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At least 307 records · Page 17

Saturn's F Ring Core: Calm in the Midst of Chaos

The long-term stability of the narrow F Ring core has been hard to understand. Instead of acting as "shepherds", Prometheus and Pandora together stir the vast preponderance of the region into a chaotic state, consistent with the orbits of newly discovered objects like S/2004S6. We show how a comb of very narrow radial locations of high stability in semimajor axis is embedded within this otherwise chaotic region. The stability of these semimajor axes relies fundamentally on the unusual combination of rapid apse precession and long synodic period which characterizes the region. This situation allows stable "antiresonances" to fall on or very close to traditional Lindblad resonances which, under more common circumstances, are destabilizing. We present numerical integrations of tens of thousands of test particles over tens of thousands of Prometheus orbits that map out the effect. The stable antiresonance zones are most stable in a subset of the region where Prometheus first-order resonances are least cluttered by Pandora resonances. This region of optimum stability is paradoxically closer to Prometheus than a location more representative of "torque balance", helping explain a longstanding paradox. One stable zone corresponds closely to the currently observed semimajor axis of the F Ring core. While the model helps explain the stability of the narrow F Ring core, it does not explain why the F Ring material all shares a common apse longitude; we speculate that collisional damping at the preferred semimajor axis (not included in the current simulations) may provide that final step. Essentially, we find that the F Ring core is not confined by a combination of Prometheus and Pandora, but a combination of Prometheus and precession.

Planetary Rings↗

Spring-Summer Temperatures Since AD 1780 Reconstructed from Stable Oxygen Isotope Ratios in White Spruce Tree-Rings from the Mackenzie Delta, Northwestern Canada

High-latitude delta(exp 18)O archives deriving from meteoric water (e.g., tree-rings and ice-cores) can provide valuable information on past temperature variability, but stationarity of temperature signals in these archives depends on the stability of moisture source/trajectory and precipitation seasonality, both of which can be affected by atmospheric circulation changes. A tree-ring delta(exp 18)O record (AD 1780-2003) from the Mackenzie Delta is evaluated as a temperature proxy based on linear regression diagnostics. The primary source of moisture for this region is the North Pacific and, thus, North Pacific atmospheric circulation variability could potentially affect the tree-ring delta(exp 18)O-temperature signal. Over the instrumental period (AD 1892-2003), tree-ring delta(exp 18)O explained 29% of interannual variability in April-July minimum temperatures, and the explained variability increases substantially at lower-frequencies. A split-period calibration/verification analysis found the delta(exp 18)O-temperature relation was time-stable, which supported a temperature reconstruction back to AD 1780. The stability of the delta(exp 18)O-temperature signal indirectly implies the study region is insensitive to North Pacific circulation effects, since North Pacific circulation was not constant over the calibration period. Simulations from the NASA-GISS ModelE isotope-enabled general circulation model confirm that meteoric delta(exp 18)O and precipitation seasonality in the study region are likely insensitive to North Pacific circulation effects, highlighting the paleoclimatic value of tree-ring and possibly other delta(exp 18)O records from this region. Our delta(exp 18)O-based temperature reconstruction is the first of its kind in northwestern North America, and one of few worldwide, and provides a long-term context for evaluating recent climate warming in the Mackenzie Delta region.

Canada↗

Redetection of the Ionospheric H3(+) Signature of Saturn's "Ring Rain"

Abstract In April 2011 Saturn's midlatitude ionospheric H3(+) emissions were detected, exhibiting anomalous (nonsolar) H3(+) latitudinal variations consistent with the transport of water from specific locations in Saturn's rings, known as ''ring rain'' . These products, transported to the planet along the magnetic field, may help to explain the unusual pattern of peaks and troughs in electron densities discovered in Saturn's ionosphere by spacecraft flybys. In the present study, we analyzed H3(+) emissions recorded on 23 April 2013, showing for the first time since the original detection that Saturn's midlatitude H3(+) emissions are indeed heavily modified. Although the 2013 emissions are dimmer by almost a factor of 3.7, the latitudinal contrast is greater and uncertainties are lower. Increased H3(+) intensities were found near planetocentric latitudes of 43 deg, 51 deg, and 63 deg, previously identified with sources at the inner edge of the B ring, A ring, and the orbit of Enceladus and associated E ring.

Ionospheric↗

Investigation of Ring-heterogeneous Geometry Approximation for Efficient and Practical SFR Analysis

A novel geometry approximation scheme named ring-heterogeneous approximation for intermediate resolution multiphysics analysis of SFRs is presented. This approach particularly targets neutronics coupled with thermo-mechanics feedback, which dominate the passive safety of SFR designs. The ring-heterogeneous approximation casts an array of pins into volume-preserving bands of materials that constitute the pins. It allows to efficiently simulate SFRs with an unstructured mesh and also to explicitly consider the deformation of each material by retaining their heterogeneity. Verification results with single assembly and core problems of the ABTR benchmark demonstrated that the ring-heterogeneous approximation is a reasonable approximation for SFRs. For a 2D full core problem, the ring-heterogeneous approximation significantly reduced the number of elements by at least a factor of 70 from a fully-heterogeneous mesh while almost exactly preserving the reference fully-heterogeneous solutions with the RMS error of only 0.02% in the ring-wise fission reaction rate.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Intrinsic activation energies for ring contraction of allylic cations in zeolites

Cyclic carbocations are important intermediates in zeolite-catalyzed chemistries such as methanol-to-hydrocarbons conversion, naphthenes ring opening, or coke formation. While information about their thermodynamic stability exists, little is known about the kinetics of formation and transformation of cyclic carbocations in zeolites. To fill this knowledge gap, ring contraction of the 1,3,5,5-tetramethylcyclohexenyl cation (C 10 H 17 + ), a representative of 6-membered ring allylic cations, was investigated by in situ UV–vis and IR spectroscopy. Protonic forms of zeolites served as catalysts, at temperatures from 80 °C to 135 °C. Significant oligomerization and hydride transfer in BEA and FAU hampered kinetics analysis, whereas ring contraction dominated in the channels of MOR. The reactant cation, characterized by an electronic absorption at 314 nm and an allylic stretch at 1549 cm −1 , contracted to both a 1,3-alkyl-substituted cyclopentenyl cation (287 nm and 1506 cm −1 ) and a 1,2,3-alkyl-substituted cyclopentenyl cation (297 nm and 1489 cm −1 ). Collection of time-resolved IR spectra and fitting of the intensities with various kinetic models revealed a third transformation, which is expected from thermodynamics: the 1,3-alkyl-substituted cyclopentenyl cation isomerizes to the 1,2,3-alkyl-substituted cyclopentenyl cation. Series of IR spectra recorded at different temperatures delivered intrinsic activation enthalpies (entropies) in MOR of 67 ± 2 kJ mol −1 (−130 ± 6 J mol −1 K −1 ) and 90 ± 3 kJ mol −1 (−70 ± 8 J mol −1 K −1 ) for the contraction to 1,3- and 1,2,3-substituted species, and of 88 ± 5 kJ mol −1 (−84 ± 12 J mol −1 K −1 ) for the isomerization. The findings characterize one path – via contraction of larger rings – to different cyclopentenyl species in zeolites; and the associated, moderate activation energies suggest such transformations contribute to many complex hydrocarbon reaction networks.

Acid catalysis↗

Ring Size Effects on the Structures of Sandwich Compounds with a Stoichiometry of C 12 H 12 M (M = Ti–Ni)

Ring size effects on geometries and electronic structures were investigated for the (C n H n )M(C m H m ) (n = 4, 5, or 6; m = 8, 7, or 6; m + n = 12; M = Ti–Ni) systems using density functional theory. The lowest-energy C 12 H 12 M structures for the early transition metals titanium, vanadium, and chromium are the experimentally known singlet (η 5 -C 5 H 5 )Ti(η 7 -C 7 H 7 ), doublet (η 5 -C 5 H 5 )V(η 7 -C 7 H 7 ), and singlet (η 6 -C 6 H 6 ) 2 Cr, respectively. The likewise experimentally known singlet (η 6 -C 6 H 6 ) 2 Ti, doublet (η 6 -C 6 H 6 ) 2 V, and singlet (η 5 -C 5 H 5 )Cr(η 7 -C 7 H 7 ) are the secondlowest- energy structures with only a small energy difference between the two vanadium structures. For the later transition metals, dibenzenemetal complexes are the lowest-energy C 12 H 12 M species with two fully bonded hexahapto benzene rings in the lowest-energy manganese and iron derivatives and one hexahapto and one dihapto benzene ring in the lowest-energy cobalt and nickel derivatives. The lowest-energy (C 5 H 5 )M(C 7 H 7 ) structures for the later transition metals iron, cobalt, and nickel have partially bonded nonplanar C 7 H 7 rings with one or two uncomplexed C=C bonds. The (C 4 H 4 )M(C 8 H 8 ) (M = Ti–Ni) structures with the metal sandwiched between four- and eight-membered rings were found to be much higher in energy than their (C 5 H 5 )M(C 7 H 7 ) and (C 6 H 6 ) 2 M isomers.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Elastomer Mechanics of Cross-Linked Linear-Ring Polymer Blends

Cross-linking a blend of linear and ring polymers creates a new topology-based dual-network elastomer in which the two components differ significantly in their topology. We use molecular simulations and topological analysis to examine key mechanical properties as functions of ring polymer volume fraction Φ R . For Φ R < Φ R *, where the rings begin to overlap, the network shear modulus G and the maximum stretch ratio λ p are weakly dependent on Φ R . For Φ R > Φ R *, entanglements trapped in the network are diluted as the rings overlap, leading to a significant decrease in G and an increase in λ p with increasing Φ R . Here, the peak tensile stress, σ p , exhibits a maximum around Φ R *, indicating an enhancement of network strength due to the stronger cohesion from the entanglements between linear and ring polymers.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Comparison of the Distribution of the In Situ Ring Current Density Based on Magnetic Field Observations From THEMIS, MMS and Cluster

Abstract We review and extend previous work on the ring current density distribution by applying the curlometer technique to multi‐spacecraft magnetic field data on different spatial scales, directly comparing the results of three space missions: Time History of Events and Macroscale Interactions during Substorms (THEMIS), The Magnetospheric Multiscale (MMS) and Cluster, that have so far accrued decades of data on a range of spatial separation scales. We suggest that the statistical results of Cluster data over two decades can illustrate well the overall form of the ring current (in the ring plane), but can underestimate the current density, while THEMIS (partially) and MMS are able to observe the detailed structure of the ring current and indeed show different behavior on some (smaller) spatial scales. These results suggest that, in addition to the local time and radial form, reported previously, the morphology of the ring current may also depend on magnetic latitude, as influenced by the tilt angle between the inner and outer magnetic fields.

Tan, X. [School of Space and Earth Sciences Beihan↗

Unified understanding of the impact of semiflexibility, concentration, and molecular weight on macromolecular-scale ring diffusion

Conformationally fluctuating, globally compact macromolecules such as polymeric rings, single-chain nanoparticles, microgels, and many-arm stars display complex dynamic behaviors due to their rich topological structure and intermolecular organization. Synthetic rings are hybrid objects with conformations that display both ideal random walk and compact globular features, which can serve as models of genomic DNA. To date, emphasis has been placed on the effect of ring molecular weight on their unusual behaviors. Here, we combine simulations and a microscopic force-level theory to build a unified understanding for how key aspects of ring dynamics depend on different tunable molecular properties including backbone rigidity, monomer concentration, degree of traditional entanglement, and molecular weight. Our large-scale molecular dynamics simulations of ring melts with very different backbone stiffnesses reveal unanticipated behaviors which agree well with our generalized theory. This includes a universal master curve for center-of-mass diffusion constants as a function of molecular weight scaled by a chemistry and thermodynamic state-dependent critical molecular weight that generalizes the concept of an entanglement cross-over for linear chains. The key physics is how backbone rigidity and monomer concentration induced changes of the entanglement length, interring packing, degree of interpenetration, and liquid compressibility slow down space-time dynamic-force correlations on macromolecular scales. A power law decay of the center-of-mass diffusion constant with inverse molecular weight squared is the first consequence, followed by an ultraslow activated hopping transport regime. Our results set the stage to address slow dynamics and kinetic arrest in different families of compact synthetic and biological polymeric systems.

Science & Technology - Other Topics↗

Measuring Topological Constraint Relaxation in Ring-Linear Polymer Blends

Polymers are an effective test bed for studying topological constraints in condensed matter due to a wide array of synthetically available chain topologies. When linear and ring polymers are blended together, emergent rheological properties are observed as the blend can be more viscous than either of the individual components. This emergent behavior arises since ring-linear blends can form long-lived topological constraints as the linear polymers thread the ring polymers. Here, in this work, we demonstrate how the Gauss linking integral can be used to efficiently evaluate the relaxation of topological constraints in ring-linear polymer blends. For majority-linear blends, the relaxation rate of topological constraints depends primarily on reptation of the linear polymers, resulting in the diffusive time τ d,R for rings of length N R blended with linear chains of length N l to scale as τ d,R ~ N$^2_R$N$^{3.4}_L$.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Half-life determination of heavy ions in a storage ring considering feeding and depleting background processes

Heavy-ion storage rings have relatively large momentum acceptance which allows for multiple ion species to circulate at the same time. This needs to be considered in radioactive decay measurements of highly charged ions, where atomic charge exchange reactions can significantly alter the intensities of parent and daughter ions. In this study, we investigate this effect using the decay curves of ion numbers in the recent 205 Tl 81+ bound-state beta decay experiment conducted using the Experimental Storage Ring at GSI Darmstadt. To understand the intricate dynamics of ion numbers, we present a set of differential equations that account for various atomic and nuclear reaction processes—bound state beta decay, atomic electron recombination and capture, and electron ionization. By incorporating appropriate boundary conditions, we develop a set of differential equations that accurately simulate the decay curves of various simultaneously stored ions in the storage ring: 205 Tl 81+ , 205 Pb 81+ , 205 Pb 82+ , 200 Hg 79+ , and 200 Hg 80+ . Through a quantitative comparison between simulations and experimental data, we provide insights into the detailed reaction mechanisms governing stored heavy ions within the storage ring. Our approach effectively models charge-changing processes, reduces the complexity of the experimental setup, and provides a simpler method for measuring the decay half-lives of highly charged ions in storage rings.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Ring Pull Strain Analysis

Ring Pull Strain Analysis (RPSA) is a framework for analysis of Digital Image Correlation (DIC) data of gaugeless ring pull testing. It is meant for analysis of rings cut from tube cross sections and pulled in a displacement-controlled tensile test. This code takes load frame data, images take during testing, and csv files from the DIC analysis of those images and allows the user to analyze and plot data from the test. Some important features of the software include getting the strain values as a function of radial distance and angle, plotting of the strain around the ring, and stress-strain analysis of the load frame data. Additional capability is included with Ring Pull Coating Analysis (RPCA, also part of the software). Additional images are taken of samples with an outer coating and are used to correlate failure of the coating with strain values measured with DIC.

Beck, Peter↗

First Sagittarius A* Event Horizon Telescope Results. VII. Polarization of the Ring

Abstract The Event Horizon Telescope observed the horizon-scale synchrotron emission region around the Galactic center supermassive black hole, Sagittarius A* (Sgr A*), in 2017. These observations revealed a bright, thick ring morphology with a diameter of 51.8 ± 2.3 μas and modest azimuthal brightness asymmetry, consistent with the expected appearance of a black hole with mass M ≈ 4 × 106 M ⊙. From these observations, we present the first resolved linear and circular polarimetric images of Sgr A*. The linear polarization images demonstrate that the emission ring is highly polarized, exhibiting a prominent spiral electric vector polarization angle pattern with a peak fractional polarization of ∼40% in the western portion of the ring. The circular polarization images feature a modestly (∼5%–10%) polarized dipole structure along the emission ring, with negative circular polarization in the western region and positive circular polarization in the eastern region, although our methods exhibit stronger disagreement than for linear polarization. We analyze the data using multiple independent imaging and modeling methods, each of which is validated using a standardized suite of synthetic data sets. While the detailed spatial distribution of the linear polarization along the ring remains uncertain owing to the intrinsic variability of the source, the spiraling polarization structure is robust to methodological choices. The degree and orientation of the linear polarization provide stringent constraints for the black hole and its surrounding magnetic fields, which we discuss in an accompanying publication.

79 ASTRONOMY AND ASTROPHYSICS↗

The liquid metal slip ring experiment for the communications technology satellite

The experiment is designed to demonstrate liquid metal slip ring (LMSR) performance in a space environment. An evaluation was made of the features of the LMSR where improvement in performance over conventional slip rings was expected. The primary measurements to be made in the experiment will allow a determination of the slip ring electrical resistance, between ring insulation and ring cleanliness.

Lovell, R. R.↗

Generation and development of a viscous vortex ring.

The vorticity transport and definition of vorticity equations are derived for an axisymmetric incompressible viscous vortex ring. The coupled system is solved numerically by the Peaceman-Rachford method and the method of successive over-relaxation. Instantaneous streaklines, velocity vector fields, vorticity contours, and streamline patterns offer a detailed picture of vortex ring generation. Results compare well with experimental observations of the behavior of viscous vortex rings. The radius, trajectory, and velocity of the ring are calculated and employed to predict the propagation velocity of the vortex ring using the vortex models of Helmholtz and Hill.

Whitehead, K. D.↗

Storm time instabilities of the ring current.

Demonstration that the resonant cyclotron instability between radiation belt protons and ion-cyclotron waves can account for many observed features of the magnetospheric ring current. Analogous results apply to the electron-whistler interaction although the former are not considered to be important for ring current energetics. Particles with energy exceeding 100 keV are readily destabilized throughout the entire magnetosphere and their fluxes are consequently limited to the stably trapped levels described by Kennel and Petschek (1966). However, at the dominant ring current energies between 10 and 100 keV, a broad zone of stability exists in the region just outside the plasmapause. Particles injected into this outer zone during substorms may remain trapped for many drift orbits allowing an intense ring current to develop. In direct contrast, this stable ring current zone is bounded by regions of rapid precipitational loss within the plasmasphere and at large radial distance in the auroral zone.

Thorne, R. M.↗

Saturn's rings - A survey.

In this review paper we first discuss the dimensions of major ring features and of the disk of the planet. We then summarize the observed photometric parameters, and because frozen H2O appears to be a major ring constituent, we compare the appropriate photometric properties of various forms of snow with those of the ring. We examine several ring models, noting certain characteristics that any model should supply. In our view, a physical means of accounting for the observed ring thickness of about 2 km is a prime requirement. There appears to be one model that presents no clear observational or theoretical inconsistency.

Cook, A. F.↗

Optical scattering properties of Saturn's ring.

Reliable data defining the photometric function of the Saturn ring system at visual (V) wavelengths are interpreted in terms of a simple scattering model. To facilitate the analysis, new photographic photometry of the ring has been carried out utilizing the Lowell observatory plate collection. Homogeneous measurements of the mean surface brightness (rings A and B together), covering almost the complete range in planetocentric solar declination angle, are presented. The ring model adopted is a plane-parallel slab of isotropically scattering particles; the single scattering albedo and the perpendicular optical thickness are both arbitrary. Results indicate that primary scattering is inadequate to describe the photometric properties of the ring; multiple scattering predominates for all angles of tilt with respect to the Sun and Earth.

Price, M. J.↗