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At least 307 records · Page 17

Polar stratospheric clouds and the ozone hole

An account is given of physical processes governing the formation of stratospheric particles, in order to dramatize the interactions between polar stratospheric clouds and the Antarctic ozone-destruction mechanism. Attention is given to the successive stages of particle nucleation, condensation/evaporation and sedimentation/coagulation phenomena, and the ways in which polar stratospheric clouds are observed. Considerable evidence exists that polar stratospheric cloud particles are composed of nitric acid. The relatively small Arctic ozone hole depletion is due to the much smaller duration of Arctic stratospheric clouds.

Hamill, Patrick↗

Planetary-scale disturbances in the southern stratosphere during early winter

The stratospheric circulation and planetary-scale dusturbances during early-winter (mid-April to mid-July) in the Southern Hemisphere are investigated using observational data collected for the 1979-1990 period, and a 3D primitive equation model of the stratosphere and mesosphere. It was found that there were six extended periods in the data set when wave 1 (which is usually quasi-stationary) traveled steadily eastward and had large amplitude. Results of simulations suggest that the development of the South Pacific warmings is connected with the amplification of wave 1 at 100 mb. The results also indicate that the development of stratospheric disturbances in the southern stratosphere during early winter depends more on the intensity of wave 1 at 100 mb than on the structure of the zonal-mean flow in the stratosphere.

Farrara, John D.↗

Statistical analysis of stratospheric temperature and ozone profile data for trends and model comparison

Work performed during the project period July 1, 1990 to June 30, 1992 on the statistical analysis of stratospheric temperature data, rawinsonde temperature data, and ozone profile data for the detection of trends is described. Our principal topics of research are trend analysis of NOAA stratospheric temperature data over the period 1978-1989; trend analysis of rawinsonde temperature data for the period 1964-1988; trend analysis of Umkehr ozone profile data for the period 1977-1991; and comparison of observed ozone and temperature trends in the lower stratosphere. Analysis of NOAA stratospheric temperature data indicates the existence of large negative trends at 0.4 mb level, with magnitudes increasing with latitudes away from the equator. Trend analysis of rawinsonde temperature data over 184 stations shows significant positive trends about 0.2 C per decade at surface to 500 mb range, decreasing to negative trends about -0.3 C at 100 to 50 mb range, and increasing slightly at 30 mb level. There is little evidence of seasonal variation in trends. Analysis of Umkehr ozone data for 12 northern hemispheric stations shows significant negative trends about -.5 percent per year in Umkehr layers 7-9 and layer 3, but somewhat less negative trends in layers 4-6. There is no pronounced seasonal variation in trends, especially in layers 4-9. A comparison was made of empirical temperature trends from rawinsonde data in the lower stratosphere with temperature changes determined from a one-dimensional radiative transfer calculation that prescribed a given ozone change over the altitude region, surface to 50 km, obtained from trend analysis of ozonsonde and Umkehr profile data. The empirical and calculated temperature trends are found in substantive agreement in profile shape and magnitude.

Tiao, G. C.↗

The atmospheric effects of stratospheric aircraft

This document presents a second report from the Atmospheric Effects of Stratospheric Aircraft (AESA) component of NASA's High-Speed Research Program (HSRP). This document presents a second report from the Atmospheric Effects of Stratospheric Aircraft (AESA) component of NASA's High Speed Research Program (HSRP). Market and technology considerations continue to provide an impetus for high-speed civil transport research. A recent United Nations Environment Program scientific assessment has shown that considerable uncertainty still exists about the possible impact of aircraft on the atmosphere. The AESA was designed to develop the body of scientific knowledge necessary for the evaluation of the impact of stratospheric aircraft on the atmosphere. The first Program report presented the basic objectives and plans for AESA. This second report presents the status of the ongoing research as reported by the principal investigators at the second annual AESA Program meeting in May 1992: Laboratory studies are probing the mechanism responsible for many of the heterogeneous reactions that occur on stratospheric particles. Understanding how the atmosphere redistributes aircraft exhaust is critical to our knowing where the perturbed air will go and for how long it will remain in the stratosphere. The assessment of fleet effects is dependent on the ability to develop scenarios which correctly simulate fleet operations.

Stolarski, Richard S.↗

Buffering of stratospheric circulation by changing amounts of tropical ozone - A Pinatubo case study

Stratospheric aerosol from Mount Pinatubo heated the tropical lower stratosphere by about 0.3 K/day mainly due to absorption of terrestrial infrared radiation. This heating was dissipated by: (1) an observed increase in stratospheric temperatures, which enhanced the radiation cooling; (2) additional mean upward motion, observed for the aerosol cloud, which led to adiabatic cooling; and (3) reductions in ozone concentrations resulting from enhanced upward motions. Each of these processes operated on a different time scale: maximum temperatures were observed after about 90 days; maximum ozone losses of about -1.5 ppm occurred after 140 days when the enhanced vertical velocities effectively lifted the ozone profile by about 2 km. We believe this shows that ozone plays an important role in buffering vertical motion in the tropical lower stratosphere, and hence the residual Brewer Dobson circulation of the whole stratosphere.

Kinne, S.↗

Modeling the quasi-biennial oscillation's effect on the winter stratospheric circulation

The influence of the equatorial quasi-biennial oscillation (QBO) on the winter middle atmosphere is modeled with a mechanistic global primitive equation model. The model's polar vortex evolution is sensitive to the lower stratosphere's tropical winds, with the polar vortex becoming more (less) disturbed as the lower stratospheric winds are more easterly (westerly). This agrees with the observed relationship between wintertime polar circulation strength and the phase of the QBO in the lower stratosphere. In these experiments it is the extratropical planetary Rossby waves that provide the tropical-extratropical coupling mechanism. More easterly tropical winds in the lower stratosphere act to confine the extratropical Rossby waves farther north and closer to the vortex at the QBO altitudes, weakening the vortex relative to the case of westerly QBO phase. While the QBO winds occur in the lower stratosphere, the anomaly in the polar vortex strength is strongest at higher levels.

O'Sullivan, Donal↗

Global normal-mode Rossby waves observed in stratospheric ozone data

Westward-propagating Rossby normal-mode planetary waves are documented in stratospheric ozone data using Solar Backscatter Ultraviolet (SBUV) satellite measurements. These modes are evidenced by enhanced spectral power and near-global coherence for westward-traveling zonal wave 1 oscillations with periods of 5-10 days. The ozone waves have maxima in high latitudes of the middle stratosphere (due to transport) and over midlatitudes in the upper stratosphere (due to photochemistry). These modes are nearly continuous throughout the eight years of SBUV observations, with maximum global coherence during the equinoxes. The upper-stratospheric waves are symmetric (in phase) between hemispheres, even for modes previously identified as antisymmetric in geopotential height. This behavior is due to differing wave vertical structure in each hemisphere; the planetary temperature waves are nearly in phase in the upper stratosphere, even though the height waves are out of phase. The observed ozone waves are furthermore compared to calculations based on linear wave transport and photochemistry, incorporating derived wind and temperature fields. Good agreement is found, showing that normal modes provide an idealized context to study the linear wave behavior of trace constituents in the real atmosphere.

Randel, William J.↗

Radon measurements in the lower tropical stratosphere - Evidence for rapid vertical transport and dehydration of tropospheric air

During the tropical experiment of NASA's Stratosphere-Troposphere Exchange Program (STEP), in situ radon and other trace constituent measurements were made aboard a NASA ER-2 high-altitude research aircraft to investigate the mechanisms of irreversible transfers from the troposphere into the tropical stratosphere. Observations made in and downwind of the cirrus shields of three large tropical cyclones and downwind of the cirrus anvil of a large cumulonimbus cloud cluster showed several clear instances of elevated radon activity occurring simultaneously with low total water mixing ratios. These observations are unambiguous evidence of an effective dehydration process, capable of reducing total water vapor mixing ratios to less than 2.5 ppmv, occurring in conjunction with troposphere-to-stratosphere transport and indicate that rapid localized convection, rather than slow regional mean motions, was responsible for the observed transports and associated with the accompanying dehydration. Radon activities measured in regions of active or recent troposphere-to-stratosphere transport were consistent with the 17 pCi/scm mean value needed to support the observed abundance of stratospheric 210 Pb.

Kritz, Mark A.↗

The coupling of the troposphere and stratosphere

A linear, time-dependent, primitive-equation, 3D numerical model is used to investigate the dynamical coupling between the troposphere and stratosphere through the vertical propagation of planetry waves. Attention is given to the roles of the tropopause in affecting the propagation of planetary waves and to the extent to which the stratosphere can determine its own wave driving, i.e., the sensitivity of the generation of the wave activity in the troposphere to the change of zonal wind in the stratosphere. Two maxima in Eliassen-Palm (EP) flux convergence are found for wave 1 in high latitudes, one in the upper stratosphere and the other in the upper troposphere. For wave 2 there is a third maximum north of the zero wind line in the tropical stratosphere. The formation of the maximum in EP-flux convergence in the upper troposphere is related to the dissipation of non-WKBJ waves near a local maximum of the refractive index. The existence of the local maximum in refractive index at the tropopause is a result of the great gradient of the buoyancy frequency as well as the vertical shear of the zonal flow there.

Chen, Ping↗

Effect of lightning on the concentration of odd nitrogen species in the lower stratosphere: An update

Revised model estimates of the effect of lightning on the lower stratospheric NOy are presented. Several changes in the Atmospheric and Environmental Research Incorporated model were made since the last evaluation of the impact of lightning. Improvements were made in the model circulation and location of tropopause in the tropics, which is now calculated from the National Meteorological Center temperature data. Changes in model circulation reduced the mass flux from the troposphere to the tropical stratosphere. The calculated mass fluxes are found to agree better with some recent estimates. The circulation changes also reduced the advective mass flux from the tropical lower stratosphere to the midlatitudes. The change in circulation and the change in the tropopause height lead to increases in the calculated concentration of N2O, O3 and NOy in the tropical lower stratosphere. The effect of lightning is to increase the calculated concentration of NOy around 64 mbar by a factor of 2, compared to a factor of 10 enhancement in the previous calculations. Comparison with the Stratosphere Troposphere Exchange Project 1987 data indicates that the inclusion of a lightning source brings the model results in closer agreement with the observations.

Kotamarthi, V. R.↗

Aerosol-associated changes in tropical stratospheric ozone following the eruption of Mount Pinatubo

The large amount of sulfuric acid aerosol formed in the stratosphere by conversion of sulfur dioxide emitted by the eruption of Mount Pinatubo (15.14 deg N, 120.35 deg E) in the Philippines around June 15, 1991, has had a pronounced effect on lower stratospheric ozone in the tropics. Measurements of stratospheric ozone in the tropics using electrochemical concentration cell (ECC) sondes before and after the eruption and the airborne UV differential absorption lidar (DIAL) system after the eruption are compared with Stratospheric Aerosol and Gas Experiment II (SAGE II) measurements from several years before the eruption and ECC sonde measurements from the year prior to the eruption to determine the resulting changes. Ozone decreases of up to 33 % compared with SAGE II climatological values were found to be directly correlated with altitude regions of enhanced aerosol loading in the 16- to 28-km range. A maximum partial-column decrease of 29 +/- Dobson units (DU) was found over the 16- to 28-km range in September 1991 along with small increases (to 5.9 +/- 2 DU) from 28 to 31.5 km. A large decrease of ozone was also found at 4 deg to 8 deg S from May to August 1992, with a maximum decrease of 33 +/- 7 DU found above Brazzaville in July. Aerosol data form the visible channel of the advanced very high resolution radiometer (AVHRR) and the visible wavelength of the UV DIAL system were used to examine the relationship between aerosol (surface area) densities and ozone changes. The tropical stratospheric ozone changes we observed in 1991 and 1992 are likely be explained by a combination of dynamical (vertical transport) perturbations, radiative perturbations on ozone photochemistry, and heterogeneous chemistry.

Grant, William B.↗

Evolution of the stratosphere during northern winter 1991/92 as diagnosed from U.K. Meteorological Office analyses

Meteorological analyses, produced at the U.K. Meteorological Office by data assimilation, are used to study the circulation of the stratosphere in the Northern Hemisphere during winter 1991/92. The analyses are supplemented by Lagrangian visualizations of the circulation. The main features discussed are (1) the changes in vertical structure of the circulation, (2) the merger of anticyclones that precipitated a strong stratospheric warming, (3) vortex roll up in the upper stratosphere, (4) the entrainment of air into the polar vortex in the middle and upper stratosphere, and (5) the influence of tropospheric blocking on the lower stratosphere. The study provides a meteorological basis for the interpretation of data from the Upper Atmosphere Research Satellite (UARS).

O'Neill, Alan↗

Simulation of stratospheric N2O in the NCAR CCM2: Comparison with CLAES data and global budget analyses

Global variability and budgets of stratospheric nitrous oxide (N2O) are studied using output from a stratospheric version of the National Center for Atmospheric Research Climate Model (CCM2). The model extends over 0-80 km, incorporating an N2O-like tracer with tropospheric source and upper-stratospheric photochemical sink, the latter parameterized using linear damping rates obtained from detailed two-dimensional model calculations. Results from the model over several seasonal cycles are compared with observations of N2O from the Cryogenic Limb Array Etalon Spectrometer (CLAES) instrument on the Upper Atmosphere Research Satellite (UARS). The model produces N2O structure and variability that is in reasonable agreement with the observations. Global budgets of stratospheric N2O are furthermore analyzed using model output, based on the transformed Eulerian-mean, zonal-mean framework. These budgets are used to quantify the importance of planetary wave constituent transport in the stratosphere, for both slow seasonal variations and fast planetary wave events. These results demonstrate that such wave fluxes act to form and sharpen the strong subtropical N2O gradients observed in satellite measurements.

Randel, William J.↗

Altitude dependence of stratospheric ozone trends based on Nimbus 7 SBUV data

A multiple regression statistical model is applied to estimate the altitude, latitude, and seasonal dependences of stratospheric ozone trends using 11.5 years of Nimbus 7 SBUV data for the period November 1978 to June 1990. In the upper stratosphere, the derived trends agree in both latitude dependence and approximate amplitude with published predictions from stratospheric models that consider gas-phase chemical processes together with the observed approx. 0.1 ppbV per year increase in tropospheric chlorine. The dominant contribution to column ozone trends occurs in the lower stratosphere where significant negative trends are present at latitudes greater than 20 deg in both hemispheres. The observed latitude dependence is qualitatively consistent with model predictions that include the effects of heterogeneous chemical ozone losses on lower stratospheric aerosols.

Hood, Lon L.↗

Global variations of zonal mean ozone during stratospheric warming events

Eight years of Solar Backscatter Ultraviolet (SBUV) ozone data are examined to study zonal mean variations associated with stratospheric planetary wave (warming) events. These fluctuations are found to be nearly global in extent, with relatively large variations in the tropics, and coherent signatures reaching up to 50 deg in the opposite (summer) hemisphere. These ozone variations are a manifestation of the global circulation cells associated with stratospheric warming events; the ozone responds dynamically in the lower stratosphere to transport, and photochemically in the upper stratosphere to the circulation-induced temperature changes. The observed ozone variations in the tropics are of particular interest because transport is dominated by zonal-mean vertical motions (eddy flux divergences and mean meridional transports are negligible), and hence, substantial simplifications to the governing equations occur. The response of the atmosphere to these impulsive circulation changes provides a situation for robust estimates of the ozone-temperature sensitivity in the upper stratosphere.

Randel, William J.↗

Relationship between ozone and temperature trends in the lower stratosphere: Latitude and seasonal dependences

A one-dimensional radiative transfer model with fixed dynamical heating is used to calculate the approximate latitude and seasonal dependences of lower stratospheric temperature changes associated with observed ozone trends. The spatial and temporal distribution of ozone profile trends in the lower stratosphere is estimated from a combination of Nimbus 7 Solar Backscattered Ultraviolet (SBUV) global measurements of the ozone column below 32 mbar for the period 1979-1990 and balloon ozonesonde profile trends at northern middle latitudes. The calculated temperature trends near 100 mbar compare favorably with those recently derived by Randel and Cobb (1994) using data from Channel 4 of the Microwave Sounding Unit (MSU) on the NOAA operational satellites, although a number of quantitative differences are found. An independent analysis reported here of 100 mbar temperatures derived from northern hemisphere radiosonde data at the Free University of Berlin (FUB) supports the validity of the satellite-derived lower stratospheric temperature trends. These results are therefore generally consistent with the hypothesis that observed lower stratospheric cooling trends are predominantly determined by reductions in radiative heating associated with stratospheric ozone depletion.

Mccormack, John P.↗

Towards a theory of tropical/midlatitude mass exchange from the earth's surface through the stratosphere

The main focus of this work is to understand the dynamics of mass exchange between the tropics and the midlatitudes and to determine any links between tropospheric exchange and that in the stratosphere. We have approached this problem from two different perspectives. The first is aimed towards understanding the troposphere's role in inducing lower stratospheric tropical/midlatitude exchange. For this project we focus on observational analysis of the lower stratosphere to assess the key regions of transport in/out of the tropics and to what extent this transport is driven by tropospheric processes. The second approach is to determine the extent to which stratospheric processes influence the troposphere. In this project we are performing potential vorticity (PV) inversions to assess the winds induced near the tropopause when the stratospheric polar vortex is displaced equatorward. These are each discussed in more detail in the subsections below. Also, we have organized a session on Tropical/Midlatitude Interaction and Transport at the Fall AGU where we will be showing our latest results.

Hartley, Dana↗

Interhemispheric differences in polar stratospheric HNO3, H2O, ClO, and O3

Simultaneous global measurements of nitric acid (HNO3), water (H2O), chlorine monoxide (ClO), and ozone (O3) in the stratosphere have been obtained over complete annual cycles in both hemispheres by the Microwave Limb Sounder on the Upper Atmosphere Research Satellite. A sizeable decrease in gas-phase HNO3 was evident in the lower stratospheric vortex over Antarctica by early June 1992, followed by a significant reduction in gas-phase H2O after mid-July. By mid-August, near the time of peak ClO, abundances of gas-phase HNO3 and H2O were extremely low. The concentrations of HNO3 and H2O over Antarctica remained depressed into November, well after temperatures in the lower stratosphere had risen above the evaporation threshold for polar stratospheric clouds, implying that denitrification and dehydration had occurred. No large decreases in either gas-phase HNO3 or H2O were observed in the 1992-1993 Arctic winter vortex. Although ClO was enhanced over the Arctic as it was over the Antarctic, Arctic O3 depletion was substantially smaller than that over Antarctica. A major factor currently limiting the formation of an Arctic ozone 'hole' is the lack of denitrification in the northern polar vortex, but future cooling of the lower stratosphere could lead to more intense denitrification and consequently larger losses of Arctic ozone.

Santee, M. L.↗