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At least 307 records · Page 17

Application of Spectral Analysis Techniques in the Intercomparison of Aerosol Data. Part II: Using Maximum Covariance Analysis to Effectively Compare Spatiotemporal Variability of Satellite and AERONET Measured Aerosol Optical Depth

Moderate Resolution Imaging SpectroRadiometer (MODIS) and Multi-angle Imaging Spectroradiomater (MISR) provide regular aerosol observations with global coverage. It is essential to examine the coherency between space- and ground-measured aerosol parameters in representing aerosol spatial and temporal variability, especially in the climate forcing and model validation context. In this paper, we introduce Maximum Covariance Analysis (MCA), also known as Singular Value Decomposition analysis as an effective way to compare correlated aerosol spatial and temporal patterns between satellite measurements and AERONET data. This technique not only successfully extracts the variability of major aerosol regimes but also allows the simultaneous examination of the aerosol variability both spatially and temporally. More importantly, it well accommodates the sparsely distributed AERONET data, for which other spectral decomposition methods, such as Principal Component Analysis, do not yield satisfactory results. The comparison shows overall good agreement between MODIS/MISR and AERONET AOD variability. The correlations between the first three modes of MCA results for both MODIS/AERONET and MISR/ AERONET are above 0.8 for the full data set and above 0.75 for the AOD anomaly data. The correlations between MODIS and MISR modes are also quite high (greater than 0.9). We also examine the extent of spatial agreement between satellite and AERONET AOD data at the selected stations. Some sites with disagreements in the MCA results, such as Kanpur, also have low spatial coherency. This should be associated partly with high AOD spatial variability and partly with uncertainties in satellite retrievals due to the seasonally varying aerosol types and surface properties.

aerosols↗

Impact of Air Traffic Reductions during the COVID-19 Pandemic on Aircraft-induced Clouds and their Radiative Effects

Air travel restrictions due to the novel coronavirus 2019 (COVID-19) pandemic drastically reduced air travel internationally during the spring of 2020. Such an extraordinary disruption of air traffic may have a profound effect on contrail formation that could allow for better quantification and scientific understanding of the radiative impacts of aviation-induced clouds on climate. This investigation synergizes MODIS, CrIS, and GOES-16 satellite analyses with weather analyses, including those from GEOS and MERRA, to compare contrail formation conditions and radiative forcings of linear contrails and thin cirrus detected over the contiguous United States (CONUS) and the North Atlantic for the 2020 air traffic slowdown period with parallel analyses conducted for a baseline period from a previous year with normal air traffic. A consistent analysis system for contrail detection and cloud property retrievals (e.g. optical depth, particle size, and altitude) from satellites, coupled with radiative transfer modeling are applied to characterize and contrast contrail cirrus properties and radiative effects estimated during the pandemic and baseline periods. Temperature and humidity profiles from numerical weather models and hyperspectral infrared measurements are used to estimate the contrail formation potential (CFP) over the study areas in order to help choose the most appropriate baseline period and to account for potential impacts of differences in meteorology on contrail formation and coverage. This study, using NASA satellite data and other assets, is expected to improve our understanding of the relationship between air traffic, contrail cirrus coverage and related impacts in order to better quantify the need for contrail formation mitigation strategies that could reduce aviation effects on climate.

William L Smith↗

Delineating the Impact of Transition‐Metal Crossover on Solid‐Electrolyte Interphase Formation with Ion Mass Spectrometry

Abstract Lithium‐metal batteries (LMB) employing cobalt‐free layered‐oxide cathodes are a sustainable path forward to achieving high energy densities, but these cathodes exhibit substantial transition‐metal dissolution during high‐voltage cycling. While transition‐metal crossover is recognized to disrupt solid‐electrolyte interphase (SEI) formation on graphite anodes, experimental evidence is necessary to demonstrate this for lithium‐metal anodes. In this work, advanced high‐resolution 3D chemical analysis is conducted with time‐of‐flight secondary‐ion mass spectrometry (TOF‐SIMS) to establish spatial correlations between the transition metals and electrolyte decomposition products found on cycled lithium‐metal anodes. Insights into the localization of various chemistries linked to crucial processes that define LMB performance, such as lithium deposition, SEI growth, and transition‐metal deposition are deduced from a precise elemental and spatial analysis of the SEI. Heterogenous transition‐metal deposition is found to perpetuate both heterogeneous SEI growth and lithium deposition on lithium‐metal anodes. These correlations are confirmed across various lithium‐metal anodes that are cycled with different cobalt‐free cathodes and electrolytes. An advanced electrolyte that is stable to higher voltages is shown to minimize transition‐metal crossover and its effects on lithium‐metal anodes. Overall, these results highlight the importance of maintaining uniform SEI coverage on lithium‐metal anodes, which is disrupted by transition‐metal crossover during operation at high voltages.

Chemistry↗

Analysis of Degradation and Electrochemical Behavior of Lithium–Oxygen Batteries under Lean Electrolyte Conditions

Lithium-oxygen batteries have garnered much attention in the past decades due to their high energy density and active material abundancy. Decreasing the electrolyte volume is critical to achieving a high energy density for practical applications. Recent works have demonstrated a serious performance limitation at lower electrolyte fillings. Here, in this work, we study specifically the difference between flooded and lean electrolyte lithium-oxygen batteries by systematically tracing the source of performance degradation. We find that the key contributor to the decrease in performance under lean electrolyte conditions stems from the lithium metal anode rather than the cathode. Solid electrolyte interphase (SEI) compositionally appears to be the same from X-ray photoelectron spectroscopy but the coverage is less uniform, and impedance is much higher under lean electrolyte conditions. Such an effect likely produced the observed poorer cycle performance at 10 μL cm -2 (similar to 28% cathode's pore volume filled) vs 100 μL cm -2 (278% of cathode's pore volume) at a capacity of 1.0 mAh cm -2 (0.1 mAh cm -2 ) using an electrolyte composition of 1 M LiTFSI in TEGDME.

Córdoba, Daniel [Argonne National Laboratory (ANL)↗

Catalog-level blinding on the bispectrum for DESI-like galaxy surveys

We evaluate the performance of the catalog-level blind analysis technique (blinding) presented in Brieden et al. (2020) in the context of a fixed template power spectrum and bispectrum analysis. This blinding scheme, which is tailored for galaxy redshift surveys similar to the Dark Energy Spectroscopic Instrument (DESI), has two components: the so-called “AP blinding” (concerning the dilation parameters α$_{∥}$, α$_{⊥}$) and “RSD blinding” (redshift space distortions, affecting the growth rate parameter f). Through extensive testing, including checks for the RSD part in cubic boxes, the impact of AP blinding on mocks with realistic survey sky coverage, and the implementation of a full AP+RSD blinding pipeline, our analysis demonstrates the effectiveness of the technique in preserving the integrity of cosmological parameter estimation when the analysis includes the bispectrum statistic. We emphasize the critical role of sophisticated — and difficult to accidentally unblind — blinding methods in precision cosmology.

79 ASTRONOMY AND ASTROPHYSICS↗

Use of the Doppler technique to track free roaming animals from satellites

The application of the Doppler effect to track wild animals is discussed, with artificial satellites used to provide wide range coverage. The limitations of radiotelemetry for the purpose of tracking animals are presented. The advantages of the artificial satellite, with specific reference to the Nimbus satellite, are examined.

Maxwell, J. C.↗

The International Planetary Patrol Program - An assessment of the first three years.

Day-to-day and hour-to-hour changes in the large-scale atmospheric and surface features of the planets can now be studied more effectively than previously possible. Since 1969 a network of observatories has obtained almost uninterrupted photographic coverage during all apparitions of Jupiter and Mars, plus some of Venus. Patrol films and catalogs are available to the scientific community. Recent or current analyses include the distribution and motion of clouds on Mars, the development and decay of Martian dust storms, the seasonal, diurnal, and random fluctuations in contrast between adjacent light and dark regions on Mars, the detection of vertical shear in the Jovian atmosphere, the longitudinal oscillation of the Red Spot, the dependence of rotation period on xenographic latitude and on time, the eruption and spread of south equatorial belt disturbances, and the retrograde circulation of the Venus cloud deck.

Baum, W. A.↗

Ice surface temperature retrieval from AVHRR, ATSR, and passive microwave satellite data: Algorithm development and application

During the second phase project year we have made progress in the development and refinement of surface temperature retrieval algorithms and in product generation. More specifically, we have accomplished the following: (1) acquired a new advanced very high resolution radiometer (AVHRR) data set for the Beaufort Sea area spanning an entire year; (2) acquired additional along-track scanning radiometer(ATSR) data for the Arctic and Antarctic now totalling over eight months; (3) refined our AVHRR Arctic and Antarctic ice surface temperature (IST) retrieval algorithm, including work specific to Greenland; (4) developed ATSR retrieval algorithms for the Arctic and Antarctic, including work specific to Greenland; (5) developed cloud masking procedures for both AVHRR and ATSR; (6) generated a two-week bi-polar global area coverage (GAC) set of composite images from which IST is being estimated; (7) investigated the effects of clouds and the atmosphere on passive microwave 'surface' temperature retrieval algorithms; and (8) generated surface temperatures for the Beaufort Sea data set, both from AVHRR and special sensor microwave imager (SSM/I).

Key, Jeff↗

Mg IX emission lines in an active region spectrum obtained with the Solar EUV Rocket Telescope and Spectrograph (SERTS)

Theoretical electron-temperature-sensitive Mg IX emission line ratios are presented for R(sub 1) = I(443.96 A)/I(368.06 A), R(sub 2) = I(439.17 A)/I(368.06 A), R(sub 3) = I(443.37 A)/I(368.06 A), R(sub 4) = I(441.22 A)/I(368.06 A), and R(sub 5) = I(448.28 A)/I(368.06 A). A comparison of these with observational data for a solar active region, obtained during a rocket flight by the Solar EUV Rocket Telescope and Spectrograph (SERTS), reveals excellent agreement between theory and observation for R(sub 1) through R(sub 4), with discrepancies that average only 9%. This provides experimental support for the accuracy of the atomic data adopted in the line ratio calculations, and also resolves discrepancies found previously when the theoretical results were compared with solar data from the S082A instrument on board Skylab. However in the case of R(sub 5), the theoretical and observed ratios differ by almost a factor of 2. This may be due to the measured intensity of the 448.28 A line being seriously affected by instrumental effects, as it lies very close to the long wavelength edge of the SERTS spectral coverage (235.46-448.76 A).

Keenan, F. P.↗

Is coverage a factor in non-Gaussianity of IMF parameters?

Recently, Feynman and Ruzmaikin (1994) showed that IMF parameters for the 1973 to 1990 period are not log-normally distributed as previously suggested by Burlaga and King (1979) for the data obtained over a shorter time period (1963-75). They studied the first four moments, namely: mean, variance, skewness, and kurtosis. For a Gaussian distribution, moments higher than the variance should vanish. In particular, Feynman and Ruzmaikin obtained very high values of kurtosis during some periods of their analysis. We note that the coverage for IMF parameters is very uneven for the period analyzed by them, ranging from less than 40% to greater than 80%. So a question arises as to whether the amount of coverage is a factor in their analysis. We decided to test this for the B(sub z) component of IMF, since it is an effective geoactive parameter for short term disturbances. Like them, we used 1-hour averaged data available on the Omnitape. We studied the scatter plots of the annual mean values of B(sub z)(nT) and its kurtosis versus the percent coverage for the year. We obtain a correlation coefficient of 0.48 and 0.42 respectively for the 1973-90 period. The probability for a chance occurrence of these correlation coefficients for 18 pair of points is less than 8%. As a rough measure of skewness, we determined the percent asymmetry between the areas of the histograms representing the distributions of the positive and the negative values of B(sub z) and studied its correlation with the coverage for the year. This analysis yields a correlation coefficient of 0.41 When we extended the analysis for the whole period for which IMF data are available (1963-93) the corresponding correlation coefficients are 0.59, 0.14, and 0.42. Our findings will be presented and discussed

Ahluwalia, H. S.↗

POET: POlarimeters for Energetic Transients

POET (Polarimeters for Energetic Transients) is a Small Explorer mission concept proposed to NASA in January 2008. The principal scientific goal of POET is to measure GRB polarization between 2 and 500 keV. The payload consists of two wide FoV instruments: a Low Energy Polarimeter (LEP) capable of polarization measurements in the energy range from 2-15 keV and a high energy polarimeter (Gamma-Ray Polarimeter Experiment - GRAPE) that will measure polarization in the 60-500 keV energy range. Spectra will be measured from 2 keV up to 1 MeV. The POET spacecraft provides a zenith-pointed platform for maximizing the exposure to deep space. Spacecraft rotation will provide a means of effectively dealing with systematics in the polarization response. POET will provide sufficient sensitivity and sky coverage to measure statistically significant polarization for up to 100 GRBs in a two-year mission. Polarization data will also be obtained for solar flares, pulsars and other sources of astronomical interest.

Hill, J. E.↗

PoET: Polarimeters for Energetic Transients

This presentation focuses on PoET (Polarimeters for Energetic Transients): a Small Explorer mission concept proposed to NASA in January 2008. The principal scientific goal of POET is to measure GRB polarization between 2 and 500 keV. The payload consists of two wide FoV instruments: a Low Energy Polarimeter (LEP) capable of polarization measurements in the energy range from 2-15 keV and a high energy polarimeter (Gamma-Ray Polarimeter Experiment - GRAPE) that will measure polarization in the 60-500 keV energy range. Spectra will be measured from 2 keV up to 1 MeV. The PoET spacecraft provides a zenith-pointed platform for maximizing the exposure to deep space. Spacecraft rotation will provide a means of effectively dealing with systematics in the polarization response. PoET will provide sufficient sensitivity and sky coverage to measure statistically significant polarization for up to 100 GRBs in a two-year mission. Polarization data will also be obtained for solar flares, pulsars and other sources of astronomical interest.

McConnell, Mark↗

The Area Coverage of Geophysical Fields as a Function of Sensor Field-of View

In many remote sensing studies of geophysical fields such as clouds, land cover, or sea ice characteristics, the fractional area coverage of the field in an image is estimated as the proportion of pixels that have the characteristic of interest (i.e., are part of the field) as determined by some thresholding operation. The effect of sensor field-of-view on this estimate is examined by modeling the unknown distribution of subpixel area fraction with the beta distribution, whose two parameters depend upon the true fractional area coverage, the pixel size, and the spatial structure of the geophysical field. Since it is often not possible to relate digital number, reflectance, or temperature to subpixel area fraction, the statistical models described are used to determine the effect of pixel size and thresholding operations on the estimate of area fraction for hypothetical geophysical fields. Examples are given for simulated cumuliform clouds and linear openings in sea ice, whose spatial structures are described by an exponential autocovariance function. It is shown that the rate and direction of change in total area fraction with changing pixel size depends on the true area fraction, the spatial structure, and the thresholding operation used.

Key, Jeffrey R.↗

Effect of Smoke on Cloud Formation during the Biomass Burning Season over the Amazon Basin

Aerosol absorption of sunlight reduces surface irradiation and heats the aerosol layer. The consequent changes in the temperature and humidity profiles can affect cloud formation extent and life time, which is called the semi-direct effect. We evaluate this aerosol semi-direct effect using data collected during the 2002 biomass burning season over the Amazon basin from the MODIS instrument on the Aqua satellite. MODIS measures the cloud coverage and the aerosol optical thickness among the clouds. We found that the radiative heating of the atmosphere and cooling of the surface due to the presence of the smoke decreases the cloud coverage. A very clear negative correlation emerges between the cloud fraction and the smoke optical depth. The results are compared to calculations using 1-D radiation model (M.D. Chou), and used to calculate this regional semi direct effect on climate forcing.

Koren, I.↗

Photogrammetry and photo interpretation applied to analyses of cloud cover, cloud type, and cloud motion

A determination was made of the areal extent of terrain obscured by clouds and cloud shadows on a portion of an Apollo 9 photograph at the instant of exposure. This photogrammetrically determined area was then compared to the cloud coverage reported by surface weather observers at approximately the same time and location, as a check on result quality. Stereograms prepared from Apollo 9 vertical photographs, illustrating various percentages of cloud coverage, are presented to help provide a quantitative appreciation of the degradation of terrain photography by clouds and their attendant shadows. A scheme, developed for the U.S. Navy, utilizing pattern recognition techniques for determining cloud motion from sequences of satellite photographs, is summarized. Clouds, turbulence, haze, and solar altitude, four elements of our natural environment which affect aerial photographic missions, are each discussed in terms of their effects on imagery obtained by aerial photography. Data of a type useful to aerial photographic mission planners, expressing photographic ground coverage in terms of flying height above terrain and camera focal length, for a standard aerial photograph format, are provided. Two oblique orbital photographs taken during the Apollo 9 flight are shown, and photo-interpretations, discussing the cloud types imaged and certain visible geographical features, are provided.

Larsen, P. A.↗

Properties of Linear Contrails Detected in 2012 Northern Hemisphere MODIS Imagery

Observation of linear contrail cirrus coverage and retrieval of their optical properties are valuable data for validating atmospheric climate models that represent contrail formation explicitly. These data can reduce our uncertainty of the regional effects of contrail-generated cirrus on global radiative forcing, and thus improve our estimation of the impact of commercial aviation on climate change. We use an automated contrail detection algorithm (CDA) to determine the coverage of linear persistent contrails over the Northern Hemisphere during 2012. The contrail detection algorithm is a modified form of the Mannstein et al. (1999) method, and uses several channels from thermal infrared MODIS data to reduce the occurrence of false positive detections. A set of contrail masks of varying sensitivity is produced to define the potential range of uncertainty in contrail coverage estimated by the CDA. Global aircraft emissions waypoint data provided by FAA allow comparison of detected contrails with commercial aircraft flight tracks. A pixel-level product based on the advected flight tracks defined by the waypoint data and U-V wind component profiles from the NASA GMAO GEOS-4 reanalysis has been developed to assign a confidence of contrail detection for the contrail mask. To account for possible contrail cirrus missed by the CDA, a post-processing method based on the assumption that pixels adjacent to detected linear contrails will have radiative signatures similar to those of the detected contrails is applied to the Northern Hemisphere data. Results from several months of MODIS observations during 2012 will be presented, representing a near-global climatology of contrail coverage. Linear contrail coverage will be compared with coverage estimates determined previously from 2006 MODIS data.

Duda, David P.↗

Coincident learning for beam-based rf station fault identification using phase information at the SLAC linac coherent light source

Anomalies in radio-frequency (rf) stations can result in unplanned downtime and performance degradation in linear accelerators such as SLAC’s Linac Coherent Light Source (LCLS). Detecting these anomalies is challenging due to the complexity of accelerator systems, high data volume, and scarcity of labeled fault data. Prior work identified faults using beam-based detection, combining rf amplitude and beam position monitor data. Due to the simplicity of the rf amplitude data, classical methods are sufficient to identify faults, but the recall is constrained by the low-frequency and asynchronous characteristics of the data. In this work, we leverage high-frequency, time-synchronous rf phase data to enhance anomaly detection in the LCLS accelerator. Due to the complexity of phase data, classical methods fail, and we instead train deep neural networks within the Coincident Anomaly Detection (CoAD) framework. We find that applying CoAD to phase data detects nearly 3 times as many anomalies as when applied to amplitude data, while achieving broader coverage across rf stations. Furthermore, the rich structure of phase data enables us to cluster anomalies into distinct physical categories. Through the integration of auxiliary system status bits, we link clusters to specific fault signatures, providing additional granularity for uncovering the root cause of faults. We also investigate interpretability via Shapley values, confirming that the learned models focus on the most informative regions of the data and providing insight for cases where the model makes mistakes. This work demonstrates that phase-based anomaly detection for rf stations improves both diagnostic coverage and root cause analysis in accelerator systems and that deep neural networks are essential for effective analysis.

Accelerator Physics (physics.acc-ph)↗

The role of ERTS in the establishment and of a nationwide land cover information system

The economic potential of utilizing an ERTS type satellite in the development, updating, and maintenance of a nation-wide land cover information system in the post-1977 time frame was examined. Several alternative acquisition systems were evaluated for land cover data acquisition, processing, and interpretation costs in order to determine, on a total life cycle cost basis, under which conditions of user demand (i.e., area of coverage, frequency of coverage, timeliness of information, and level of information detail) an ERTS type satellite would be cost effective, and what the annual cost savings benefits would be. It was concluded that a three satellite system with high and low altitude aircraft and ground survey team utilizing automatic interpretation and classification techniques is an economically sound proposal.

Abram, P.↗