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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 307 records · Page 17
All sourcesNASA NTRSDOE OSTI
NASA NTRS1973

The electric field in the vicinity of a photo-emitting plate in a plasma

Knowledge of the electric field in the vicinity of a spacecraft provides necessary corrections to measurements of ambient fields and charged particle fluxes and a required parameter to understand the motion of dust particles and grains around the spacecraft. The complex problem of the entire electric field, needed for grain transport calculations, is treated for the one-dimensional case. By approximations to the analysis of a photo-emitting plate immersed in a dilute plasma, explicit expressions for the potential and the electric field were derived. The two classes of implicit solutions for the potential reported by them are shown to yield essentially identical results for the conditions in our solar system. The values were obtained following assumptions of a later paper by Guernsey and Fu, in which the emitted photoelectron distribution is taken as Maxwellian. These results are compared with a simple model due to Grand and Tunaley, wherein the effect of the dilute plasma is neglected entirely.

Barengoltz, J.↗
NASA NTRS1974

Non-Newtonian effects on flow-generated cavitation and on cavitation in a pressure field

Observations are presented which show that the stresses in a flow field of very dilute polymer are not well enough described by the Navier-Stokes equations to accurately predict cavitation. The contitutive equation for the particular polymer and concentration used is needed. The second-order fluid form in which accelerations are relatively important appears capable of explaining observed cavitation suppression by changing the pressure field due to flow. Bubble dynamics in stationary dilute polymer solutions are also examined and found to be little different from those in water.

Ellis, A. T.↗
NASA NTRS1976

Two techniques for eliminating luminol interference material and flow system configurations for luminol and firefly luciferase systems

Two methods for eliminating luminol interference materials are described. One method eliminates interference from organic material by pre-reacting a sample with dilute hydrogen peroxide. The reaction rate resolution method for eliminating inorganic forms of interference is also described. The combination of the two methods makes the luminol system more specific for bacteria. Flow system designs for both the firefly luciferase and luminol bacteria detection systems are described. The firefly luciferase flow system incorporating nitric acid extraction and optimal dilutions has a functional sensitivity of 3 x 100,000 E. coli/ml. The luminol flow system incorporates the hydrogen peroxide pretreatment and the reaction rate resolution techniques for eliminating interference. The functional sensitivity of the luminol flow system is 1 x 10,000 E. coli/ml.

Thomas, R. R.↗
NASA NTRS1975

Performance of filament-wound vessels from an organic fiber in several epoxy matrices

A study was carried out to select a state-of-the-art epoxy for wet filament winding. Ten epoxy systems were used to filament wind pressure vessels with a high-modulus, high-strength organic fiber. Data are reported on vessel performance, fiber strand strengths, and shear strengths for the different systems. Using our criteria (processibility, neat resin properties, and vessel performance), we find that an epoxy system based on the rubber-modified bis-phenol-F resin, diluted with vinyl cyclohexane dioxide and cured with mixed aromatic amines, can easily replace bis-phenol-A epoxies diluted with bis-(2, 3-epoxycyclopentyl) ether (such as ERL 2256 epoxy of Union Carbide) with comparable overall performance.

Chiao, T. T.↗
NASA NTRS1977

Mossbauer effect studies in iron containing nonmagnetic impurities

Mossbauer parameters of dilute quaternary (Fe-XYZ) alloys where X, Y, Z, are Al, Ge, and La, respectively were studied. A comparison between the computed and the observed values indicates that changes in effective hyperfine field, outer peak widths and the isomer shift predicted on the basis of binary alloys of the individual impurities are equal, within experimental errors, to those obtained in quaternary (Fe-XYZ) alloys. The effects of simultaneously present dilute impurities are shown to be additive, independent of their respective electronic configurations.

Singh, J. J.↗
NASA NTRS1978

Nitric oxide formation in gas turbine engines: A theoretical and experimental study

A modified Zeldovich kinetic scheme was used to predict nitric oxide formation in the burned gases. Nonuniformities in fuel-air ratio in the primary zone were accounted for by a distribution of fuel-air ratios. This was followed by one or more dilution zones in which a Monte Carlo calculation was employed to follow the mixing and dilution processes. Predictions of NOX emissions were compared with various available experimental data, and satisfactory agreement was achieved. In particular, the model is applied to the NASA swirl-can modular combustor. The operating characteristics of this combustor which can be inferred from the modeling predictions are described. Parametric studies are presented which examine the influence of the modeling parameters on the NOX emission level. A series of flow visualization experiments demonstrates the fuel droplet breakup and turbulent recirculation processes. A tracer experiment quantitatively follows the jets from the swirler as they move downstream and entrain surrounding gases. Techniques were developed for calculating both fuel-air ratio and degree of nonuniformity from measurements of CO2, CO, O2, and hydrocarbons. A burning experiment made use of these techniques to map out the flow field in terms of local equivalence ratio and mixture nonuniformity.

Mikus, T.↗
NASA NTRS1978

Ambient cure polyimide foams

Flame and temperature resistant polyimide foams are prepared by the reaction of an aromatic dianhydride, (pyromellitic dianhydride) with an aromatic polyisocyanate, (polymethylene polyphenylisocyanate), in the presence of an inorganic acid and furfuryl alcohol. Usable acids include dilute sulfuric acid, dilute nitric acid, hydrochloric acid, polyphosphoric acid, and phosphoric acid, with the latter being preferred. The dianhydride and the isocyanate in about equimolar proportions constitute about 50% of the reaction mixture, the rest being made up with the acid and the alcohol in a ratio of about 1:10. An exothermic reaction between the acid and the alcohol provides the heat necessary for the other components to polymerize without recourse to external heat sources. The mixture can be sprayed on any surface to form polymeric foam in locations where the application of heat is not practical or possible, for instance, between walls or on mine tunnel surfaces.

Sawko, P. M.↗
NASA NTRS1980

Heat Capacity Mapping Mission (HCMM) thermal surface water mapping and its correlation to LANDSAT

Graphics are presented which show HCMM mapped water-surface temperature in Lake Anna, a 13,000 dendrically-shaped lake which provides cooling for a nuclear power plant in Virginia. The HCMM digital data, produced by NASA were processed by NOAA/NESS into image and line-printer form. A LANDSAT image of the lake illustrates the relationship between MSS band 7 data and the HCMM data as processed by the NASA image processing facility which transforms the data to the same distortion-free hotline oblique Mercator projection. Spatial correlation of the two images is relatively simple by either digital or analog means and the HCMM image has a potential accuracy approaching the 80 m of the original LANDSAT data. While it is difficult to get readings that are not diluted by radiation from cooler adjacent land areas in narrow portions of the lake, digital data indicated by the line-printer display five different temperatures for open-water areas. Where the water surface response was not diluted by land areas, the temperature difference recorded by HCMM corresponds to in situ readings with rsme on the order of 1 C.

Colvocoresses, A. P.↗
NASA NTRS1981

Drift and dispersion studies of ocean-dumped waste using Landsat imagery and current drogues

The drift and dispersion of industrial acid wastes dumped 64 km off the Delaware coast were investigated using 16 Landsat images. Waste plume drift velocities and spread rates were obtained, and principal component analysis was performed to discriminate the acid waste from other pollutants. Waste plumes averaged drifting rates from 0.59 km/hr to 3.39 km/hr into the southwest quadrant, and remained above the thermocline, which formed at depths ranging from 13 m to 24 m. Rapid waste movement toward shore occurred primarily during storms, although plumes were rapidly dispersed and diluted at spread rates in excess of 4 cm/sec. Landsat data analysis also indicates plume width increase of about 1.5 cm/sec during calm sea conditions, which is also in agreement with Falk's (1974) estimates of plume dilution.

Klemas, V.↗
NASA NTRS1984

Controlling Metal-Halide Vapor Density in Lasers

Streams of buffer gas convect and dilute metal-halide vapor. Technique uses flow of buffer gas through reservoir, which contains heated metal halide, to convect vapors into discharge tube. Second stream of buffer gas dilutes vapor. Final vapor density in laser tube controlled and changed by adjusting either one or both of buffer gas flow rates.

Pivirotto, T. J.↗
NASA NTRS1982

The thermal conductivity of oxygen

The paper presents new experimental measurements of the thermal conductivity of oxygen for thirteen isotherms at temperatures from 78 to 310 K with pressures to 70 MPa and densities from 0 to 40 mol/L. The measurements were made with a transient hot wire apparatus and they cover a wide range of physical states including the dilute gas, the moderately dense gas, the near critical region, the compressed liquid states, and the vapor at temperatures below the critical temperature. The thermal conductivity surface is represented with an equation that is based in part on an existing correlation of the dilute gas. The date are compared with the experimental measurements of others through the new correlation. The new measurements show that the critical enhancement extends to quite high temperatures, about 300 K. The precision (2 sigma) of the oxygen of the oxygen measurements is between 0.5 and 0.8 percent for wire temperature transients of 4 to 5 K, while the accuracy is estimated to be 1.5 percent.

Roder, H. M.↗
NASA NTRS1983

Gravitational effects on plant growth hormone concentration

Dolk's (1936) finding that more growth hormone diffuses from the lower side of a gravity-stimulated plant shoot than from the upper side is presently confirmed by means of both an isotope dilution assay and selected ion monitoring-gas chromatography-mass spectrometry, and it is established that the asymmetrically distributed hormone is indole-3-acetic acid (IAA). This is the first physicochemical demonstration that there is more IAA on the lower sides of a geostimulated plant shoot. It is also found that free IAA primarily occurs in the conductive vascular tissues of the shoot, while IAA esters predominate in the growing cortical cells. A highly sensitive gas chromatographic isotope dilution assay shows that the hormone asymmetry also occurs in the nonvascular tissue.

Bandurski, R. S.↗
NASA NTRS1983

Executive summary, aerothermal modeling program, phase 1

Submodels used in the combustor analytical models that were successfully used in designing advanced technology combustors were assessed. Specific recommendations for further improvement of model accuracy for combustor design purposes were made. Based upon an exhaustive literature survey, a number of test cases were selected to assess accuracy of submodels of turbulence, turbulence/chemistry interaction, spray combustion, and dilution jet mixing processes within a confined cross-stream. These test cases included simple flows and complex flows with and without swirl. Nonrecirculating and recirculating, and nonreactive and reactive flows were investigated. It was concluded that the current models give qualitative trends for the recirculating secondary flows (as encountered in a gas turbine combustor primary zone), but the predictions are good for the dilution zone.

Srinivasan, R.↗
NASA NTRS1983

Aerothermal modeling program, phase 1

The combustor performance submodels for complex flows are evaluated. The benchmark test cases for complex nonswirling flows are identified and analyzed. The introduction of swirl into the flow creates much faster mixing, caused by radial pressure gradients and increase in turbulence generation. These phenomena are more difficult to predict than the effects due to geometrical streamline curvatures, like the curved duct, and sudden expansion. Flow fields with swirl, both confined and unconfined are studied. The role of the dilution zone to achieve the turbine inlet radial profile plays an important part, therefore temperature field measurements were made in several idealized dilution zone configurations.

Srinivasan, R.↗
NASA NTRS1983

Friction and wear of iron in sulfuric acid

Elemental iron sliding on aluminum oxide in aerated sulfuric acid concentrations ranging from very dilute (0.000007 N; i.e., 4 ppm) to very concentrated (96 percent acid) was studied. Load and reciprocating sliding speeds were kept constant. With the most dilute acid of 0.7 to 0.0002 N, a complex corrosion product formed that was friable and often increased friction and wear. At concentrations of 0.001 N, metal losses were essentially by wear alone. Because no buildup of corrosion products occurred, this acid concentration became the standard from which to separate metal loss from direct corrosion and mechanical wear losses. When the acid concentration was increased to 5 percent, the high corrosion rate of iron in sulfuric acid strongly dominated the total wear loss. This strong corrosion increased to 30 percent acid, and decreased somewhat at 50 percent in accordance with expectations. However, the low corrosion of iron expected at acid concentrations of 65 to 96 percent was not observed in the wear area. It is apparent that the normal passivating film was being worn away and a galvanic cell established which rapidly attached to the wear area.

Rengstorff, G. W. P.↗
NASA NTRS1984

Interaction of sulfuric acid corrosion and mechanical wear of iron

Friction and wear experiments were conducted with elemental iron sliding on aluminum oxide in aerated sulfuric acid at concentrations ranging from very dilute (0.00007 N; i.e., 4 ppm) to very concentrated (96 percent acid). Load and reciprocating sliding speed were kept constant. With the most dilute acid concentration of 0.00007 to 0.0002 N, a complex corrosion product formed that was friable and often increased friction and wear. At slightly higher concentrations of 0.001 N, metal losses were essentially by wear alone. Because no buildup of corrosion products occurred, this acid concentration became the standard from which to separate metal loss from direct corrosion and mechanical wear losses. When the acid concentration was increased to 5 percent (1 N), the well-established high corrosion rate of iron in sulfuric acid strongly dominated the total wear loss. This strong corrosion increased to 30 percent acid and decreased somewhat to 50 percent acid in accordance with expectations. However, the low corrosion of iron expected at acid concentrations of 65 to 96 percent was not observed in the wear area. It was apparent that the normal passivating film was being worn away and a galvanic cell established that rapidly attacked the wear area. Under the conditions where direct corrosion losses were highest, the coefficient of friction was the lowest.

Rengstorff, G. W. P.↗
NASA NTRS1983

Interstellar ice

The 3250/cm 'ice' band observed in absorption and polarization in interstellar spectra is studied in the laboratory in low-temperature solid mixtures of H2O and other molecules. General empirical rules are derived which relate the shape and relative intensity of the H2O infrared absorptions to the degree of H2O dilution and hydrogen-bonding capacity of the dilutant. The chemical composition of mantles accreting on interstellar grains inside dense (1000-100,000/cu cm) molecular clouds has been calculated numerically. The reaction scheme comprises gas-phase as well as grain surface reactions. The results show that in most circumstances grain mantles consist of the molecules H2O, H2CO, NH3, N2, O2, CO, and CO2. The expected infrared characteristics of the calculated grain mantles are discussed with an emphasis on the observed 3250/cm 'ice' band. Grain mantles accreted at a density of about 10,000/cu cm contain large concentrations of H2O (about 60 percent) and produce a broad 3250/cm 'ice' band.

Tielens, A. G. G. M.↗
NASA NTRS1984

The chemical durability of tektites - A laboratory study and correlation with long-term corrosion behavior

Leach tests carried out on tektite specimens (indochinites and australites) under high-dilution conditions show a common behavior characterized by low leach rates (0.00018 g/sq m per d, or 7.2 x 10 to the -12th m/d at 23 C) and an activation energy of (79,600 + or - 700 J/mol). The extent of selective leaching is very small, of the order of 10 to the -8th m. Extrapolation of test results over the lifetime of the tektites gives an excellent agreement with field observations on the extent of corrosion, and this is an important step in establishing the validity of laboratory tests as a basis for the development of models and predictions concerning long-term durabilities at least in the limiting case of high dilution or rapid flow. The results are also shown to be in agreement with various previous observations on the corrosion resistance of tektites. The chemical durability of tektites is observed to be consistent with their composition, highlighting requirements of high corrosion resistance in glasses; these requirements include a silica content in excess of 67 mol percent, an extremely low water content, and an alkali content which is low both absolutely and relative to the di- and poly-valent metal oxide levels. It is shown that artificial glasses which fulfil these criteria are no less corrosion-resistant than the corresponding natural glasses. These conclusions have bearing on the development, as well as on the evaluation, of glasses intended for very long service, such as radioactive waste vitrification media.

Barkatt, A.↗