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NASA NTRS1991

Spectroscopic binary orbits from ultraviolet radial velocities. VIII - LZ Cephei (HD 209481)

We present a study of the double-lined spectroscopic binary LZ Cep based on high-resolution IUE spectra. We determine the radial velocities by using a cross-correlation technique incorporating profile fitting; this allows measurements of velocity separations down to unusually small values. The final velocity curve has a small but significant eccentricity. By considering other constraints, we construct a model for the system, which correctly predicts the light curve; in the model, the secondary fills its critical equipotential lobe. The secondary is conspicuously overluminous for its mass, and must have reached its present configuration following a phase of case A mass transfer.

Howarth, Ian D.↗

NASA NTRS1993

Determination of spectroscopic properties of atmospheric molecules from high resolution vacuum ultraviolet cross section and wavelength measurements

An account is given of progress during the six-month period 1 Nov. 1992 to 30 Apr. 1993 on work on (1) cross section measurements of the Schumann-Runge continuum; (2) the determination of the predissociation linewidths of the Schumann-Runge bands of O2; (3) the determination of the molecular constants of the ground state of O2; (4) cross section measurements of CO2 in wavelength region 120-170 nm; and (4) determination of dissociation energy of O2. The experimental investigations are effected at high resolution with a 6.65 m scanning spectrometer which is, by virtue of its small instrumental width (FWHM = 0.0013 nm), uniquely suitable for cross section measurements of molecular bands with discrete rotational structure. Below 175 nm and in the region of the S-R continuum, synchrotron radiation is suitable for cross section measurements. All of these spectroscopic measurements are needed for accurate calculations of the production of atomic oxygen and penetration of solar radiation into the Earth's atmosphere.

Parkinson, W. H.↗

NASA NTRS1993

Spectroscopic ellipsometry studies of HF treated Si (100) surfaces

Both ex situ and in situ spectroscopic ellipsometry (SE) measurements were employed to investigate the effects of HF cleaning on Si surfaces. The hydrogen-terminated (H-terminated) Si surface was modeled as an equivalent dielectric layer, and monitored in real time by SE measurements. The SE analyses indicate that after a 20-s 9:1 HF dip without rinse, the Si(100) surface was passivated by the hydrogen termination and remained chemically stable. Roughness of the HF-etched bare Si(100) surface was observed, in an ultrahigh vacuum (UHV) chamber, and analyzed by the in situ SE. Evidence for desorption of the H-terminated Si surface-layer, after being heated to approximately 550 C in the UHV chamber, is presented and discussed. This is the first use of an ex situ and in situ real-time, nondestructive technique capable of showing state of passivation, the rate of reoxidation, and the surface roughness of the H-terminated Si surfaces.

Yao, Huade↗

NASA NTRS1993

Spectroscopic ellipsometric characterization of Si/Si(1-x)Ge(x) strained-layer superlattices

Spectroscopic ellipsometry (SE) was employed to characterize Si/Si(1-x)Ge(x) strained-layer superlattices. An algorithm was developed, using the available optical constants measured at a number of fixed x values of Ge composition, to compute the dielectric function spectrum of Si(1-x)Ge(x) at an arbitrary x value in the spectral range 17 to 5.6 eV. The ellipsometrically determined superlattice thicknesses and alloy compositional fractions were in excellent agreement with results from high-resolution x ray diffraction studies. The silicon surfaces of the superlattices were subjected to a 9:1 HF cleaning prior to the SE measurements. The HF solution removed silicon oxides on the semiconductor surface, and terminated the Si surface with hydrogen-silicon bonds, which were monitored over a period of several weeks, after the HF cleaning, by SE measurements. An equivalent dielectric layer model was established to describe the hydrogen-terminated Si surface layer. The passivated Si surface remained unchanged for greater than 2 h, and very little surface oxidation took place even over 3 to 4 days.

Yao, H.↗

NASA NTRS1994

Mercury: Mid-infrared (7.3 - 13.5 microns) spectroscopic observations showing features characteristic of plagioclase

Mid-infrared spectroscopic observations of the surface of Mercury are reported for the wavelength range 7.3 to 13.5 microns. The observed spectral radiance emanated from equatorial and low latitude regions between 110-130 deg Mercurian longitude. The area is primarily an intercrater plain. The spectra show distinct and recognizable features, the principal Christiansen emission peak being the most prominent. The Christiansen feature strongly suggests the presence of plagioclase (Ca,Na)(Al,Si)AlSi2O8, (in particular labradorite: Ab(50) - Ab(30)). In addition we have studied the effects of thermal gradients to gain insight into the effects of thermal conditions on the spectral radiance of rock samples. This simulates the thermophysical effects as the rotating surface of Mercury is alternately heated and cooled. The spectral features of the samples are retained; however, the relative and absolute amplitudes vary as illustrated by laboratory reflectance and emittance spectra from quartzite.

Kozlowski, R. W. H.↗

NASA NTRS1994

Theoretical studies of spectroscopic problems of importance for atmospheric radiation measurements

Many of the instruments used to deduce the physical parameters of the Earth's atmosphere necessary for climate studies or for pollution monitoring (for instance, temperature versus pressure or number densities of trace molecules) rely on the existence of accurate spectroscopic data and an understanding of the physical processes responsible for the absorption or emission of radiation. During the summer, research was either continued or begun on three distinct problems: (1) an improved theoretical framework for the calculation of the far-wing absorption of allowed spectral lines; (2) a refinement of the calculation of the collision-induced fundamental spectrum of N2; and (3) an investigation of possible line-mixing effects in the fundamental spectrum of CH4. Progress in these three areas is summarized below. During the past few years, we have developed a theoretical framework for the calculation of the absorption of radiation by the far wings of spectral lines. Such absorption due to water vapor plays a crucial role in the greenhouse effect as well as limiting the retrieval of temperature profiles from satellite data. Several improvements in the theory have been made and the results are being prepared for publication. Last year we published results for the theoretical calculation of the absorption of radiation due to the dipoles induced during binary collisions of N2 molecules using independently measured molecular parameters; the results were in reasonable agreement with experimental data. However, recent measurements have revealed new fine structure that has been attributed to line-mixing effects. We do not think that this is correct, rather that the structure results from short-range anisotropic dipoles. We are in the process of including this refinement in our theoretical calculation in order to compare with the new experimental data. Subtle changes in the spectra of CH4 measured by researchers at Langley have also been attributed to line-mixing effects. By analyzing the same spectral lines we have attempted to verify or rule out possible line-mixing mechanisms. Due to the complexity and richness of the spectrum of this highly symmetric molecule, as well as the small magnitude of the effects, a detailed first-principle calculation of the mixing is a difficult problem. Before such a program is undertaken it is important to glean as much information as possible concerning the possible mechanisms by a systematic analysis of the existing data.

Tipping, Richard H.↗

NASA NTRS1995

Spectroscopic ellipsometry as a sensitive monitor of materials contamination

Spectroscopic ellipsometry is demonstrated to be extremely sensitive to contamination layers in the thickness range from 0.1 nm to 10 microns. In the present experiments we deposit either a thin lubricating oil (WD-40) or mineral oil continuously onto Ir, Cu, Al, Au, and V substrates from a bubbler, and monitor its thickness growth from sub-nanometer to tens of nanometers as a function of time. Re-evaporation of contaminant oils is also monitored in real-time by ellipsometry.

Hale, Jeffrey S.↗

NASA NTRS1994

A model for the spectroscopic variations of the peculiar symbiotic star MWC 560

In this note, we show that the ultraviolet and optical spectroscopic variability of this unique symbiotic star can be understood in terms of a time variable collimated stellar wind with a rapid acceleration near the source. Using the radial velocities observed during the ultraviolet bright phase, we find that a variation in the mass loss rate of a factor of ten can explain the ultraviolet spectral changes. The acceleration is far faster than normally observed in radiatively driven stellar winds and may be due to mechanical driving of the outflow from the disk.

Shore, Steven N.↗

NASA NTRS1994

W134: A new pre-main-sequence double-lined spectroscopic binary

We report the discovery that the pre-main-sequence star Walker 134 in the young cluster NGC 2264 is a double-lined spectroscopic binary. Both components are G stars with strong Li I 6708 A absorption lines. Twenty radial velocity measurements have been used to determined the orbital elements of this system. The orbit has a period of 6.3532 +/- 0.0012 days and is circular within the limits of our velocity resolution; e less than 0.01. The total system mass is stellar mass sin(exp 3) i = 3.16 solar mass with a mass ratio of 1.04. Estimates for the orbit inclination angle and stellar radii place the system near the threshold for eclipse observability; howerver, no decrease in brightness was seen during two attempts at photometric monitoring. The circular orbit of W 134 fills an important gap in the period distribution of pre-main-sequence binaries and thereby constrains the effectiveness of tidal orbital circularization during the pre-main sequence.

Padgett, Deborah L.↗

NASA NTRS1994

HD 53975: An O-type spectroscopic binary with a large mass ratio

We present radial velocities and line profiles of the O-type star HD 53975, which we find to be a spectroscopic binary with a period of 6.0173 days. Although there are no obvious signatures of the secondary in the line profiles, we have used the merit function of Shafter et al. (1980) to show that a secondary component is present in lines found in B-type spectra. We have compared the observed merit functions with merit functions for model profiles constructed assuming a main-sequence secondary, and this comparison consistently indicates a companion with a mass ratio of q = M(sub 2)/M(sub 1) = 0.23 +/- 0.04 and a magnitude difference Delta m = 3.3 +/- 0.4. We present a tomographic reconstruction of the spectrum of the secondary for these parameters. We suggest that other large mass ratio binaries may be found among the O stars when observed with high-resolution and high signal-to-noise ratio spectroscopy.

Gies, D. R.↗

NASA NTRS1991

Study of InGaAs-based modulation doped field effect transistor structures using variable-angle spectroscopic ellipsometry

Variable-angle spectroscopic ellipsometry was used to estimate the thicknesses of all layers within the optical penetration depth of InGaAs-based modulation doped field effect transistor structures. Strained and unstrained InGaAs channels were made by molecular beam epitaxy (MBE) on InP substrates and by metal-organic chemical vapor deposition on GaAs substrates. In most cases, ellipsometrically determined thicknesses were within 10% of the growth-calibration results. The MBE-made InGaAs strained layers showed large strain effects, indicating a probable shift in the critical points of their dielectric function toward the InP lattice-matched concentration.

Alterovitz, S. A.↗

NASA NTRS1995

Spectroscopic measurements of element abundances in the solar corona: Variations on the FIP theme

Solar wind and solar energetic particle (SEP) data yield systematic differences between elemental abundances in the corona and in the photosphere related to the first ionization potential (FIP) of the elements: low-FIP elements are preferentially enhanced relative to high-FIP elements by about a factor of four. Spectroscopic studies of the inner corona show that such a pattern may apply on average but not in detail for coronal loops: substantial abundance differences occur between different types of coronal structures, and variations have been found from flare to flare, from one active region to another, and over time in the same region; further, in some flares, anomalies such as enhanced Ne:O ratios, distinctly at odds with the FIP pattern, show that a competing element selection mechanism sometimes operates. Details of the observed abundance variability -- such as the magnitude of the variations, the relevant temporal and spatial scales, and correlations with other properties of the given coronal structure -- may give important clues to the processes which supply and heat the corona, or they may reflect the changing physical conditions or locations where those processes take place. However, many such details remain to be established definitively. At present, abundance variability is primarily a major complication to data analysis and interpretation. However, once it is better understood, it may provide a new diagnostic tool for probing the lower layers of the solar atmosphere.

Saba, J. L. R.↗

NASA NTRS1995

Spectroscopic Measurement Of Temperature And Pressure of O(2)

Spectroscopic technique useful in measuring temperature and pressure of oxygen in laboratory experiments involving high temperatures and/or high pressures. Devised for use in experiments in which oxygen or gas containing oxygen subjected to sudden adiabatic compression, as in shock tube. Also useful in combustion experiments and other experiments in which gaseous oxygen plays role.

Tapphorn, Ralph M.↗

NASA NTRS1995

Spectroscopic Investigation of Ce(3+) Doped Fluoride Crystals

Doping of the trivalent rare-earth cerium ion into fluoride crystals is of interest in producing turnable ultra-violet solid state lasers. These lasers are desirable for many applications in medicine, industry, and scientific research, including remote sensing. High absorption and stimulated emission cross sections of the dipole allowed 4f-5d transitions show promise in cerium as a laser ion in crystals. Several research groups have already reported the observation of stimulated emission of cerium in LiYF4, LiSrAlF6, and LiCaAlF6. However, the color center formation in the crystals due to the excited state absorption of ultra-violet pump light adds difficulty to achieving laser action. We have investigated the spectroscopic properties of cerium such as absorption and emission spectra, and lifetimes in four different fluoride crystals, including LiCaAlF6, LiSrAlF6, KyF4 and LiYF4. We have derived the polarized absorption and stimulated emission cross sections from transmission and fluorescence emission measurements for each of the host crystals. we have measured the lifetime of the lowest 5d level; moreover, investigated the temperature dependence of this lifetime and color center formation. Our results on absorption and stimulated emission cross sections for LiCaAlF6 and LiSrAlF6 are similar to the results already published.

Reinhart, Donald H.↗

NASA NTRS1995

Spectroscopic diagnostics of extended corona and solar wind with UVCS/Spartan

The primary goal of the Ultraviolet Coronal Spectrometer on Spartan 201 (UVCS/Spartan) is to make spectroscopic diagnostic measurements that can be used to derive plasma parameters in the extended solar corona where it is believed that significant heating of the corona and acceleration of the solar wind take place. Direct and indirect measurements of particle velocity distribution, thermal and non-thermal temperatures, and bulk outflow velocities are crucial to aid in the identification of physical processes that may be responsible for coronal heating and solar wind acceleration. UVCS/Spartan has made two flights in April 1993 and September 1994, the latter coinciding with the South Polar Passage of the Ulysses spacecraft. Observations were made of the large-scale structures and sub-structures of coronal holes and streamers at heliocentric heights between 1.5 solar radii and 3.5 solar radii. Measurements were made of H I Lyman-alpha intensities and profiles, and line intensities of minor ions like O(5+) and Fe(11+). We will present results from the flights and discuss how these measurements are used to constrain values for the proton thermal and non-thermal kinetic temperatures, proton bulk outflow velocities, and minor ion temperatures and bulk outflow velocities. Plans for the upcoming flight in July 1995 will also be discussed.

Strachan, L.↗

NASA NTRS1996

Characterization of SiGe/Ge heterostructures and graded layers using variable angle spectroscopic ellipsometry

Variable angle spectroscopic ellipsometry (VASE) has been used to characterize Si(x)Ge(1-x)/Ge superlattices (SLs) grown on Ge substrates and thick Si(x)Ge(1-x)/Ge heterostructures grown on Si substrates. Our VASE analysis yielded the thicknesses and alloy compositions of all layers within the optical penetration depth of the surface. In addition, strain effects were observed in the VASE results for layers under both compressive and tensile strain. Results for the SL structures were found to be in close agreement with high resolution x-ray diffraction measurements made on the same samples. The VASE analysis has been upgraded to characterize linearly graded Si(x)Ge(1-x) buffer layers. The algorithm has been used to determine the total thickness of the buffer layer along with the start and end alloy composition by breaking the total thickness into many (typically more than 20) equal layers. Our ellipsometric results for 1 (mu)m buffer layers graded in the ranges 0.7 less than or = x less than or = 1.0, and 0.5 less than or = x less than or = 1.0 are presented, and compare favorably with the nominal values.

Croke, E. T.↗

NASA NTRS1995

Characterization of High Ge Content SiGe Heterostructures and Graded Alloy Layers Using Spectroscopic Ellipsometry

Si(x)Ge(1-x)heterostructures on Si substrates have been widely studied due to the maturity of Si technology. However, work on Si(x)Ge)1-x) heterostructures on Ge substrates has not received much attention. A Si(x)Ge(1-x) layer on a Si substrate is under compressive strain while Si(x)Ge(1-x) on Ge is under tensile strain; thus the critical points will behave differently. In order to accurately characterize high Ge content Si(x)Ge(1-x) layers the energy shift algorithm used to calculate alloy compositions, has been modified. These results have been used along with variable angle spectroscopic ellipsometry (VASE) measurements to characterize Si(x)Ge(1-x)/Ge superlattices grown on Ge substrates. The results agree closely with high resolution x-ray diffraction measurements made on the same samples. The modified energy shift algorithm also allows the VASE analysis to be upgraded in order to characterize linearly graded layers. In this work VASE has been used to characterize graded Si(x)Ge(1-x) layers in terms of the total thickness, and the start and end alloy composition. Results are presented for a 1 micrometer Si(x)Ge(1-x) layer linearly graded in the range 0.5 less than or equal to x less than or equal to 1.0.

Heyd, A. R.↗

NASA NTRS1997

Determination of Spectroscopic Properties of Atmospheric Molecules from High Resolution Vacuum Ultraviolet Cross Section and Wavelength Measurements

An account is given of progress during the period 8/l/96-7/31/97 on work on (a) cross section measurements of O2 S-R using a Fourier transform spectrometer (FTS) at the Photon Factory in Japan; (b) the determination of the predissociation linewidths of the Schumann-Runge bands (S-R) of 02; (c) cross section measurements of 02 Herzberg bands using a Fourier transform spectrometer (FTS) at Imperial College; and (d) cross section measurements of H2O in the wavelength region 120-188 nm. The experimental investigations are effected at high resolution with a 6.65 m scanning spectrometer and with the Fourier transform spectrometer. Below 175 nm, synchrotron radiation is most suitable for cross section measurements in combination with spectrometers at the Photon Factory Japan. Cross section measurements of the Doppler limited bands depend on using the very high resolution, available with the Fourier transform spectrometer, (0.025/cm resolution). All of these spectroscopic measurements are needed for accurate calculations of the production of atomic oxygen, the penetration of solar radiation into the Earth's atmosphere, and photochemistry of minor molecules.

Parkinson, W. H.↗