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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 307 records · Page 17

Optical contacting for gravity probe star tracker

A star-tracker telescope, constructed entirely of fused silica elements optically contacted together, has been proposed to provide submilliarc-second pointing accuracy for Gravity Probe. A bibliography and discussion on optical contacting (the bonding of very flat, highly polished surfaces without the use of adhesives) are presented. Then results from preliminary experiments on the strength of optical contacts including a tensile strength test in liquid helium are discussed. Suggestions are made for further study to verify an optical contacting method for the Gravity Probe star-tracker telescope.

Wright, J. J.↗

Polyenamines from aromatic diacetylenic diketones and diamines

The synthesis and characterization of several polyenamine ketones are discussed wherein conjugated diacetylenic diketones and aromatic diamines are used as a route to the formation of high molecular weight polyenamine ketones which exhibit good mechanical properties and can be cast into creasible films. Typical polymerization conditions involved the reaction of stoichiometric amounts of 1,4- or 1,3-PPPO and a diamine at 60 to 130 C in m-cresol at (w/w) solids content of 8 to 26% for a specified period of time under a nitrogen atmosphere. Novel polyenamine ketones were prepared with inherent viscosities as high as 1.99 dl/g and tough, clear amber films with tensile strengths of 12,400 psi and tensile moduli of 397,000 psi were cast from solutions of the polymers in chloroform. In most cases, the elemental analyses for the polyenamine ketones agree within + or - 0.3% of the theoretical values.

Hergenrother, Paul M.↗

Polyenamines from aromatic diacetylenic diketones and diamines

The synthesis and characterization of several ployenamine ketones are discussed wherein conjugated diacetylenic diketones and aromatic diamines are used as a route to the formation of high molecular weight polyenamine ketones which exhibit good mechanical properties and can be cast into creasible films. Typical polymerization conditions involved the reaction of stoichiometric amounts of 1,4- or 1,3-PPPO and a diamine at 60°-130° C. in m-cresol at (w/w) solids content of 8-26% for a specified period of time under a nitrogen atmosphere. Novel polyenamine ketones were prepared with inherent viscosities as high as 1.99 dl/g and tough, clear amber films with tensile strengths of 12,400 psi and tensile moduli of 397,000 psi were cast from solutions of the polymers in chloroform. The polymers exhibited T g s as high as 235° C. and weight losses of 14% after aging at 232° C. in circulating air for sixty hours. The specific conditions for the preparation of the various polyenamine ketones are presented in Table I. In most cases, the elemental analyses for the polyenamine ketones, shown in Table II, agree within ±0.3% of the theoretical values.

Paul M Hergenrother↗

Alloys For Corrosive, Hydrogen-Rich Environments

"NASA-23" denotes class of alloys resisting both embrittlement by hydrogen and corrosion. Weldable and castable and formed by such standard processes as rolling, forging, and wire drawing. Heat-treated to obtain desired combinations of strength and ductility in ranges of 100 to 180 kpsi yield strength, 120 to 200 kpsi ultimate tensile strength, and 10 to 30 percent elongation at break. Used in place of most common aerospace structural alloy, Inconel(R) 718.

Mcpherson, William B.↗

Development of a Computational Framework for the Design of Resilient Space Structures

Cyber-physical testing provides a unique platform to enable the design of resilient space structures. This hybrid approach requires the development of a structural model that accounts for various hazards (e.g., micrometeorite and debris impact) and interacts with physical tests and other sub-system models (e.g., thermal) of the space habitat. A two-dimensional finite element analysis code was developed in MATLAB to facilitate the evaluation of potential designs under operating and unexpected loads and prepare the computational framework for eventually performing cyber-physical testing. The code’s efficiency was enhanced by using an object-oriented programming approach that reduced data transfer between functions. In this study, the code is implemented to predict the response of a dome-style structure made of regolith concrete to impact loading and identify the force magnitude that will cause the tensile strength to be exceeded in domes with different thicknesses.

Tensile strength↗

Correlation of tensile and shear strengths of metals with their friction properties

The relation between the theoretical tensile and the shear strengths and the friction properties of metals in contact with diamond, boron nitride, silicon carbide, manganese-zinc ferrite, and the metals themselves in vacuum was investigated. The relationship between the actual shear strength and the friction properties of the metal was also investigated. An estimate of the theoretical uniaxial tensile strength was obtained in terms of the equilibrium surface energy, interplanar spacing of the planes perpendicular to the tensile axis, and the Young's modulus of elasticity. An estimate of the theoretical shear strength for metals was obtained from the shear modulus, the repeat distance of atoms in the direction of shear of the metal and the interplanar spacing of the shear planes. The coefficient of friction for metals was found to be related to the theoretical tensile, theoretical shear, and actual shear strengths of metals. The higher the strength of the metal, the lower the coefficient of friction.

Miyoshi, K.↗

Ultra-high-strength boron fibers

Boron-on-tungsten fibers with tensile strength and strain-to-failure values increased by fifty percent over commercial grades are produced by controlled chemical-etching process. Improved fibers have potential applications as lightweight composites in ground vehicles, spacecraft, and rotors for energy storage.

Behrendt, D. R.↗

New tungsten alloy has high strength at elevated temperatures

Tungsten-hafnium-carbon alloy has tensile strengths of 88,200 psi at 3000 deg F and 62,500 psi at 3500 deg F. Possible industrial applications for this alloy would include electrical components such as switches and spark plugs, die materials for die casting steels, and heating elements.

Source record↗

Mechanical properties of particulate composites based on a body-centered-cubic Mg-Li alloy containing boron

The effect of substituting the Mg metal in Mg-B composites by a Mg-14 wt pct Li solid solution on the ductility of the resulting composite was investigated using elastic modulus measurements on the P/M composite material prepared with a dispersion of B particles (in a vol pct range of 0-30) in a matrix of Mg-14 wt pct Li-1.5 wt pct Al. It was found that the elastic modulus of the composites increased rapidly with increasing boron, with specific stiffness values reaching about two times that of most structural materials. The values of the compression and tensile strengths increased significantly with boron additions. Good tensile ductility was achieved at the level of 10 vol pct B. However, at 20 vol pct B, the Mg-Li composite exhibited only limited tensile ductility (about 2 percent total elongation).

Whalen, R. T.↗

Studies of fiber-matrix adhesion on compression strength

A study was initiated on the effect of the matrix polymer and the fiber matrix bond strength of carbon fiber polymer matrix composites. The work includes tests with micro-composites, single ply composites, laminates, and multi-axial loaded cylinders. The results obtained thus far indicate that weak fiber-matrix adhesion dramatically reduces 0 degree compression strength. Evidence is also presented that the flaws in the carbon fiber that govern compression strength differ from those that determine fiber tensile strength. Examination of post-failure damage in the single ply tests indicates kink banding at the crack tip.

Bascom, Willard D.↗

Nanoscale Materials Make for Large-Scale Applications

Since its dawning days, NASA has been at the forefront of developing and improving materials for aerospace applications. In particular, NASA requires dramatic advancements in material properties to enhance the performance, robustness, and reliability of its launch vehicles, spacecraft, and the International Space Station. Such advancements over the years include noise-abatement materials, fire-resistant fibers, heat-absorbing insulation, and light-but-strong moldable composites. In 1991, a new carbon fiber called a carbon nanotube was discovered and fully substantiated by a Japanese electron microscopist. Its dramatic strength and low density (20 times the tensile strength and one-sixth the density of steel) were turning the heads of materials scientists and engineers all around the world, including those who developed equipment for NASA. While NASA did not invent the carbon nanotube, it is working to advance the fibrous material for widespread, low-cost application in sending humans beyond low-Earth orbit, well into the outer reaches of the universe. Carbon nanotubes have the potential to reduce spacecraft weight by 50 percent or more, by replacing the heavier copper wires currently used, according to NASA scientists. Furthermore, NASA researchers have reported a new method for producing integrated circuits using carbon nanotubes instead of copper for interconnects. This technology has the capability to extend the life of the silicon chip industry by 10 years. Because of this growing interest in carbon nanotubes and their perpetual possibilities, NASA has funded both internal and external research in this field.

Source record↗

High-Pressure Lightweight Thrusters

Returning samples of Martian soil and rock to Earth is of great interest to scientists. There were numerous studies to evaluate Mars Sample Return (MSR) mission architectures, technology needs, development plans, and requirements. The largest propulsion risk element of the MSR mission is the Mars Ascent Vehicle (MAV). Along with the baseline solid-propellant vehicle, liquid propellants have been considered. Similar requirements apply to other lander ascent engines and reaction control systems. The performance of current state-ofthe- art liquid propellant engines can be significantly improved by increasing both combustion temperature and pressure. Pump-fed propulsion is suggested for a single-stage bipropellant MAV. Achieving a 90-percent stage propellant fraction is thought to be possible on a 100-kg scale, including sufficient thrust for lifting off Mars. To increase the performance of storable bipropellant rocket engines, a high-pressure, lightweight combustion chamber was designed. Iridium liner electrodeposition was investigated on complex-shaped thrust chamber mandrels. Dense, uniform iridium liners were produced on chamber and cylindrical mandrels. Carbon/carbon composite (C/C) structures were braided over iridium-lined mandrels and densified by chemical vapor infiltration. Niobium deposition was evaluated for forming a metallic attachment flange on the carbon/ carbon structure. The new thrust chamber was designed to exceed state-of-the-art performance, and was manufactured with an 83-percent weight savings. High-performance C/Cs possess a unique set of properties that make them desirable materials for high-temperature structures used in rocket propulsion components, hypersonic vehicles, and aircraft brakes. In particular, more attention is focused on 3D braided C/Cs due to their mesh-work structure. Research on the properties of C/Cs has shown that the strength of composites is strongly affected by the fiber-matrix interfacial bonding, and that weakening interface realizes pseudo-plastic behavior with significant increase in the tensile strength. The investigation of high-temperature strength of C/Cs under high-rate heating (critical for thrust chambers) shows that tensile and compression strength increases from 70 MPa at room temperature to 110 MPa at 1,773 K, and up to 125 MPa at 2,473 K. Despite these unique properties, the use of C/Cs is limited by its high oxidation rate at elevated temperatures. Lining carbon/carbon chambers with a thin layer of iridium or iridium and rhenium is an innovative way to use proven refractory metals and provide the oxidation barrier necessary to enable the use of carbon/ carbon composites. Due to the lower density of C/Cs as compared to SiC/SiC composites, an iridium liner can be added to the C/C structure and still be below the overall thruster weight. Weight calculations show that C/C, C/C with 50 microns of Ir, and C/C with 100 microns of Ir are of less weight than alternative materials for the same construction.

Holmes, Richard↗