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At least 307 records · Page 17

Temperature distributions and gradients in laser-heated plasmas relevant to magnetized liner inertial fusion

We present two-dimensional temperature measurements of magnetized and unmagnetized plasma experiments performed at Z relevant to the preheat stage in magnetized liner inertial fusion. The deuterium gas fill was doped with a trace amount of argon for spectroscopy purposes, and time-integrated spatially resolved spectra and narrow-band images were collected in both experiments. The spectrum and image data were included in two separate multiobjective analysis methods to extract the electron temperature spatial distribution T e ( r , z ) . The results indicate that the magnetic field increases T e , the axial extent of the laser heating, and the magnitude of the radial temperature gradients. Comparisons with simulations reveal that the simulations overpredict the extent of the laser heating and underpredict the temperature. Temperature gradient scale lengths extracted from the measurements also permit an assessment of the importance of nonlocal heat transport.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Final Measurement of the 235 U Antineutrino Energy Spectrum with the PROSPECT-I Detector at HFIR

This Letter reports one of the most precise measurements to date of the antineutrino spectrum from a purely 235 U-fueled reactor, made with the final dataset from the PROSPECT-I detector at the High Flux Isotope Reactor. By extracting information from previously unused detector segments, this analysis effectively doubles the statistics of the previous PROSPECT measurement. Further, the reconstructed energy spectrum is unfolded into antineutrino energy and compared with both the Huber-Mueller model and a spectrum from a commercial reactor burning multiple fuel isotopes. A local excess over the model is observed in the 5–7 MeV energy region. Comparison of the PROSPECT results with those from commercial reactors provides new constraints on the origin of this excess, disfavoring at 2.0 and 3.7 standard deviations the hypotheses that antineutrinos from 235 U are solely responsible and noncontributors to the excess observed at commercial reactors, respectively.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Revisiting the assignment of atomic charges in metal oxides based on core-level x-ray photoelectron spectra: The case of Ti in SrTiO3(001)

We demonstrate that assigning formal charges to transition metal (TM) cations based on core-level (CL) x-ray photoemission binding energies in oxides leads to physically inconsistent pictures of electronic structure. O 2p–TM 3d hybridization is well known to result in significant covalency in TM–O bonds, thereby reducing TM cation charges from their fully ionic values. However, the ionic bonding model remains the working paradigm for assigning TM CL features, and the resulting cation charges are often taken to be representative of the material under study. Here, we show that a more physically meaningful way to assign charges is to extract information about charge distributions utilizing Dirac–Hartree–Fock theory to calculate CL spectra from first principles and then use the resulting wave functions to determine charges based on orbital occupancies. TM cation charges can also be determined using density functional theory and Bader population analysis. We illustrate these two methods using the Ti 2p spectrum for SrTiO3(001) and show that the agreement between them is excellent. Significantly, the resulting Ti charge is considerably lower than the formal charge. The high degree of similarity between the Ti 2p spectrum for SrTiO3 and those for the rutile and anatase polymorphs of TiO2 suggests that the charge densities surrounding Ti in the latter materials are similar to that in SrTiO3. Taking a broader perspective, oxides containing other first-row transition metals also exhibit covalent character, leading to TM cation charges lower than the analogous fully ionic values in these materials as well.

Chambers, Scott A. (ORCID:000000025415043X)↗

Sulfur Pellets Responses to a Bare and Steel Reflected Pulse of the Oak Ridge National Laboratory Health Physics Research Reactor

The experiments analyzed in this report were conducted at the Health Physics Research Reactor (HPRR), also known as the $\textit{Fast Burst Reactor}$. The reactor was designed and built at Oak Ridge National Laboratory (ORNL) in 1961. The HPRR was an unmoderated, unshielded fast reactor that used highly enriched uranium and molybdenum alloy as fuel. The reactor was initially sent to the Nevada Test Site in 1962, where it was used to evaluate radiation doses received as a result of the Hiroshima and Nagasaki bombings during World War II. A few years later, the reactor was sent back to ORNL to be part of the Dosimetry Application Research (DOSAR) facility shown in Figure 1, which included a reactor building shown on the left (west) of the picture and a control and laboratory building in the upper right corner (northeast). The critical assembly was used for numerous technical studies, including systems calibration, dosimetry, radiobiology of plants and animals, testing of radiation alarms, as well as teaching and training in radiation dosimetry and nuclear engineering. Between 1963 and 1987, the HPRR was operated for thousands of hours, achieving criticality close to 10,000 times and motivating many publications. The HPRR was decommissioned in 1987. The goal of this effort was to use historical data from operation of the HPRR to create a criticality accident alarm system (CAAS) benchmark to be included in the $\textit{International Handbook of Evaluated Criticality Safety Benchmark Experiments}$ (ICSBEP Handbook). A thorough inspection was performed of all available documentation and information available. The most promising experiments that were selected for evaluation were those described in the 1987 ORNL report entitled $\textit{Health Physics Research Reactor Reference Dosimetry}$, ORNL-6240. The report includes reference dosimetry results of the shielded and unshielded configurations of the HPRR after burst operations. Because of changes to the reactor positioning and storage systems that were made in 1985, the previous dosimetry reports became obsolete, and the newly designed experiments were needed to create the HPRR’s adjusted dosimetry data. The various results reported in ORNL-6240 include reference doses and dose equivalents from different conventions at different distances and elevations as determined using the detected neutron fluence and conversion factors. The HPRR neutron fluence was obtained through different methods, including sulfur pellet analysis and threshold detector unit data. Information about the HPRR spectrum was also obtained through Bonner sphere measurements. This benchmark is focused on a part of the measured sulfur fluences reported in Appendix H of ORNL-6240. Standard commercial sulfur pellets were placed at different distances from the HPRR centerline during burst operation and were activated due to the 32 S(n,p) 32 P reaction. The resulting 32 P activity was then measured and the information about the corresponding sulfur fluence and/or neutron dose could be extracted. Many of those measurements have 7 been performed with the HPRR in its bare configuration or with different shields (combinations of Lucite, concrete, steel). All the necessary, precise information about material and/or dimensions of the different shields was not found, so it was decided to focus only on the unshielded and steel-shielded configurations to minimize the benchmark uncertainty. A total of 31 cases (24 unshielded and 7 shielded cases at different positions) of sulfur fluence were selected before evaluation to develop the benchmark.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Modeling Carbon-Based Nanomaterials (CNMs) and Derived Composites and Devices

A review of different modeling techniques, specifically in the framework of carbon-based nanomaterials (CNMs, including nanoparticles such as graphene and carbon nanotubes—CNTs) and the composites and devices that can be derived from them, is presented. The article emphasizes that the overall performance of these materials depends on mechanisms that operate across different time and spatial scales, requiring tailored approaches based on the material type, size, internal structure/configuration, and the specific properties of interest. Far from attempting to cover the entire spectrum of models, this review examines a wide range of analysis and simulation techniques, highlighting their potential use, some of their weaknesses and strengths, and presenting the latest developments and some application examples. In this way, it is shown how modeling can provide key information for tailoring or designing new materials for specific components or systems or to obtain certain functionalities. At the same time, it is revealed to be an area constantly undergoing development and improvement, as evidenced by the progress made by various of these techniques and the new modeling approaches that have emerged in recent years.

Chiminelli, Agustίn (ORCID:0000000230312107)↗

Modification of conventional peak shapes to accurately represent spectral asymmetry: High-Resolution X-ray photoelectron spectra of [C 4 C 1 Pyrr][NTf 2 ] and [C 8 C 1 Im][NTf 2 ] ionic liquids

X-ray photoelectron spectroscopy (XPS) is one of the most widely used techniques for surface characterization. Analysis of XPS data is challenging and requires the analyst to fit the data with synthetic line shapes to reach physically meaningful interpretations. Experimental spectral envelopes, however, are complex and display asymmetric features that are often ignored or attributed to additional chemical components. The high-resolution XPS spectra of [C 4 C 1 Pyrr][NTf 2 ] and [C 8 C 1 Im][NTf 2 ] all exhibit a degree of asymmetry which is systematically observed at the higher binding energy side of photoemission envelopes. Here, we present the development of a refined fitting procedure for XPS spectra of these ionic liquid-based systems which include (a) Shirley background offset necessary to account for the insulator-like region and (b) spectral asymmetry in C 1s and N 1s regions. Further, Shirley and trapezoid components are applied to compensate for inelastic scattering taking place during electron transitions as high as 7.8 eV above the start of the fitting region in C 1s high-resolution spectrum. To demonstrate the fitness of this model, we present an analysis of a 2:1 mixture of [C 4 C 1 Pyrr][NTf 2 ]: [C 8 C 1 Im][NTf 2 ].

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Survey on stochastic distribution systems: A full probability density function control theory with potential applications

Complex systems seen either in general engineering practice or economics are subjected to ever increased uncertainties that are mostly represented as random variables or parameters, and the characteristics of random variables are represented by their probability density functions (PDFs). Controlling their PDFs means to shape their stochastic distributions and in general it would provide a full treatment for system analysis and operational control and optimization. This leads to the development of stochastic distribution control (SDC) systems theory in the past decades, where the original aim of the controller design is to realize a shape control of the distributions of certain random variables in their PDFs sense for some engineering processes. Indeed, once the PDFs of these random variables or parameters are used to describe their distribution characters, the control task is to obtain control signals so that the output PDFs of stochastic systems are made to follow their target PDFs. The subject of SDC was initially originated for non-Gaussian stochastic control systems design but has found a wide spectrum of applications in general systems in terms of data-driven modeling, analysis, signal processing (filtering), data mining via multivariable statistics, decision-making (optimization) for systems subjected to uncertainties and even in economics. In this context, SDC constitutes an effective primer tool for complex system analysis, control and operational optimizations. In this review paper, a detailed survey of the developments on the research of SDC systems will be made together with their wide spectrum applications and future perspectives.

42 ENGINEERING↗

A Transductive Graph Neural Network learning for Grid Resilience Analysis

Power grids are critical infrastructures that require robust resilience analysis to ensure reliable and uninterrupted electricity supply. Traditional simulation-based methods for grid resilience analysis suffer from computational complexity and limited ability to capture the full spectrum of potential disruptions. This paper presents a novel approach to enhance grid resilience by leveraging transductive graph neural network (GNN) learning to identify critical nodes and links. By leveraging the graph structure and system features, GNNs effectively learn resilience metrics and accurately identify critical nodes based on actual grid operational behavior. The efficacy of the proposed approach is demonstrated through case studies on node criticality scoring and critical node/line identification in cascading outage scenarios. The results highlight the advantages of learning-based methods over traditional simulation-based approaches and their potential to revolutionize grid resilience analysis. The contributions of this paper include a graph-based scalable approach for fast cascading analysis, an inductive formulation for training GNN models, and a transfer learning-based approach to scale the model to largescale power systems.

grid resilience, graph neural networks, transducti↗

As-run physics analysis for the EPRI-2 experiment for cycle 153B

The purpose of this ECAR is to document the as-run physics analysis and source term in Curies and decay heat rate (Watts) for the shipment of the EPRI-2 experiment located in the Center Flux Trap (CFT). EPRI-2 was irradiated during cycle 153B. The experiment irradiation ended on April 13, 2013. The as-run heat rates and flux/fluence results were calculated using the MCNP ATR full core model. The heat rates and flux are calculated based on an average center lobe power of 30.8 MW. The fluence is based on the operating time of 13.45 days. ORIGEN2 Version 2.2 is used to determine the decay heat rate, gamma spectrum, and source term for the EPRI-2 experiment. The source term analysis was performed as requested by the project staff to demonstrate compliance with shipping requirements in the GE-2000 cask following irradiation as well as provide an estimated source term to support Post-Irradiation Examination as needed.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Hyper Suprime-Cam Year 3 results: Cosmology from cosmic shear power spectra

Here, we measure weak lensing cosmic shear power spectra from the 3-year galaxy shear catalog of the Hyper Suprime-Cam (HSC) Subaru Strategic Program imaging survey. The shear catalog covers 416 deg 2 of the northern sky, with a mean i-band seeing of 0.59 arcsec and an effective galaxy number density of 15 arcmin —2 within our adopted redshift range. With an i-band magnitude limit of 24.5 mag, and four tomographic redshift bins spanning 0.3 ≤ z ph ≤ 1.5 based on photometric redshifts, we obtain a high-significance measurement of the cosmic shear power spectra, with a signal-to-noise ratio of approximately 26.4 in the multipole range 300 < ℓ < 1800. The accuracy of our power spectrum measurement is tested against realistic mock shear catalogs, and we use these catalogs to get a reliable measurement of the covariance of the power spectrum measurements. We use a robust blinding procedure to avoid confirmation bias, and model various uncertainties and sources of bias in our analysis, including point spread function systematics, redshift distribution uncertainties, the intrinsic alignment of galaxies and the modeling of the matter power spectrum. For a flat Λ CDM model, we find S 8 ≡ σ 8 (Ω m /0.3) 0.5 = ${0.776}_{—0.033}^{+0.032}$, which is in excellent agreement with the constraints from the other HSC Year 3 cosmology analyses, as well as those from a number of other cosmic shear experiments. This result implies a ~2σ-level tension with the Planck 2018 cosmology. We study the effect that various systematic errors and modeling choices could have on this value, and find that they can shift the best-fit value of S 8 by no more than ~ 0.5σ, indicating that our result is robust to such systematics.

79 ASTRONOMY AND ASTROPHYSICS↗

Trace Elemental Analysis of Bulk Thorium Using an Automated Separation–Inductively Coupled Plasma Optical Emission Spectroscopy Methodology

Presented here is a novel automated method for determining the trace element composition of bulk thorium by inductively coupled plasma–optical emission spectroscopy (ICP-OES). ICP-OES is a universal approach for measuring the trace elemental impurities present in actinide-rich materials; however, due to the emission rich spectrum of the actinide, a separation from the trace elements is warranted for spectrochemical analysis. Here, AG MP-1 ion exchange resin was utilized for retention of the Th matrix, while allowing the trace element impurities to be separated prior to subsequent analysis using ICP-OES. After demonstrating the separation on traditional gravity-driven columns, the methodology was transitioned to an automated platform for comparison. This automated platform utilizes syringe-driven sample and solvent flow and can collect the trace element and thorium fractions in separate locations. Finally, while reducing the sample size (500 µL, 1.5 mg of Th), maintaining the overall separation efficiency (recoveries >95%), and illustrating the sample throughput ability (n = 10+), this automated methodology could be readily adopted to nuclear facilities in which the determination of trace elemental impurities in Th samples is warranted.

47 OTHER INSTRUMENTATION↗

Machine learning-driven predictive resource management in complex science workflows

Here, the collaborative efforts of large communities in science experiments, often comprising thousands of global members, reflect a monumental commitment to exploration and discovery. Recently, advanced and complex data processing has gained increasing importance in science experiments. Data processing workflows typically consist of multiple intricate steps, and the precise specification of resource requirements is crucial for each step to allocate optimal resources for effective processing. Estimating resource requirements in advance is challenging due to a wide range of analysis scenarios, varying skill levels among community members, and the continuously increasing spectrum of computing options. One practical approach to mitigate these challenges involves initially processing a subset of each step to measure precise resource utilization from actual processing profiles before completing the entire step. While this two-staged approach enables processing on optimal resources for most of the workflow, it has drawbacks such as initial inaccuracies leading to potential failures and suboptimal resource usage, along with overhead from waiting for initial processing completion, which is critical for fast-turnaround analyses. In this context, our study introduces a novel pipeline of machine learning models within a comprehensive workflow management system, the Production and Distributed Analysis (PanDA) system. These models employ advanced machine learning techniques to predict key resource requirements, overcoming challenges posed by limited upfront knowledge of characteristics at each step. Accurate forecasts of resource requirements enable informed and proactive decision-making in workflow management, enhancing the efficiency of handling diverse, complex workflows across heterogeneous resources.

97 MATHEMATICS AND COMPUTING↗

DUNE-PRISM – A New Method to Measure Neutrino Oscillations

The Deep Underground Neutrino Experiment (DUNE) is a next-generation long baseline neutrino oscillation experiment designed to make precision measurements in a 1.2 2.4 MW neutrino beam, which is directed 1285 km from the Fermi National Accelerator Laboratory (Fermilab) to the Sandford Underground Research Facility (SURF) in South Dakota. Neutrinos are measured at two detector facilities: a near detector located at Fermilab close where the beam is produced and a far detector at SURF. The neutrino beam can be configured to be composed primarily of either muon or anti-muon neutrinos. DUNE measures the disappearance of muon and anti-muon neutrinos and appearance electron and anti-electron neutrinos in the neutrino beam. Measuring these neutrino flavour transitions provides DUNE with sensitivity to the neutrino mass ordering, $\delta_{CP}$, $\theta_{13}$, $\theta_{23}$ and the magnitude of $\Delta m^2_{23}$. The DUNE Precision Reaction Independent Spectrum Measurement (DUNE-PRISM) concept presents a novel way to perform a neutrino oscillation analysis, which has the potential to significantly reduce the impact of large systematic uncertainties in the neutrino interaction model. The PRISM method linearly combines measurements of off-axis neutrino interactions at the DUNE near detector to produce data-driven predictions of the oscillated neutrino event rate spectrum at the far detector. By building an oscillated far detector prediction directly from data, any unknown or poorly modelled neutrino interaction effects will be naturally incorporated into the measurement of the parameters of the neutrino oscillation model. This thesis presents the first complete neutrino oscillation analysis for DUNE using the PRISM method. Details of the methodology are fully explained and the prospects for further improvements to the techniques described are highlighted. The expected impact and relative importance of the neutrino flux, cross section and detector systematic uncertainties are described in detail. Finally, this thesis demonstrates that the PRISM method is capable of performing a measurement of the oscillation parameters that is robust against neutrino interaction modelling errors.

Hasnip, Ciaran↗

Analysis of BOSS galaxy data with weighted skew-spectra

We present the first application of the weighted skew-spectra to analyze non-Gaussian information in galaxy survey data. Using the tree-level galaxy skew-spectra together with the one-loop power spectrum multipoles, we analyze the Sloan Digital Sky Survey (SDSS)-III Baryon Oscillation Spectroscopic Survey (BOSS) galaxy clustering data, and target our search towards the equilateral bispectrum shape of primordial non-Gaussianity. We use the Effective Field Theory model for the galaxy power spectrum and bispectrum, and account for systematic effects, such as the survey geometry. From our likelihood analysis, we find f NL equil = -34 +296 -334 at 68% CL, consistent with previous works, while systematic errors from our treatment of the survey geometry lead to an unreliable estimation of f NL ortho . As a result, we further constrain the bias and counterterm parameters, while keeping the cosmology fixed to Planck 2018 values. As a check, we also validate our analysis pipeline using theNseries simulation suite.

79 ASTRONOMY AND ASTROPHYSICS↗

DESI 2024 VII: cosmological constraints from the full-shape modeling of clustering measurements

We present cosmological results from the measurement of clustering of galaxy, quasar and Lyman-α forest tracers from the first year of observations with the Dark Energy Spectroscopic Instrument (DESI Data Release 1). We adopt the full-shape (FS) modeling of the power spectrum, including the effects of redshift-space distortions, in an analysis which has been thoroughly validated in a series of supporting papers as summarised in [1]. We combine the full-shape information with DESI's DR1 constraints from the baryon acoustic oscillations (BAO) of these tracers. In the flat ΛCDM cosmological model, DESI (FS+BAO), combined with a baryon density prior from Big Bang Nucleosynthesis and a weak prior on the scalar spectral index, determines matter density to Ω m = 0.2962 ± 0.0095, and the amplitude of mass fluctuations to σ 8 = 0.842 ± 0.034. The addition of the cosmic microwave background (CMB) data tightens these constraints to Ω m = 0.3056 ± 0.0049 and σ 8 = 0.8121 ± 0.0053, while further addition of the joint clustering and lensing analysis from the Dark Energy Survey Year-3 (DESY3) data further improves these measurements, and leads to a 0.4% determination of the Hubble constant, H 0 = (68.40 ± 0.27) km s -1 Mpc -1 . In models with a time-varying dark energy equation of state parametrised by w 0 and w a , combinations of DESI (FS+BAO) with CMB and type Ia supernovae continue to show the preference, previously found in the DESI DR1 BAO analysis, for w 0 > -1 and w a < 0 with similar levels of significance. DESI data, in combination with the CMB, improve the upper limits on the sum of the neutrino masses relative to the case when only the DR1 BAO was available, giving ∑m ν < 0.071 eV at 95% confidence. We finally constrain deviations from general relativity represented by two modified gravity parameters. DESI (FS+BAO) data alone measure the parameter that controls the clustering of massive particles, μ 0 = 0.11 +0.45 -0.54 , in agreement with the zero value predicted by general relativity. The combination of DESI with the CMB and the clustering and lensing analysis from DESY3 constrains both modified-gravity parameters, giving μ 0 = 0.04 ± 0.22 and Σ 0 = 0.044 ± 0.047, again in agreement with general relativity.

79 ASTRONOMY AND ASTROPHYSICS↗

Cumulative fission yields of short-lived fission products from 235 U and 239 Pu measured by HPGe gamma-ray spectroscopy

In this study, we present a preliminary investigation focused on determining cumulative fission yields for short-lived fission products. Our analysis involves examining gamma spectra from the irradiated samples of 235 U and 239 Pu using the High Flux Isotope Reactor. The motivation stems from the observed discrepancy in the antineutrino energy spectrum within the range of 5 to 7 MeV. While several hypotheses have been proposed, a thorough analysis of fission yields provides an additional way of gaining insight into this unexplained phenomenon. Our study suggests that the measured gamma rays from 100 Nb, 140 Cs and 95 Sr are consistent with the expected values. However, 93 Rb, 96 Y, 97 Y and 142 Cs cannot be quantified due to insufficient statistics, interference from other gamma rays and the Compton scattering background. Additionally, the calculated cumulative fission yields based on the measured 140 Cs and 95 Sr are found to be consistent with the JEFF3.3 fission yield library. In conclusion, the present work shows that the potential of improving gamma-ray spectroscopy in the fission yields as a means to improve our understanding of the antineutrino spectrum.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Revealing pressure-driven structural transitions in the hybrid improper ferroelectric Sr 3 Sn 2 O 7

In this work, we combine diamond anvil cell techniques and synchrotron-based infrared spectroscopy with a detailed symmetry analysis and lattice dynamics calculations to uncover a series of pressure induced structural phase transitions in the hybrid improper ferroelectric Sr 3 Sn 2 O 7 . The microscopic character of each high pressure phase is determined by comparing the measured spectrum with the predicted vibrational patterns of several related but distinct candidate space groups. Our analysis reveals a sequence of compression-induced transitions from A2 1 am ↔ Pnab ↔ Acaa ↔ I4/mmm at room temperature. Remarkably, this space group progression matches the sequence of temperature-dependent structural transitions observed in Sr 3 Sn 2 O 7 between 77 and 1000 K. Other hybrid improper ferroelectrics display a similar set of transitions, suggesting that pressure and probably strain will be very effective tuning parameters for this entire class of materials.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Power spectrum and form factor in random diagonal matrices and integrable billiards

Triggered by a controversy surrounding a universal behavior of the power spectrum in quantum systems exhibiting regular classical dynamics, we focus on a model of random diagonal matrices (RDM), often associated with the Poisson spectral universality class, and examine how the power spectrum and the form factor get affected by two-sided truncations of RDM spectra. Having developed a nonperturbative description of both statistics, we perform their detailed asymptotic analysis to demonstrate explicitly how a traditional assumption (lying at the heart of the controversy) – that the power spectrum is merely determined by the spectral form factor – breaks down for truncated spectra. This observation has important consequences as we further argue that bounded quantum systems with integrable classical dynamics are described by heavily truncated rather than complete RDM spectra. High-precision numerical simulations of semicircular and irrational rectangular billiards lend independent support to these conclusions.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗