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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 307 records · Page 17

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NASA NTRS2012

Fabrication of a Kilopixel Array of Superconducting Microcalorimeters with Microstripline Wiring

A document describes the fabrication of a two-dimensional microcalorimeter array that uses microstrip wiring and integrated heat sinking to enable use of high-performance pixel designs at kilopixel scales (32 X 32). Each pixel is the high-resolution design employed in small-array test devices, which consist of a Mo/Au TES (transition edge sensor) on a silicon nitride membrane and an electroplated Bi/Au absorber. The pixel pitch within the array is 300 microns, where absorbers 290 microns on a side are cantilevered over a silicon support grid with 100-micron-wide beams. The high-density wiring and heat sinking are both carried by the silicon beams to the edge of the array. All pixels are wired out to the array edge. ECR (electron cyclotron resonance) oxide underlayer is deposited underneath the sensor layer. The sensor (TES) layer consists of a superconducting underlayer and a normal metal top layer. If the sensor is deposited at high temperature, the ECR oxide can be vacuum annealed to improve film smoothness and etch characteristics. This process is designed to recover high-resolution, single-pixel x-ray microcalorimeter performance within arrays of arbitrarily large format. The critical current limiting parts of the circuit are designed to have simple interfaces that can be independently verified. The lead-to-TES interface is entirely determined in a single layer that has multiple points of interface to maximize critical current. The lead rails that overlap the TES sensor element contact both the superconducting underlayer and the TES normal metal

Chervenak, James↗

NASA NTRS1968

Improved limiter for turn-on current transient

Circuit limits the turn-on current transient to a specified amplitude and provides a low-impedance path between supply voltage and load after a prescribed time interval. The circuit offers a wide range of flexibility in adjusting peak current and automatic control of the initial peak current.

Hallberg, F. C.↗

NASA NTRS2019

TPSAS-NF1676L-32493-DND

The Committee on Earth Observation Satellites (CEOS) System Engineering Office (SEO) has supported the Open Data Cube (ODC) initiative to provide a data architecture solution that has value to its global users and increases the impact of EO satellite data. ODC is an open-source platform for processing satellite data. We have developed software products and tools around the core ODC that would help users perform machine learning on EO satellite data. The recent United Nations (UN) Sustainable Development Agenda provides a shared blueprint for peace and prosperity for people and for the planet, considering our current situation and helping to create a plan. The core of this agenda is a set of seventeen Sustainable Development Goals (SDGs), which represent an urgent call for action by all countries - both developed and developing - in a global partnership. The CEOS SEO team has recently developed and released a set of innovative Jupyter notebooks addressing UN SDGs 6.6.1 (spatial extents of water-related ecosystems), 11.3.1 (ratio of land consumption rate to population growth rate), and 15.3.1 (proportion of land that is degraded over total land area). These notebooks empower users by providing features that will assist with streamlining analysis ready data retrieval, processing, and visualization. We have recently incorporated several machine learning techniques in these notebooks. In this paper, we present the lessons learned from our experience on classifying land using supervised and unsupervised machine learning techniques using ODC framework for UN SDGs. We identify the current limitations of ODC to seamlessly support machine learning techniques. We propose features that would help machine learning, specifically within the ODC framework. We propose a thematic indexing/loading of data for both unsupervised learning as well as data annotation/labeling pipeline. Currently, ODC supports machine learning by separating data-management from the analysis process. It works as a mechanism to load cubes of data. ODC does not natively support features that are vital in machine learning such as validation splits, fair/balanced sampling, establishing load size constraints, etc. We believe that our proposed features will empower users by providing features that bring machine learning techniques closed to ODC. Enhancements to ODC to better accommodate machine learning techniques can assist in fulfilling UN SDGs such as 6.3.2, 6.4.2, 6.6.1, 11.3.1, 14.1.1, 15.1.1, 15.3.1, and 15.4.2.

Syed R Rizvi↗

NASA NTRS2007

High-Energy-Density, Low-Temperature Li/CFx Primary Cells

High-energy-density primary (nonrechargeable) electrochemical cells capable of relatively high discharge currents at temperatures as low as -40 C have been developed through modification of the chemistry of commercial Li/CFx cells and batteries. The commercial Li/CFx units are not suitable for high-current and low-temperature applications because they are current limited and their maximum discharge rates decrease with decreasing temperature. The term "Li/CFx" refers to an anode made of lithium and a cathode made of a fluorinated carbonaceous material (typically graphite). In commercial cells, x typically ranges from 1.05 to 1.1. This cell composition makes it possible to attain specific energies up to 800 Wh/kg, but in order to prevent cell polarization and the consequent large loss of cell capacity, it is typically necessary to keep discharge currents below C/50 (where C is numerically equal to the current that, flowing during a charge or discharge time of one hour, would integrate to the nominal charge or discharge capacity of a cell). This limitation has been attributed to the low electronic conductivity of CFx for x approx. 1. To some extent, the limitation might be overcome by making cathodes thinner, and some battery manufacturers have obtained promising results using thin cathode structures in spiral configurations. The present approach includes not only making cathodes relatively thin [.2 mils (.0.051 mm)] but also using sub-fluorinated CFx cathode materials (x < 1) in conjunction with electrolytes formulated for use at low temperatures. The reason for choosing sub-fluorinated CFx cathode materials is that their electronic conductivities are high, relative to those for which x > 1. It was known from recent prior research that cells containing sub-fluorinated CFx cathodes (x between 0.33 and 0.66) are capable of retaining substantial portions of their nominal low-current specific energies when discharged at rates as high as 5C at room temperature. However, until experimental cells were fabricated following the present approach and tested, it was not known whether or to what extent low-temperature performance would be improved.

Whitacre, Jay↗

DOE OSTI2021

Materials challenges and opportunities for quantum computing hardware

Combatting noise on the platform The potential of quantum computers to solve problems that are intractable for classical computers has driven advances in hardware fabrication. In practice, the main challenge in realizing quantum computers is that general, many-particle quantum states are highly sensitive to noise, which inevitably causes errors in quantum algorithms. Some noise sources are inherent to the current materials platforms. de Leon et al. review some of the materials challenges for five platforms for quantum computers and propose directions for their solution. Science , this issue p. eabb2823

Science & Technology - Other Topics↗

NASA NTRS1982

A 10-kW series resonant converter design, transistor characterization, and base-drive optimization

The development, components, and performance of a transistor-based 10 kW series resonant converter for use in resonant circuits in space applications is described. The transistors serve to switch on the converter current, which has a half-sinusoid waveform when the transistor is in saturation. The goal of the program was to handle an input-output voltage range of 230-270 Vdc, an output voltage range of 200-500 Vdc, and a current limit range of 0-20 A. Testing procedures for the D60T and D7ST transistors are outlined and base drive waveforms are presented. The total device dissipation was minimized and found to be independent of the regenerative feedback ratio at lower current levels. Dissipation was set at within 10% and rise times were found to be acceptable. The finished unit displayed a 91% efficiency at full power levels of 500 V and 20 A and 93.7% at 500 V and 10 A.

Robson, R. R.↗

NASA NTRS1991

Prediction techniques for jet-induced effects in hover on STOVL aircraft

Prediction techniques for jet induced lift effects during hover are available, relatively easy to use, and produce adequate results for preliminary design work. Although deficiencies of the current method were found, it is still currently the best way to estimate jet induced lift effects short of using computational fluid dynamics. Its use is summarized. The new summarized method, represents the first step toward the use of surface pressure data in an empirical method, as opposed to just balance data in the current method, for calculating jet induced effects. Although the new method is currently limited to flat plate configurations having two circular jets of equal thrust, it has the potential of more accurately predicting jet induced effects including a means for estimating the pitching moment in hover. As this method was developed from a very limited amount of data, broader applications of the method require the inclusion of new data on additional configurations. However, within this small data base, the new method does a better job in predicting jet induced effects in hover than the current method.

Wardwell, Douglas A.↗

DOE OSTI2023

Effect of water droplet growth dynamics on electrode current in fuel-cell catalyst layers

Fuel cells are a promising next-generation energy-conversion technology designed to replace internal combustion engines in transportation applications. However, much work remains to optimize them. Operation at high humidities causes liquid water droplet formation on Pt catalyst particles during oxygen reduction, potentially impeding reactant arrival to the reactive electrode. In this work, four different cases of water droplet growth in fuel-cell catalyst layers are considered: pinned or advancing droplets on a bare Pt surface, advancing droplets on a Nafion film, and water-layer growth in carbon nanopores. Transient drop growth is captured with a combination of mass, species mass, and momentum balances, and the subsequent limiting current is determined via oxygen diffusion and Tafel kinetics. Further, water droplets are found not to be mass-transfer limiting due to the relatively large liquid-gas area compared to the Pt nanoparticle. Mass-transfer-limited behavior is calculated in carbon nanopores.

25 ENERGY STORAGE↗

DOE OSTI2021

Phase evolution during reactive flash sintering of Li 6.25 Al 0.25 La 3 Zr 2 O 12 starting from a chemically prepared powder

Here, reactive flash sintering (RFS) of a chemically prepared multiphase precursor powder was performed to fabricate Li 6.25 Al 0.25 La 3 Zr 2 O 12 (Al-LLZO) ceramics. This approach allowed for obtaining single-phase dense samples in a remarkably short processing time of 30 s, at a furnace temperature of 600 °C, with an electric field of 50 V cm -1 and a current limit of 150 mA mm -2 . The ceramics display high bulk conductivity of 0.18 mS cm -1 at room temperature. Furthermore, phase evolution is studied by in-situ X-ray diffraction during: i) conventional heating and ii) RFS under current rate mode. As expected, the intermediate phases progressively dissolved into the Al-LLZO matrix by conventional heating. On the other hand, RFS promoted the growth of the intermediate La 2 Zr 2 O 7 , an effect that was overcome by the thermally driven formation of Al-LLZO at higher temperatures. The observed different reaction pathway suggests that RFS can be used for stabilizing phases that are not thermodynamically favored upon conventional heating.

36 MATERIALS SCIENCE↗

NASA NTRS1985

Potential of CCDs for UV and X-ray plasma diagnostics

A program is under way to develop charge-coupled device (CCD) sensors for space-based X-ray astronomy imaging spectrometers. To date, laboratory line-emission spectra have been acquired throughout the range of 277 to 8000 eV (carbon through copper K-alpha emission) and CCD sensitivity has been demonstrated throughout the range of 1.1 through 8000 eV. Image resolution is excellent, limited almost entirely by the 15 micron pixel size. These results are presented and specialized techniques are described which permit such low energy response, high spectral resolution, and efficient charge collection. Finally, analysis is presented of one particular CCD characteristic which currently limits UV and X-ray performance: charge diffusion.

Janesick, J. R.↗

NASA NTRS1990

Queueing models for token and slotted ring networks

Currently the end-to-end delay characteristics of very high speed local area networks are not well understood. The transmission speed of computer networks is increasing, and local area networks especially are finding increasing use in real time systems. Ring networks operation is generally well understood for both token rings and slotted rings. There is, however, a severe lack of queueing models for high layer operation. There are several factors which contribute to the processing delay of a packet, as opposed to the transmission delay, e.g., packet priority, its length, the user load, the processor load, the use of priority preemption, the use of preemption at packet reception, the number of processors, the number of protocol processing layers, the speed of each processor, and queue length limitations. Currently existing medium access queueing models are extended by adding modeling techniques which will handle exhaustive limited service both with and without priority traffic, and modeling capabilities are extended into the upper layers of the OSI model. Some of the model are parameterized solution methods, since it is shown that certain models do not exist as parameterized solutions, but rather as solution methods.

Peden, Jeffery H.↗

NASA NTRS2001

Atmospheric Constraints on Landing Site Selection

The Martian atmosphere is a significant part of the environment that the Mars Exploration Rovers (MER) will encounter. As such, it imposes important constraints on where the rovers can and cannot land. Unfortunately, as there are no meteorological instruments on the rovers, there is little atmospheric science that can be accomplished, and no scientific preference for landing sites. The atmosphere constrains landing site selection in two main areas, the entry descent and landing (EDL) process and the survivability of the rovers on the surface. EDL is influenced by the density profile and boundary layer winds (up to altitudes of 5 to 10 km). Surface survivability involves atmospheric dust, temperatures and winds. During EDL, the atmosphere is used to slow the lander down, both ballistically and on the parachute. This limits the maximum elevation of the landing site to -1.3 km below the MOLA reference aeroid. The landers need to encounter a sufficiently dense atmosphere to be able to stop, and the deeper the landing site, the more column integrated atmosphere the lander can pass through before reaching the surface. The current limit was determined both by a desire to be able to reach the hematite region and by a set of atmosphere models we developed for EDL simulations. These are based on Thermal Emission Spectrometer (TES) atmospheric profile measurements, Ames Mars General Circulation Model (MGCM) results, and the 1-D Ames GCM radiative/convective model by J. Murphy. The latter is used for the near surface diurnal cycle. The current version of our model encompasses representative latitude bands, but we intend to make specific models for the final candidate landing sites to insure that they fall within the general envelope. The second constraint imposed on potential landing sites through the EDL process is the near surface wind. The wind in the lower approximately 5 km determines the horizontal velocity that the landers have when they land. Due to the mechanics of the landing process, the total velocity (including both the horizontal and vertical components) determines whether or not the landers are successful. Unfortunately, the landing system has no easy way to nullify any horizontal velocity imparted by the wind, so the landing sites selected need to have as little wind as possible. In addition to the mean wind velocity, the landing system is sensitive to vertical wind shear in the lowest kilometer or so. Wind shear can deflect the retro rockets (RADs) from their nominal vertical orientation producing unwanted horizontal spacecraft velocities. Both mean velocity and wind shear are dominated by the the local topography and other surface properties (in particular albedo and thermal inertia which control the surface temperature). This is seen even in simplified 2-D mesoscale models. The effects in a fully 3-D model are expected to he even more topographically dependent. In particular there is potential for wind channeling in canyons and other terrain features. Boundary layer winds and wind shear are currently being modeled based on terrestrial data and boundary layer scaling laws modified for Martian conditions. We hope to supplement this with mesoscale model results (from several sources) once the number of landing sites is reduced to a manageable number.

Kass, David M.↗

DOE OSTI2022

Failure Modes of Platinized pn+-GaInP Photocathodes for Solar-Driven H2 Evolution

The long-term stability for the hydrogen-evolution reaction (HER) of homojunction pn+-Ga0.52In0.48P photocathodes (band gap = 1.8 eV) with an electrodeposited Pt catalyst (pn+-GaInP/Pt) has been systematically evaluated in both acidic and alkaline electrolytes. Electrode dissolution during chronoamperometry was correlated with changes over time in the current density-potential (J-E) behavior to reveal the underlying failure mechanism. Pristine pn+-GaInP/Pt photocathodes yielded an open-circuit photopotential (Eoc) as positive as >1.0 V vs the potential of the reversible hydrogen electrode (RHE) and a light-limited current density (Jph) of >12 mA cm-2 (1-sun illumination). However, Eoc and Jph gradually degraded at either pH 0 or pH 14. The performance degradation was attributed to three different failure modes: (1) gradual thinning of the n+-emitter layer due to GaInP dissolution in acid; (2) active corrosion of the underlying GaAs substrate at positive potentials causing delamination of the upper GaInP epilayers; and (3) direct GaAs/electrolyte contact compromising the operational stability of the device. This work reveals the importance of both substrate stability and structural integrity of integrated photoelectrodes toward stable solar fuel generation.

CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS,S↗

NASA NTRS2016

A Comprehensive Radial Velocity Error Budget for Next Generation Doppler Spectrometers

We describe a detailed radial velocity error budget for the NASA-NSF Extreme Precision Doppler Spectrometer instrument concept NEID (NN-explore Exoplanet Investigations with Doppler spectroscopy). Such an instrument performance budget is a necessity for both identifying the variety of noise sources currently limiting Doppler measurements, and estimating the achievable performance of next generation exoplanet hunting Doppler spectrometers. For these instruments, no single source of instrumental error is expected to set the overall measurement floor. Rather, the overall instrumental measurement precision is set by the contribution of many individual error sources. We use a combination of numerical simulations, educated estimates based on published materials, extrapolations of physical models, results from laboratory measurements of spectroscopic subsystems, and informed upper limits for a variety of error sources to identify likely sources of systematic error and construct our global instrument performance error budget. While natively focused on the performance of the NEID instrument, this modular performance budget is immediately adaptable to a number of current and future instruments. Such an approach is an important step in charting a path towards improving Doppler measurement precisions to the levels necessary for discovering Earth-like planets.

NASA-NSF Extreme Precision Doppler Spectrometer in↗

NASA NTRS1986

Macroscopic T nonconservation - Prospects for a new experiment

Breakdown of time-reversal invariance can be detected in macroscopic samples as a magnetic alignment along an electric field. It is shown that both fundamental and practical limits to the detection of this effect in paramagnets correspond to measurement of electron electric dipole moments down to d(e) of about 10 to the -28th e cm on 50-g quantities of EuS near its Curie point; this compares to the current limit of d(e) not greater than 10 to the -24th e cm. Strategies for still greater sensitivity are outlined.

Bialek, W.↗

NASA NTRS1989

Isothermal life prediction of composite lamina using a damage mechanics approach

A method for predicting isothermal plastic fatigue life of a composite lamina is presented in which both fibers and matrix are isotropic materials. In general, the fatigue resistances of the matrix, fibers, and interfacial material must be known in order to predict composite fatigue life. Composite fatigue life is predicted using only the matrix fatigue resistance due to inelasticity micromechanisms. The effect of the fiber orientation on loading direction is accounted for while predicting composite life. The application is currently limited to isothermal cases where the internal thermal stresses that might arise from thermal strain mismatch between fibers and matrix are negligible. The theory is formulated to predict the fatigue life of a composite lamina under either load or strain control. It is applied currently to predict the life of tungsten-copper composite lamina at 260 C under tension-tension load control. The calculated life of the lamina is in good agreement with available composite low cycle fatigue data.

Abuelfoutouh, Nader M.↗

NASA NTRS1989

Isothermal life prediction of composite lamina using a damage mechanics approach

Abuelfoutouh, Nader Mohamed↗

NASA NTRS2015

Transitioning Earth Remote Sensing Data to Benefit Society: A Paradigm for a Center of Excellence

Over the past decade there has been a substantial increase in the number of Earth remote sensing satellites launched for research and operational usage and numerous others planned by the international community. These satellites have been used to varying degrees by their supporting agencies for weather and environmental monitoring, climate studies, disaster monitoring and response, and other humanitarian activities. While there are success stories on useful applications of remote sensing data, the broader use of these satellite assets by other organizations and entities has been limited for a number of reasons including lack of data services, data dissemination issues, and a general failure to engage the broader end user community with useful data access and knowledge of how to use the data and products. This paper describes some of these current limitations on the broader use of Earth remote sensing data by the international community and describes the concept of a general "Center of Excellence" to facilitate the development, transition, and utilization of these Earth remote sensing observations by the broader international community.

Transition to operations↗