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At least 307 records · Page 17

Delta wing surface pressures for high angle of attack maneuvers

A wind tunnel experiment was performed on a delta wing with a leading edge sweep of 70 deg. Unsteady pressures were measured on the suction surface of the wing as it was oscillated from 0-30 deg, and 2-60 deg angle-of-attack. Pressure coefficients were measured at different surface locations for two pitch rates. Static pressure measurements were also obtained for comparison with the dynamic results. The Reynolds number was fixed at 420,000, based on the centerline chord length. Pressure measurements were made from 35-90 percent of the chord, along a ray from the apex at 60 percent of the local semispan. Spanwise measurements were also made at a constant chord location, x/c = 75 percent from the apex. The unsteady pressure data over the 0-30 deg angle-of-attack range showed pressures fluctuating in phase with model motion, and little overshoot from the static values. The pressures for the large amplitude motion showed large overshoots from the static values. In addition, during the high angle-of-attack portion of the motion, the upstroke (angle of attack increasing) pressure coefficients were typically much lower than the downstroke values. For the lower pitch rate, there was little difference between upstroke and downstroke pressures at the low angles of attack.

Thompson, S. A.↗

Absorption in X-ray spectra of high-redshift quasars

We present evidence that X-ray absorption is common in high-redshift quasars. We have studied six high-redshift (z approximately 3) quasars with the ROSAT Position Sensitive Proportional Counter (PSPC) of which four are in directions of low Galactic N(sub H). Three out of these four show excess absorption, while only three in approximately 50 z approximately less than 0.4 quasars do, indicating that such absorption must be common, but not ubiquitous, at high redshifts, and that the absorbers must lie at z greater than 0.4. The six quasars were: S5 0014+81, Q0420-388, PKS 0438-436, S4 0636+680. PKS 2000-330, PKS 2126-158, which have redshifts between 2.85 and 3.78. PKS 0438-436 and PKS 2126-158 show evidence for absorption above the local Galactic value at better than 99.999% confidence level. If the absorber is at the redshift of the quasar, then values of N(sub H) = (0.86(+0.49, -0.28)) x 10(exp 22) atoms/sq cm for PKS 0438-436, and N(sub H) = (1.45(+1.20, -0.64)) x 10(exp 22) atoms/ sq cm for PKS 2126-158, are implied, assuming solar abundances. The spectrum of S4 0636+680 also suggests the presence of a similarly large absorption column density at the 98% confidence level. This absorption reverses the trend for the most luminous active galactic nuclei (AGN) to have the least X-ray absorption, so a new mechanism is likely to be responsible. Intervening absorption due to damped Lyman(alpha) systems is a plausible cause. We also suggest, as an intrinsic model, that intracluster material, e.g., a cooling flow, around the quasar could account for both the X-ray spectrum and other properties of these quasars. All the quasars are radio-loud and three are gigahertz peaked (two of the three showing absorption). No excess absorption above the Galactic value is seen toward Q0420-388. This quasar has two damped Lyman(alpha) systems at z = 3.08. The limit on the X-ray column density implies a low ionization fraction, N(H I)/N(H) approximately greater than 4 x 10(exp -3) (3 (sigma)), for solar abundances, for these systems, and can set a weak limit on the size of the absorber. In the emitted frame these PSPC spectra cover the band approximately 0.5-10 keV, which has been well observed for low-redshift quasars and AGN. Comparison of high and low-redshift spectra in this emitted band shows no change of mean spectral index greater than Delta alpha(sub E) greater than 0.3 (99% confidence) with either redshift or luminosity, for radio-loud quasars.

Elvis, Martin↗

Vestibulosympathetic reflex during orthostatic challenge in aging humans

Aging attenuates the increase in muscle sympathetic nerve activity (MSNA) and elicits hypotension during otolith organ engagement in humans. The purpose of the present study was to determine the neural and cardiovascular responses to otolithic engagement during orthostatic stress in older adults. We hypothesized that age-related impairments in the vestibulosympathetic reflex would persist during orthostatic challenge in older subjects and might compromise arterial blood pressure regulation. MSNA, arterial blood pressure, and heart rate responses to head-down rotation (HDR) performed with and without lower body negative pressure (LBNP) in prone subjects were measured. Ten young (27 +/- 1 yr) and 11 older subjects (64 +/- 1 yr) were studied prospectively. HDR performed alone elicited an attenuated increase in MSNA in older subjects (Delta106 +/- 28 vs. Delta20 +/- 7% for young and older subjects). HDR performed during simultaneous orthostatic stress increased total MSNA further in young (Delta53 +/- 15%; P < 0.05) but not older subjects (Delta-5 +/- 4%). Older subjects demonstrated consistent significant hypotension during HDR performed both alone (Delta-6 +/- 2 mmHg) and during LBNP (Delta-7 +/- 2 mmHg). These data provide experimental support for the concept that age-related impairments in the vestibulosympathetic reflex persist during orthostatic challenge in older adults. Furthermore, these findings are consistent with the concept that age-related alterations in vestibular function might contribute to altered orthostatic blood pressure regulation with age in humans.

Clinical Trial↗

Tracking and Data Relay Satellite (TDRS-3) Range Biases and Momentum Unload Modeling for Terra (EOS-AMI)

The Flight Dynamics Facility (FDF) reports its performance in meeting Tracking and Data Relay Satellite (TDRS) predicted ephemeris accuracy requirements with TDRS-3. The Terra (Earth Observing System AM-1) satellite has 3-sigma TDRS requirements of 75 m for total position accuracy predicted over one day onboard. The study sample includes selected cases over 21 months after Guam Remote Ground Terminal (GRGT) support started in June 1998. For daily solutions with a 1.5-day prediction span, predicted results of the study were below the Terra requirement by at least 12 m. Refined range bias estimation and modeled momentum unloads are needed to meet Terra's requirements for TDRS-3. Maintained at 275 W longitude over the zone of exclusion, TDRS-3 is analyzed separately from other TDRSs because of its unique tracking data. Only the Bilateration Ranging Transponder (BRT) at Alice Springs (ALS), Australia, and the Telemetry, Tracking and Command (TT&C) system at Guam are used for routine operational tracking data for TDRS-3. Simultaneous batch orbit solutions with three TDRSs and either the Compton Gamma Ray Observatory (GRO) or Terra were done with the Goddard Trajectory Determination System (GTDS) to periodically refine the TT&C and BRT System (BRTS) range biases. As new biases were determined, significant changes were made in estimating the absolute position. FDF achieved similar results using a sequential filter with all operational TDRSs and four user satellites. Definitive accuracy (3-sigma) is expected to be below 50 m. The White Sands Complex (WSC) performs momentum unloads to maintain three-axis stabilized attitude of TDRSs. The relationship between velocity changes (delta-V) and reaction wheel speed changes was empirically determined for roll/yaw unloads. A theoretical relationship was verified and used for pitch unloads. Modeling both pitch and roll/yaw momentum unloads is necessary to meet the 75-m requirement. Moving the orbit solution epoch an hour before a momentum unload can improve delta-V optimization and prediction accuracy over 1.5 days.

Ward, Douglas T.↗

Noncosmological signal contributions to the COBE DMR anisotropy maps

We examine the COBE Differential Microwave Radiometer (DMR) data for evidence of noncosmological source contributions. The DMR maps are cross-correlated with maps of rich clusters, extragalactic IRAS sources, HEAO 1 A-2 X-ray emission, and 5 GHz radio sources. We limit the rms contributions from these sources on a 7 deg angular scale to less than 10 micro-K (95 percent confidence level) in the DMR maps, although the LMC probably contributes about 50 micro-K to a limited region of the sky. Thus, our previous interpretation that the fluctuations in the COBE DMR data are most likely due to cosmic fluctuations at the surface of last scattering remains intact. The Comptonization parameter for hot electrons traced by rich clusters is limited to delta(y) less than 2 x 10 exp -6 (95 percent confidence level) averaged over the 7 deg DMR beam.

Bennett, C. L.↗

Analysis of Broad-Lined Type Ic Supernovae From the (Intermediate) Palomar Transient Factory

We study 34 Type Ic supernovae that have broad spectral features (SNe Ic-BL). This is the only SN type found in association with long duration gamma-ray bursts (GRBs).We obtained our photometric data with the Palomar Transient Factory (PTF) and its continuation, the intermediate PTF (iPTF). This is the first large, homogeneous sample of SNe Ic-BL from an untargeted survey. Furthermore, given the high observational cadence of iPTF, most of these SNe Ic-BL were discovered soon after explosion. We present K-corrected Bgriz light curves of these SNe, obtained through photometry on template-subtracted images. We analyzed the shape of the r-band light curves, finding a correlation between the decline parameter delta m15 and the rise parameter delta m-10. We studied the SN colors and, based on g - r, we estimated the host-galaxy extinction for each event. Peak r-band absolute magnitudes have an average of -18:6 +- 0:5 mag. We fit each r-band light curve with that of SN 1998bw (scaled and stretched) to derive the explosion epochs. We computed the bolometric light curves using bolometric corrections, r-band data, and g - r colors. Expansion velocities from Fe ii were obtained by fitting spectral templates of SNe Ic. Bolometric light curves and velocities at peak were fitted using the semianalytic Arnett model to estimate ejecta mass Mej, explosion energy EK and 56Ni mass M(56Ni) for each SN. We find average values of Mej = 4 +- 3 M sun, EK = (7 +- 6) x 1051 erg, and M(56Ni) = 0:31 +- 0:16 M . The parameter distributions were compared to those presented in the literature and are overall in agreement with them. We also estimated the degree of 56Ni mixing using scaling relations derived from hydrodynamical models and we find that all the SNe are strongly mixed. The derived explosion parameters imply that at least 21% of the progenitors of SNe Ic-BL are compatible with massive (>28 M ), possibly single stars, whereas at least 64% might come from less massive stars in close binary systems.

Supernovae↗

Development of the NASA/FLAGRO computer program

A preliminary version of a new computer program has been developed for calculating crack propagation in cyclically loaded structures. The new program, titled NASA/FLAGRO, has numerous enhanced features over previous programs used for safe life analysis on space systems. The essential features of the new program consist of modular design, promptive input using a cathode ray tube terminal, improved crack growth rate analytical methods, many new crack case solutions, and incorporation of user-defined files for material properties and fatigue spectrums. Also, five options made available in the program are to compute: (1) safe life of a part with a preexisting crack; (2) critical crack size for a specified stress level; (3) stress-intensity factor numerical values for making comparisons or checks of solutions; (4) least-squares fit of growth rate equations to crack growth rate data; and (5) the conversion of a versus N data to Delta K versus da/dN.

Forman, Royce G.↗

The Ultra High Resolution XUV Spectroheliograph. III - A modified configuration for a free flying platform

The Ultra-High Resolution XUV Spectroheliograph (UHRXS) is a comprehensive solar observatory capable of studying solar phenomena at soft X-ray, XUV, EUV, and VUV wavelengths with normal incidence imaging multilayer telescopes capable of very high angular resolution (about 0.1 arcsec), and spectrographs able to achieve high spectral resolution. This instrument has been selected by NASA for flight as an attached payload on the Space Station Freedom. Recent developments have made it clear that accommodations for attached payloads on Freedom will not become available during the initial operations of Freedom and may never be available. We have studied the changes that must be made to place the UHRXS instrument on a Free Flying Plafform such as the Delta Launched Explorer Bus. We report on the configuration, performance, and accommodation on a free flying platform of the revised UHRXS concept.

Walker, Arthur B. C., Jr.↗

Observation of radiation induced changes in stress and electrical properties in MOS devices

Strain measurements using X-ray diffraction were performed on irradiated commercial and radiation-hardened metal gate CMOS devices in addition to polysilicon gate NMOS devices. I-V curves were taken and V(ot) and V(it) were separated using the subthreshold slope method for all devices. A correlation has been shown to exist between physical strain relaxation and the electrical properties as a function of radiation dose and recovery. Data shown suggest that the physical response (strain relaxation) in the silicon at the oxide interface is a measure of the type of damage induced and the recovery mechanism. Postradiation measurements of Delta V(it) and Delta V(ot) taken immediately after irradiation support the conclusions of V. Zekeriya and T.-P. Ma (1983) and K. Kasama et al. (1986, 1987); compressive stress at the silicon/SiO2 interface does reduce radiation damage in the device.

Shaw, D. C.↗

Delta WIND Mission Science Briefing

The science objectives of the WIND mission are to: 1) provide complete plasma, energetic particle, and magnetic field input for magnetospheric and ionospheric studies; 2) Determine the magnetospheric output to interplanetary space in the up-stream region; 3) Investigate basic plasma processes occurring in the near-Earth solar wind; and 4) Provide baseline ecliptic plane observations to be used in heliospheric latitudes from ULYSSES. The WIND science briefing is presented by George Diller, NASA public affairs; Dr. Robert L. Carovillano, Project Scientist for the Global Geospace Science Initiative, NASA Headquarters; Dr. Mario H. Acuna, Project Scientist for the WIND Project, Goddard Space Flight Center (GSFC); Dr. Keith W. Ogilvie, Principle Investigator, Solar Wind Experiment at GSFC; Dr. Jean Louis Bougeret, Principle Investigator, Radio/Plasma Wave Experiment, Paris; and Dr. Eugeny Mazets, Co-Principle Investigator, Russian Gamma Ray Spectrometer Instrument, St. Pertersburg, Russia. Dr. Carovillano presents a cartoon slide of the Solar Terrestrial System and describes the Sun and the Magnetic field of the Earth. Dr. Acuna also presents a cartoon slide describing GEOTAIL, POLAR, WIND, SOHO, ULYSSES and Cluster which are the various tools used to study the complex solar terrestrial system. Dr. Ogilvie explains four particle and wave instruments on WIND. These instruments will be used to study the contributions and characteristics of plasma and plasma waves that occur in the solar wind. Dr. Bougeret explains the European participation in the WIND mission. He also shows a slide presentation of SOHO and the CLUSTER spacecraft. Dr. Mazets explains the main objective of the Transient Gamma Ray Spectrometer (TGRS) aboard the WIND spacecraft, which is to perform high resolution measurements of Gamma Ray Burst spectra and time histories, with emphasis on the search for line features in the energy spectra. The briefing ends with a question and answer period. See NONP-NASA-VT-2000078325 for additional question and answer footage.

Source record↗

Ares V Launch Capability Enables Future Space Telescopes

NASA's Ares V cargo launch vehicle offers the potential to completely change the paradigm of future space science mission architectures. A major finding of the NASA Advanced Telescope and Observatory Capability Roadmap Study was that current launch vehicle mass and volume constraints severely limit future space science missions. And thus, that significant technology development is required to package increasingly larger collecting apertures into existing launch shrouds. The Ares V greatly relaxes these constraints. For example, while a Delta IV has the ability to launch approximate a 4.5 meter diameter payload with a mass of 13,000 kg to L2, the Ares V is projected to have the ability to launch an 8 to 12 meter diameter payload with a mass of 60,000 kg to L2 and 130,000 kg to Low Earth Orbit. This paper summarizes the Ares V payload launch capability and introduces how it might enable new classes of future space telescopes such as 6 to 8 meter class monolithic primary mirror observatories, 15 meter class segmented telescopes, 6 to 8 meter class x-ray telescopes or high-energy particle calorimeters.

Stahl, H. Philip↗

An Unusual Rotationally Modulated Attenuation Band in the Jovian Hectometric Radio Emission Spectrum

A well-defined attenuation band modulated by the rotation of Jupiter has been found in the spectrum of Jovian hectometric radiation using data from the Galileo plasma wave instrument. The center frequency of this band usually occurs in the frequency range from about 1 to 3 MHz and the bandwidth is about 10 to 20 percent. The center frequency varies systematically with the rotation of Jupiter and has two peaks per rotation, the first at a system III longitude of about 50 deg, and the second at about 185 deg. It is now believed that the attenuation occurs as the ray path from a high-latitude cyclotron maser source passes approximately parallel to the magnetic field near the northern or southern edges of the Io L-shell. The peak at 50 deg system 3 longitude is attributed to radiation from a southern hemisphere source and the peak at 185 deg is from a northern hemisphere source. The attenuation is thought to be caused by coherent scattering or shallow angle reflection from field-aligned density irregularities near the Io L-shell. The narrow bandwidth indicates that the density irregularities are confined to a very narrow range of L values (Delta L = 0.2 to 0.4) near the Io L-shell.

Gurnett, D. A.↗

Coordinated Analysis of Organic Matter in Primitive Meteorites

Carbonaceous chondrites (CC) preserve a diverse range of organic matter formed within cold interstellar environments, the solar nebula, and during subsequent parent body asteroidal processing. This organic matter maintains a unique geochemical and istopic record of organic evolution [1-4]. Bulk studies of organics within CC have revealed a complex array of organic species. However, bulk studies invariably involve solvent extraction, resulting in a loss of spatial context of the host mineral matrix [3, 5]. Correlated in situ chemical and isotopic studies suggest preservation of interstellar organics in the form of spherical, often hollow, micrometer sized organic nano-globules. Nanoglobules often exhibit significant delta 15N and delta D enrichments that imply formation through fractionation of ion-molecule reactions within cold molecular clouds and/or the outer protoplanetary disk [5]. In situ studies such as 6-8 are necessary to understand the organic evolutionary stages of nanoglobules and other components in the nebula and parent body [7]. We carried out coordinated in situ micrometer-scale chemical, mineralogical and isotopic studies of the Murchison (CM2), QUE 99177 (CR3), and Tagish Lake (C2 Ung) CC. These studies were performed using fluorescent microscopy, two-step laser mass spectrometry (microL2MS), NanoSIMS, and Scanning Electron Microscopy (SEM) with Energy Dispersive X-Ray Spectroscopy (EDX). Comparative analysis of three different meteorites will help reveal the effects of parent body processes on the chemistry and isotopic composition of organic matter.

meteorites↗

Aerocapture Trajectory Design for Uranus Orbiter

Introduction: The recently released National Academies Planetary Science and Astrobiology Decadal Survey 2023-2032 [1] identified the Ice Giants as the top priority science destination. While the survey acknowledged the potential for either a Uranus Orbiter and Probe (UOP) mission or a Neptune-Triton Odyssey mission, it ultimately identified the former as the highest priority new flagship mission. UOP missions calls for a launch window of opportunity between 2031-2038 with 12-15 year interplanetary cruise time along with a fully-propulsive Uranus Orbit Insertion burn on the order of a few km/s. However, a mission to Uranus with the same science payload could utilize aerocapture for orbit insertion to achieve both a significant reduction in the interplanetary cruise time and reduction in propulsive burn costs. Why Aerocapture: Aerocapture is a promising propellant and time-saving orbital insertion technique for planetary destinations with an atmosphere. Although not flight-proven, previous aerocapture systems studies in the literature have demonstrated both the validity and robustness of the technique at various planetary destinations. With respect to the Ice Giant planets, Neptune has seen more of the analysis in the literature. For science missions at Neptune, aerocapture can enable 1.4 times more delivered mass to orbit than an all-propulsive mission for the same launch vehicle while reducing interplanetary cruise times by more than 3 years [2] Additionally with modern guidance and control, Neptune aerocapture with blunt-body aeroshells is realizable [3][4]. There are limited papers in the literature investigating Uranus aerocapture with those available providing a preliminary feasibility assessment [5]. Consequently, the two-year funded NASA Space Technology Mission Directorate (STMD)-funded project, titled Aerocapture System as an Enabling Technology for Ice Giants Missions, aims to mature the analysis and technology state of Uranus aerocapture. Trajectory Design: This paper presents the current state of the trajectory design in support of the new aerocapture project. The project design philosophy is inspired from recent Neptune aerocapture studies, which employed modern guidance and control, in the sense that blunt-body aeroshells are analyzed. An assessment of the theoretical flight path angle corridor width is conducted for a range of ballistic coefficients and lift-to-drag ratios for both Space Launch System and Falcon Heavy Launch Vehicle interplanetary trajectory solutions. The results from the corridor width assessment provide an assessment of the aerocapture design-space and qualitative metrics on trajectory design considerations. The Program to Optimize Simulated Trajectories II (POST2) is utilized to run Monte Carlo simulations of Uranus aerocapture three-degree-of-freedom bank angle modulated trajectories using a closed-loop numerical-predictor corrector guidance algorithm. UranusGRAM 2021 is utilized as the atmospheric model [6]. A Uranus-developed aerodatabase, originally derived from Mars Science Laboratory (MSL), is utilized to provide vehicle aerodynamics over a wide range of hypersonic flow regimes. A MSL-derived 70 deg 4.5m diameter sphere-cone aeroshell that houses the UOP payload mass is assumed. Robustness testing and performance analysis is conducted, including the assessment of entry state errors, atmosphere density variations, and aerodynamic dispersions. Post-aerocapture Delta-V and aerothermal statistics are formulated into propellant mass and TPS requirements. The results presented in the paper will demonstrate the trajectory viability of Uranus aerocapture. Preliminary Results: Preliminary trajectory design results indicates successful Uranus aerocapture with a blunt-body aeroshell housing the same payload mass as the UOP mission from an Earth-to-Uranus interplanetary trajectory arriving in less than 7 years. From this interplanetary trajectory, aerocapture provides an orbit insertion Delta-V capability of 6.9 km/s requiring less than 300 m/s for post-aerocapture correction burns (15% of wet mass allocated to propellant). To put this into perspective, the UOP study utilized an Earth-to-Uranus trajectory that arrives in 13 years and requires more than 1000 m/s for fully-propulsive orbit insertion (40% of wet mass allocated to propellant). Achieving the same 6.9 km/s Delta-V capability fully-propulsively is mass prohibitive (97% of wet mass allocated to propellant). Nevertheless, aerocapture has the potential to reduce interplanetary transit times to Uranus by half while delivering the same payload mass to orbit in a reduced propellant mass footprint.

Rohan Deshmukh↗

A Hadronic Synchrotron Mirror Model for the "Orphan" Tev Flare in 1ES 1959+650

Very high energy gamma-ray flares of TeV blazars are generally accompanied by simultaneous flaring activity in X-rays. The recent observations by the Whipple collaboration of an "orphan" TeV flare of 1 ES 1959+650 (without a simultaneous X-ray flare) are very difficult to reconcile with the standard leptonic synchrotron self-Compton model, which is routinely very successfully employed to explain the spectral energy distribution and spectral variability of TeV blazars. In this paper an alternative scenario is suggested in which the orphan TeV flare may originate from relativistic protons, interacting with an external photon field supplied by electron synchrotron radiation reflected off a dilute reflector. While the external photons will be virtually "invisible" to the comoving ultrarelativistic electrons in the jet because of Klein-Nishina effects, their Doppler-boosted energy is high enough to excite a Delta-resonance from relativistic protons with Lorentz factors of gamma(sub p) approx. 10(exp 3)-10(exp 4). This model is capable of explaining the orphan TeV flare of 1ES 1959+650 with plausible parameters, thus constraining the number and characteristic energy of relativistic protons in the jet of this blazar.

Bottcher, Markus↗

Neutrino Emission in the Hadronic Synchrotron Mirror Model: The "Orphan" Flare from 1ES 1959+650

A challenge to standard leptonic synchrotron self-Compton (SSC) models is the so-called orphan TeV flares, i.e., enhanced very high energy (VHE) gamma-ray emission without any contemporaneous X-ray flaring activity, that have recently been observed in TeV blazars (e.g., 1ES 1959+650). In order to explain the orphan TeV flare of 1 ES 1959+650 observed in 2002 June, the so-called hadronic synchrotron mirror model has been developed. Here relativistic protons are proposed to exist in the jet and interact with reflected electron synchrotron radiation of the precursor SSC flare. If the reflector is located in the cloud region, time shifts of several days are possible between the precursor and the orphan flare. The external photons, blue-shifted in the comoving jet frame, are able to excite the Delta(1232) resonance when interacting with protons of Lorentz factors gamma(sub p) approx. 10(exp 3)-10(exp 4). The decay products of this resonance include charged pions, which, on decay, give rise to neutrino production during the orphan flare. In this paper we calculate the expected neutrino emission for the 2002 June 4 orphan TeV flare of 1ES 1959+650. We compare our results with the recent observations of AMANDA-II of a neutrino event in spatial and temporal coincidence with the orphan flare of this blazar. We find that the expected neutrino signal from the hadronic synchrotron mirror model is insufficient to explain the claimed neutrino signal from the direction of 1ES 1959+650.

Reimer, A.↗

Cosmic ray isotope resolution obtained using a new Cerenkov-total energy telescope

The details of a recent measurement of the cosmic ray isotopic composition of Z equals or exceeds 10 nuclei are given, using a new technique combining a Cerenkov and total energy counter. In terms of sigma, the characteristic width of a Gaussian distribution of mass measurement, values of mass resolution have been obtained ranging from about 0.4 AMU at a Z about 14, to about 0.8 AMU at a Z about 26, using the Cerenkov-total energy (C x E) technique. It is customary to claim that two equal Gaussian distributions may be resolved for values of sigma less than 0.4 x the separation of their means. With these criteria isotopes separated by delta A = 2 are being resolved up to a Z about 26 using the C x E technique. An important source of error in these measurements is the determination of the mass of each of the isotopes on an absolute scale.

Webber, W. R.↗

Thermodynamics of the potassium-sulfur-oxygen and related systems

The chemical reactions which occur when potassium sulfide, K2S, and potassium sulfite, K2SO3, are heated at temperatures where their vapor pressures are significant, were studied and the vapor pressures and the partial pressures of the chemical products were measured. Mass spectrometry of the vapor of potassium sulfide revealed only K(g). X-ray studies of the solid residues from vaporization experiments revealed K2S2(s) and chemical analyses of the same solid residues showed that the residues approached a composition K2Sx with x in the range 3-4. Vapor pressure of K2S was measured by simultaneous Knudsen-effusion and torsion-effusion (SKETE) in crucibles of aluminum oxide and of graphite. In each such experiment, the vapor pressures agreed initially, but then the apparent pressure by Knudsen-effusion increased suddenly and remained much greater than that by torsion-effusion for the remainder of the experiment. Results of third-law analysis of the torsion pressures imply a delta H (298K) of formation of K2S(s) of -364 + or - 12 kJ/mol. Vapor pressures over K2SO3(s) were measured by simultaneous Knudsen and torsion-effusion and by mass spectrometry. The vapor pressures of both K2S2O5(s) and K2SO3(s) were nonreproducible at a given temperature due to the vaporization reactions of the materials being irreversible under conditions in effusion cells.

Edwards, J. G.↗