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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 307 records · Page 17
All sourcesNASA NTRSDOE OSTI
NASA NTRS1972

Surface studies on Surveyor 3 tubing sections

Sections C and E of the unpainted, polished aluminum tubing from the strut of the radar altimeter and Doppler velocity sensor were examined in a transmission electron microscope for micrometeorite damage and ion bombardment. Both sections were contaminated and eroded on one side; it is suggested that these conditions were caused by sandblasting by lunar dust and retrorocket plume contamination during Surveyor 3 landing. Microcraters of different configurations were found on the bright sides of the tubes. Several degrees of violence were involved in the formation of the craters, and the particle size could be responsible for some differences. All micropits found were on the bright areas and data indicate 0.2 hypervelocity impact/sq cm and 2/sq cm for other types of craters. The greatest degree of damage resulted from particle impact and was limited to a maximum depth of 2 microns.

Buvinger, E. A.↗
NASA NTRS1973

An Exploratory Study of the Microstructure of Mullite Fibers

The microstructures of mullite composition fibers were examined by transmission electron microscopic techniques and by X-ray diffraction analyses. Both spun and monofilament fiber structures contained little porosity, nor did the degree of porosity change after heating the monofilament to 1205 C for one half hour. Thermal exposure produced crystallite growth and nucleation from the amorphous phase in all three of the spun fibers. After 116 hours at 1426 C, the crystallites of the standard spun fibers became contiguous. In addition, the surface crystallites of these fibers were found to be more than twice as large as the interior crystallites.

Santoro, G.↗
NASA NTRS1974

Summary of in situ epitaxial nucleation and growth measurements

In situ nucleation and growth measurements of Ag and Au on single-crystal PbSe thin films were made using a transmission electron microscope. Properties studied were polymorphism, crystalline perfection, and the stoichiometric composition of the initial and the autoepitaxially thickened PbSe substrates. The quantitative nucleation and cluster growth measurements were limited to low-saturation conditions. The epitaxial orientations are discussed, and evidence is presented as to the stage of deposition at which the epitaxial order for Ag is introduced. Strong substrate/overgrowth interaction manifested itself by alloying and interdiffusion.

Poppa, H.↗
NASA NTRS1974

On the irradiation history and origin of gas-rich meteorites

Transmission electron microscope study of the track density gradients and irradiation geometries of track-rich grains and chondrules in sections of Fayetteville and Kapoeta, and in sections of lunar breccias and grains from lunar soil. A substantial fraction (50 to 90%) of the meteoritic track-rich grains and chondrules show evidence of having been irradiated anisotropically in their different faces, as would be expected for irradiation on the surface of a parent body. The observations thus support the hypothesis that the irradiation of these grains and chondrules took place on the regoliths of asteroidal-sized bodies. Measurements of steepest track density gradients indicate that, while there are finite differences between spectra exhibited by individual gas-rich meteorites, the average solar flare spectral shapes have been similar over the last 4 b.y. or so.

Rajan, R. S.↗
NASA NTRS1977

Effects of high temperature and e-beam irradiation on the stability of refractory thin films

Refractory thin films of Al2O3, ZrO2, MgO, ThO2, and BN have been investigated in situ in an UHV transmission electron microscope. The electron transparent refractory films were prepared by electron-beam evaporation, anodization, RF sputtering, and thinning of bulk crystal materials. The study concentrates on monitoring the thermal and mechanical stability of the films, phase and structural changes, and electron irradiation effects as a function of film-preparation conditions. With increasing temperatures, five different crystallographic phases were observed for both anodized and electron-beam-evaporated alumina films. Zirconia films exhibited two phase transitions upon heating to 1200 C and electron-irradiation-induced crystallization of ZrO2 even at room temperature. MgO, ThO2, and BN films did not undergo any noticeable phase transformation but ruptured due to sintering below 1200 C.

Lee, E. H.↗
NASA NTRS1977

Shock-produced olivine glass - First observation

Transmission electron microscope (TEM) observations of an experimentally shock-deformed single crystal of natural peridot, /Mg(0.88)Fe(0.12)/2SiO4, recovered from peak pressures of about 56 billion pascals revealed the presence of amorphous zones located within crystalline regions with a high density of tangled dislocations. This is the first reported observation of olivine glass. The shocked sample exhibits a wide variation in the degree of shock deformation on a small scale, and the glass appears to be intimately associated with the highest density of dislocations. This study suggests that olivine glass may be formed as a result of shock at pressures above about 50 to 55 billion pascals and that further TEM observations of naturally shocked olivines may demonstrate the presence of glass.

Jeanloz, R.↗
NASA NTRS1978

Radiation sensitivity of quartz crystal oscillators experiment for the Long Duration Exposure Facility /LDEF/

A proposed experiment, which has been selected by NASA for inclusion in the Long Duration Exposure Facility (LDEF), is discussed. The objective of the experiment is to obtain information relevant to predicting and improving the radiation sensitivity of quartz oscillators. Specifically, the effect of exposing various grades of quartz oscillators to an orbital environment will be compared with observations obtained using the transmission electron microscope which suggest that the technique may be used to classify quartz-crystals according to their radiation sensitivity.

Venables, J. D.↗
NASA NTRS1978

Chemical and structural studies of 'Brownlee' particles

Several techniques were applied to the study of small particles (around 10 microns) collected in the upper atmosphere by U-2 aircraft. The major element chemistry of roughly 1/3 of the particles is similar to that of chondritic meteorites, although considerable variation of element ratios is observed from particle to particle, and even within a given particle. All particles of 'chondritic' composition are polycrystalline aggregates. About half have fully re-entrant structures; the remaining ones have more compact structures ranging from platey to spherical morphologies. Micro-crystallites with various internal structures are observed in the size range from less than 100 A to several microns. Although tracks are clearly observed in transmission electron microscope examination of terrestrial analog crystals, no tracks of solar flare origin have yet been identified in the U-2 particles. Induced fission track analysis of one aggregate shows that the U concentration is less than 15 ppbm, lending support to the extraterrestrial origin hypothesis.

Flynn, G. J.↗
NASA NTRS1979

Investigations of submicron sized metal particles in glass coatings of lunar breccia 15286

Almost all the submicron metal particles in the glass coating of breccia 15286 are rounded and contain two phases, metal and sulfide (FeS). The Ni content of the metal phase as determined by scanning transmission electron microscope X-ray analysis ranged from 9.4 to 15.5 wt %. The sulfide was nearly stoichiometric troilite containing up to 1.3 wt % Ni. The close chemical and microstructural similarities between the coarse (greater than 1-micron) and the submicron sized metal indicate a common origin probably as meteoritic debris. Metal-silicate melt experiments under controlled oxygen partial pressured indicate that the metal particles may have formed from a fine dispersion of immiscible metal-sulfide droplets into an impact-generated silicate melt.

Mehta, S.↗
NASA NTRS1980

Interplanetary dust collected in the earth's stratosphere - The question of solar flare tracks

The negative result of a transmission electron microscope (TEM) search for solar flare tracks in 10 micron interplanetary dust particles (Flynn et al., 1978) which have been collected in the earth's stratosphere with a program of sampling initiated by Brownlee et al. (1976) has been reported previously. In this paper, it is shown that silicates in the particles record laboratory iron-ion tracks which are detectable in the TEM. The absence of tracks in the silicates could be due to track annealing on atmospheric entry, and may indicate a particle emissivity below 0.3, or that many of the particles broke up on encounter with the atmosphere. Alternatively, the lifetime of 10 micron dust particles at 1 AU could be shorter than that given by previous estimates.

Fraundorf, P.↗
NASA NTRS1982

The survival of solar flare tracks in interplanetary dust silicates on deceleration in the earth's atmosphere

Pulse heating experiments on magnesium-rich olivine and pyroxene, two silicates often found in micrometeorites collected in the stratosphere, show that iron ion tracks remain detectable in the transmission electron microscope for temperature maxima up to approximately 600 C. Assuming thermal emissivities near unity, this implies that micrometeorites with surface densities above 1 mg/sq cm are likely to have their track record erased, and that tracks in reentrant or low-density micrometeorites smaller than 7 microns in size are likely to survive atmospheric entry.

Fraundorf, P.↗
NASA NTRS1983

In-situ TEM investigations of graphic-epitaxy and small particles

Palladium was deposited inside a controlled-vacuum specimen chamber of a transmission electron microscope (TEM) onto MgO and alpha-alumina substrate surfaces. Annealing and various effects of gas exposure of the particulate Pd deposits were studied in-situ by high resolution TEM and electron diffraction. Whereas substrate temperatures of 500 C or annealing of room temperature (RT) deposits to 500 C were needed to obtain epitaxy on sapphire, RT deposits on MgO were perfectly epitaxial. For Pd/MgO a lattice expansion of 2 to 4% was noted; the highest values of expansion were found for the smallest particles. The lattice expansion of small Pd particles on alumina substrates was less than 1%. Long-time RT exposure of Pd/MgO in a vacuum yielded some moblity and coalescence events, but notably fewer than for Pd on sapphire. Exposure to air or oxygen greatly enhanced the particle mobility and coalescence and also resulted in the flattening of Pd particles on MgO substrates. Electron-beam irradiation further enhanced this effect. Exposure to air for several tens of hours of Pd/MgO led to strong coalescence.

Heinemann, K.↗
NASA NTRS1983

Epsilon carbide - A low-temperature component of interplanetary dust particles

Transmission electron microscope study of a chondritic interplanetary dust particle has revealed the presence of epsilon iron-nickel carbide, a low-temperature carbide previously encountered only in metallurgical studies. In these studies epsilon-carbide was synthesized by carburization of iron or nickel grains in a stream of carbon monoxide or carbon monoxide plus hydrogen. Similar carburization of an iron-nickel metal in situ may have produced epsilon-carbide during particle heating on atmospheric entry or in solar orbit. Alternatively, the epsilon-carbide may be a by-product of Fischer-Tropsch reactions in the solar nebula. Such reactions have been proposed as the mechanism of hydrocarbon formation in the early solar system.

Christoffersen, R.↗
NASA NTRS1983

Comparison of Yamato and Victoria Land polymict eucrites - A view from mineralogical and isotopic studies

New interior samples of four Yamato polymict eucrites (Y74159, Y74450, Y75011, and Y75015) have been studied by electron microprobe, transmission electron microscope, and X-ray diffraction techniques, and compared with several samples of the Victoria Land polymict eucrites. These same samples have been analysed using Rb-Sr and Nd-Sm isotopic systematics. Several grains of inverted pigeonite, with blebby augite similar to those in Binda and Moama, have been identified in all four Yamato eucrites. Coarse-grained meso-stasis-rich subophitic basalts, which contain Mg-rich pigeonite (with Fe-rich olivine veinlets) zoned outward to a subcalcic ferroaugite rims, have also been found. These unique clasts were not found in ALH76005, 77302, 78040, 7858, and 78165 and EET eucrites. The tight grouping of Rb/Sr and Sm/Nd ratos, and similar modal compositions of the Yamato group indicate that they are most likely to be pieces from a single fall, and distinct from the ALH and EET groups. However, the Yamato, Allan Hills, and Elephant Moraine groups may sample a few distinct magmas or similar but different source regions on the same parent body.

Takeda, H.↗
NASA NTRS1984

Remanent magnetization of a 'paramagnetic' composition in the ilmenite-hematite solid solution stress

In the ilmenite-hematite solid solution series, compositions more ilmenite-rich than Ilm(73)Hem(27) are classically thought to be paramagnetic at room temperature. Ilm(80)Hem(20) samples have nevertheless been synthesized that acquire hard saturation remanent and thermoremanent moments. From analysis of AC demagnetization data, the source of the measured remanence is believed to be a single-domain (SD) like material within the IlM(80)Hem(20) grains themselves. On the basis of transmission electron microscope observations, it is suggested that transformation-induced domain boundaries, which in part are enriched in hematite component relative to the bulk composition of the grains, could act as the magnetic carrier of the SD-like remanence.

Lawson, C. A.↗
NASA NTRS1985

Hydrated interplanetary dust particle linked with carbonaceous chondrites?

The results of transmission electron microscope observations of a hydrated interplanetary dust particle (IDP) containing Fe-, Mg-rich smectite or mica as a major phase are reported. The sheet silicate appears to have formed by alteration of anhydrous silicates. Fassaite, a Ca, Al clinopyroxene, also occurs in this particle, and one of the crystals exhibits solar-flare tracks, clearly indicating that it is extraterrestrial. Fassaite is a major constituent of the Ca-, Al-rich refractory inclusions found in the carbonaceous chondrites, so its presence in this particle suggests that there may be a link between hydrated IDPs and carbonaceous chondrites in the early history of the solar system.

Tomeoka, K.↗
NASA NTRS1986

An ultrahigh vacuum multipurpose specimen chamber with sample introduction system for in situ transmission electron microscopy investigations

A commercial transmission electron microscope (TEM), with flat-plate upper pole piece configuration of the objective lens, and top-entry specimen introduction was modified by introducing an ultrahigh vacuum (UHV) specimen chamber for in situ TEM experimentation. The pumping and design principles and special features of this UHV chamber, which makes it possible to obtain 5 x 10 to the -10th mbar pressure at the site of the specimen, while maintaining the airlock system that allows operation in the 10 to the -10th mbar range within 15 min after specimen change, are described. Design operating pressures and image quality (resolution of metal particles smaller than 1 nm in size) were achieved. Schematic drawings and design dimensions are included.

Heinemann, K.↗
NASA NTRS1986

Fractographic and microstructural evaluation of 3500-hour durability specimens

Long term durability testing of candidate ceramic materials for advanced gas turbine applications was performed. Specimens of the materials were exposed to combustion atmospheres under temperature cyclic conditions for times up to 3500 hours and at peak temperatures of 1200 and 1370 C. The specimen strengths after exposure were measured at room temperature and at 1200 C. In addition, a number of physical measurements were taken; however, no microstructural examination of the specimens was performed. Materials examined include: sintered alpha silicon carbide, sintered silicon nitride, and reaction bonded silicon nitride. Sample preparation techniques were developed to provide high quality thin-section specimens which can be examined by transmitted light or thinned using an ion mill for subsequent transmission electron microscopic examination. Specimen preparation techniques and the results of optical and electron microscopic examination of the reaction interfaces of the selected specimens are presented.

Miller, A. D.↗