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At least 307 records · Page 17

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NASA NTRS1977

Infrared heterodyne spectroscopy of atmospheric ozone

The absorption spectrum of atmospheric ozone is measured within a 1/cm region at 1100/cm, using an IR heterodyne detector (spectrometer with CO2 local oscillator) developed for astronomical work. Absorption spectra obtained by passing radiation from the tunable diode laser through an absorption cell, heterodyne spectra of atmospheric ozone, and a predicted atmospheric spectrum are compared. Water vapor absorbing in the region of interest (1100/cm) is also considered. Preliminary results encourage the use of diode laser local oscillators in tunable heterodyne detector systems for spectroscopy of atmospheric ozone and remote high-resolution spectroscopy of atmospheric constituents and pollutants.

Frerking, M. A.↗

NASA NTRS1977

Auger spectroscopy analysis in adhesion, friction and wear studies

The paper reviews the current use of Auger electron spectroscopy in adhesion, friction, wear and lubrication studies. Conventional Auger spectroscopy is adopted to complement LEED studies of the adhesion of metal single crystals. In addition, Auger cylindrical mirror analysis is applied to the study of changes in surface chemistry during dynamic friction and wear experiments on polycrystalline metals and alloys. Important conclusions are that (1) segregation of alloying elements to the surface of metals can alter adhesion behavior; (2) hydrocarbons are adsorbed readily to clean iron surfaces at 23 C; (3) transfer from one surface to another for dissimilar materials in contact can be followed in sliding or rubbing friction studies; and (4) the friction process can enhance surface activity for metals with hydrocarbons.

Buckley, D. H.↗

NASA NTRS1977

Double resonance spectroscopy of multiple-photon excited molecules

Multiple infrared photon absorption is a quite general process which molecules can undergo when placed in a high flux of infrared energy, such as the focussed beam of a CO2 laser. In order to understand how this process works, one must be able to follow the evolution of the molecules through their internal states, populated by photon absorption. Double-resonance spectroscopy is the method of a choice for getting at this information. A system pumped by CO2 laser radiation can be examined with a tunable laser probe beam, such as that from a lead-salt diode laser. From such an experiment, one can directly observe Rabi modulation of the absorption lines, determine elementary state-to-state relaxation pathways, and locate higher excited vibrational states. Systems currently under investigation include SF6 and vinyl chloride. In suitable cases, the probe beam can be a tunable visible or UV source, such as a dye laser. Fluorescence spectroscopy can then be used to monitor the transient absorptions produced by multiple-photon excitation. Among the systems which can be examined are biacetyl and glyoxal.

Steinfeld, J. I.↗

NASA NTRS1978

Photoacoustic spectroscopy of condensed matter

Photoacoustic spectroscopy is a new analytical tool that provides a simple nondestructive technique for obtaining information about the electronic absorption spectrum of samples such as powders, semisolids, gels, and liquids. It can also be applied to samples which cannot be examined by conventional optical methods. Numerous applications of this technique in the field of inorganic and organic semiconductors, biology, and catalysis have been described. Among the advantages of photoacoustic spectroscopy, the signal is almost insensitive to light scattering by the sample and information can be obtained about nonradiative deactivation processes. Signal saturation, which can modify the intensity of individual absorption bands in special cases, is a drawback of the method.

Somoano, R. B.↗

NASA NTRS1979

Infrared spectroscopy of stars

This paper reviews applications of IR techniques in stellar classification, studies of stellar photospheres, elemental and isotopic abundances, and the nature of remnant and ejected matter in near-circumstellar regions. Qualitative IR spectral classification of cool and hot stars is discussed, along with IR spectra of peculiar composite star systems and of obscured stars, and IR characteristics of stellar populations. The use of IR spectroscopy in theoretical modeling of stellar atmospheres is examined, IR indicators of stellar atmospheric composition are described, and contributions of IR spectroscopy to the study of stellar recycling of interstellar matter are summarized. The future of IR astronomy is also considered.

Merrill, K. M.↗

NASA NTRS1980

Infrared heterodyne spectroscopy in astronomy

A heterodyne spectrometer was constructed and applied to problems in infrared astronomical spectroscopy. The instrument offers distinct observational advantages for the detection and analysis of individual spectral lines at Doppler-limited resolution. Observations of carbon dioxide in planetary atmospheres and ammonia in circumstellar environments demonstrate the substantial role that infrared heterodyne techniques will play in the astronomical spectroscopy of the future.

Betz, A.↗

NASA NTRS1980

X-ray astronomical spectroscopy

The current status of the X-ray spectroscopy of celestial X-ray sources, ranging from nearby stars to distant quasars, is reviewed. Particular emphasis is placed on the role of such spectroscopy as a useful and unique tool in the elucidation of the physical parameters of the sources. The spectroscopic analysis of degenerate and nondegenerate stellar systems, galactic clusters and active galactic nuclei, and supernova remnants is discussed.

Holt, S. S.↗

NASA NTRS1979

Deep-level transient spectroscopy studies of Ni- and Zn-diffused vapor-phase-epitaxy n-GaAs

The paper presents deep-level transient spectroscopy studies of Ni- and Zn-diffused vapor-phase epitaxy n-GaAs. Nickel diffused into VPE n-GaAs reduces the hole diffusion length L sub p from 4.3 to 1.1 microns. Deep-level transient spectroscopy was used to identify energy levels in Ni-diffused GaAs; the as-grown VPE GaAs contains traces of these levels and an electron trap. Ni diffusion reduces the concentration of this level by an amount that matches the increase in concentration of each of the two Ni-related levels. A technique for measuring minority-carrier capture cross sections was developed, which indicates that L sub p in Ni-diffused VPE n-GaAs is controlled by the E sub c - 0.39 eV defect level.

Partin, D. L.↗

NASA NTRS1981

Electron spectroscopy of the diamond surface

The diamond surface is studied by ionization loss spectroscopy and Auger electron spectroscopy. For surfaces heated to temperatures not exceeding 900 C, the band gap was found to be devoid of empty states in the absence of electron beam effects. The incident electron beam generates empty states in the band gap and loss of structure in the valence band for these surfaces. A cross section of 1.4 x 10 to the -19th sq cm was obtained for this effect. For surfaces heated to temperatures exceeding 900 C the spectra were identical to those from surfaces modified by the electron beam. The diamond surface undergoes a thermal conversion in its electronic structure at about 900 C.

Pepper, S. V.↗

NASA NTRS1980

Wavelength-modulated photocapacitance spectroscopy

Derivative deep-level spectroscopy was achieved with wavelength-modulated photocapacitance employing MOS structures and Schottky barriers. The energy position and photoionization characteristics of deep levels of melt-grown GaAs and the Cr level in high-resistivity GaAs were determined. The advantages of this method over existing methods for deep-level spectroscopy are discussed.

Kamieniecki, E.↗

NASA NTRS1981

The use of ultrasonic spectroscopy to characterize calcified lesions

A quantitative basis is developed for the medical application of ultrasonic spectroscopy, particularly in the characterization of calcified lesions associated with atherosclerotic conditions. A theory of the field radiation patterns of disk and ring sources is presented which can be used to predict minima in the reflection spectra of a target as a function of frequency and angle relative to the acoustic axis. The theory is then tested experimentally for objects of known geometry by the use of a time delay spectroscopy system using a swept frequency technique, and results are obtained which demonstrate the usefulness of the technique. Finally, the theory is verified in the determination of lesion diameter and orientation from spectra received from calcified lesions on in vitro arterial specimens as a function of angle.

Rooney, J. A.↗

NASA NTRS1981

Ultraviolet spectroscopy of comets using sounding rockets, IUE and Spacelab

Ultraviolet spectroscopy is a very powerful tool for the study of cometary atmospheres since the four elemental cosmic species, H, C, N and O, as well as several simple molecules made from these species, have their strong resonance transitions in the ultraviolet region of the spectrum. However, due to the opacity of the atmosphere to ultraviolet, these observations must be made from space. Results are presented for observations of sevral comets along with plans for further cometary spectroscopy.

Feldman, P. D.↗

NASA NTRS1982

Molecular spectroscopy and planetary exploration from space

Examples of the role which molecular spectroscopy played in the interpretation of the thermal emission spectra of Earth, Mars, and Jupiter are given. Some advantages of molecular spectroscopy from a spacecraft passing close to a planet, or from an orbiter, over ground based techniques are discussed. Specifically the possibility of obtaining spectra over a wide spectral range (1) without the obscuring effect of Earth's atmosphere, (2) at much higher spatial resolution, and (3) from directions and with phase angles inaccessible from Earth.

Hanel, R.↗

NASA NTRS1982

Ultra high resolution molecular beam cars spectroscopy with application to planetary atmospheric molecules

The measurement of high resolution pulsed and continuous wave (CW) coherent anti-Stokes Raman spectroscopy (CARS) measurements in pulsed and steady state supersonic expansions were demonstrated. Pulsed molecular beam sources were characterized, and saturation of a Raman transition and, for the first time, the Raman spectrum of a complex molecular cluster were observed. The observation of CW CARS spectra in a molecular expansion and the effects of transit time broadening is described. Supersonic expansion is established as a viable technique for high resolution Raman spectroscopy of cold molecules with resolutions of 100 MH2.

Byer, R. L.↗

NASA NTRS1982

Evidence for high-altitude haze thickening on the dark side of Venus from 10-micron heterodyne spectroscopy of CO2

Infrared heterodyne spectroscopy provides data for isolated spectral lines with a spectral resolution which is small compared to the Doppler width. Heterodyne spectroscopy of CO2 lines near 10 micrometers was first reported for the atmosphere of Venus by Betz et al. (1976). The present investigation is concerned with observations of two absorption lines of (C-12)(O-16)2 conducted with an infrared heterodyne spectrometer interfaced with a solar telescope. The 10.8598-micrometer P(44) line was observed on the day side of Venus and the 10.3337-micrometer R(8) line was observed on the night side. It is shown that continuous opacity due to haze, and possible departures from vibrational LTE in CO2, are crucial considerations in fitting the observed lines.

Deming, D.↗

NASA NTRS1982

Atmospheric trace molecule spectroscopy

The Spacelab investigation entitled Atmospheric Trace Molecule Spectroscopy (ATMOS) is designed to obtain fundamental information related to the chemistry and physics of the Earth's upper atmosphere using the techniques of infrared absorption spectroscopy. There are two principal objectives to be met. The first is the determination, on a global scale, of the compositional structure of the upper atmosphere and its spatial variability. The establishment of this variability represents the first step toward determining the characteristic residence times for the upper atmospheric constituents; the magnitudes of their sources and sinks; and, ultimately, an understanding of their effects on the stability of the stratosphere. The second objective is to provide the high-resolution, calibrated spectral information which is essential for the detailed design of advanced instrumentation for subsequent global monitoring of specific species found to be critical to atmospheric stability. This information will be disseminated in the form of a three dimensional atlas of solar absorption spectra obtained over a range of latitudes, longitudes, and altitudes.

Farmer, C. B.↗

NASA NTRS1982

X-ray spectroscopy of the galaxy M87 - Radiative accretion of the hot plasma halo

Canizares et al. (1979) have reported the detection of the O VIII Lyman-alpha line from the vicinity of the giant elliptical galaxy M87 in the Virgo cluster. The detection is based on high-resolution X-ray spectroscopy studies performed with the Focal Plane Crystal Spectrometer on the Einstein Observatory. The presence of a strong O VIII line indicates the existence of some material which is cooler than the bulk of the X-ray emitting gas surrounding M87. The result is interpreted as favoring models which call for radiative accretion of the hot gas onto M87. The present investigation is concerned with further high-resolution X-ray spectroscopy of M87. Seven additional emission line blends due primarily to ionized iron have been detected. These data make it possible to derive the approximate distribution of the quantity of emitting material over more than a decade in temperature for the central part of the M87 source. The obtained results are in excellent agreement with expectations for radiative, pressure driven accretion.

Canizares, C. R.↗

NASA NTRS1982

Diamond /111/ studied by electron energy loss spectroscopy in the characteristic loss region

Unoccupied surface states on diamond (111) annealed at greater than 900 C are studied by electron energy loss spectroscopy with valence band excitation. A feature found at 2.1 eV loss energy is attributed to an excitation from occupied surface states into unoccupied surface states of energy within the bulk band gap. A surface band gap of approximately 1 eV is estimated. This result supports a previous suggestion for unoccupied band gap states based on core level energy loss spectroscopy. Using the valence band excitation energy loss spectrosocpy, it is also suggested that hydrogen is removed from the as-polished diamond surface by a Menzel-Gomer-Redhead mechanism.

Pepper, S. V.↗