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NASA NTRS2017

Novel Polyimide Battery Separator Imbibed with Room-Temperature Ionic Liquids

The journey to Mars will require advancements in many existing technologies, including space power and energy storage systems. According to the 2015 NASA Technology Roadmaps, energy storage is a critical technology area to develop for both terrestrial as well as future long-term space missions. Currently, batteries represent one of the major areas in need of advancement, both in terms of energy density as well as safety. Recently, concerns regarding the fire safety of commercial lithium-ion batteries have prompted efforts to produce nonflammable battery components, namely the electrolyte and separator. Commercial lithium-ion batteries utilize polyolefin separators imbibed with a lithium salt dissolved in cyclic carbonates. This separator/electrolyte combination imparts good ionic conductivities in the range of 10(exp -2) to 10(exp -3) S/cm. However, the cyclic carbonates and polyolefin separator are inherently flammable. Room-temperature ionic liquids (RTILs) appear to be a safer alternative to cyclic carbonates. They offer good ionic conductivities, similar to those observed in cyclic carbonates, but are inherently nonvolatile and nonflammable giving them a safety advantage. Many promising RTILs for battery electrolytes are not compatible with commercial polyolefin separator materials. Polyimide aerogels possess an open-porous, fibrillar network architecture which offers a high degree of porosity (typically greater than 85 porous), required for lithium ion conduction, as well as good mechanical properties. Furthermore, these materials are compatible with all tested RTILs. By creating a polyimide gel and imbibing the gel with a RTIL containing a lithium salt instead of super critically drying them to form aerogels, a nonflammable separator/electrolyte system with conductivities in the range of 1x10(exp -3) S/cm has been demonstrated.

Polyimide↗

NASA NTRSDate not supplied

Cryogenic Fluid Management Technologies Enabling for the Artemis Program and Beyond

NASA is endeavoring on an ambitious return to the Moon and eventually on to Mars through the Artemis Program leveraging innovative technologies to establish sustainable exploration architectures collaborating with US commercial and international partners[1]. Future NASA architectures have baselined cryogenic propulsion systems to support lunar missions and ultimately future missions to Mars. NASA has been investing in maturing CFM active and passive storage, transfer, and gauging technologies over the last decade plus primarily focused on ground development with a few small-scale microgravity fluid experiments. Recently, NASA created a Cryogenic Fluid Management (CFM)Technology Roadmap identifying the critical gaps requiring further development to reach a technology readiness level (TRL) of 6 prior to infusion to flight applications. To address the technology gaps the Space Technology Mission Directorate(STMD)strategically plans to invest in a diversified CFM portfolio approach through ground and flight demonstrations ,collaborating with international partners, and leveraging Public Private Partnerships (PPPs) opportunities with US industry through the Tipping Point and Announcement of Collaborative Opportunities (ACO) solicitations. Once proven, these system capabilities will enable the high performing cryogenic propellant systems needed for the Artemis Program and beyond.

Cryogenic Fluid Management↗

NASA NTRSDate not supplied

Cryogenic Fluid Management for the Artemis Program and Beyond

NASA is endeavoring on an ambitious return to the Moon and eventually on to Mars through the Artemis Program leveraging innovative technologies to establish sustainable exploration architectures collaborating with US commercial and international partners [1]. Future NASA architectures have baselined cryogenic propulsion systems to support lunar missions and ultimately future missions to Mars. NASA has been investing in maturing CFM active and passive storage, transfer, and gauging technologies over the last decade plus primarily focused on ground development with a few small-scale microgravity fluid experiments. Recently, NASA created a Cryogenic Fluid Management (CFM) Technology Roadmap identifying the critical gaps requiring further development to reach a technology readiness level (TRL) of 6 prior to infusion to flight applications. To address the technology gaps the Space Technology Mission Directorate (STMD) strategically plans to invest in a diversified CFM portfolio approach through ground and flight demonstrations, collaborating with international partners, and leveraging Public Private Partnerships (PPPs) opportunities with US industry through the Tipping Point and Announcement of Collaborative Opportunities (ACO) solicitations. Once proven, these system capabilities will enable the high performing cryogenic propellant systems needed for the Artemis Program and beyond.

Cryogenic Fluid Management↗

NASA NTRS2002

Lithium-ion cell technology demonstration for future NASA applications

NASA requires lightweight rechargeable batteries for future missions to Mars and the outer planets that are capable of operating over a wide range of temperatures, with high specific energy and energy densities. Due to their attractive performance characteristics, lithium-ion batteries have been identified as the battery chemistry of choice for a number of future applications, including planetary orbiters, rovers and landers. For example, under the Mars Surveyor Program MSP 01 lithium-ion batteries were developed by Lithion (each being 28 V, 25 Ah, 8-cells. and 9 kg) and fully qualified prior to mission cancellation. In addition to the requirement of being able to supply at least 90 cycles on the surface of Mars, the battery demonstrated operational capability (both charge and discharge) over a large temperature range (-2O'C to +4OoC), with tolerance to non-operational excursions to -30nd 50Currently, JPL is implementing lithium-ion technology on the 2003 Mars Exploration Rover (MER), which will be coupled with a solar array. This mission has similar performance requirements to that of the 2001 Lander in that high energy density and a wide operating temperature range are necessitated. In addition to planetary rover and lander applications, we are also engaged in determining the viability of using lithium-ion technology for orbiter applications that require exceptionally long life (>20,000 cydes at partial depth of discharge). To assess the viabili of lithium-ion cells for these applications, a number of performance characterization tests have been performed (at the cell and battery level) on state-of-art prototype lihium- ion cells, induding: assessing the cycle life performance (at varying DODs), life characteristics at extreme temperatures (< -10nd >+4OoC), rate capability as a function of temperature (-30' to 4OoC), pulse capability, self-discharge and storage characteristics, as well as, mission profile capability. This paper will describe the current and future NASA missions that are considering lithium ion batteries and will contain results of the cell testing conducted to-date to validate the technology for these missions.

lithium-ion batteries Mars landers Mars rovers↗

NASA NTRS2016

Bringing the Future Within Reach: Celebrating 75 Years of the NASA John H. Glenn Research Center

The National Aeronautics and Space Administration (NASA) Glenn Research Center in Cleveland, Ohio, has been making the future for 75 years. The center's work with aircraft engines, high-energy fuels, communications technology, electric propulsion, energy conversion and storage, and materials and structures has been, and continues to be, crucial to both the Agency and the region. Glenn has partnered with industry, universities, and other agencies to continually advance technologies that are propelling the nation's aerospace community into the future. Nonetheless these continued accomplishments would not be possible without the legacy of our first three decades of research, which led to over one hundred R&D 100 Awards, three Robert J. Collier Trophies, and an Emmy. Glenn, which is located in Cleveland, Ohio, is 1 of 10 NASA field centers, and 1 of only 3 that stem from an earlier research organization-the National Advisory Committee for Aeronautics (NACA). Glenn began operation in 1942 as the NACA Aircraft Engine Research Laboratory (AERL). In 1947 the NACA renamed the lab the Flight Propulsion Laboratory to reflect the expansion of the research. In September 1948, following the death of the NACA's Director of Aeronautics, George Lewis, the NACA rededicated the lab as the Lewis Flight Propulsion Laboratory. On 1 October 1958, the lab was incorporated into the new NASA space agency and was renamed the NASA Lewis Research Center. Following John Glenn's return to space on the space shuttle, on 1 March 1999 the center name was changed once again, becoming the NASA John H. Glenn Research Center.

Arrighi, Robert S.↗

NASA NTRS2019

Moon Base Life Support Design Depends on Launch Cost, Crew Size, and Mission Duration

Brief human space missions such as Apollo and the Space Shuttle used material storage for life support but a long mission such as a space station uses a recycling life support system. The upcoming Moon visits will probably be brief with few crew at first but in the future there may be a long-term or even permanent Moon base with a large crew. The initial life support system will probably use storage and resupply of materials from Earth, but it could be replaced later by recycling, especially if launch cost per kilogram is high. Moon base life support design is investigated considering requirements, performance, reliability, cost, and risk. The launch cost, crew size, and mission duration are variable parameters that affect the life support design choice. Greater launch cost, crew size, or mission duration all tend to make recycling more cost-effective than resupply.

Jones, Harry W.↗

NASA NTRS2013

Cryogenic Propellant Storage and Transfer (CPST) Technology Maturation: Establishing a Foundation for a Technology Demonstration Mission (TDM)

As part of U.S. National Space Policy, NASA is seeking an innovative path for human space exploration, which strengthens the capability to extend human and robotic presence throughout the solar system. NASA is laying the groundwork to enable humans to safely reach multiple potential destinations, including asteroids, Lagrange points, the Moon and Mars. In support of this, NASA is embarking on the Technology Demonstration Mission Cryogenic Propellant Storage and Transfer (TDM CPST) Project to test and validate key cryogenic capabilities and technologies required for future exploration elements, opening up the architecture for large cryogenic propulsion stages (CPS) and propellant depots. The TDM CPST project will provide an on-orbit demonstration of the capability to store, transfer, and measure cryogenic propellants for a duration which is relevant to enable long term human space exploration missions beyond low Earth orbit (LEO). Recognizing that key cryogenic fluid management technologies anticipated for on-orbit (flight) demonstration needed to be matured to a readiness level appropriate for infusion into the design of the flight demonstration, the NASA Headquarters Space Technology Mission Directorate authorized funding for a one-year (FY12) ground based technology maturation program. The strategy, proposed by the CPST Project Manager, focused on maturation through modeling, studies, and ground tests of the storage and fluid transfer Cryogenic Fluid Management (CFM) technology sub-elements and components that were not already at a Technology Readiness Level (TRL) of 5. A technology maturation plan (TMP) was subsequently approved which described: the CFM technologies selected for maturation, the ground testing approach to be used, quantified success criteria of the technologies, hardware and data deliverables, and a deliverable to provide an assessment of the technology readiness after completion of the test, study or modeling activity. This paper will present the testing, studies, and modeling that occurred in FY12 to mature cryogenic fluid management technologies for propellant storage, transfer, and supply, to examine extensibility to full scale, long duration missions, and to develop and validate analytical models. Finally, the paper will briefly describe an upcoming test to demonstrate Liquid Oxygen (LO2) Zero Boil- Off (ZBO).

Doherty, Michael P.↗

NASA NTRS2014

Cryogenic Propellant Storage and Transfer (CPST) Technology Maturation: Establishing a Foundation for a Technology Demonstration Mission (TDM)

Doherty, Michael P.↗

NASA NTRS1980

Thermal storage requirements for parabolic dish solar power plants

The cost effectiveness of a high temperature thermal storage system is investigated for a representative parabolic dish solar power plant. The plant supplies electrical power in accordance with a specific, seasonally varying demand profile. The solar power received by the plant is supplemented by power from fuel combustion. The cost of electricity generated by the solar power plant is calculated, using the cost of mass-producible subsystems (specifically, parabolic dishes, receivers, and power conversion units) now being designed for this type of solar plant. The trade-off between fuel and thermal storage is derived in terms of storage effectiveness, the cost of storage devices, and the cost of fuel. Thermal storage requirements, such as storage capacity, storage effectiveness, and storage cost are established based on the cost of fuel and the overall objective of minimizing the cost of the electricity produced by the system. As the cost of fuel increases at a rate faster than general inflation, thermal storage systems in the $40 to $70/kWthr range could become cost effective in the near future.

Wen, L.↗

NASA NTRS1988

Nucleate pool boiling: High gravity to reduced gravity; liquid metals to cryogens

Requirements for the proper functioning of equipment and personnel in reduced gravity associated with space platforms and future space station modules introduce unique problems in temperature control; power generation; energy dissipation; the storage, transfer, control and conditioning of fluids; and liquid-vapor separation. The phase change of boiling is significant in all of these. Although both pool and flow boiling would be involved, research results to date include only pool boiling because buoyancy effects are maximized for this case. The effective application of forced convection boiling heat transfer in the microgravity of space will require a well grounded and cogent understanding of the mechanisms involved. Experimental results are presented for pool boiling from a single geometrical configuration, a flat surface, covering a wide range of body forces from a/g = 20 to 1 to a/g = 0 to -1 for a cryogenic liquid, and from a/g = 20 to 1 for water and a liquid metal. Similarities in behavior are noted for these three fluids at the higher gravity levels, and may reasonably be expected to continue at reduced gravity levels.

Merte, Herman, Jr.↗

NASA NTRS1994

High-performance, flexible, deployable array development for space applications

Flexible, deployable arrays are an attractive alternative to conventional solar arrays for near-term and future space power applications, particularly due to their potential for high specific power and low storage volume. Combined with low-cost flexible thin-film photovoltaics, these arrays have the potential to become an enabling or an enhancing technology for many missions. In order to expedite the acceptance of thin-film photovoltaics for space applications, however, parallel development of flexible photovoltaics and the corresponding deployable structure is essential. Many innovative technologies must be incorporated in these arrays to ensure a significant performance increase over conventional technologies. For example, innovative mechanisms which employ shape memory alloys for storage latches, deployment mechanisms, and array positioning gimbals can be incorporated into flexible array design with significant improvement in the areas of cost, weight, and reliability. This paper discusses recent activities at Martin Marietta regarding the development of flexible, deployable solar array technology. Particular emphasis is placed on the novel use of shape memory alloys for lightweight deployment elements to improve the overall specific power of the array. Array performance projections with flexible thin-film copper-indium-diselenide (CIS) are presented, and government-sponsored solar array programs recently initiated at Martin Marietta through NASA and Air Force Phillips Laboratory are discussed.

Gehling, Russell N.↗

NASA NTRS2004

Global Change Data Center: Mission, Organization, Major Activities, and 2003 Highlights

Rapid, efficient access to Earth sciences data from satellites and ground validation stations is fundamental to the nation's efforts to understand the effects of global environmental changes and their implications for public policy. It becomes a bigger challenge in the future when data volumes increase from current levels to terabytes per day. Demands on data storage, data access, network throughput, processing power, and database and information management are increased by orders of magnitude, while budgets remain constant and even shrink.The Global Change Data Center's (GCDC) mission is to develop and operate data systems, generate science products, and provide archival and distribution services for Earth science data in support of the U.S. Global Change Program and NASA's Earth Sciences Enterprise. The ultimate product of the GCDC activities is access to data to support research, education, and public policy.

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NASA NTRS2011

Issues of Long-Term Cryogenic Propellant Storage in Microgravity

Modern multi-layer insulation (MLI) allows to sharply reduce the heat leak into cryogenic propellant storage tanks through the tank surface and, as a consequence, significantly extend the storage duration. In this situation the MLI penetrations, such as support struts, feed lines, etc., become one of the most significant challenges of the tanks heat management. This problem is especially acute for liquid hydrogen (LH2) storage, since currently no efficient cryocoolers exist that operate at very low LH2 temperatures (20K). Even small heat leaks under microgravity conditions and over the period of many months give rise to a complex slowly-developing, large-scale spatiotemporal physical phenomena in a multi-phase liquid-vapor mixture. These phenomena are not well-understood nor can be easily controlled. They can be of a potentially hazardous nature for long-term on-orbital cryogenic torage, propellant loading, tank chilldown, engine restart, and other in-space cryogenic fluid management operations. To support the engineering design solutions that would mitigate these effects a detailed physics-based analysis of heat transfer, vapor bubble formation, growth, motion, coalescence and collapse is required in the presence of stirring jets of different configurations and passive cooling devices such as MLI, thermodynamic vent system, and vapor-cooled shield. To develop physics-based models and correlations reliable for microgravity conditions and long-time scales there is a need for new fundamental data to be collected from on-orbit cryogenic storage experiments. Our report discusses some of these physical phenomena and the design requirements and future studies necessary for their mitigation. Special attention is payed to the phenomena occurring near MLI penetrations.

Muratov, C. B.↗

NASA NTRS2013

Performance Gains of Propellant Management Devices for Liquid Hydrogen Depots

This paper presents background, experimental design, and preliminary experimental results for the liquid hydrogen bubble point tests conducted at the Cryogenic Components Cell 7 facility at the NASA Glenn Research Center in Cleveland, Ohio. The purpose of the test series was to investigate the parameters that affect liquid acquisition device (LAD) performance in a liquid hydrogen (LH2) propellant tank, to mitigate risk in the final design of the LAD for the Cryogenic Propellant Storage and Transfer Technology Demonstration Mission, and to provide insight into optimal LAD operation for future LH2 depots. Preliminary test results show an increase in performance and screen retention over the low reference LH2 bubble point value for a 325 2300 screen in three separate ways, thus improving fundamental LH2 LAD performance. By using a finer mesh screen, operating at a colder liquid temperature, and pressurizing with a noncondensible pressurant gas, a significant increase in margin is achieved in bubble point pressure for LH2 screen channel LADs.

Hartwig, Jason W.↗

NASA NTRS1989

COLD-SAT: Cryogenic On-Orbit Liquid Depot-Storage, Acquisition and Transfer

NASA is entering an era of expanded space activity. Space-based transportation systems will carry cargo and humans from low earth orbit to geosynchronous orbit, to lunar bases, and to the Martian surface. Support of these future missions will require new, long lived, on-orbit systems using subcritical cryogens for propellants and life support systems. Such on-orbit systems present low gravity fluid management challenges of long term storage and efficient fluid transfer and supply techniques. Development of these cryogenic systems requires on-orbit experimentation to demonstrate the capability of performing these fluid management tasks and to obtain the engineering data base required to correlate analytical tools used for system design.

Source record↗

NASA NTRS2007

Systems Modeling to Implement Integrated System Health Management Capability

ISHM capability includes: detection of anomalies, diagnosis of causes of anomalies, prediction of future anomalies, and user interfaces that enable integrated awareness (past, present, and future) by users. This is achieved by focused management of data, information and knowledge (DIaK) that will likely be distributed across networks. Management of DIaK implies storage, sharing (timely availability), maintaining, evolving, and processing. Processing of DIaK encapsulates strategies, methodologies, algorithms, etc. focused on achieving high ISHM Functional Capability Level (FCL). High FCL means a high degree of success in detecting anomalies, diagnosing causes, predicting future anomalies, and enabling health integrated awareness by the user. A model that enables ISHM capability, and hence, DIaK management, is denominated the ISHM Model of the System (IMS). We describe aspects of the IMS that focus on processing of DIaK. Strategies, methodologies, and algorithms require proper context. We describe an approach to define and use contexts, implementation in an object-oriented software environment (G2), and validation using actual test data from a methane thruster test program at NASA SSC. Context is linked to existence of relationships among elements of a system. For example, the context to use a strategy to detect leak is to identify closed subsystems (e.g. bounded by closed valves and by tanks) that include pressure sensors, and check if the pressure is changing. We call these subsystems Pressurizable Subsystems. If pressure changes are detected, then all members of the closed subsystem become suspect of leakage. In this case, the context is defined by identifying a subsystem that is suitable for applying a strategy. Contexts are defined in many ways. Often, a context is defined by relationships of function (e.g. liquid flow, maintaining pressure, etc.), form (e.g. part of the same component, connected to other components, etc.), or space (e.g. physically close, touching the same common element, etc.). The context might be defined dynamically (if conditions for the context appear and disappear dynamically) or statically. Although this approach is akin to case-based reasoning, we are implementing it using a software environment that embodies tools to define and manage relationships (of any nature) among objects in a very intuitive manner. Context for higher level inferences (that use detected anomalies or events), primarily for diagnosis and prognosis, are related to causal relationships. This is useful to develop root-cause analysis trees showing an event linked to its possible causes and effects. The innovation pertaining to RCA trees encompasses use of previously defined subsystems as well as individual elements in the tree. This approach allows more powerful implementations of RCA capability in object-oriented environments. For example, if a pressurizable subsystem is leaking, its root-cause representation within an RCA tree will show that the cause is that all elements of that subsystem are suspect of leak. Such a tree would apply to all instances of leak-events detected and all elements in all pressurizable subsystems in the system. Example subsystems in our environment to build IMS include: Pressurizable Subsystem, Fluid-Fill Subsystem, Flow-Thru-Valve Subsystem, and Fluid Supply Subsystem. The software environment for IMS is designed to potentially allow definition of any relationship suitable to create a context to achieve ISHM capability.

Figueroa, Jorge F.↗

NASA NTRS1987

High temperature electrolyzer/fuel cell power cycle: Preliminary design considerations

A model of a high temperature electrolyzer/fuel cell, hydrogen/oxygen, thermally regenerative power cycle is developed and used to simulate system performance for varying system parameters. Initial estimates of system efficiency, weight, and volume are provided for a one KWe module assuming specific electrolyzer and fuel cell characteristics, both current and future. Specific interest is placed on examining the system responses to changes in device voltage versus current density operating curves, and the associated optimum operating ranges. The performance of a solar-powered, space based system in low earth orbit is examined in terms of the light-dark periods requiring storage. The storage design tradeoffs between thermal energy, electrical energy, and hydrogen/oxygen mass storage are examined. The current technology module is based on the 1000 C solid oxide electrolyzer cell and the alkaline fuel cell. The Future Technology system examines benefits involved with developing a 1800K electrolyzer operating with an advanced fuel cell.

Morehouse, Jeffrey H.↗

NASA NTRS1979

A small helium-cooled infrared telescope for Spacelab 2

A helium cooled telescope of 15 cm aperture is being designed and constructed jointly by the University of Arizona, the Smithsonian Astrophysical Observatory and the Marshall Space Flight Center for high sensitivity infrared astronomical observations from Spacelab 2. A focal plane array of ten detectors provide a total field of view of 3 deg and cover the wavelength regions 4.5-8.5, 6-7, 9-16, 18-30 and 80-120 microns. A highly redundant all sky survey will be conducted by repeated scanning of the sky during many orbits of the spacecraft. High redundancy will allow discrimination among variable and constant celestial sources and several types of variable nearby sources. The principal astronomical result of the survey will be the absolute flux measurement of low surface brightness, large scale celestial infrared emissions but it will also extend existing IR sky surveys by a factor of 10 in point source sensitivity. The experiment will also make significant engineering measurements of contaminants in the Shuttle environment, test the technology of storage and utilization of large quantities of superfluid helium in space and test mechanical designs for future infrared telescopes for the Space Shuttle.

Gautier, T. N., III↗