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At least 307 records · Page 17

The adhesion, friction, and wear of binary alloys in contact with single-crystal silicon carbide

Sliding friction experiments were conducted with various iron-base alloys (alloying elements were Ti, Cr, Ni, Rh, and W) in contact with a single-crystal silicon carbide (0001) surface in vacuum. Results indicate atomic size misfit and concentration of alloying elements play a dominant role in controlling adhesion, friction, and wear properties of iron-base binary alloys. The controlling mechanism of the alloy properties is an intrinsic effect involving the resistance to shear fracture of cohesive bonding in the alloy. The coefficient of friction generally increases with an increase in solute concentration. The coefficient of friction increases as the solute-to-iron atomic radius ratio increases or decreases from unity. Alloys having higher solute concentration produce more transfer to silicon carbide than do alloys having low solute concentrations. The chemical activity of the alloying element is also an important parameter in controlling adhesion and friction of alloys.

Miyoshi, K.↗

Effect of load, area of contact, and contact stress on the wear mechanisms of a bonded solid lubricant film

A pin on disk type of friction and wear apparatus was used to study the effect of load, contact stress and rider area of contact on the friction and wear properties of polyimide bonded graphite fluoride films. Different rider area contacts were obtained by initially generating flats (with areas of 0.0035, 0.0071, 0.0145, and 0.0240 cm) on 0.476-cm radius hemispherically tipped riders. Different projected contact stresses were obtained by applying loads of 2.5- to 58.8-N to the flats. Two film wear mechanisms were observed. The first was found to be a linear function of contact stress and was independent of rider area of contact. The second was found to increase exponentially as the stress increased. The second also appeared to be a function of rider contact area. Wear equations for each mechanism were empirically derived from the experimental data. In general, friction coefficients increased with increasing rider contact area and with sliding duration. This was related to the build up of thick rider transfer films.

Fusaro, R. L.↗

Effect of load, area of contact, and contact stress on the tribological properties of polyimide bonded graphite fluoride films

A pin-on-disk type of friction and wear apparatus was used to study the effect of load, contact stress and rider area of contact on the friction and wear properties of polyimide-bonded graphite fluoride films. Different rider area contacts were obtained by initially generating flats (with areas of 0.0035, 0.0071, 0.0145, and 0.0240 cm) on 0.476-cm radius hemispherically-tipped riders. Different projected contact stresses were obtained by applying loads of 2.5-to 58.8-N to the flats. Two film wear mechanisms were observed. The first was found to be a linear function of contact stress and was independent of rider area of contact. The second was found to increase exponentially as the stress increased. The second also appeared to be a function of rider contact area. Wear equations for each mechanism were empirically derived from the experimental data. In general, friction coefficients increased with increasing rider contact area and with sliding duration. This was related to the build-up of thick rider transfer films.

Fusaro, R. L.↗

User's manual for tooth contact analysis of face-milled spiral bevel gears with given machine-tool settings

Research was performed to develop a computer program that will: (1) simulate the meshing and bearing contact for face milled spiral beval gears with given machine tool settings; and (2) to obtain the output, some of the data is required for hydrodynamic analysis. It is assumed that the machine tool settings and the blank data will be taken from the Gleason summaries. The theoretical aspects of the program are based on 'Local Synthesis and Tooth Contact Analysis of Face Mill Milled Spiral Bevel Gears'. The difference between the computer programs developed herein and the other one is as follows: (1) the mean contact point of tooth surfaces for gears with given machine tool settings must be determined iteratively, while parameters (H and V) are changed (H represents displacement along the pinion axis, V represents the gear displacement that is perpendicular to the plane drawn through the axes of the pinion and the gear of their initial positions), this means that when V differs from zero, the axis of the pionion and the gear are crossed but not intersected; (2) in addition to the regular output data (transmission errors and bearing contact), the new computer program provides information about the contacting force for each contact point and the sliding and the so-called rolling velocity. The following topics are covered: (1) instructions for the users as to how to insert the input data; (2) explanations regarding the output data; (3) numerical example; and (4) listing of the program.

Litvin, Faydor L.↗

Femtosecond Laser-Structured Transparent Anti-Fog Polycarbonate for Visor Applications

AlchLight has developed transparent anti-fog superhydrophobic polycarbonates for spacesuit helmets using femtosecond pulsed laser surface patterning technology. In contrast to conventional complex chemical coating processes, our laser patterning permanently alters the intrinsic wetting property of polycarbonate with little change to its transparency. The processing procedure is studied and optimized to produce the ideal superhydrophobic property and transparency. We were able to obtain a high contact angle (>150°), small sliding angle (<10°), and high transmission (>70%) over the visible wavelengths for polycarbonates. The anti-fog effect was also investigated. This technology will have a range of applications in spacesuit, automotive, medical, energy, and sports industries.

Spacesuit↗

Adhesion and friction of iron-base binary alloys in contact with silicon carbide in vacuum

Single pass sliding friction experiments were conducted with various iron base binary alloys (alloying elements were Ti, Cr, Mn, Ni, Rh, and W) in contact with a single crystal silicon carbide /0001/ surface in vacuum. Results indicate that atomic size and concentration of alloying elements play an important role in controlling adhesion and friction properties of iron base binary alloys. The coefficient of friction generally increases with an increase in solute concentration. The coefficient of friction increases linearly as the solute to iron atomic radius ratio increases or decreases from unity. The chemical activity of the alloying elements was also an important parameter in controlling adhesion and friction of alloys, as these latter properties are highly dependent upon the d bond character of the elements.

Miyoshi, K.↗

Candidate Coatings and Dry Traction Drives for Planetary Vehicles

Robert Fusaro and Fred Oswald of the Mechanical Components Branch discussed 'Candidate Coatings and Dry Traction Drives for Planetary Vehicles'. Vehicles to be designed for exploration of planets and moons of the solar system will require reliable mechanical drives to operate efficiently. Long-term operation of these drives will be challenging because of extreme operating conditions. These extreme conditions include: very high and/or very cold temperatures, wide temperature ranges, dust, vacuum or low-pressure atmospheres, and corrosive environments. Most drives used on Earth involve oil-lubricated gears. However, due to the extreme conditions on planetary surfaces, it may not be advisable or even possible to use oil lubrication. Unfortunately, solid lubricants do not work well when applied to gears because of the high contact stress conditions and large sliding motion between the teeth, which cause wear and limit life. We believe traction drives will provide an attractive alternative to gear drives. Traction drives are composed of rollers that provide geometry more conducive to solid lubrication. Minimal slip occurs in this contact geometry and thus there is very low wear to the solid lubricant. The challenge for these solid-lubricated drives is finding materials or coatings that provide the required long-life while also providing high traction. We seek materials that provide low wear with high friction.

Fusaro, Robert↗

Resistance to Sliding on Atomic Scales

The structure and stability of agglomerates of micron-sized particles is determined by the mechanical properties of the individual contacts between the constituent particles. In this paper we study the possibility of aggregate rearrangements by sliding. Since the contacts between (sub)micron particles are only a few hundred atoms in diameter, processes on atomic levels will play the dominating roll. We study a theoretical model of sliding friction for surfaces that are either flat or contain steps in their grids. The results show that sliding over flat surfaces may produce a large range of friction coefficients, including zero if the adhesive forces are small compared to the binding forces inside a body. However, both grid alignment and steps in the surface will lead to high values for friction. These processes combined virtually eliminate the possibility of sliding in a collision of two (sub)micron sized particles at velocities low enough for sticking to occur. On the other hand we show that in collisions between aggregates sliding may be an important factor for energy dissipation and compaction.

Dominik, C.↗

Low-Friction Joint for Robot Fingers

Mechanical linkage allows adjacent parts to move relative to each other with low friction and with no chatter, slipping, or backlash. Low-friction joint of two surfaces in rolling contact, held in alinement by taut flexible bands. No sliding friction or "stick-slip" motion: Only rolling-contact and bending friction within bands. Proposed linkage intended for finger joints in mechanical hands for robots and manipulators.

Ruoff, C. F.↗

Surface temperatures and glassy state investigations in tribology, part 1

The research in this report is divided into two categories: (1) lubricant rheological behavior, and (2) thermal behavior of a simulated elastohydrodynamic contact. The studies of the lubricant rheological behavior consists of high pressure, low shear rate viscosity measurements, viscoelastic transition measurements, by volume dilatometry, dielectric transitions at atmospheric pressure and light scattering transitions. Lubricant shear stress-strain behavior in the amorphous glassy state was measured on several fluids. It appears clear from these investigations that many lubricants undergo viscoplastic transitions in typical EHD contacts and that the lubricant has a limiting maximum shear stress it can support which in turn will determine the traction in the contact except in cases of very low slide-roll ratio. Surface temperature measurements were made for a naphthenic mineral oil and a polyphenyl ether. The maximum surface temperature in these experiments was approximately symmetrical about the zero slide-roll ration except for absolute values of slide-roll ratio greater than about 0.9. Additional surface temperature measurements were made in contacts with rough surfaces where the composite surface roughness was approximately equal to the EHD film thickness. A regression analysis was done to obtain a predictive equation for surface temperatures as a function of pressure, sliding speed, and surface roughness. A correction factor for surface roughness effects to the typical flash temperature analysis was found.

Winer, W. O.↗

Mitigating municipal solid waste fouling in biofuel conversion via screw surface modifications

Here, municipal solid waste (MSW)'s 40–60 % carbon content makes it a feedstock for biofuel production via pyrolysis. One challenge in the conversion process is MSW fouling due to thermal decomposition. The accumulated deposit on the injection screw often leads to plugging and constriction. This study examined the morphology and composition of the MSW fouling deposit and conducted a thermal simulation to understand the temperature gradience of the injection screw. Surface modifications including smoothening and anti-adhesion coating were proposed for the injection screw to address the deposit problem. For evaluating the candidate mitigations, a bench-scale fouling test was developed with the gas environment, temperature, and sliding speed relevant to the contact interface between the MSW particles and the screw. Results suggested that a smoother screw surface could reduce the grip and a non-metallic coating with a lower surface energy could decrease adhesion, consequently leading to less fouling. Specifically, reducing the roughness from 2 to 0.6 and then to 0.2 μm proportionally decreased the amount of deposit, and the diamond-like-carbon, CrN, and NiCr–CrC composite coatings effectively hindered the fouling process. This study provides fundamental insights into the MSW fouling and proof-of-concept of potential mitigations through the screw surface modification.

09 BIOMASS FUELS↗

Discrepant wear behavior of carbon nanotubes (CNTs) and dispersant in four-ball unidirectional and ball-on-flat reciprocating sliding tests

Carbon nanotubes (CNTs), basically rolled graphene sheets, have been studied lately as oil additives in the literature. However, we observed discrepant impact of CNTs on wear protection from two common tribological tests, four-ball unidirectional sliding and high frequency reciprocating rig (HFRR) ball-on-flat reciprocating sliding. To gain a stable suspension and dispersion of the CNTs in the oil, the CNT surface was functionalized with a phenyl ligand and a dispersant, polyisobutylene succinimide (PIBSI), was added. In the four-ball test, PIBSI alone failed to protect the surface but the CNTs effectively reduced the wear loss. The observations in the HFRR test however were the opposite: the PIBSI alone provided strong wear reduction but the CNTs had no positive impact. Here, such a discrepancy was hypothetically attributed to the different wear protection mechanisms by the PIBSI and CNTs which responded distinctively under different testing conditions. Additional unidirectional and reciprocating sliding tests with matching Hertzian contact pressures were able to validate the hypothesis. Worn surface morphological examination and tribofilm chemical analysis further supported the proposed wear mechanisms. Fundamental understanding gained in this study provides insights into the potential benefits and limitations of using CNTs in lubrication.

36 MATERIALS SCIENCE↗

Auger spectroscopy analysis in adhesion, friction and wear studies

The paper reviews the current use of Auger electron spectroscopy in adhesion, friction, wear and lubrication studies. Conventional Auger spectroscopy is adopted to complement LEED studies of the adhesion of metal single crystals. In addition, Auger cylindrical mirror analysis is applied to the study of changes in surface chemistry during dynamic friction and wear experiments on polycrystalline metals and alloys. Important conclusions are that (1) segregation of alloying elements to the surface of metals can alter adhesion behavior; (2) hydrocarbons are adsorbed readily to clean iron surfaces at 23 C; (3) transfer from one surface to another for dissimilar materials in contact can be followed in sliding or rubbing friction studies; and (4) the friction process can enhance surface activity for metals with hydrocarbons.

Buckley, D. H.↗

Ion Processes Modify Tribological Properties Of Surfaces

NASA technical memorandum reviews state of art of use of ion-assisted treatments to coat and otherwise modify surfaces of materials to reduce friction and increase resistance to wear. Focuses upon treatment of materials destined for use in sliding, rolling, rotating, and/or oscillating contact under such severe environmental conditions as variable temperature, ionizing radiation, vacuum, and oxidizing or corrosive atmospheres at high temperatures.

Spalvins, Talivaldis↗

Tribometer for Lubrication Studies in Vacuum

The NASA Lewis Research Center has developed a new way to evaluate the liquid lubricants used in ball bearings in space mechanisms. For this evaluation, a liquid lubricant is exercised in the rolling contact vacuum tribometer shown in the photo. This tribometer, which is essentially a thrust bearing with three balls and flat races, has contact stresses similar to those in a typical preloaded, angular contact ball bearing. The rotating top plate drives the balls in an outward-winding spiral orbit instead of a circular path. Upon contact with the "guide plate," the balls are forced back to their initial smaller orbit radius; they then repeat this spiral orbit thousands of times. The orbit rate of the balls is low enough, 2 to 5 rpm, to allow the system to operate in the boundary lubrication regime that is most stressful to the liquid lubricant. This system can determine the friction coefficient, lubricant lifetime, and species evolved from the liquid lubricant by tribodegradation. The lifetime of the lubricant charge is only few micrograms, which is "used up" by degradation during rolling. The friction increases when the lubricant is exhausted. The species evolved by the degrading lubricant are determined by a quadrupole residual gas analyzer that directly views the rotating elements. The flat races (plates) and 0.5-in.-diameter balls are of a configuration and size that permit easy post-test examination by optical and electron microscopy and the full suite of modern surface and thin-film chemical analytical techniques, including infrared and Raman microspectroscopy and x-ray photoelectron spectroscopy. In addition, the simple sphere-on-a-flat-plate geometry allows an easy analysis of the contact stresses at all parts of the ball orbit and an understanding of the frictional energy losses to the lubricant. The analysis showed that when the ball contacts the guide plate, gross sliding occurs between the ball and rotating upper plate as the ball forced back to a smaller orbit radius. The friction force due to gross sliding is sensed by the piezoelectric force transducer behind the guide plate and furnishes the coefficient of friction for the system. This tribometer has been used to determine the relative lifetimes of Fomblin Z-25, a lubricant often used in space mechanisms, as a function of the material of the plates against which it was run. The balls were 440C steel in all cases; the plate materials were aluminum, chromium (Cr), 440C steel (17 wt % Cr), and 4150 steel (1 wt % Cr). As shown in the bar graph, the lifetime is greatest for the plate material with least chromium, thus implicating chromium as a tribochemically active element attacking Fomblin Z-25.

Pepper, Stephen V.↗

Computing Contact Stresses In Gear Teeth

Improved method of computing contact stresses in gear teeth accounts for complicating effects like those of static and sliding friction. Provides iterative procedure for determination of contact region and nodal contact forces along with contact stresses. Method based on equations and computational procedure incorporating these effects routinely.

Oswald, Fred B.↗