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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 307 records · Page 17
All sourcesNASA NTRSDOE OSTI
DOE OSTI2024

Dynamic metal-linker bonds in metal–organic frameworks

Metal-linker bonds serve as the “glue” that binds metal ions to multitopic organic ligands in the porous materials known as metal–organic frameworks (MOFs). Despite ample evidence of bond lability in molecular and polymeric coordination compounds, the metal-linker bonds of MOFs were long assumed to be rigid and static. Given the importance of ligand fields in determining the behaviour of metal species, labile bonding in MOFs would help explain outstanding questions about MOF behaviour, while providing a design tool for controlling dynamic and stimuli-responsive optoelectronic, magnetic, catalytic, and mechanical phenomena. Here, in this work, we present emerging evidence that MOF metal-linker bonds exist in dynamic equilibria between weakly and tightly bond conformations, and that these equilibria respond to guest–host chemistry, drive phase change behavior, and exhibit size-dependence in MOF nanoparticles.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

Spontaneous emission dynamics of Eu 3+ ions coupled to hyperbolic metamaterials

We show that sub-wavelength nanostructured systems with tunable electromagnetic properties, such as hyperbolic metamaterials (HMMs), provide a useful platform to tailor spontaneous emission processes. Here, we investigate a system comprising Eu 3+ (NO 3 ) 3 ·6H 2 O nanocrystals on an HMM structure featuring a hexagonal array of Ag nanowires in a porous Al2O 3 matrix. The HMM-coupled Eu 3+ ions exhibit up to a 2.4 fold increase in their decay rate, accompanied by an enhancement of the emission rate of the 5 D 0 → 7 F 2 transition. Using finite-difference time-domain modeling, we corroborate these observations with the increase in the photonic density of states seen by the Eu 3+ ions in the proximity of the HMM. Our results indicate that HMMs can serve as a valuable tool to control the emission from weak transitions and, hence, hint at a route toward more practical applications of rare-earth ions in nanoscale optoelectronics and quantum devices.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2021

An Analysis of Postharvest Fungal Pathogens Reveals Temporal–Spatial and Host–Pathogen Associations with Fungicide Resistance-Related Mutations

Fungicides are the primary tools to control a wide range of postharvest fungal pathogens. Fungicide resistance is a widespread problem that has reduced the efficacy of fungicides. Resistance to FRAC-1 (Fungicide Resistance Action Committee-1) chemistries is associated with mutations in amino acid position 198 in the β-tubulin gene. In our study, we conducted a meta-analysis of β-tubulin sequences to infer temporal, spatial, plant host, and pathogen genus patterns of fungicide resistance in postharvest fungal pathogens. In total, data were acquired from 2,647 specimens from 12 genera of fungal phytopathogens residing in 53 countries on >200 hosts collected between 1926 and 2020. The specimens containing a position 198 mutation were globally distributed in a variety of pathosystems. Analyses showed that there are associations among the mutation and the year an isolate was collected, the pathogen genus, the pathogen host, and the collection region. Interestingly, fungicide-resistant β-tubulin genotypes have been in a decline since their peak between 2005 and 2009. FRAC-1 fungicide usage data followed a similar pattern in that applications have been in a decline since their peak between 1997 and 2003. The data show that, with the reduction of selection pressure, FRAC-1 fungicide resistance in fungal populations will decline within 5 to 10 years. Based on this line of evidence, we contend that a β-tubulin position 198 mutation has uncharacterized fitness cost(s) on fungi in nature. The compiled dataset can inform end users on the regions and hosts that are most prone to contain resistant pathogens and assist decisions concerning fungicide resistance management strategies.

Plant Sciences↗
DOE OSTI2020

Photon energy and polarization-dependent electronic structure of Cr-doped Bi 2 Se 3

In this article, we report a comparative study of the electronic structure of Cr-doped and pristine Bi 2 Se 3 . Circular dichroism and photon-energy-dependent angle-resolved photoemission experiments were performed. Even though the surface states seen on the Cr-doped samples are gapped, they exhibit strong circular dichroism, for which we provide its origin in accordance with the nontrivial band structure of the bulk. We note the surface electronic structure measurements with linear and circular polarized light show signatures that the orbital composition of the surface states is changed with Cr doping. Our observations not only provide further spectroscopic information about topological materials, but also promotes an alternative experimental tool to control their spin-orbital texture.

36 MATERIALS SCIENCE↗
DOE OSTI2024

Automated pipeline processing X-ray diffraction data from dynamic compression experiments on the Extreme Conditions Beamline of PETRA III

Presented and discussed here is the implementation of a software solution that provides prompt X-ray diffraction data analysis during fast dynamic compression experiments conducted within the dynamic diamond anvil cell technique. It includes efficient data collection, streaming of data and metadata to a high-performance cluster (HPC), fast azimuthal data integration on the cluster, and tools for controlling the data processing steps and visualizing the data using the DIOPTAS software package. This data processing pipeline is invaluable for a great number of studies. The potential of the pipeline is illustrated with two examples of data collected on ammonia–water mixtures and multiphase mineral assemblies under high pressure. The pipeline is designed to be generic in nature and could be readily adapted to provide rapid feedback for many other X-ray diffraction techniques, e.g. large-volume press studies, in situ stress/strain studies, phase transformation studies, chemical reactions studied with high-resolution diffraction etc.

97 MATHEMATICS AND COMPUTING↗
DOE OSTI2026

A New UV Spot Test for Quality Control

Here, we present a fast, low-cost ultraviolet (UV) spot test to screen photovoltaic modules for UV-induced degradation (UVID). The measurement is based on a fiber-coupled arc lamp that delivers a highly accelerated local UV dose-approximately five years of equivalent field exposure in less than a day. Spot-exposed areas are evaluated using electroluminescence imaging. We test a “known bad” product, which was observed to experience UVID in the field, and a “known good” product which did not exhibit UVID in the field. Results indicate that the method may be useful as a quick and relatively inexpensive quality control screening tool for customers and manufacturers.

14 SOLAR ENERGY↗
DOE OSTI2022

Machine Straightness Error Measurement Based on Optical Fiber Fabry–Pérot Interferometer Monitoring Technique

Abstract In this research, we propose an Error Separation Technique (EST) based on optical fiber sensors for on-machine straightness error measurement. Two fiber optic Fabry–Pérot interferometers have been developed serving as two displacement sensors. The displacement distance is computed according to the reflected spectrum from interferometers, which can achieve a sub-micrometer resolution. The two-point method has been employed to separate the straightness error of the slides and the profile error of a fine-polished standard block. The spacing distance between two interferometers is determined by the diameter of optical fibers so that the EST's resolution has the potential to reach the sub-millimeter scale. In the experiment, the straightness error has been measured on a commercially available computer numerical control machine tool, and the measurement has been conducted on its x-axis. The spacing distance between two optical fiber sensors is 1.5 mm which equals the EST's resolution along the machine tool's x-axis. The separated profile error of the measured standard block is around 30 µm which has been verified by a high precision Coordinate Measurement Machine (CMM). The magnitude of the separated straightness error is around 40 µm. This technique is flexible and simple to be conducted, which can contribute to the micro-machine tool calibration and other straightness error applications.

Engineering↗
DOE OSTI2022

Impact of lithium wall conditioning and wave-frequency on high density lower hybrid current drive experiment on EAST

A series of dedicated lower hybrid current drive (LHCD) experiments on EAST shows that lithium wall conditioning extends LH current drive and heating up to the line-averaged density of n ̅_e≈ 4x1019 m-3 for both 2.45 and 4.6 GHz. Current drive at such a high density is crucial for the development of long-pulse non-inductive scenarios on EAST. With lithiation, the LH power injection of 1.5 MW at 2.45 GHz resulted in a drop of loop voltage of ~ 0.3 V, which is a comparable loop voltage drop observed with 1.1 MW at 4.6 GHz. The observed decrease in loop voltage is attributed mostly to the RF heating effect. Another LHCD experiment suggests that lithium wall coating has a more significant impact on the scrape-off-layer (SOL) properties than changes in the Greenwald fraction. LHCD at 2.45 GHz still suffers from a loss of efficiency. Enhanced power ionization in front of the launcher may cause the onset of density-dependent wave instabilities. The rise in the midplane SOL density may also accelerate a transition in the divertor regime, leading to additional ionization and collisional losses in the X-point divertor plasma. Ray-tracing modeling supports that a lower wave frequency is more prone to collisional power loss. The experiments confirm that lithiation is a useful tool to control the SOL plasma, and suggest that density control in front of the launcher may be critical to mitigating power loss mechanisms in the plasma boundary.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
NASA NTRS1968

Numerical Control Machine Data Manual

Numerical Control Machine Data Manual provides programmers with specific information for various types and sizes of numerical control machine tools and auxiliary equipment.

Mackey, R. T., Sr.↗
NASA NTRS1975

Interactive cutting path analysis programs

The operation of numerically controlled machine tools is interactively simulated. Four programs were developed to graphically display the cutting paths for a Monarch lathe, Cintimatic mill, Strippit sheet metal punch, and the wiring path for a Standard wire wrap machine. These programs are run on a IMLAC PDS-ID graphic display system under the DOS-3 disk operating system. The cutting path analysis programs accept input via both paper tape and disk file.

Weiner, J. M.↗
NASA NTRS1975

Use of the LANDSAT-2 Data Collection System in the Colorado River Basin Weather Modification Program

The author has identified the following significant results. The LANDSAT data collection system has proven itself to be a valuable tool for control of cloud seeding operations and for verification of weather forecasts. These platforms have proven to be reliable weather resistant units suitable for the collection of hydrometeorological data from remote severe weather environments. The detailed design of the wind speed and direction system and the wire-wrapping of the logic boards were completed.

Kahan, A. M.↗
NASA NTRS1981

AIRCL: A programmed system for generating NC tapes for airplane models. User's manual

A computer program is presented which calculates the cutter location file needed to machine models of airplane wings or wing-fuselage combinations on numerically controlled machine tools. Input to the program is a data file consisting of coordinates on the fuselage and wing. From this data file, the program calculates tool offsets, determines the intersection between wing and fuselage tool paths, and generates additional information needed to machine the fuselage and/or wing. Output from the program can be post processed for use on a variety of milling machines. Information on program structure and methodology is given as well as the user's manual for implementation of the program.

Akgerman, N.↗
NASA NTRS1980

Design, fabrication and test of a complex helicopter airframe section

A design solution is developed for the fabrication of an all-composite helicopter airframe cabin roof structure. Although this is inherently a complex structure, the parts count has been minimized by the avoidance of many mechanical fasteners, and a weight reduction of 26% has been obtained. The reduction of parts and elimination of mechanical fasteners will also result in a lowering of labor costs. The bonded graphite/epoxy elements of the structure employed aluminum tooling with control on all mating surfaces to yield accurate bond lines. A summary of static test results is presented for the basic structure and for the structure with mechanically fastened skin stiffeners. It is shown that the shear buckles caused the skin to peel from the stiffeners at about 960 lb/in. shear flow, calling for the addition of stiffeners with more bond area.

Rich, M. J.↗
NASA NTRS1981

The evolution of computer monitoring of real time data during the Atlas Centaur launch countdown

In the last decade, improvements in computer technology have provided new 'tools' for controlling and monitoring critical missile systems. In this connection, computers have gradually taken a large role in monitoring all flights and ground systems on the Atlas Centaur. The wide body Centaur which will be launched in the Space Shuttle Cargo Bay will use computers to an even greater extent. It is planned to use the wide body Centaur to boost the Galileo spacecraft toward Jupiter in 1985. The critical systems which must be monitored prior to liftoff are examined. Computers have now been programmed to monitor all critical parameters continuously. At this time, there are two separate computer systems used to monitor these parameters.

Thomas, W. F.↗
NASA NTRS1984

Using a commercial CAD system for simultaneous input to theoretical aerodynamic programs and wind-tunnel model construction

The Computer Aided Design (CAD) system's common geometry database was used to generate input for theoretical programs and numerically controlled (NC) tool paths for wind tunnel part fabrication. This eliminates the duplication of work in generating separate geometry databases for each type of analysis. Another advantage is that it reduces the uncertainty due to geometric differences when comparing theoretical aerodynamic data with wind tunnel data. The system was adapted to aerodynamic research by developing programs written in Design Analysis Language (DAL). These programs reduced the amount of time required to construct complex geometries and to generate input for theoretical programs. Certain shortcomings of the Design, Drafting, and Manufacturing (DDM) software limited the effectiveness of these programs and some of the Calma NC software. The complexity of aircraft configurations suggests that more types of surface and curve geometry should be added to the system. Some of these shortcomings may be eliminated as improved versions of DDM are made available.

Enomoto, F.↗
NASA NTRS1985

Spline Curves, Wire Frames and Bvalue

The methods that were developed for wire-frame design are described. The principal tools for control of a curve during interactive design are mathematical ducks. The simplest of these devices is an analog of the draftsman's lead weight that he uses to control a mechanical spline also create Ducks for controlling differential and integral properties of curves were created. Other methods presented include: constructing the end of a Bezier polygon to gain quick and reasonably confident control of the end tangent vector, end curvature and end torsion; keeping the magnitude of unwanted curvature oscillations within tolerance; constructing the railroad curves that appear in many engineering design problems; and controlling the frame to minimize errors at mesh points and to optimize the shapes of the curve elements.

Smith, L.↗
NASA NTRS1988

Space Station Freedom - Technical and management challenges

The development of the Space Station is reviewed, focusing on the technical and managerial aspects of the program. The optimization of the Space Station configuration, utilization impacts on design, technical aspects of the distribution systems, and the problems of designing for a lifetime of 30 years or more are discussed. In addition, cost reduction studies, testing and verification, determining the assembly sequence, and operational communications and support systems are examined. Managerial aspects of the program include organization, program control, management tools and processes, and the integration of elements from the international partners.

Moser, Thomas L.↗
NASA NTRS1991

Lessons learned in the development of the STOL intelligent tutoring system

Lessons learned during the development of the NASA Systems Test and Operations Language (STOL) Intelligent Tutoring System (ITS), being developed at NASA Goddard Space Flight Center are presented. The purpose of the intelligent tutor is to train STOL users by adapting tutoring based on inferred student strengths and weaknesses. This system has been under development for over one year and numerous lessons learned have emerged. These observations are presented in three sections, as follows. The first section addresses the methodology employed in the development of the STOL ITS and briefly presents the ITS architecture. The second presents lessons learned, in the areas of: intelligent tutor development; documentation and reporting; cost and schedule control; and tools and shells effectiveness. The third section presents recommendations which may be considered by other ITS developers, addressing: access, use and selection of subject matter experts; steps involved in ITS development; use of ITS interface design prototypes as part of knowledge engineering; and tools and shells effectiveness.

Seamster, Thomas↗