than those found in other groups. The relative abundance of Alloprevotella was significantly lower in PC, LD, and MD groups than in NC and HD groups ( p < 0.05). The relative abundance of Oscillibacter was significantly higher in HD group than in other groups ( p < 0.05). Thus, L. barbarum leaf homogenate fed to rats could increase their growth performance, internal organ weights and additionally enhance the relative abundance of beneficial bacteria. Therefore, based on the obtained data in the current study, a dose of L. barbarum leaf homogenate supplemented with 2 g/kg in diet is recommended, however, further studies are required to confirm, especially in animals.

Guo, Yindi↗

Carbon monoxide observations of a rotating dust globule

Results are presented for observations of the J = 1-0 rotational lines of (C-12)(O-16), (C-13)(O-16), and (C-12)(O-18) at rest frequencies of 115.2712, 110.2014, and 109.7822 GHz, respectively, in the direction of the small dust cloud B361. For a distance of 350 pc, the cloud is found to have an overall radius of about 1.2 pc and a core radius of about 0.4 pc. The core density is estimated to be about 10,000 per cu cm, and it is shown that the density at the center is high enough for the CO to be collisionally thermalized. A cloud temperature of 8.5 K is determined, a lower limit of 125 solar masses is placed on the core mass, and it is suggested that most of the mass is contained within the inner 6% of the cloud volume. The dense inner core is found to be rotating with a velocity gradient of 2.9 km/s per pc. A n(CO)/n(H) ratio that is no more than 0.07 of the solar n(C)/n(H) ratio is derived, indicating that most of the carbon present in the cloud is not in the form of CO.

Milman, A. S.↗

Fractographic evaluation of creep effects on strain-controlled fatigue-cracking of AISI 304LC and 316 stainless steel

Analysis of high temperature low cycle fatigue of AISI 304LC and 316 stainless steels by the method of strainrange partitioning results in four separate strainrange versus life relationships, depending upon the way in which creep-strain and plastic strain are combined within a cycle. Fractography is used in this investigation of the creep-fatigue interaction associated with these cycles. The PP and PC-cycle fractures were transgranular. The PC-cycle resulted in fewer cycles of initiation and shorter total cyclic life for the same applied inelastic strainrange. The CC-cycle had mixed transgranular and intergranular fracture, fewer cycles of initiation and shorter cycle life than PP or PC. The CP-cycle had fully integranular cracking, and failed in fewer cycles than were required for cracks to initate for PP,PC, and CC.

Oldrieve, R. E.↗

Separability of agricultural cover types in spectral channels and wavelength regions

Spectral channels and wavelength regions (visible, near infrared, middle infrared and thermal infrared) were evaluated with respect to their estimated probability of correct classification (Pc) in discriminating agricultural cover types. Multispectral scanner data in twelve spectral channels in the wavelength range of 0.4 to 11.7 microns acquired in the middle of July for three flightlines, were analyzed by applying automatic pattern recognition techniques. The same analysis was performed for the data acquired in the middle of August, 1971, over the same three flightlines, to investigate the effect of time on the results. The effect of deletion of each spectral channel as well as each wavelength region on Pc is given. Values of Pc for all possible combinations of wavelength regions in the subsets of one to twelve spectral channels are also given. The overall values of Pc were found to be greater for the data of the middle of August than the data of the middle of July.

Kumar, R.↗

Description of the three axis low-g accelerometer package

The three axis low-g accelerometer package designed for use on the Space Processing Application Rocket (SPAR) Program is described. The package consists of the following major sections: (1) three Kearfott model 2412 accelerometers mounted in an orthogonal triad configuration on a temperature controlled, thermally isolated cube, (2) the accelerometer servoelectronics (printed circuit cards PC-6 through PC-12), and (3) the signal conditioner (printed circuit cards PC-15 and PC-16). The measurement range is 0 + or - 0.031 g with a quantization of 1.1 x 10 to the 7th power g. The package was flown successfully on six SPAR launches with the Black Brant booster. These flights provide approximately 300 s of free fall or zero-g environment.

Amalavage, A. J.↗

Separability of agricultural cover types in spectral channels and wavelength regions

This study was a continuation of a more complete evaluation of the spectral channels as well as wavelength regions - visible, near infrared, middle infrared, and thermal infrared - with respect to their estimated probability of correct classification Pc in discriminating agricultural cover types reported previously by Kumar and Silva (1977). Multispectral scanner data in twelve spectral channels in the wavelength range of 0.4-11.7 microns acquired in the middle of July for three flightlines were analyzed by applying automatic pattern recognition techniques. The same analysis was performed for the data acquired in the middle of August 1971, over the same three flightlines, to investigate the effect of time on the results. The effect of deletion of each spectral channel as well as each wavelength region on Pc is given. Values of Pc for all possible combinations of wavelength regions in the subsets of one to twelve spectral channels are also given. The overall values of Pc were found to be greater for the data of the middle of August than the data of the middle of July.

Kumar, R.↗

Substorm associated micropulsations at synchronous orbit

The state of the art of observations of substorm associated waves in GEO is reviewed and research directions are indicated. Data were taken from fluxgate magnetometers on board the ATS 1 and 6 spacecraft in GEO. Mixed mode Pc 4 and 5 waves, with the largest amplitude of magnetic pulsations observed at GEO, have been found to display a quasi-sinusoidal waveform with amplitudes from 10-30 gamma and a period of 50-200 sec. The wave spectra confined the excited frequencies to a narrow band, and possible generating mechanisms for the Pc 4 and 5 waves are discussed. Pc 1 and 2 magnetic pulsations are the most common in GEO, with Pc 1 occurring every third day, particularly in the afternoon to dusk sector and during major substorm expansion onset. Pi 2 outbursts are observed in the majority of substorms passing through the midnight sector and have been correlated with changes in field aligned currents.

Mcpherron, R. L.↗

VLBI observations of the nucleus of Centaurus A

VLBI observations of the nucleus of Centaurus A made at 2.3 GHz on baselines with minimum fringe spacings of 0.15 and 0.0027 arcsec are presented. Results show that the nuclear component is elongated with a maximum extent of approximately 0.05 arcsec which is equivalent to a size of approximately 1 pc at the 5 Mpc distance of Centaurus A. The position angle of the nucleus is found to be 30 + or - 20 degrees, while the ratio of nuclear jet length to width is less than or approximately equal to 20. The nuclear flux density is determined to be 6.8 Jy, while no core component is found with an extent less than or approximately equal to 0.001 (less than or approximately equal to 0.02 pc) with a flux density of greater than or approximately equal to 20 mJy. A model of the Centaurus A nucleus composed of at least two components is developed on the basis of these results in conjunction with earlier VLBI and spectral data. The first component is an elongated source of approximately 0.05 arcsec (approximately 1 pc) size which contains most of the 2.3 GHz nuclear flux, while the second component is a source of approximately 0.0005 arcsec (approximately 0.01 pc) size which is nearly completely self-absorbed at 2.3 GHz but strengthens at higher frequencies.

Preston, R. A.↗

The extent of the local hi halo

Forty-five high-latitude, OB stars have been observed in the Ly alpha and 21 cm lines of HI in an effort to map out the vertical distribution and extent of the local HI halo. The 25 stars for which a reliable HI colum density can be obtained from Ly alpha lie between 60 and 3100 pc from the plane. The principal result is that the total column density of HI at z 1 kpc is, on the average, 5 + or - 3 x 10 the 19th power/sq cm, or 15% of the total sub HI. At relatively low z the data toward some stars suggest a low effective scale height and fairly high average foreground density, while toward others the effective scale height is large and the average density is low. This can be understood as the result of irregularities in the interstellar medium. A model with half of the HI mass in clouds having radii of a few pc and a Gaussian vertical distribution with sigma sub 2 = 135 pc, and half of the mass in an exponential component with a scale height of 500 pc, gives a satisfactory fit to the data. The technique of comparing Ly alpha and 21 cm column densities is also used to discuss the problem of estimating the distance to several possibly subluminous stars.

Lockman, F. J.↗

Far-infrared and submillimeter survey of the galactic center and nearby galactic plane

Maps are presented with 12-arcmin resolution of the Galactic Center and adjacent galactic plane, from l(Pc) = 359 deg to l(Pc) = 5 deg. The data were obtained with the Steward Observatory's cryogenically-cooled, balloon-borne telescope. The data are from channels filtered for a bandpass of 70 to 110 microns and for a longpass of wavelength greater than 80 microns. For the typical effective temperature of 25 K of a galactic H II region at this spatial resolution, the effective wavelengths of the channels are 93 microns and 145 microns. Continuous emission is mapped along the galactic plane in both wavelengths. There are two contrasts between the immediate vicinity of SgrA l(Pc) smaller than 1 deg, and the galactic plane in general. Firstly, for l(Pi) greater than 1 deg the galactic plane narrows dramatically at 93 microns, while retaining its width at 145 microns. Secondly, the individual sources at l(Pc) (which are associated with H II regions) have greater peak brightness in the 145-micron channel than the 93-micron channel, while SgrA has approximately equal peak brightness in each. The maps demonstrate the importance of submillimeter wavelengths to galactic surveys.

Campbell, M. F.↗

Hardware/Software Expansion of Display Terminal and CPU

IBM PC coupling used to expand capabilities of expensive specialpurpose system. IBM PC was interfaced to Tektronix CP1151 computer through teletype port of Tektronix 4010-1 computer display terminal. Electronic interface built to provide isolation, level shifting, and signal inversion between IBM PC RS-232 port and 4010-1 terminal teletype port. Modifications to 4010-1 terminal made to increase teletype rate from 110 to 9,600 baud. Software for both computers developed to give control of DPO system to IBM PC and provide data/program file exchange between two computers. Coupling demonstrates utilization of low-cost microcomputer hardware and software to expand capabilities of expensive special-purpose computer systems.

Adams, B. R.↗

The extent of the local H I halo

Forty-five high-latitude, OB stars have been observed in the Ly alpha and 21 cm lines of HI in an effort to map out the vertical distribution and extent of the local HI halo. The 25 stars for which a reliable HI column density can be obtained from Ly alpha lie between 60 and 3100 pc from the plane. The principal result is that the total column density of HI at an absolute value of z greater than 1 kpc is, on the average, 5 + or - 3 x 10 to the 19th power/sq cm, or 15 percent of the total sub HI. At relatively low z the data toward some stars suggest a low effective scale height and fairly high average foreground density, while toward others the effective scale height is large and the average density is low. This can be understood as the result of irregularities in the interstellar medium. A model with half of the HI mass in clouds having radii of a few pc and a Gaussian vertical distribution with sigma sub 2 = 135 pc, and half of the mass in an exponential component with a scale height of 500 pc, gives a satisfactory fit to the data. The technique of comparing Ly alpha and 21 cm column densities is also used to discuss the problem of estimating the distance to several possibly subluminous stars.

Lockman, F. J.↗

Aperture synthesis observations of the molecular ring in the galactic center

Reported are 88 GHz aperture synthesis observations of HCN J=1 yields 0 emission and absorption in the central 5 pc of the Galaxy. The data, taken by the Hat Creek mm-interferometer at 5" to 10" spatial and 4 km/s spectral resolution, show a complete, clumpy ring of molecular gas surrounding the ionized central 2 pc of the Galaxy. The ring is the inner edge of a larger disk extending to about 5 pc. Comparison with sub-mm line data suggests that the HCN 1-0 line is slightly optically thick and originates in subthermally populated gas. The clumpy line emission distribution reflects a combination of hydrogen volume and column density variations. The new data clearly show a close physical relation between the molecular and the ionized gas in the central cavity. The western arc appears to be the ionized inner surface of the molecular ring, and the northern arm and bar may be streamers of ionized gas falling from the ring toward the center. The dominant large scale velocity pattern of the majority of the molecular gas in the inner 5 pc is rotation. No overall radial motion of the ring greater than about 20 km/s is apparent. The rotation is perturbed in several ways; (1) there is a very large local velocity dispersion, (2) the ring shows changes in position angle and inclination (warps), (3) there is a bright, redshifted cloud which appears to be located in the western part of the ring but does not participate in the rotation. These characteristics and the high degree of clumpiness indicate a non-equilibrium configuration of short (less than or approx. 10 to the 4th power to 10 to the 5th power y) dynamical lifetime. The warping and tilting of the structure and the short dynamical lifetime make an accurate determination of equilibrium rotation velocity uncertain.

Guesten, R.↗

A molecular cloud in the local, hot interstellar medium

Echelle spectra recorded at the D lines of Na I are reported for nine A or F stars. Lying at approximate distances ranging from 25 to 230 pc, the stars are projected on or near the high-latitude molecular cloud MBM 12 at l = 159 deg, b = -34 deg. Among a subgroup of five of these stars separated by no more than 1.2 deg on the sky, four which are located at distances d more than 70 pc show strong interstellar D line absorption near the radial velocity of the CO emission observed in this general direction. The fifth star, at roughly 60 pc, shows no detectable absorption. MBM 12 therefore probably lies at roughly 65 pc, within the local region filled primarily by very hot, low-density gas, a conclusion supported by the large internal velocity dispersion of the molecular cloud complex.

Hobbs, L. M.↗

Do flux transfer events cause long-period micropulsations in the dayside magnetosphere?

Russell and Elphic (1979) suggested the possibility that flux transfer events (FTEs) generate long-period micropulsations in the outer, dayside magnetosphere. The reasons for this hypothesis are examined and results are presented for two pulsation surveys designed to test it. In the first survey, observations of micropulsations by GOES 2 are compared with ISEE 3 and IMP observations of interplanetary magnetic field (IMF) direction; since FTEs are highly correlated with southward IMF, a similar correlation between pulsations and southward IMF was sought. In the second survey, a catalog of ISEE 1 and 2 magnetopause crossings is compared with magnetometer readings from GOES 2 and 3 to determine whether Pc 4 and Pc 5 pulsations are more likely to occur after FTEs have taken place. Results indicate that there is a correlation between FTEs and transversely polarized Pc 4 pulsations with periods between 60 and 120 s, but not between FTEs and Pc pulsations with periods greater than 120 s. This suggests that the generating (or driving) frequency associated with FTEs lies between 60 and 120

Gillis, E. J.↗

Liposomes with polyribonucleotides as model of precellular systems

Three types of liposomes were prepared under anoxic conditions: from dipalmitoyl phosphatidyl choline (DPPC), from egg yolk phosphatidyl choline (PC), and from PC with cholesterol (PC:Chol). These were used for encapsulation of poly(U) and poly(C). It was found that 36 to 70 percent of the available liposome lipids and 2 to 5 percent of the polyribonucleotides could be entrapped. An enhanced encapsulation of poly(U) and poly(C) by all three types of liposomes was observed in the presence of 0.001 to 0.01 M Zn(2+), with the effect being greatest with DPPC. The presence of 1.0 M urea inhibited the formation of PC liposomes.

Baeza, Isabel↗