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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 307 records · Page 17
All sourcesNASA NTRSDOE OSTI
NASA NTRS2008

Lidar Measurements of Stratospheric Ozone, Aerosols and Temperature during the SAUNA Campaign at Sodankyla, Finland

The Sodankyla Total Column Ozone Intercomparison (SAUNA) campaign took place at the Finnish Meteorological Institute Arctic Research Center (FMI-ARC) at Sodankyla, Finland (67.37 N) in two separate phases during early spring 2006, and winter 2007. These campaigns has several goals: to determine and improve the accuracy of total column ozone measurements during periods of low solar zenith angle and high total column ozone; to determine the effect of ozone profile shape on the total column retrieval; and to make validate satellite ozone measurements under these same conditions. The GSFC Stratospheric Ozone Lidar (STROZ), which makes profile measurements of ozone temperature, aerosols and water vapor participated in both phases of the campaign. During the deployments, more than 30 profile measurements were made by the lidar instrument, along with Dobson, Brewer, DOAS, ozonesonde, and satellite measurements. The presentation will concentrate on STROZ lidar results from the second phase of the campaign and comparisons with other instruments will be discussed. This will include both ground-based and satellite comparisons.

McGee, T.↗
NASA NTRS2002

Micro-machined planar field asymmetric ion mobility spectrometer as a gas chromatographic detector

A planar high field asymmetric waveform ion mobility spectrometer (PFAIMS) with a micro-machined drift tube was characterized as a detector for capillary gas chromatography. The performance of the PFAIMS was compared directly to that of a flame ionization detector (FID) for the separation of a ketone mixture from butanone to decanone. Effluent from the column was continuously sampled by the detector and mobility scans could be obtained throughout the chromatographic analysis providing chemical inforrmation in mobility scans orthogonal to retention time. Limits of detection were approximately I ng for measurement of positive ions and were comparable or slightly better than those for the FID. Direct comparison of calibration curves for the FAIMS and the FID was possible over four orders of magnitude with a semi-log plot. The concentration dependence of the PFAIMS mobility scans showed the dependence between ion intensity and ion clustering, evident in other mobility spectrometers and atmospheric pressure ionization technologies. Ions were identified using mass spectrometry as the protonated monomer and the proton bound dimer of the ketones. Residence time for column effluent in the PFAIMS was calculated as approximately 1 ms and a 36% increase in extra-column broadening versus the FID occurred with the PFAIMS.

NASA Discipline Life Sciences Technologies↗
NASA NTRS2014

The Broad-Band X-Ray Spectrum of IC 4329A from a Joint NuSTAR/Suzaku Observation

We have obtained a deep, simultaneous observation of the bright, nearby Seyfert galaxy IC 4329A with Suzaku and NuSTAR (Nuclear Spectroscopic Telescope Array). Through a detailed spectral analysis, we are able to robustly separate the continuum, absorption, and distant reflection components in the spectrum. The absorbing column is found to be modest (approximately 6 times 10 (sup 21) per square centimeter), and does not introduce any significant curvature in the Fe K band. We are able to place a strong constraint on the presence of a broadened Fe K alpha line (E (sub rest) equals 6.46 (from plus 0.08 to minus 0.07) kiloelectronvolts with sigma equals 0.33 (from plus 0.08 to minus 0.07) kiloelectronvolts and EW equals 34 (from plus 8 to minus 7) electronvolts), though we are not able to constrain any of the parameters of a relativistic reflection model. These results highlight the range in broad Fe K line strengths observed in nearby, bright, active galactic nuclei (roughly an order of magnitude), and imply a corresponding range in the physical properties of the inner accretion disk in these sources. We have also updated our previously reported measurement of the high-energy cutoff of the hard X-ray emission using both observatories rather than just NuSTAR alone: E (sub cut) equals 186 plus or minus 14 kiloelectronvolts. This high-energy cutoff acts as a proxy for the temperature of the coronal electron plasma, enabling us to further separate this parameter from the plasmas optical depth and to update our results for these parameters as well. We derive kT 50 (from plus 6 to minus 3) kiloelectronvolts with tau equals 2.34 (from plus +0.16 to minus 0.11) using a spherical geometry, kT equals 61 plus or minus1 kiloelectronvolt with tau equals 0.68 plus or minus 0.02 for a slab geometry, with both having an equivalent goodness-of-fit.

Dynamics - stars↗
NASA NTRS1985

Microgravity electrophoresis: A study of the factors that affect free-fluid separation

Electrophoresis experiments have been performed in the microgravity environment of the Space Shuttle. Test particles (fixed human and rabbit erythrocytes) migrated as expected in a static column and test macromolecules (human serum albumin, ovalbumin, hemoglobin A, and Pneumococcus polysaccharide 6B) migrated as expected in a continuous flow apparatus. The concentrations studied exceeded those that can be used in free-fluid separation and purification processes at unit gravity.

Source record↗
DOE OSTI2023

Microporous metal–organic frameworks for the purification of propylene

Separation of propylene from its analogous hydrocarbons such as propane is of great importance in the petrochemical industry to produce valuable chemical feedstocks with desired purity. However, the well-established method currently used for industrial propane/propylene separation is energy intensive. It involves repeated cycling in the cryogenic and high-pressure distillation process and requires multiple columns and high reflux ratios because of the very similar physical properties of the two species. Thus, it is identified as one of the most capital- and energy-intensive processes. Adsorptive separation based on porous adsorbents is regarded as an alternative energy-efficient technology to replace or supplement the traditional heat-driven cryogenic distillation processes. In this context, metal–organic frameworks (MOFs) have emerged as the most promising candidates for propane/propylene separation, taking into consideration their unique tunability with respect to pore geometry and pore functionality. In this highlight, we summarize the latest advancement in developing MOFs as physisorbents for the separation and purification of propylene from propane, with a focus on those that demonstrate selective molecular exclusion and propane-selective adsorption. We discuss the adsorption preferences related to the material design and separation mechanisms, and review the existing challenges. Lastly, we offer our perspectives on various strategies for the future design of MOFs that hold true potential for propylene purification under industrial settings.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1973

Laboratory and field observations of the growth of columnar and plate crystals from frozen droplets

A laboratory experiment was initiated to grow the banded columnar crystals found in cirrus clouds and to determine if they nucleated through a freezing nucleus. Banded columnar crystals were collected in cirrus clouds and also grown in a laboratory cold box over a temperature range of -20 to -46C. They were observed to grow from a frozen droplet through several distinct crystalline transitions. The first distinct crystalline form observed following the growth of a frozen droplet was a polyhedral crystal. With further growth, the polyhedral crystal developed end plates, and it appeared to be a 'double plate.' Then the separation between the plates nearly filled in to leave the characteristic band. Certain columns (-6 to -10C) and plates (-10 to -20C) were also observed to grow from a frozen droplet and showed similar crystalline transitions.

Heymsfield, A. J.↗
NASA NTRS1979

Isoelectric focusing of proteins and peptides

Egg-white solution was chosen as the reference solution in order to assess the effects of operational parameters (voltage, flow rate, ampholine pH range and concentration, and protein concentration) of the RIEF apparatus on protein resolution. Topics of discussion include: (1) comparison of RIEF apparatus to conventional IEF techniques (column and PAG) with respect to resolution and throughput; (2) peptide and protein separation (AHF, Thymosin - Fraction 5, vasoactive peptide, L-asparaginase and ACP); and (3) detection of peptides - dansyl derivatives of amino acids and peptides, post-focusing fluorescent labeling of amino acids, peptides and proteins, and ampholine extraction from focused gels.

Egen, N.↗
DOE OSTI2022

Developing Inorganic Resins for Radium and Actinium Generators and Purifications

The inorganic, normal-phase sorbents alumina, titania, and zirconia were evaluated and screened for the separation of Ba, La, 228 Ra, 228 Ac, and 212 Pb in a dilute acid matrix. The results show that the sorbents are capable of fractionating the ions between pH 1–8. Acetate and total metal ion concentrations were experimentally evaluated as factors that could affect retention using La and Ba surrogates. Pseudo-second order rate constants were derived and the uptake of La was determined to be endothermic. A stationary zirconia column was used to isolate Ba from La and Ra from Ac/Pb; elution profiles of each separation are presented. The utility and implications of these sorbents are discussed with respects to large-scale production of 225 Ac from radium targets. This work was published in 2020 and in 2022.

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEA↗
DOE OSTI2024

Adsorption Equilibrium, Kinetics, and Column Breakthrough Data for Aqueous Solutions of Binary-Acid and Ternary-Acid Mixtures of Acetic Acid, Butyric Acid, and Lactic Acid on IRN-78 Ion-Exchange Resin at Initial pH Levels of ∼3–7 and at 25–55 °C

This work is part of an effort to develop thermophysical property data and models supporting adsorptive process development for organic acid separation from a dilute aqueous solution of fermentation broth. It presents systematic experimental measurements for aqueous-phase adsorption equilibrium, kinetics, and column breakthrough for three binary-acid aqueous mixtures (acetic acid + lactic acid, butyric acid + lactic acid, and acetic acid + butyric acid) and one ternary-acid aqueous mixture (acetic acid + butyric acid + lactic acid) on Amberlite IRN-78 ion-exchange resin. The equilibrium measurements covered broad ranges of the initial acid concentration (100–400 mmol/L), initial pH (∼3–7), and temperature (25–55 °C). The equilibrium data for the binary-acid and ternary-acid aqueous mixtures indicate selective adsorption of lactic acid at initial pH levels of ∼3 and 4, while acetic acid and butyric acid are selectively adsorbed at initial pH levels of 5, 6, and 7. The subsequent kinetics and column breakthrough experiments were performed at 200 mmol/L with equimolar ratios, an initial pH of 6, and 25 °C. In conclusion, the measurements provide essential data sets for rigorous thermodynamic modeling and process simulation of adsorptive separation processes for organic acid separation from fermentation broth.

Adsorption↗
NASA NTRS2020

Radiography in High Mass X-Ray Binaries: Micro-Structure of the Stellar Wind Through Variability of the Column Density

Context. In high mass X-ray binaries, an accreting compact object orbits a high mass star, which loses mass through a dense and in homogeneous wind. Aims. Using the compact object as an X-ray backlight, the time variability of the absorbing column density in the wind can be exploited in order to shed light on the micro-structure of the wind and obtain unbiased stellar mass-loss rates for high mass stars. Methods. We developed a simplified representation of the stellar wind where all the matter is gathered in spherical “clumps” that are radially advected away from the star. This model enables us to explore the connections between the stochastic properties of the wind and the variability of the column density for a comprehensive set of parameters related to the orbit and to the wind micro-structure, such as the size of the clumps and their individual mass. In particular, we focus on the evolution with the orbital phase of the standard deviation of the column density and of the characteristic duration of enhanced absorption episodes. Using the porosity length, we derive analytical predictions and compare them to the standard deviations and coherence time scales that were obtained. Results. We identified the favorable systems and orbital phases to determine the wind micro-structure. The coherence time scale of the column density is shown to be the self-crossing time of a single clump in front of the compact object. We thus provide a procedure to get accurate measurements of the size and of the mass of the clumps, purely based on the observable time variability of the column density. Conclusions. The coherence time scale grants direct access to the size of the clumps, while their mass can be deduced separately from the amplitude of the variability. We further show how monitoring the variability at superior conjunctions can probe the onset of the clump-forming region above the stellar photosphere. If the high column density variations in some high mass X-ray binaries are due to unaccreted clumps which are passing by the line-of-sight, this would require high mass clumps to reproduce the observed peak-to-peak amplitude and coherence time scales. These clump properties are marginally compatible with the ones derived from radiative-hydrodynamics simulations. Alternatively, the following components could contribute to the variability of the column density: larger orbital scale structures produced by a mechanism that has yet to be identified or a dense environment in the immediate vicinity of the accretor, such as an accretion disk, an outflow, or a spherical shell surrounding the magnetosphere of the accreting neutron star.

stars: mass loss↗
NASA NTRS1979

Sunspots and the physics of magnetic flux tubes. IX - Umbral dots and longitudinal overstability

The dynamical properties of the sunspot field and of a column of hot gas confined by such a vertical magnetic field are examined in order to understand the umbral dot within the context of the magnetic sunspot structure. Attention is given to the conditions necessary for gas intrusion, longitudinal as well as convective overstability, the growing modes, and the even mode. With the hypothesis that the subsurface magnetic field of a sunspot splits into many separate flux tubes with field-free gas between, it is suggested that the field-free columns occasionally punch their way up through the overlying magnetic field to the surface, appearing there as the bright, field-free umbral dots. Effects fostering the phenomenon are also discussed, that is, the enhanced temperature of a column of rising gas, the strongly reduced overhead magnetic pressure, and the initiated upward intrusion; these effects are illustrated with examples.

Parker, E. N.↗
DOE OSTI2020

Study of the Cosmic Rays and Interstellar Medium in Local H I Clouds Using Fermi -LAT Gamma-Ray Observations

An accurate estimate of the interstellar gas density distribution is crucial to understanding the interstellar medium (ISM) and Galactic cosmic rays (CRs). To comprehend the ISM and CRs in a local environment, a study of the diffuse $γ$-ray emission in a midlatitude region of the third quadrant was performed. Specifically, the $γ$-ray data in the 0.1–25.6 GeV energy range of the Fermi Large Area Telescope (LAT) and other interstellar gas tracers such as the HI4PI survey data and the Planck dust thermal emission model were used, and the northern and southern regions were analyzed separately. The variation of the dust emission D em with the total neutral gas column density N H was studied in high dust temperature areas, and the N H /D em ratio was calibrated using $γ$-ray data under the assumption of a uniform CR intensity in the studied regions. The measured integrated $γ$-ray emissivities above 100 MeV are (1.58 ± 0.04) x 10 -26 photons s -1 sr -1 H-atom-1 and (1.59 ± 0.02) x 10-26 photons s-1 sr-1 H-atom -1 in the northern and southern regions, respectively, supporting the existence of a uniform CR intensity in the vicinity of the solar system. While most of the gas can be interpreted to be H I with a spin temperature of T S = 125 K or higher, an area dominated by optically thick H I with T S ~ 40 K was identified.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS1972

A method of isolating organic compounds present in water

Water sample is passed through a column containing macroreticular resin, which absorbs only nonionic organic compounds. These compounds are selectively separated using aqueous eluents of varying pH, or completely exuded with small amount of an organic eluent.

Calder, G. V.↗
NASA NTRS1986

Analysis of a spacecraft instrument ball bearing assembly lubricated by a perfluoroalkylether

An analysis of a spacecraft instrument ball bearing assembly, subjected to a scanning life test, was performed to determine the possible case of rotational problems involving these units aboard several satellites. The analysis indicated an ineffective transfer of a fluorinated liquid lubricant from a phenolic retainer to the bearing balls. Part of the analysis led to a novel HPLC separation method employing a fluorinated mobile phase in conjunction with silica based size exclusion columns.

Morales, W.↗
DOE OSTI2021

Functionalized coating polymers and uses thereof

The present invention relates to functionalized polymers useful for coating surfaces, such as the internal bore of a column. In particular embodiments, such functionalized polymers provide a selective stationary phase useful for separating and detecting organophosphorous agents. Methods of using such polymers are also described herein.

Whiting, Joshua J.↗
NASA NTRS1985

Multiplex gas chromatography for use in space craft

Gas chromatography is a powerful technique for the analysis of gaseous mixtures. Some limitations in this technique still exist which can be alleviated with multiplex gas chromatography (MGC). In MGC, rapid multiple sample injections are made into the column without having to wait for one determination to be finished before taking a new sample. The resulting data must then be reduced using computational methods such as cross correlation. In order to efficiently perform multiplexgas chromatography, experiments in the laboratory and on board future space craft, skills, equipment, and computer software were developed. Three new techniques for modulating, i.e., changing, sample concentrations were demonstrated by using desorption, decomposition, and catalytic modulators. In all of them, the need for a separate gas stream as the carrier was avoided by placing the modulator at the head of the column to directly modulate a sample stream. Finally, the analysis of an environmental sample by multiplex chromatography was accomplished by employing silver oxide to catalytically modulate methane in ambient air.

Valentin, J. R.↗
DOE OSTI2022

Optimization of flow in additively manufactured porous columns with graded permeability

Chemical engineering systems often involve a functional porous medium, such as in catalyzed reactive flows, fluid purifiers, and chromatographic separations. Ideally, the flow rates throughout the porous medium are uniform, and all portions of the medium contribute efficiently to its function. The permeability is a property of a porous medium that depends on pore geometry and relates flow rate to pressure drop. Additive manufacturing techniques raise the possibilities that permeability can be arbitrarily specified in three dimensions, and that a broader range of permeabilities can be achieved than by traditional manufacturing methods. Using numerical optimization methods, we show that designs with spatially varying permeability can achieve greater flow uniformity than designs with uniform permeability. We consider geometries involving hemispherical regions that distribute flow, as in many glass chromatography columns. By several measures, significant improvements in flow uniformity can be obtained by modifying permeability only near the inlet and outlet.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗