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NASA NTRS2016

Effect of 1% Inspired CO2 During Head-Down Tilt on Ocular Structures, Cerebral Blood Flow, and Visual Acuity in Healthy Human Subjects

The cephalad fluid shift induced by microgravity has been hypothesized to elevate intracranial pressure (ICP) and contribute to the development of the visual impairment/intracranial pressure (VIIP) syndrome experienced by many astronauts during and after long-duration space flight. In addition, elevated ambient partial pressure of carbon dioxide (PCO2) on the International Space Station (ISS) has also been hypothesized to contribute to the development of VIIP. We seek to determine if an acute, mild CO2 exposure, similar to that occurring on the ISS, combined with the cephalad fluid shift induced by head-down tilt will induce ophthalmic and ICP changes consistent with the VIIP syndrome.

Laurie, S. S.↗

NASA NTRS2015

Mars Atmospheric Characterization Using Advanced 2-Micron Orbiting Lidar

Mars atmospheric characterization is critical for exploring the planet. Future Mars missions require landing massive payloads to the surface with high accuracy. The accuracy of entry, descent and landing (EDL) of a payload is a major technical challenge for future Mars missions. Mars EDL depends on atmospheric conditions such as density, wind and dust as well as surface topography. A Mars orbiting 2-micron lidar system is presented in this paper. This advanced lidar is capable of measuring atmospheric pressure and temperature profiles using the most abundant atmospheric carbon dioxide (CO2) on Mars. In addition Martian winds and surface altimetry can be mapped, independent of background radiation or geographical location. This orbiting lidar is a valuable tool for developing EDL models for future Mars missions.

Singh, U.↗

NASA NTRS2017

Electrochemical Device Comprising an Electrically-Conductive, Selectively-Permeable Membrane

An electrochemical device, such as a fuel cell or an electrolyzer. In one embodiment, the electrochemical device includes a membrane electrode assembly (MEA), an anodic gas diffusion medium in contact with the anode of the MEA, a cathodic gas diffusion medium in contact with the cathode, a first bipolar plate in contact with the anodic gas diffusion medium, and a second bipolar plate in contact with the cathodic gas diffusion medium. Each of the bipolar plates includes an electrically-conductive, non-porous, liquid-permeable, substantially gas-impermeable membrane in contact with its respective gas diffusion medium, the membrane including a solid polymer electrolyte and a non-particulate, electrically-conductive material, such as carbon nanotubes, carbon nanofibers, and/or metal nanowires. In addition, each bipolar plate also includes an electrically-conductive fluid chamber in contact with the electrically-conductive, selectively-permeable membrane and further includes a non-porous and electrically-conductive plate in contact with the fluid chamber.

Mittelsteadt, Cortney K.↗

NASA NTRSDate not supplied

Understanding Thermal Transport in Polymer –Silver Nanowire Composites

Understanding thermal transport across filler-polymer interfaces and filler-filler contacts within polymer composites is of great importance for better thermal design of the composites that are widely used in high-performance heat exchangers, energy storage devices, and flexible electronics. Over the past several decades, considerable progress has been made in improving the thermal conductivity of polymer composites, but several key questions concerning the influence of interfacial thermal resistance, or Kapitza resistance, still remain. Firstly, the thermal properties of these composites are highly dependent on thermal transport through the filler network and its contacts. For metallic nanofillers, the thermal conductivity is often estimated using the Wiedemann-Franz law based on electrical conductivity; however, it remains a question whether the Wiedemann-Franz law still holds at nanoscale contacts. Through investigation of silver nanowires of varying sizes, we were able to demonstrate that the Lorenz number for silver nanowire increases with decreasing nanowire diameter. Examination of the corresponding electrical and thermal conductivities indicate that these changes are due to that the relative contribution of phonons becomes more significant as a result of elastic stiffening. Furthermore, we show that for silver nanowires, the contact thermal resistance is ~8 times lower than that of multi-walled carbon nanotube (MWCNT) of similar diameters. Additionally, through systematic studies of electrospun polymer-silver nanowire composite nanofibers, we investigated the impact of interface morphology on the thermal conductivity enhancement of the composite system and probed the value of the Kapitza resistance for individual polymer-filler interfaces. For polymer nanofibers containing continuous, single silver nanowires, the thermal conductivity increases linearly with increasing volume fraction of silver, which is consistent with the prediction of percolation theory for samples above the percolation limit. By comparing this linear trend to the measured thermal conductivities of composite nanofibers with more complex structures, we were able to determine the resistance associated with any additional polymer-filler boundaries. In doing so we find that the thermal boundary resistance for polyvinylpyrrolidone (PVP)–silver interfaces is significantly lower than that of comparable polymer-MWCNT composite systems.Together our studies provide new insights into thermal transport in polymer nanocomposites and should help facilitate the design of high performance polymeric thermal interface material.

Thermal transport↗

NASA NTRSDate not supplied

Understanding Thermal Transport in Polymer - Silver Nanowire Composites

Understanding thermal transport across filler-polymer interfaces and filler-filler contacts within polymer composites is of great importance for better thermal design of the composites that are widely used in high-performance heat exchangers, energy storage devices, and flexible electronics. Over the past several decades, considerable progress has been made in improving the thermal conductivity of polymer composites, but several key questions concerning the influence of interfacial thermal resistance, or Kapitza resistance, still remain. Firstly, the thermal properties of these composites are highly dependent on thermal transport through the filler network and its contacts. For metallic nanofillers, the thermal conductivity is often estimated using the Wiedemann-Franz law based on electrical conductivity; however, it remains a question whether the Wiedemann-Franz law still holds at nanoscale contacts. Through investigation of silver nanowires of varying sizes, we were able to demonstrate that the Lorenz number for silver nanowire increases with decreasing nanowire diameter. Examination of the corresponding electrical and thermal conductivities indicate that these changes are due to that the relative contribution of phonons becomes more significant as a result of elastic stiffening. Furthermore, we show that for silver nanowires, the contact thermal resistance is ~8 times lower than that of multi-walled carbon nanotube (MWCNT) of similar diameters. Additionally, through systematic studies of electrospun polymer-silver nanowire composite nanofibers, we investigated the impact of interface morphology on the thermal conductivity enhancement of the composite system and probed the value of the Kapitza resistance for individual polymer-filler interfaces. For polymer nanofibers containing continuous, single silver nanowires, the thermal conductivity increases linearly with increasing volume fraction of silver, which is consistent with the prediction of percolation theory for samples above the percolation limit. By comparing this linear trend to the measured thermal conductivities of composite nanofibers with more complex structures, we were able to determine the resistance associated with any additional polymer-filler boundaries. In doing so we find that the thermal boundary resistance for polyvinylpyrrolidone (PVP)–silver interfaces is significantly lower than that of comparable polymer-MWCNT composite systems. Together our studies provide new insights into thermal transport in polymer nanocomposites and should help facilitate the design of high performance polymeric thermal interface material.

Matthew L. Fitzgerald↗

NASA NTRSDate not supplied

H2 / DeCarbonization Studies: History and Ongoing

An ongoing study is collecting and reviewing hydrogen and low/zero carbon aircraft and related studies. In addition to previous NASA studies, international and as well as other US sponsored hydrogen, other fuels and infrastructure efforts supporting aviation aircraft are included. These reports and presentations are summarized here to develop further insight as well as help identify potential research areas to support reduction or elimination of harmful emissions from aviation aircraft. Although not all possible studies have been identified and included here, it is believed that sufficient information has been collected to help guide subsequent efforts. Efforts pertaining to aircraft emissions and assessing climate impact have only just started to be included.

fuel↗

NASA NTRS2022

Soil Carbon Losses Reduce Soil Moisture in Global Climate Model Simulations

Most agricultural soils have experienced substantial soil organic carbon losses in time. These losses motivate recent calls to restore organic carbon in agricultural lands to improve biogeochemical cycling and for climate change mitigation. Declines in organic carbon also reduce soil infiltration and water holding capacity, which may have important effects on regional hydrology and climate. To explore the regional hydroclimate impacts of soil organic carbon changes, we conduct new global climate model experiments with NASA Goddard Institute for Space Studies ModelE that include spatially explicit soil organic carbon concentrations associated with different human land management scenarios. Compared to a “no land use” case, a year 2010 soil degradation scenario, in which organic carbon content (OCC; weight %) is reduced by a factor of ∼0.12 on average across agricultural soils, resulted in soil moisture losses between 0.5 and 1 temporal standard deviations over eastern Asia, northern Europe, and the eastern United States. In a more extreme idealized scenario where OCC is reduced uniformly by 0.66 across agricultural soils, soil moisture losses exceed one standard deviation in both hemispheres. Within the model, these soil moisture declines occur primarily due to reductions in porosity (and to a lesser extent infiltration) that overall soil water holding capacity. These results demonstrate that changes in soil organic carbon can have meaningful, large-scale effects on regional hydroclimate and should be considered in climate model evaluations and developments. Further, this also suggests that soil restoration efforts targeting the carbon cycle are likely to have additional benefits for improving drought resilience.

Atmosphere-land interaction↗

NASA NTRSDate not supplied

NASA's Composite Overwrap Lessons Learned on 40k Thrust Chamber Assemblies

Filament wound carbon fiber/polymer composite overwraps combined with additively manufactured (AM) copper alloy combustion chambers are a critical part of NASA’s Rapid Analysis and Manufacturing Propulsion Technology (RAMPT) project. The composite overwrap is a high strength-to-weight material and allows for significant weight reduction of the high-pressure thrust chamber assembly, reduction of overall cost, and reduced fabrication time while offering structural robustness. Integrated AM/composite overwrap chamber assemblies using 2,000 lbf (2k) and 7,000 lbf (7k) thrust were successfully hot fire tested at NASA Marshall Space Flight Center (MSFC). These assemblies allowed the team to learn lessons related to the design, analysis, and manufacturing of these integrated assemblies. A final goal of the RAMPT project is to design and test a 40,000 lbf (40k) thrust chamber assembly. The40k chamber presented the team several new challenges including an integral inlet port in the main body of the composite overwrap. Through multiple iterations of manufacturing techniques, varied materials, and Non-Destructive Evaluations (NDE), many lessons were learned to obtain a final design solution that would not only allow for the interrupted port inlet but also allow for sufficient material margins for the most critically stressed part of the chamber. This paper will cover the manufacturing techniques exploring fabric designs to help subsidize the coverage in the areas left bare by the inlet port during the filament winding process and custom tooling needed for the final full chamber processing. The original material choice of bismaleimide (BMI) 5250-4 from the 7k chamber performed well for the extreme environment of hot fire testing but proved to be difficult with the increased scale and interrupted port design of the 40kchamber. Discussion in this paper will cover these changes, including evaluation of the design, comparison to the prior 2k and 7k designs, and show the final hardware that will be tested. One primary goal of this work and RAMPT project is to provide this development process and data to industry for infusion into future engine designs.

Filament Wound↗

NASA NTRS2014

A Five-year Performance Study of Low VOC Coatings over Zinc Thermal Spray for the Protection of Carbon Steel at the Kennedy Space Center

The launch facilities at the Kennedy Space Center (KSC) are located approximately 1000 feet from the Atlantic Ocean where they are exposed to salt deposits, high humidity, high UV degradation, and acidic exhaust from solid rocket boosters. These assets are constructed from carbon steel, which requires a suitable coating to provide long-term protection to reduce corrosion and its associated costs. While currently used coating systems provide excellent corrosion control performance, they are subject to occupational, safety, and environmental regulations at the Federal and State levels that limit their use. Many contain high volatile organic compounds (VOCs), hazardous air pollutants, and other hazardous materials. Hazardous waste from coating operations include vacuum filters, zinc dust, hazardous paint related material, and solid paint. There are also worker safety issues such as exposure to solvents and isocyanates. To address these issues, top-coated thermal spray zinc coating systems were investigated as a promising environmentally friendly corrosion protection for carbon steel in an acidic launch environment. Additional benefits of the combined coating system include a long service life, cathodic protection to the substrate, no volatile contaminants, and high service temperatures. This paper reports the results of a performance based study to evaluate low VOC topcoats (for thermal spray zinc coatings) on carbon steel for use in a space launch environment.

Zinc Thermal Spray↗

NASA NTRS1988

Carbon cycle instability as a cause of the late Pleistocene ice age oscillations - Modeling the asymmetric response

A dynamical model of the Pleistocene ice ages is presented, which incorporates many of the qualitative ideas advanced recently regarding the possible role of ocean circulation, chemistry, temperature, and productivity in regulating long-term atmospheric carbon dioxide variations. This model involves one additional term (and free parameter) beyond that included in a previous model (Saltzman and Sutera, 1987), providing the capacity for an asymmetric response. It is shown that many of the main features exhibited by the delta(O-18)-derived ice record and the Vostok core/delta(C-13)-derived carbon dioxide record in the late Pleistocene can be deduced as a free oscillatory solution of the model.

Saltzman, Barry↗

NASA NTRS2011

One-carbon (bio ?) Geochemistry in Subsurface Waters of the Serpentinizing Coast Range Ophiolite

Serpentinization - the aqueous alteration of ultramafic rocks - typically imparts a highly reducing and alkaline character to the reacting fluids. In turn, these can influence the speciation and potential for metabolism of one-carbon compounds in the system. We examined the aqueous geochemistry and assessed the biological potential of one-carbon compounds in the subsurface of the McLaughlin Natural Reserve (Coast Range Ophiolite, California, USA). Fluids from wells sunk at depths of 25-90 meters have pH values ranging from 9.7 to 11.5 and dissolved inorganic carbon (DIC concentrations) generally below 60 micromolar. Methane is present at concentrations up to 1.3 millimolar (approximately one-atmosphere saturation), and hydrogen concentrations are below 15 nanomolar, suggesting active consumption of H2 and production of CH4. However, methane production from CO2 is thermodynamically unfavorable under these conditions. Additionally, the speciation of DIC predominantly into carbonate at these high pH values creates a problem of carbon availability for any organisms that require CO2 (or bicarbonate) for catabolism or anabolism. A potential alternative is carbon monoxide, which is present in these waters at concentrations 2000-fold higher than equilibrium with atmospheric CO. CO is utilized in a variety of metabolisms, including methanogenesis, and bioavailability is not adversely affected by pH-dependent speciation (as for DIC). Methanogenesis from CO under in situ conditions is thermodynamically favorable and would satisfy biological energy requirements with respect to both Gibbs Energy yield and power.

McLaughlin Natural Reserve↗

NASA NTRS1979

Venus upper atmosphere neutral gas composition - First observations of the diurnal variations

Measurements of the composition, temperature, and diurnal variations of the major neutral constituents in the thermosphere of Venus are being made with a quadrupole mass spectrometer on the Pioneer Venus Orbiter. Concentrations of carbon dioxide, carbon monoxide, molecular nitrogen, atomic oxygen, and helium are presented, in addition to an empirical model of the data. The concentrations of the heavy gases, carbon dioxide, carbon monoxide, and molecular nitrogen, rapidly decrease from the evening terminator toward the nightside; the concentration of atomic oxygen remains nearly constant and the helium concentration increases, an indication of a nightside bulge. The kinetic temperature inferred from scale heights drops rapidly from 230 K at the terminator to 130 K at a solar zenith angle of 120 deg, and to 112 K at the antisolar point.

Niemann, H. B.↗

NASA NTRS1986

Observations of the 157.7 micron (C II) emission from the galactic H II regions W3 and W51

The 157.7 micron ground-state fine-structure transition of singly ionized carbon was detected from three positions, each in galactic H II region W3 and W51. These findings show that this emission goes beyond the H II regions and the carbon recombination region in each source. In addition these observations establish a lower limit to the luminosity in the 157.7 micron (C II) line of 360 solar luminosity from W3 and 41 solar luminosity from W51. Mechanisms for 157.7 micron-line excitation are discussed, and it is noted that a substantial part of the observed emission originates in the thin carbon recombination line-emitting region which borders on the H II regions and the warm atomic and molecular gas at the surface of neighboring molecular clouds. It is proposed that excitation by electrons present in the diffuse gas surrounding W51 contributes to the extended 157.7 micron (C II) line emission from this region. It was found that the (C II)FIR continuum ratios for W3 and W51 are in agreement with those of other galactic H II regions.

Melnick, G.↗

NASA NTRS1997

Overview of the International Space Station System Level Trace Contaminant Injection Test

Trace contaminant control onboard the International Space Station will be accomplished not only by the Trace Contaminant Control Subassembly but also by other Environmental Control and Life Support System subassemblies. These additional removal routes include absorption by humidity condensate in the Temperature and Humidity Control Condensing Heat Exchanger and adsorption by the Carbon Dioxide Removal Assembly. The Trace Contaminant Injection Test, which was performed at NASA's Marshall Space Flight Center, investigated the system-level removal of trace contaminants by the International Space Station Atmosphere Revitalization, and Temperature/Humidity Control Subsystems, (November-December 1997). It is a follow-on to the Integrated Atmosphere Revitalization Test conducted in 1996. An estimate for the magnitude of the assisting role provided by the Carbon Dioxide Removal Assembly and the Temperature and Humidity Control unit was obtained. In addition, data on the purity of Carbon Dioxide Removal Assembly carbon dioxide product were obtained to support Environmental Control and Life Support System Air Revitalization Subsystem loop closure.

Tatara, James D.↗

NASA NTRS1973

Research on oxygen recovery systems for use in space capsules

An improved electrochemical process was investigated for the recovery of oxygen from the atmospheres of manned space capsules. The objective of the proposed system is to recover the oxygen from CO2 with high efficiency and to recover the additional amount of oxygen from water that is required to provide a total oxygen makeup stream of about 2.0 lb/man-day. The carbon from the CO2 must be converted into a readily disposable or usable form. The results are given of initial experiments with a porous stainless steel cathode in a LiCl-KCl electrolyte with small additions of oxide, carbonate, and hydroxide.

Selman, J. R.↗

NASA NTRS2022

Development of an Effective Finite-rate Oxidation Model for NuSil-coated Charred Carbon Preform Ablators

Recently, a detailed effective finite-rate surface chemistry model was developed for the oxidation of FiberForm [1] using the molecular beam experimental data of Poovathingal et al., [2]. FiberForm is the major building block of the thermal protection system (TPS) material Phenolic Impregnated Carbon Ablator (PICA), commonly used by NASA. The surface chemistry model consists of detailed surface reaction mechanisms such as adsorption, desorption, and several types of Langmuir-Hinshelwood (LH) reactions to characterize the oxygen-carbon interactions at the surface. This model provides excellent agreement with the experimental data for oxidation product compositions and corresponding translational energy distributions. Further, an effective oxidation model was constructed that captures the equivalent interaction of oxygen inside the microstructure (including multiple surface collisions) via a modified reactivity for a smooth wall boundary condition. This enables the use of this model directly into Computational Fluid Dynamics (CFD) codes and Material Response (MR) codes to accurately simulate the gas–surface interactions within FiberForm without using the detailed micro-structure. However, this effective model is valid only for the virgin FiberForm. As the TPS material undergoes ablation, the preform carbon burns and turns into char. In addition, PICA is also coated with a protective silicon coating called NuSil for the purpose of mitigating the spread of phenolic dust, and limit contamination during clean room operations. Fig. 1 shows a X-ray microtomography image of a charred NuSil-coated PICA. The NuSil layer introduces species containing silicon into the product mixture. Further, the reactivity of the carbon within the char layer is different from the virgin FiberForm as shown in Fig. 2. Recently a new set of molecular beam experiments were performed on this NuSil-coated TPS material [3] with the same type of oxygen beam used in the previous experiments. Using the latest experimental data, the previously developed effective model will be extended to account for the charred carbon as well as the NuSil coating. Finally, this new effective model with three phases – preform carbon, char, and NuSil; will be compared and validated against the experimental product compositions.

K Swaminathan Gopalan↗

NASA NTRS1993

Cometary interplanetary dust particles? An update on carbon in anhydrous IDPS

Chondritic anhydrous interplanetary dust particles (IDP's) are widely considered to be the most pristine samples available for the study of the early solar system because of their primitive mineralogy, chemistry, and isotopic characteristics. Previously, anhydrous IDP's were analyzed quantitatively for light elements and found that these particles have significantly higher bulk carbon abundances than known chondritic meteorites. A relationship between carbon abundance and silicate mineralogy was also identified which, in general, shows that particles dominated by pyroxenes have a higher carbon abundance than those dominated by olivines. Particles containing equal amounts of olivine and pyroxene show a range of carbon contents and can be grouped with either the pyroxene- or olivine-dominated particles based on their carbon abundance. It was suggested that high carbon pyroxene-rich IDP's are derived from cometary sources. Bulk compositions and mineralogy of our additional IDP's were determined; one particle has the highest carbon abundance reported in IDP's or any other chondritic material, with the possible exception of the carbon-rich Halley particles.

Thomas, K. L.↗

NASA NTRS2005

Tribological Behavior of Nano-Onions in Krytox 143AB Evaluated

Nanoparticles have been developed over the past 10 years and have found several applications. This work presents the use of carbon nano-onions as a potential oil additive for aerospace applications. Researchers at the NASA Glenn Research Center tested lubricant lifetimes in ambient air and ultrahigh vacuum and characterized the breakdown products of the friction and wear. These carbon nanoparticles can provide adequate lubrication very similar to that of graphitic material when run in air. Soot represents one of the very first nanostructured materials, although it has rarely been considered as such. Changes in the carbon nanostructure, resulting in increased graphitic layer plane length, correlate with reactivity loss. Upon heating spherically shaped nanometer-sized carbon black in the absence of oxidant, graphene sheets form, and the initial soot particle templates the growth of a graphitic particle into what is best described as a sphere with many flat sides having a hollow interior. Because there are no edge sites, these polygonal graphitic particles, or nano-onions, are relatively resistant to oxidation. Graphite is used as a solid lubricant because of its stability at moderately high temperatures. However, the temperature at which graphite oxidizes rapidly is strongly influenced by surface area. With the size of particles typically employed in lubrication, a great amount of thermal stability is lost because of size reduction either during preparation or during lubrication of contacting parts. Therefore, we have undertaken a study of the lubricating ability of graphitic nano-onions (ref. 1).

Street, Kenneth W.↗