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At least 307 records · Page 17

First Time-Resolved Leader Spectra Associated With a Downward Terrestrial Gamma-Ray Flash Detected at the Telescope Array Surface Detector

Optical emissions associated with Terrestrial Gamma ray Flashes (TGFs) have recently become important subjects in space-based and ground-based observations as they can help us understand how TGFs are produced during thunderstorms. In this paper, we present the first time-resolved leader spectra of the optical component associated with a downward TGF. The TGF was observed by the Telescope Array Surface Detector (TASD) simultaneously with other lightning detectors, including a Lightning Mapping Array (LMA), an INTerFerometer (INTF), a Fast Antenna (FA), and a spectroscopic system. The spectroscopic system recorded leader spectra at 29,900 frames per second (33.44 μs time resolution), covering a spectral range from 400 to 900 nm, with 2.1 nm per pixel. The recordings of the leader spectra began 11.7 ms before the -18 kA return stroke and at a height of 2.37 km above the ground. These spectra reveal that optical emissions of singly ionized nitrogen and oxygen occur between 167 μs before and 267 μs after the TGF detection, while optical emissions of neutrals (H I, 656 nm; N I, 744 nm, and O I, 777 nm) occur right at the moment of the detection. The time-dependent spectra reveal differences in the optical emissions of lightning leaders with and without downward TGFs.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

From ETROC to VTROC

The Endcap Timing ReadOut Chip (ETROC) is designed to process LGAD signals with time resolution down to about 40-50ps per hit, to reach 30-35ps per track with two detector layers. The ETROC2 is the first full size (16x16) prototype design and is fully compatible with the final chip specifications in terms of functionality. The ETROC2 has been extensively tested recently. In this talk, the testing results of the ETROC2 will be presented first, including performance study using charge injection, laser and beam, as well as TID testing and wafer probe testing to study the yield. In addition, future challenges of precision position and timing ASIC design will be discussed, based on what we have learned from the ETROC development, and how the challenges could be addressed in the VTROC, Vertically integrated Timing ReadOut chip (funded as SBIR phase 2) for precision position and timing detector R&D.

Liu, Ted↗

WIND Toolkit Long-Term Ensemble Dataset

WIND Toolkit Long-term Ensemble Dataset (WTK-LED), an updated version of the meteorological WIND Toolkit, is a meteorological dataset providing high-resolution time series, including interannual variability and model uncertainty of wind speed at every modeling grid point to indicate ranges of possible wind speeds. The data were produced using the Weather Research and Forecasting Model (WRF). The vertical grid used in WTK-LED includes many vertical layers in the atmospheric boundary layer to provide information of atmospheric quantities across the rotor layer of utility scale and distributed wind turbines. The WTK-LED includes: (1) Numerical simulations of wind speed and other meteorological variables covering the contiguous United States (CONUS) and Alaska, with high-resolution (5-minute [min], 2-kilometer [km]) data for 3 years (2018-2020): WTK-LED CONUS, WTK-LED Alaska. (2) Climate simulations from Argonne National Laboratory covering North America, including Alaska, Canada, and most of Mexico and the Caribbean islands. These simulations complement the new WTK-LED to offer a 4-km, hourly dataset covering 20 years (2001-2020): WTK-LED Climate. (3) Specific long-term, high-resolution offshore simulations have been conducted separately for the U.S. coasts, Hawaii, and the Great Lakes, leading to the 2023 National Offshore Wind dataset: NOW-23. The data for Hawaii include land-based data and are part of WTK-LED Hawaii. Because the accuracy of simulations from a mesoscale model, such as WRF, varies depending on the location and weather situation, and can reach up to several m/s for wind speed, we provide simulated wind speed uncertainty estimates to the community to be used in conjunction with the deterministic model simulations. This dataset was developed to satisfy a wide group of stakeholders across various wind energy disciplines, including but not limited to stakeholders in the distributed and utility scale wind industry, the new emerging airborne wind energy field, grid integration, power systems modeling, environmental modeling, and researchers in academia, and to close some of the gaps that current public datasets have. Based on our validation results to date, we suggest use cases and applications for each dataset of the WTK-LED as shown in "WTK-LED Use Cases" resource below.

Array↗

Distributionally Robust Decentralized Volt-Var Control With Network Reconfiguration

Here, this paper presents a decentralized volt-var optimization (VVO) and network reconfiguration strategy to address the challenges arising from the growing integration of distributed energy resources, particularly photovoltaic (PV) generation units, in active distribution networks. To reconcile control measures with different time resolutions and empower local control centers to handle intermittency locally, the proposed approach leverages a two-stage distributionally robust optimization; decisions on slow-responding control measures and set points that link neighboring subnetworks are made in advance while considering all plausible distributions of uncertain PV outputs. We present a decomposition algorithm with an acceleration scheme for solving the proposed model. Numerical experiments on the IEEE 123 bus distribution system are given to demonstrate its outstanding out-of-sample performance and computational efficiency, which suggests that the proposed method can effectively localize uncertainty via risk-informed proactive timely decisions.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Beam Test Results of the RADiCAL—A Radiation Hard Innovative EM Calorimeter

High-performance calorimetry conducted at future hadron colliders, such as the FCC-hh, poses a significant challenge for applying current detector technologies due to unprecedented beam luminosities and radiation fields. Solutions include developing scintillators that are capable of separating events at the sub-fifty picosecond level while also maintaining performance after extreme and constant neutron and ionizing radiation exposure. The radiation-hard innovative calorimeter (RADiCAL) is an approach that incorporates radiation tolerant materials in a sampling “shashlik”-style calorimeter configuration, using quartz capillaries filled with organic liquid or polymer-based wavelength shifters embedded in layers of tungsten plates and lutetium-yttrium oxyorthosilicate (LYSO) crystals. Here, this novel design intends to address the priority research directions (PRD) for calorimetry listed in the DOE basic research needs (BRN) workshop for high energy physics (HEP) instrumentation. Here we report preliminary results from an experimental run at the Fermilab Test Beam Facility (FTBF) in June 2022. These tests demonstrate that the RADiCAL concept is capable of ¡50 ps timing resolution.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Sub-picosecond Production of Solute Radical Cations in Tetrahydrofuran after Radiolysis

Ultrafast hole transfer from solvent radical cations produced by radiolysis with ~10 ps, 9 MeV electron pulses to solutes was investigated in tetrahydrofuran (THF). Because of rapid fragmentation of initially produced THF +• , solute radical cations are not expected and have not previously been reported. Using 9,9-Dihexyl-2,7-dibromofluorene (Br 2 F) at 5 to 1000 mM, Br 2 F +• was observed with radiation chemical yields up to G = 2.23 / 100 eV absorbed. While more than half of this was the result of direct solute ionization, the results highlight the importance of capture of holes from THF +• prior to solvation and fragmentation. The observed data show a time-resolution limited (15 ps) rise in transient absorption of Br 2 F +• , identical in form to reports of pre-solvated or dry electron capture in water and a few organic liquids, including THF. The results were thus interpreted with a similar formalism, finding C 37 = 1.7 M, the concentration at which 37% of holes escape capture. The yield of solvent hole capture can be accounted for by the formation of solvent holes adjacent to solute molecules reacting faster than they can fragment, however mechanisms such as delocalized holes or rapid hopping may play a role. Finally, low temperature results find over two times more capture, supporting the speculation that if THF +• was longer lived, the yield of capture in under 15 ps would have been at least 2x larger at 1 M Br 2 F, possibly capturing nearly all available holes from the solvent.

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEA↗

Multi-seasonal measurements of the ground-level atmospheric ice-nucleating particle abundance on the North Slope of Alaska

Atmospheric ice-nucleating particles (INPs) are an important subset of aerosol particles that are responsible for the heterogeneous formation of ice crystals. INPs modulate the arctic cloud phase (liquid vs. ice), resulting in implications for radiative feedbacks. The number of arctic INP studies investigating specific INP episodes or sources increased recently. However, existing studies are based on short-duration field data, and long-term datasets are lacking. Continuous, long-term measurements are key to determining the abundance and variability of ambient arctic INPs and constraining aerosol–cloud interactions, e.g., to verify and/or improve simulations of mixed-phase clouds. Here, we present a new long-duration INP dataset from the Arctic: 2 years of predominantly immersion-mode INP concentrations (n INP ) measured continuously at the National Oceanic and Atmospheric Administration's Barrow Atmospheric Baseline Observatory (BRW) on the North Slope of Alaska. A portable ice nucleation experiment chamber (PINE-03), which simulates adiabatic expansion cooling, was used to directly measure the ground-level INP abundance with an approximately 12 min time resolution from October 2021 to December 2023. We document PINE-03 n INP measurements as well as estimated ice nucleation active surface site density (n s ) over a wide range of heterogeneous freezing temperatures from −16 to −31 °C from which we introduce new season-specific parameterizations suitable for modeling mixed-phase clouds. Collocated aerosol and meteorological data were analyzed to assess the correlation between ambient n INP , air mass origin region, and meteorological variability. Our findings suggest (1) very high freezing efficiency of INPs across the measured temperatures (n s ≈ 2×10 8 –10 10 m −2 for −16 to −31 °C), which is a factor of 10–1000 times greater efficiency as compared to that found in the previous mid-latitude INP measurements in fall using the same instrument; (2) surprisingly high n INP (≥ 1 L −1 at −25 °C) for the examined temperatures throughout the year that were not measured by PINE-03 at other sites; and (3) high n INP in spring, possibly related to arctic haze episodes. Relatively low concentrations of aerosol surface area and contrasting high-INP concentrations at BRW relative to mid-latitude sites are the possible reasons for the observed high freezing efficiency.

54 ENVIRONMENTAL SCIENCES↗

A general spatial-temporal framework for short-term building temperature forecasting at arbitrary locations with crowdsourcing weather data

Weather forecasting has been a critical component to predict and control building energy consumption for better building energy management. Without accessibility to other data sources, the onsite observed temperatures or the airport temperatures are used in forecast models. In this paper, we present a novel approach by utilizing the crowdsourcing weather data from neighboring personal weather stations (PWS) to improve the weather forecast accuracy around buildings using a general spatial-temporal modeling framework. The final forecast is based on the ensemble of local forecasts for the target location using neighboring PWSs. Our approach is distinguished from existing literature in various aspects. First, we leverage the crowdsourcing weather data from PWS in addition to public data sources. In this way, the data is at much finer time resolution (e.g., at 5-minute frequency) and spatial resolution (e.g., arbitrary location vs grid). Second, our proposed model incorporates spatial-temporal correlation information of weather variables between the target building and a set of neighboring PWSs so that underlying correlations can be effectively captured to improve forecasting performance. Here, we demonstrate the performance of the proposed framework by comparing to the benchmark models on temperature forecasting for a building located at an arbitrary location at San Antonio, Texas, USA. In general, the proposed model framework equipped with machine learning technique such as Random Forest can improve forecasting by 50% compares with persistent model and has 90% chance to outperform airport forecast in short-term forecasting. In a real-time setting, the proposed model framework can provide more accurate temperature forecasting results compared with using airport temperature forecast for most forecast horizon. Moreover, we analyze the sensitivity of model parameters to gain insights on how crowdsourcing data from the neighboring personal weather stations impacts forecasting performance. Finally, we implement our model in other cities such as Syracuse and Chicago to test the model's performance in different landforms and climate types.

54 ENVIRONMENTAL SCIENCES↗

New opportunities at the next-generation neutrino experiments I: BSM neutrino physics and dark matter

The combination of the high intensity proton beam facilities and massive detectors for precision measurements of neutrino oscillation parameters including the charge-parity violating (CPV) phase will open the door to help make beyond the standard model (BSM) physics reachable even in low energy regimes in the accelerator-based experiments. Large-mass detectors with highly precise tracking and energy measurements, excellent timing resolution, and low energy thresholds will enable the searches for BSM phenomena from cosmogenic origin, as well. Therefore, it is also conceivable that BSM topics in the next-generation neutrino experiments could be the dominant physics topics in the foreseeable future, as the precision of the neutrino oscillation parameter and CPV measurements continue to improve. This paper reviews the current landscape of BSM theory in neutrino experiments in two selected areas of the BSM topics-dark matter and neutrino related BSM-and summarizes the current results from existing neutrino experiments to set benchmarks for both theory and experiment. This paper then provides a review of upcoming neutrino experiments throughout the next 10 to 15 year time scale and their capabilities to set the foundation for potential reach in BSM physics in the two aforementioned themes. An important outcome of this paper is to ensure theoretical and simulation tools exist to carry out studies of these new areas of physics, from the first day of the experiments, such as Deep Underground Neutrino Experiment in the U.S. and Hyper-Kamiokande Experiment in Japan.

dark sector↗

Phase transitions in Zr at sub-nanosecond time scales

Here solid-solid phase transitions are investigated in Zr thin films using shock compression induced by a short laser pulse (<1 ns). Shock wave profiles are measured at free surfaces for films of different thicknesses (a few micrometers) using chirped-pulse line velocimetry with 10 ps time resolution. Experiments are performed at pressures up to ~50 GPa, which is sufficient to reach the ω and β phases under equilibrium conditions. The shock wave structures are analyzed using a general Lagrangian analysis method, which allows for the calculation of stress–strain paths and assessments of phase transition behavior. In agreement with recent short laser pulse experiments using ultra-fast x-ray diffraction, we do not find any clear evidence of the α–ω transition, though this would be expected from the phase diagram. Instead, we infer a direct transformation to a metastable β-phase at lower shock pressures (<20 GPa) and equilibrium β at higher pressures. Through the velocimetry analysis, we find α–β transformation onset times of less than ~100 ps and completion times of less than ~200 ps.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

ETROC1: the first full chain precision timing prototype ASIC for CMS MTD endcap timing layer upgrade

We present the design and characterization of the first fullchain precision timing prototype ASIC, named ETL Readout Chipversion 1 (ETROC1) for the CMS MTD endcap timing layer (ETL)upgrade. The ETL utilizes Low Gain Avalanche Diode (LGAD) sensors todetect charged particles, with the goal to achieve a time resolutionof 40–50 ps per hit, and 30–40 ps per track with hits from twodetector layers. The ETROC1 is composed of a 5 × 5 pixelarray and peripheral circuits. The pixel array includes a4 × 4 active pixel array with an H-tree shaped networkdelivering clock and charge injection signals. Each active pixel iscomposed of various components, including a bump pad, a chargeinjection circuit, a pre-amplifier, a discriminator, adigital-to-analog converter, and a time-to-digital converter. Thesecomponents play essential roles as the front-end link in processingLGAD signals and measuring timing-related information. Theperipheral circuits provide clock signals and readoutfunctionalities. The size of the ETROC1 chip is7 mm× 9 mm. ETROC1 has been fabricated in a 65 nmCMOS process, and extensively tested under stimuli of chargeinjection, infrared laser, and proton beam. The time resolution ofbump-bonded ETROC1 + LGAD chipsets reaches 42–46 ps per hit in thebeam test.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Direct observation of coherent femtosecond solvent reorganization coupled to intramolecular electron transfer

It is well known that the solvent plays a critical role in ultrafast electron-transfer reactions. However, solvent reorganization occurs on multiple length scales, and selectively measuring short-range solute–solvent interactions at the atomic level with femtosecond time resolution remains a challenge. Here we report femtosecond X-ray scattering and emission measurements following photoinduced charge-transfer excitation in a mixed-valence bimetallic (Fe ii Ru iii ) complex in water, and their interpretation using non-equilibrium molecular dynamics simulations. Combined experimental and computational analysis reveals that the charge-transfer excited state has a lifetime of 62 fs and that coherent translational motions of the first solvation shell are coupled to the back electron transfer. Overall, our molecular dynamics simulations identify that the observed coherent translational motions arise from hydrogen bonding changes between the solute and nearby water molecules upon photoexcitation, and have an amplitude of tenths of ångströms, 120–200 cm -1 frequency and ~100 fs relaxation time. This study provides an atomistic view of coherent solvent reorganization mediating ultrafast intramolecular electron transfer.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

PERSIANN Dynamic Infrared–Rain Rate Model (PDIR) for High-Resolution, Real-Time Satellite Precipitation Estimation

Precipitation measurements with high spatiotemporal resolution are a vital input for hydrometeorological and water resources studies; decision-making in disaster management; and weather, climate, and hydrological forecasting. Moreover, real-time precipitation estimation with high precision is pivotal for the monitoring and managing of catastrophic hydroclimate disasters such as flash floods, which frequently transpire after extreme rainfall. While algorithms that exclusively use satellite infrared data as input are attractive owing to their rich spatiotemporal resolution and near-instantaneous availability, their sole reliance on cloud-top brightness temperature (T b ) readings causes underestimates in wet regions and overestimates in dry regions—this is especially evident over the western contiguous United States (CONUS). We introduce an algorithm, the Precipitation Estimations from Remotely Sensed Information Using Artificial Neural Networks (PERSIANN) Dynamic Infrared–Rain rate model (PDIR), which utilizes climatological data to construct a dynamic (i.e., laterally shifting) T b –rain rate relationship that has several notable advantages over other quantitative precipitation-estimation algorithms and noteworthy skill over the western CONUS. Validation of PDIR over the western CONUS shows a promising degree of skill, notably at the annual scale, where it performs well in comparison to other satellite-based products. Analysis of two extreme landfalling atmospheric rivers show that solely IR-based PDIR performs reasonably well compared to other IR- and PMW-based satellite rainfall products, marking its potential to be effective in real-time monitoring of extreme storms. This research suggests that IR-based algorithms that contain the spatiotemporal richness and near-instantaneous availability needed for rapid natural hazards response may soon contain the skill needed for hydrologic and water resource applications.

54 ENVIRONMENTAL SCIENCES↗

Vertically Self-Oriented, Ultrafast 1D ZnO:Li Nanorods as Scintillators for Thermal Neutron Detection

Detection of special nuclear materials (SNMs) is of vital importance in the prevention of nuclear terrorism and to secure states’ national security. Neutron detection is a particularly useful tool to identify SNM, and neutron-sensitive scintillators have many promising properties, such as ease of use, good time resolution, and high detection efficiency. In this work, we develop highly stable, self-oriented, ultrafast 1D ZnO:Li (and codoped with Al, Ga, and In) nanorods (NRs) as thermal neutron-sensitive scintillators. Lithium-6 has high thermal neutron cross section for the (n, α) reaction in ZnO:Li scintillators which have a vertical nano array design greatly increasing the effective surface area and scintillation efficiency. Cost-effective low-temperature (95 °C) hydrothermal growth is used to obtain highly crystalline ZnO:Li nano scintillators by combining nuclear range data and electron transport mechanisms. Among the studies using low-temperature hydrothermal synthesis and a relatively low annealing temperature (≈350 °C) along with optimized NRs (length ≈ 5–8 μm, mean diameter ≈ 700 nm) for thermal neutron detection, this study reports the shortest scintillation decay time (≈ 470 ps) so far to the best of our knowledge. In conclusion, this nano array scintillator combines the advantages of a low-cost growth technique with environmentally friendly and widely available materials.

Ions↗

Direct Study of Changes in Catalyst Structure-Kinetic Properties During Redox Transitions

The Temporal Analysis of Products (TAP) pulse response methodology is a transient technique that provides the time resolution needed to deconvolve reaction steps from the complex networks typical in industrial catalytic processes. Traditionally, TAP measurements observe gas phase dynamics at the reactor exit but lack direct measurements of changes in the catalyst itself. Recently, a new operando technique was developed that couples gas phase transients to dynamic changes in metal centers with the precise TAP methodology for nanomole titration. Using an industrial CrOx/Al2O3 catalyst used for propane dehydrogenation, we demonstrate the capabilities of this unique device to reveal key catalytic processes: 1) total propane oxidation not associated with chromia centers, 2) reduction of Cr6+ to Cr3+ correlated with selective product formation, and 3) subsequent carbon accumulation. By utilizing incremental pulsing in a diffusion-only transport regime, the spectrokinetic device allows us to resolve detailed changes in catalyst structure, composition, and kinetic function that are otherwise indistinguishable in conventional operando devices. The unification of the TAP methodology with time-resolved spectroscopic measurements offers new and unique insights into the complex kinetic phenomena regulated by solid catalyst surfaces.

03 - NATURAL GAS↗

A detailed study of pre-heating effects in electron beam melting powder bed fusion process

Metal-based additive manufacturing processes, such as powder bed fusion with electron beam (PBF-EB) process, also referred to as electron beam melting (EBM), can produce high-density parts with minimal residual stresses due to the uniform and coherent preheating of the powder bed. However, understanding and controlling the multiple stages of preheating is required to enable the production of high-quality, consistent parts of various materials. This work presents a large-scale, multi-layer, three-dimensional numerical analysis focused on studying the preheating stages for predicting thermal history during the PBF-EB process. The model follows a continuous multi-stage cyclic process, that incorporates all the main stages of the PBF-EB process for 316 L stainless steel. This includes the gradual deposition of a new powder layer, the first and second preheating levels of the powder bed, and the energy deposition during melting (excluding the actual melt-pool behavior simulation). The model employs an adaptive time-scaling approach that automatically adjusts the energy deposition for each solution time-increment. This allows for localized changes in time-resolution over an otherwise computationally expensive multi-layer procedure. The material property variations are also taken into account, with an emphasis on the subtle irreversible changes in powder effective thermal conductivity after the two requisite preheating stages of the powder bed. This effect is studied using simplified conductivity models from the literature for partially sintered powder, validated by a dedicated experiment and numerical simulation. The large-scale model is then used to estimate the actual temperatures during first and second preheating levels for 316 L steel, which is not yet fully supported commercially for PBF-EB. Model predictions are corroborated by experiments, using and analyzing IR images, taken at the completion of each layer by the machine’s built-in infrared camera. The current model also incorporates a qualitative assessment for the effects of conductivity change during pre-heating, as well as evaluates the applicability of the time-scaling approach.

36 MATERIALS SCIENCE↗

The CLAS12 Forward Time-of-Flight system

The Forward Time-of-Flight system for the large-acceptance CLAS12 spectrometer in Hall B at the Thomas Jefferson National Accelerator Facility is described. The system is positioned at distances in the range from 6.2 m to 7.2 m from the beam–target interaction point and spans laboratory polar angles from 5 deg → 45 deg and nearly the full azimuth. The system consists of 540 individual scintillation counters with double-ended readout that range in length from 17 cm to 426 cm of discrete widths of 6 cm, 15 cm, and 22 cm, and of discrete thicknesses of 5 cm and 6 cm. We see the effective counter time resolution for passing charged particles varies from 50 ps for the shortest counters at small angles to 200 ps for the longest counters at large angles. The detectors are part of the forward-angle particle identification system for CLAS12 during offline event reconstruction and are a component of the online data acquisition trigger to select final state event topologies with forward-going charged particles.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

State-of-the-art and evolution of UFSD sensors design at FBK

Over the past few years, there has been growing interest in the development of silicon sensors able to simultaneously measure accurately the time of passage and the position of impinging charged particles. In this contribution, a review of the progresses in the design of UFSD (Ultra-Fast Silicon Detectors) sensors, manufactured at the FBK (Fondazione Bruno Kessler) Foundry, aiming at tracking charged particles in 4 dimensions, is presented. The state-of-the-art UFSD sensors, with excellent timing capability, are planned to be used in both ATLAS and CMS experiments detector upgrade, in order to reduce the background due to the presence of overlapping events in the same bunch crossing. The latest results on sensors characterization including time resolution, radiation resistance and uniformity of the response are here summarized, pointing out the interplay between the design of the gain layer and the UFSD performances. The research is now focusing on the maximization of the sensor fill factor, to be able to reduce the pixel size, exploring the implementation of shallow trenches for the pixel isolation and the development of resistive AC-coupled UFSD sensors. In conclusion, a brief review on research paths tailored for detection of low energy X-rays or for low material budget applications is given.

47 OTHER INSTRUMENTATION↗