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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 307 records · Page 17

Formation of Minor Phases in a Nickel-Based Disk Superalloy

The minor phases of powder metallurgy disk superalloy LSHR were studied. Samples were consistently heat treated at three different temperatures for long times to approximate equilibrium. Additional heat treatments were also performed for shorter times, to then assess non-equilibrium conditions. Minor phases including MC carbides, M23C6 carbides, M3B2 borides, and sigma were identified. Their transformation temperatures, lattice parameters, compositions, average sizes and total area fractions were determined, and compared to estimates of an existing phase prediction software package. Parameters measured at equilibrium sometimes agreed reasonably well with software model estimates, with potential for further improvements. Results for shorter times representing non-equilibrium indicated significant potential for further extension of the software to such conditions, which are more commonly observed during heat treatments and service at high temperatures for disk applications.

Gabb, T. P.↗

Salt Marsh Formation in the Lower Hudson River Estuary

Salt marshes are constant depositional environments and as a result contain accurate indicators of past relative sea level rise and salinity. The Hudson River marshes are at least twice as deep when compared to coastal marshes on either side of the mouth of the Hudson. The reason for this difference in sedimentation is unclear. This study uses macrofossil data as well as sediment stratigraphy in order to understand the formation and evolution of these marshes. The composition of seeds, roots, shoots and foraminifera, are used to indicate past sea levels. The four sites involved in this study are, from south to north, the Arthur Kill Marsh in Staten Island (40 36 N, 74 77W), Piermont marsh (N 4100; 73 55W) Croton Point (41 14 N; 73 50W) and Iona Island (41 18N, 73 58W). These are all tidally influenced but with increasing distances from the New York Bight, which gives a good spectrum of tidal influence. AMS-C14 dates on basal macrofossils will document the time of each marsh formation. Basal material from Arthur Kill (8 m) includes freshwater seeds such as Viola, Potomageton and Alnus along with Salix buds. Basal material from Croton Point (10 m) includes fibrous woody material, foraminifera and Zanichellia seeds and other brackish vegetational components. The basal material from Piermont (13.77 m) is lacking any identifiable macrofossils between 150 and 500 microns. The basal material from Iona Island (10 m) has vegetation such as Scirpus and Cyperus seeds, probably implying a brackish environment. The freshwater origin of the Arthur Kill marsh in Staten Island is significant because it predates either sea level rise or the western channel incision. Additional implications for this study include evidence for changes in river channel geomorphology. Reasons for the relatively deeper river marshes include possible basal clay compaction, high production due to river and marine nutrients as well as tectonic activity. This study provides the groundwork for more high-resolution studies of these marshes to understand the fluctuations in salinity caused by relative sea level rise, tectonic faulting and/or changes in precipitation/evaporation.

Merley, Michael↗

Applicability of 1D site response analysis to shallow sedimentary basins: A critical evaluation through physics-based 3D ground motion simulations

One-dimensional site response analysis (1D SRA) remains the standard practice in considering the effect of local soil deposits and predicting site-specific ground motions, although its range of applicability to realistic seismic wavefields is still in question. In this 1D approach, horizontal and vertical ground shaking are assumed to be induced by vertically propagating shear and compressional waves, respectively. A recent study based on analytical two-dimensional (2D) plane waves and simple point source earthquake simulations has shown two mechanistic limitations in this 1D modelling technique for general inclined seismic waves, that is, systematic over-prediction of the vertical motion and wave trapping in the 1D soil column. In this article, we evaluate in detail the applicability of this 1D modelling approach to realistic three-dimensional (3D) simulated seismic wavefields in shallow sedimentary basins. Linear-viscoelastic 1D SRA predictions using two types of input motions that are commonly used in practice—rock outcrop and in-column motions, are compared with the reference true site response results from 3D earthquake simulations in terms of various measures in the frequency and time domain. It is shown that the horizontal motion in the 3D seismic wavefield exhibits dominant shear wave propagation phenomenon, while the vertical motion is a combined effect of compressional and shear waves and can be over-predicted by the 1D approach when the incident seismic waves are inclined. Direct evidence of the wave refraction process that leads to the vertical motion over-prediction is provided. 1D SRA with in-column inputs can yield motions that have significantly longer duration compared to the true 3D site response solution due to trapped waves, casting in doubt the frequent need for increased soil damping in existing site studies to compensate for wave attenuation due to scattering alone. Sensitivity investigation on the increase of soil profile damping by a multiplier D mul shows D mul values compatible with those found in the literature for both horizontal and vertical motions. It is shown that the level of D mul optimized for a best match of the spectral acceleration is dependent on the characteristic of the input motion and a larger D mul is typically required for the vertical component. In contrast, 1D SRA with outcrop motions predicts motions with shorter significant duration due to its inability to capture the basin-edge generated surface waves. A suite of ground motion simulations was performed to assess the sensitivity of the observations to the basin geologic structure including the velocity gradient, rock-basin impedance contrast and basin depth. The analysis results show that the accuracy of the simplified 1D procedure is dependent on the wavefield composition of both the input motions and the true 3D site response solution. While the horizontal motions in shallow sedimentary basins can, to the first order, be reasonably captured by the simplified 1D approach, 1D SRA for the vertical component is in general not reliable and contributions from inclined shear waves should be accounted for in site-specific evaluation of the vertical design ground motion.

1D assumption↗

Fatigue retardation due to creep in a fibrous composite

Experiments performed to determine the effects of temperature and creep strain on the fatigue life of a graphite/epoxy composite laminate show that (1) sustained periods of static loading have significant retardation effects on the fatigue degradation rate of the laminated composite, and (2) cyclic loading with a lower frequency preceding higher frequency loading also prolongs the fatigue life. A creep crack hypothesis is proposed that can provide reasonable interpretations for these experimental results.

Sun, C. T.↗

Containerless processing of glass forming melts: D-1, MEA/A-2 experiment 81F01 conducted on STS-61A flight, October 1985

Results of experiment 81F01, which was conducted in the Material Experiment Assembly MEA/A-2 on the D-1 Spacelab Mission (STS-61A), are presented. The general plan of the experiment was to heat, melt, and quench six spherical samples of different glass forming compositions while they were levitated in a single axis acoustic levitator furnace (SAAL). In addition, two non-melting sintered alumina samples were used to check the operational characteristics of the SAAL under reduced gravity conditions. Three of the eight samples were levitated between 1250 and 1500 C before the lack of coolant created an over-temperature condition that caused the SAAL to shut down prematurely. Two of the three samples processed were calcia-gallia-silica and soda-lime-silica glass forming compositions. Evidence of a two to three times increase in the tendency for glass formation was obtained for the calcia-gallia-silica. The final glass appeared reasonably homogeneous even though it was made from hot pressed powders containing deliberate heterogeneities. A photographic record was obtained of the microgravity sample processing sequences.

Day, D. E.↗

Physical and chemical analysis of a Ni/H2 cell

A cycled aerospace nickel hydrogen (Ni/H2) cell was subjected to destructive physical analysis to determine the reason for a capacity loss after 5,967 cycles at 60 percent depth of discharge. The positive plates in the cell were analyzed in terms of chemical composition, active material utilization, charge efficiency, and thickness increase. The microstructure of a cross section of the positive plate was determined by backscattered electron image analysis. The results suggest that the capacity loss in the cell is caused by low charge acceptance and low active material utilization at the positive plate. The oxidized nickel species content of the positive plate increased due to corrosion of the nickel sintered skeleton. This appears to circumvent the orderly reaction of the active material. Microstructural analysis has indicated that a new phase of active material is formed with cycling.

H Vaidyanathan↗

Spectral Band Characterization for Hyperspectral Monitoring of Water Quality

A method for selecting the set of spectral characteristics that provides the smallest increase in prediction error is of interest to those using hyperspectral imaging (HSI) to monitor water quality. The spectral characteristics of interest to these applications are spectral bandwidth and location. Three water quality constituents of interest that are detectable via remote sensing are chlorophyll (CHL), total suspended solids (TSS), and colored dissolved organic matter (CDOM). Hyperspectral data provides a rich source of information regarding the content and composition of these materials, but often provides more data than an analyst can manage. This study addresses the spectral characteristics need for water quality monitoring for two reasons. First, determination of the greatest contribution of these spectral characteristics would greatly improve computational ease and efficiency. Second, understanding the spectral capabilities of different spectral resolutions and specific regions is an essential part of future system development and characterization. As new systems are developed and tested, water quality managers will be asked to determine sensor specifications that provide the most accurate and efficient water quality measurements. We address these issues using data from the Airborne Visible/Infrared Imaging Spectrometer (AVIRIS) and a set of models to predict constituent concentrations.

Vermillion, Stephanie C.↗

Tensile and flexural strength of non-graphitic superhybrid composites: Predictions and comparisons

Equations are presented and described which can be used to predict bounds on the tensile and flexural strengths of nongraphitic superhybrid (NGSH) composites. These equations are derived by taking into account the measured stress-strain behavior, the lamination residual stresses and the sequence of events leading to fracture. The required input for using these equations includes constituents, properties (elastic and strength), NGSH elastic properties, cure temperature, and ply stress influence coefficients. Results predicted by these equations are in reasonably good agreement with measured data for strength and for the apparent knees in the nonlinear stress-strain curve. The lower bound values are conservative compared to measured data. These equations are relatively simple and are suitable for use in the preliminary design and initial sizing of structural components made from NGSH composites.

Chamis, C. C.↗

Are interpretations of ancient marine temperatures constrained by the presence of ancient marine organisms?

The relationship between marine temperature and marine organisms is investigated. The adaptation of organisms to extreme temperatures is studied; it is observed that chemautotrophic and chemoheterotrophic prokaryotes adapt to 100 C, photoautotrophic prokaryotes to 73 C, and fungi to 60 C. The physiological and molecular factors related to thermal limits in organisms such as enzymes, lipids, or plasma membranes, are examined. Two types of thermal adaptations, resistance and capacity, are detected in organisms. Reasons for species distributions according to temperature barriers are proposed by Read (1967) and Bullock (1955) and are related to enzyme limits. The effects of an organism's composition on thermal stability is analyzed.

Valentine, J. W.↗

Modeling Solar Zenith Angle Effects on the Polar Wind

We use the Polar Wind Outflow Model (PWOM) to study the geomagnetically quiet conditions in the polar cap during solar maximum. The PWOM solves the gyrotropic transport equations for O+, H+, and He+ along several magnetic field lines in the polar region in order to reconstruct the full 3D solution. We directly compare our simulation results to the data based empirical model of Kitamura et al. (2011) of electron density which is based on 63 months of Akebono satellite observations. The modeled ion and electron temperatures are also compared with a statistical compilation of quiet time data obtained by the EISCAT Svalbard Radar (ESR) and Intercosmos Satellites. The data and model agree reasonably well, albeit with some differences. This study shows that photoelectrons play an important role in explaining the differences between sunlit and dark results of electron density, ion composition, as well as ion and electron temperatures of the quiet time polar wind solution. Moreover, these results provide an initial validation of the PWOM s ability to model the quiet time "background" solution.

Glocer, A↗

Observational constraints on interstellar dust models

No single model has been able to account for all of the observed spectroscopic properties of interstellar or circumstellar dust. The reason for this is that, despite the agreement that the grains are composed of silicaceous/metal oxide and carbonaceous material, there is strong disagreement as to their exact structure and composition. This led Draine and Lee (1984) to use interstellar extinction data to define an interstellar graphitic material; new observational findings have made even that identification uncertain. But the great advantage of their approach is that they used observations at all of the wavelengths available to define the material. Here, the authors attempt a variation of that approach. They examine recent UV and IR data and attempt to put constraints on the possible types of interstellar grain composition, and to connect these constraints with grain models. A summary of some of the important constraints imposed by the observations is given.

Hecht, James H.↗

Thermal Challenge for Sun-Viewing Instruments on Solar Probe 3 R(sub s) from Sun

The Solar Probe science team at NASA GSFC is considering enhance science observations by adding the nadir viewing Plasma Spectrometer instrument and using heat shields to protect the Plasma Wave antennas to permit full extension at 3 R. The electrostatic mirror of the Plasma Spectrometer is thermally protected from the Sun by a miniature sunshield that consists of two carbon-carbon composite layers, and a much smaller carbon-carbon heat shield. The sun-viewing surface of the miniature sunshield has an Al2O3 thin film coating. The slope of the sunshield is minimized to the smallest possible extent so that it can still accommodate the elliptical electrostatic mirror. Two small MLI flaps minimize the heat radiation from the Plasma Spectrometer to the spacecraft bus. This design meets the thermal requirements. Each of the four Plasma Wave wire antennas is 5 m long, and thermally protected from the Sun by a sunshield. The sunshield consists of two carbon-carbon composite sheets. One sheet views the Sun, and one does not. The slope of most of the sun-viewing sheet is 23deg with the nadir axis. For mechanical reason, it gradually increases to 37.5deg at the tip. The exterior of the sun viewing surfaces has a thin film of Al2O3. The exterior of the shaded sheets has a thin film of vapor deposited rhodium. It minimizes the heat radiation to the spacecraft bus. A high temperature MLI blanket between the carbon-carbon sheets radiatively isolates them. The thermal design meets the temperature requirements, but exceeds the 20 W limit of heat radiation to the spacecraft bus by 20 W. Thermal options to reduce the heat radiation include reducing the alpha to epsilon ratio of the Al2O3 thin film and reducing the number of antennas to three. Testing in 2006 includes thermal model validation and materials testing. High temperature ovens and a high light intensity Vortex Lamp will be used.

Choi, Michael K.↗

Micromechanics Based Design/Analysis Codes for Advanced Composites

Advanced high temperature Ceramic Matrix Composites (CMC) hold an enormous potential for use in aero and space related applications specifically for propulsion system components. Consequently, this has led to a multitude of research activities pertaining to fabrication, testing and modeling of these materials. The efforts directed at the development of ceramic matrix composites have focused primarily on improving the properties of the constituents as individual phases. It has, however, become increasingly clear that for CMC to be successfully employed in high temperature applications, research and development efforts should also focus on optimizing the synergistic performance of the constituent phases within the as-produced microstructure of the complex shaped CMC part. Despite their attractive features, the introduction of these materials in a wide spectrum of applications has been excruciatingly slow. The reasons are the high costs associated with the manufacturing and a complete experimental testing and characterization of these materials. Often designers/analysts do not have a consistent set of necessary properties and design allowables to be able to confidently design and analyze structural components made from these composites. Furthermore, the anisotropy of these materials accentuates the burden both on the test engineers and the designers by requiring a vastly increased amount of data/characterization compared to conventional materials.

Mital, Subodh K.↗

Biologically controlled minerals as potential indicators of life

Minerals can be produced and deposited either by abiotic or biologic means. Regardless of their origin, mineral crystals reflect the environment conditions (e.g., temperature, pressure, chemical composition, and redox potential) present during crystal formation. Biologically-produced mineral crystals are grown or reworked under the control of their host organism and reflect an environment different from the abiotic environment. In addition, minerals of either biologic or abiotic origin have great longevities. For these reasons, biologically produced minerals have been proposed as biomarkers. Biomarkers are key morphological, chemical, and isotopic signatures of living systems that can be used to determine if life processes have occurred. Studies of biologically controlled minerals produced by the protist, Paramecium tetraurelia, were initiated since techniques have already been developed to culture them and isolate their crystalline material, and methods are already in place to analyze this material. Two direct crystalline phases were identified. One phase, whose chemical composition is high in Mg, was identified as struvite. The second phase, whose chemical composition is high in Ca, has not been previously found occurring naturally and may be considered a newly discovered material. Analyses are underway to determine the characteristics of these minerals in order to compare them with characteristics of these minerals in order to compare them with characteristics of minerals formed abiotically, but with the same chemical composition.

Schwartz, D. E.↗

The composition of interstellar grain mantles

The molecular composition of interstellar grain mantles was calculated employing gas phase and grain surface reactions. The calculated mixtures consist mainly of H2O, H2CO, N2, CO, O2, CO2, H2O2, NH3, and their deuterated counterparts in varying ratios. The exact compositions depend strongly on the physical conditions in the gas phase. The calculated mixtures were compared to the observations by using laboratory spectra of grain mantle analogs. The two agree reasonably except for the strength of the 6.8 micron band.

Tielens, Alexander G. G. M.↗

Limitations to modeling the thermosphere and exosphere

Correlations were noted between solar 10cm radio flux, the indices of geomagnetic activity, and what happens in the atmosphere. There are also correlations between events in the troposphere and density in the thermosphere. Gravity waves in the thermosphere are not handled in existing models. A reasonable estimate is that they contribute perhaps ten percent to the deviation between model density values and the effective density as it influences satellite orbital motion. Another factor is atmospheric composition which influences density through the different scale heights of components of different molecular weight in this regime.

Slowey, John↗

Pb isotope constaints on the extent of crustal recycling into a steady state mantle

Isotopic and geochemical evidence was discussed against recycling of continental crust into the mantle. Element ratios such as Sm/Nd, Th/Sc, and U/Pb in sedimentary masses have remained relatively constant throughout Earth history, and this can only be reconciled with steady state recycling models if new crustal materials added from the mantle have had similar ratios. Such recycling models would also require shorter processing times for U, Th, and Pb through the mantle than are geodynamically reasonable. Models favoring subduction of pelagic sediments as the only recycling mechanism fail to account for the Pb isotopic signature of the mantle. Recycling of bulk crust with Pb isotopic compositions similar to those expected for primitive mantle would be permissable with available data, but there appear to be no plausible tectonic mechanisms to carry this out.

Galer, S. J. G.↗

A Vlasov theory for laminated composite circular beams with thin-walled open cross section

A Vlasov type beam theory for open-cross-section thin-walled circular beams constructed from laminated composite materials is presented. Comparisons are made to a branched shell analysis for a series of laminated thin-walled open cross-section curved beams. The results show that reasonable accuracy can be obtained for a variety of beam types, with a considerable reduction in analysis cost.

Woodson, Marshall B.↗