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At least 307 records · Page 17

True Emission Factors for Forest Fires and the Role of Non-Fire NOx

True Emission Factors for Forest Fires and the Role of Non-Fire NOx Robert B. Chatfield and Meinrat Andreae The standard way to estimate biomass burning emissions factors from airborne, surface, or laboratory data is to relate the emitted pollutant concentration to the carbon burned, C(sub tot), and liberated to the air, mostly CO2. We approximate total emitted carbon C(sub tot) ~ (CO2 + CO). Emission ratios that are based on CO, describing burning effects, delta-parameter delta-CO, are often used to quantify fire emissions. These are not as useful as emission factors, for they often complicate analyses, since delta-CO delta-CO2 may vary by unto tenfold, and can have bias artifacts of similar magnitude. We present a methodology that estimates both emission factors and a reasonable description of background C(sub tot). High O3 values require a history of the balanced interaction of two pollutant types, nitrogen oxides (NOx) and a radical source, VOCs. However, high VOC NOx ratios seen in many plumes, especially from smoldering-dominated fires, make substantial O3 formation less likely. One particularly intense fire we analyzed, the notorious Rim Fire of 2013, near Yosemite, California. It produced notable quantities of free NOx and (both gas- and particle-phase) Cl species. Consequently, we also outline a quantitative way to assess the effects of anthropogenic or lightning NOx. We provide the example of California burning emissions using measurements of HCHO, NO, and the photolysis rate j(sub HCHO).

Chatfield, Robert B.↗

Chemical composition of the atmospheric aerosol in the troposphere over the Hudson Bay lowlands and Quebec-Labrador regions of Canada

Atmospheric aerosols were collected in the boundary layer and free troposphere over continental and coastal subarctic regions of Canada during the July - August 1990 joint U.S.-Canadian Arctic Boundary Layer Expedition (ABLE) 3B/Northern Wetlands Study (NOWES). The samples were analyzed for the following water soluble species: sulfate, nitrate, ammonium, potassium, sodium, chloride, oxalate, methylsulfonate, and total amine nitrogen. Ammonium and sulfate were the major water soluble components of these aerosols. The nearly neutral (overall) chemical composition of summertime aerosol particles contrasts their strongly acidic wintertime composition. Aerosol samples were separated into several air mass categories and characterized in terms of chemical composition, associated mixing ratios of gaseous compounds, and meteorological parameters. The fundamental category represented particles associated with 'background' air masses. The summertime atmospheric aerosols in background air over the North American subarctic and Arctic regions were characterized by relatively small and spatially uniform mixing ratios of the measured species. These aerosol particles were aged to the extent that they had lost their primary source signature. The chemical profile of the background air aerosols was frequently modified by additions from biomass fire plumes, aged tropical marine air, and intrusions of upper tropospheric/lower stratospheric air. Aerosols in boundary layer background air over the boreal forest region of Quebec-Labrador had significantly larger mixing ratios of ammonium and sulfate relative to the Hudson Bay region. This may reflect infiltration of anthropogenic pollution or be due to natural emissions from this region.

Gorzelska, K.↗

Completing below-ground carbon budgets for pastures, recovering forests, and mature forests of Amazonia

The objective of this grant was to complete below-ground carbon budgets for pastures and forest soils in the Amazon. Profiles of radon and carbon dioxide were used to estimate depth distribution of CO2 production in soil. This information is necessary for determining the importance of deep roots as sources of carbon inputs. Samples were collected for measuring root biomass from new research sites at Santana de Araguaia and Trombetas. Soil gases will be analyzed for CO2 and (14)CO2, and soil organic matter will be analyzed for C-14. Estimates of soil texture from the RADAMBRASIL database were merged with climate data to calculate soil water extraction by forest canopies during the dry season. In addition, a preliminary map of areas where deep roots are needed for deep soil water was produced. A list of manuscripts and papers prepared during the reporting periods is given.

Davidson, Eric A.↗

Soil nitrogen cycling and nitrous oxide flux in a Rocky Mountain Douglas-fir forest - Effects of fertilization, irrigation and carbon addition

Nitrous oxide fluxes and soil nitrogen transformations were measured in experimentally-treated high elevation Douglas-fir forests in northwestern New Mexico, USA. On an annual basis, forests that were fertilized with 200 kg N/ha emitted an average of 0.66 kg/ha of N2O-N, with highest fluxes occurring in July and August when soils were both warm and wet. Control, irrigated, and woodchip treated plots did not differ, and annual average fluxes ranged from 0.03 to 0.23 kg/ha. Annual net nitrogen mineralization and nitrate production were estimated in soil and forest floor using in situ incubations; fertilized soil mineralized 277 kg/ha/y in contrast to 18 kg/ha/y in control plots. Relative recovery of 15NH4-N applied to soil in laboratory incubations was principally in the form of NO3-N in the fertilized soils, while recovery was mostly in microbial biomass-N in the other treatments. Fertilization apparently added nitrogen that exceeded the heterotrophic microbial demand, resulting in higher rates of nitrate production and higher nitrous oxide fluxes. Despite the elevated nitrous oxide emission resulting from fertilization, we estimate that global inputs of nitrogen into forests are not currently contributing significantly to the increasing concentrations of nitrous oxide in the atmosphere.

Matson, Pamela A.↗

Canopy reflectance modeling in a tropical wooded grassland

Geometric/optical canopy reflectance modeling and spatial/spectral pattern recognition are used to study the form and structure of savanna in West Africa. An invertible plant canopy reflectance model is tested for its ability to estimate the amount of woody vegetation cover in areas of sparsely wooded grassland from remotely sensed data. Dry woodlands and wooded grasslands, commonly referred to as savannas, are important ecologically and economically in Africa, and cover approximately forty percent of the continent by some estimates. The Sahelian and Sudanian savanna make up the important and sensitive transition zone between the tropical forests and the arid Saharan region. The depletion of woody cover, used for fodder and fuel in these regions, has become a very severe problem for the people living there. LANDSAT Thematic Mapper (TM) data is used to stratify woodland and wooded grassland into areas of relatively homogeneous canopy cover, and then by applying an invertible forest canopy reflectance model to estimate directly the height and spacing of the trees in the stands. Since height and spacing are proportional to biomass in some cases, a successful application of the segmentation/modeling techniques will allow direct estimation of woody biomass, as well as cover density, over significant areas of these valuable and sensitive ecosystems. Sahelian savanna sites in the Gourma area of Mali being used by the NASA/GIMMS project (Global Inventory Modeling and Monitoring System, at Goddard Space Flight Center), in conjunction with CIPEA/Mali (Centre International pour l'Elevage en Afrique) will be used for testing the canopy model. The model will also be tested in a Sudanian zone crop/woodland area in the Region of Segou, Mali.

Simonett, D.↗

Biomass Burning Emissions in the Cerrado of Brazil Computed with Remote Sensing Data and GIS

Biomass burnin is a common force in much of the developing tropical world where it has wide-ranging environmental impacts. Fire is a component of tropical deforestation and is 0 p often used to clear broad expanses of land for shifting agriculture and cattle ranching. Frequent burning in the tropical savannas is a distinct problem from that of primary forest. In Brazil, most of the burning occurs in the cerrado which occupies approximately 1,800,000 km2, primarily on the great plateau in central Brazil. Wildland and agricultural fires are dramatic sources of regional air pollution in central Brazil. Biomass burning is an important source of a large number of trace gases including greenhouse gases and other chemically active species. Knowledge of trace gas emissions from biomass burning in Brazil is limited by a number of factors, most notably relative emission factors for gases from specific fire types/fuels and accurate estimates of temporal and spatial distribution and extent of fire activity. Estimates of trace gas emissions during September 1992 will be presented that incorporates a digital map of vegetation classes, pyrogenic emission factors calculated from ground and aircraft missions, and Instituto Nacional de Pesquisas Espaciais (INPE) fire products derived from Advanced Very High Resolution Radiometer (AVHRR) data. The regional emissions calculated from National Oceanographic and Atmospheric Administration (NOAA) AVHRR estimates of fire activity will provide an independent estimate for comparison with results obtained by the National Aeronautics and Space Administration (NASA) Transport and Atmospheric Chemistry Near the Equator - Atlantic (TRACE-A) experiments.

Guild, Liane S.↗

Satellite Boreal Measurements over Alaska and Canada During June-July 2004: Simultaneous Measurements of Upper Tropospheric CO, C2H6, HCN, CH3Cl, CH4, C2H2, CH2OH, HCOOH, OCS, and SF6 Mixing Ratios

Simultaneous ACE (Atmospheric Chemistry Experiment) upper tropospheric CO, C2H6, HCN, CH3Cl, CH4 , C2H2 , CH30H, HCOOH, and OCS measurements show plumes up to 185 ppbv (10 (exp -9) per unit volume) for CO, 1.36 ppbv for C2H6, 755 pptv (10(exp -12) per unit volume) for HCN, 1.12 ppbv for CH3C1, 1.82 ppmv, (10(exp -6) per unit volume) for CH4, 0.178 ppbv for C2H2, 3.89 ppbv for CH30H, 0.843 ppbv for HCOOH, and 0.48 ppbv for OCS in western Canada and Alaska at 50 deg N-68 deg N latitude between 29 June and 23 July 2004. Enhancement ratios and emission factors for HCOOH, CH30H, HCN, C2H6, and OCS relative to CO at 250-350 hPa are inferred from measurements of young plumes compared with lower mixing ratios assumed to represent background conditions based on a CO emission factor derived from boreal measurements. Results are generally consistent with the limited data reported for various vegetative types and emission phases measured in extratropical forests including boreal forests. The low correlation between fire product emission mixing ratios and the S176 mixing ratio is consistent with no significant SF6 emissions from the biomass fires.

Rinsland, Curtis P.↗

Development of Corrections for Biomass Burning Effects in Version 2 of GEWEX/SRB Algorithm

The objectives of this project were: (1) To incorporate into an existing version of the University of Maryland Surface Radiation Budget (SRB) model, optical parameters of forest fire aerosols, using best available information, as well as optical properties of other aerosols, identified as significant. (2) To run the model on regional scales with the new parametrization and information on forest fire occurrence and plume advection, as available from NASA LARC, and test improvements in inferring surface fluxes against daily values of measured fluxes. (3) Develop strategy how to incorporate the new parametrization on global scale and how to transfer modified model to NASA LARC.

Pinker, Rachel T.↗

Surface Soil Changes Following Selective Logging in an Eastern Amazon Forest

In the Brazilian Amazon, selective logging is second only to forest conversion in its extent. Conversion to pasture or agriculture tends to reduce soil nutrients and site productivity over time unless fertilizers are added. Logging removes nutrients in bole wood, enough that repeated logging could deplete essential nutrients over time. After a single logging event, nutrient losses are likely to be too small to observe in the large soil nutrient pools, but disturbances associated with logging also alter soil properties. Selective logging, particularly reduced-impact logging, results in consistent patterns of disturbance that may be associated with particular changes in soil properties. Soil bulk density, pH, carbon (C), nitrogen (N), phosphorus (P), calcium (Ca), magnesium (Mg), potassium (K), iron (Fe), aluminum (Al), delta(sup 3)C, delta(sup 15)N, and P fractionations were measured on the soils of four different types of loggingrelated disturbances: roads, decks, skids, and treefall gaps. Litter biomass and percent bare ground were also determined in these areas. To evaluate the importance of fresh foliage inputs from downed tree crowns in treefall gaps, foliar nutrients for mature forest trees were also determined and compared to that of fresh litterfall. The immediate impacts of logging on soil properties and how these might link to the longer-term estimated nutrient losses and the observed changes in soils were studied.

Olander, Lydia P.↗

El Nino Drought Increased Canopy Turnover in Amazon Forests

Amazon droughts, including the 2015-2016 El Ni~no, may reduce forest net primary productivityand increase canopy tree mortality, thereby altering both the short- and the longtermnet forest carbon balance. Given the broad extent of drought impacts, inventory plots oreddy flux towers may not capture regional variability in forest response to drought. We used multi-temporal airborne Lidar data and field measurements of coarse woodydebris to estimate patterns of canopy turnover and associated carbon losses in intact and fragmentedforests in the central Brazilian Amazon between 2013-2014 and 2014-2016. Average annualized canopy turnover rates increased by 65% during the drought period inboth intact and fragmented forests. The average size and height of turnover events was similarfor both time intervals, in contrast to expectations that the 2015-2016 El Ni~no droughtwould disproportionally affect large trees. Lidar biomass relationships between canopyturnover and field measurements of coarse woody debris were modest (R2 0.3), given similarcoarse woody debris production and Lidar-derived changes in canopy volume from singletree and multiple branch fall events. Our findings suggest that El Ni~no conditions accelerated canopy turnover in central Amazonforests, increasing coarse woody debris production by 62% to 1.22 Mg C ha1(exp) yr1(exp) indrought years.

ecosystem models↗

Soil nitrogen cycling and nitrous oxide flux in a Rocky Mountain Douglas-fir forest - Effects of fertilization, irrigation and carbon addition

Nitrous oxide fluxes and soil nitrogen transformations were measured in experimentally-treated high elevation Douglas-fir forests in northwestern New Mexico. On an annual basis, forests that were fertilized with 200 kg N/ha emitted an average of 0.66 kg/ha of N2O-N, with highest fluxes occurring in July and August when soils were both warm and wet. Control, irrigated, and woodchip treated plots were not different from each other, and annual average fluxes ranged from 0.03 to 0.23 kg/ha. Fertilized soil mineralized 277 kg/ha per year in contrast to 18 kg/ha per year in control plots. Relative recovery of (N-15)H4-N applied to soil in laboratory incubations was principally in the form of NO3-N in the fertilized soils, while recovery was mostly in microbial biomass-N in the other treatments. Fertilization apparently added nitrogen that exceeded the heterotrophic microbial demand, resulting in higher rates of nitrate production and higher nitrous oxide fluxes. Global inputs of nitrogen into forests are not currently contributing significantly to the increasing concentrations of nitrous oxide in the atmosphere.

Matson, Pamela A.↗

Characteristics and Composition of Atmospheric Aerosols in Phimai, Central Thailand During BASE-ASIA

Popular summary: Atmospheric aerosols play an important role in the Earth's climate system, and can also have adverse effects on air quality and human health. The environmental impacts of aerosols, on the other hand, are highly regional, since their temporal/spatial distribution is inhomogeneous and highly depends on the regional emission sources. To better understand the effects of aerosols, intensive field experiments are necessary to characterize the chemical and physical properties on a region-by-region basis. From late February to early May in 2006, NASA/GSFC's SMARTLabs facility was deployed at a rural site in central Thailand, Southeast Asia, to conduct a field experiment dubbed BASE-ASIA (Biomass-burning Aerosols in South East-Asia: Smoke Impact Assessment). The group was joined by scientists from the University of Hawaii and other regional institutes. Comprehensive measurements were made during the experiment, including aerosol chemical composition, optical and microphysical properties, as well as surface energetics and local . meteorology. This study analyzes part of the data from the BASE-ASIA experiment. It was found that, even for the relatively remote rural site, the aerosol loading was still substantial. Besides agricultural burning in the area, industrial pollution near the Bangkok metropolitan area, about 200 km southeast of the site, and even long-range transport from China, also contribute to the area's aerosol loading. The results indicate that aerosol pollution has developed into a regional problem for northern Indochina, and may become more severe as the region's population and economy continue to grow. Abstract: Comprehensive measurements of atmospheric aerosols were made in Phimai, central Thailand (15.l83 N, 102.565 E, elevation: 206 m) during the BASE-ASIA field experiment from late February to early May in 2006. The observed aerosol loading was sizable for this rural site (mean aerosol scattering: 108 +/- 64 Mm(exp -1); absorption: 15 +/- 8 Mm(exp -1); PM(sub 10) concentration: 33 +/- 17 miro-g/ cubic m and dominated by submicron particles. Major aerosol compounds included carbonaceous (OC: 9.5 +/- 3.6miro-g/ cubic m; EC: 2.0 2.3 miro-g/ cubic m and secondary species (SO4(2-): 6.4 +/- 3.7 miro-g/ cubic m, NH4(+): 2.2 +/- 1.3 miro-g/ cubic m). While the site was seldom under the direct influence of large forest fires to its north, agricultural fires were ubiquitous during the experiment, as suggested by the substantial concentration of K+ (0.56 +/- 0.33 micro-g/ cubic m). Besides biomass burning, aerosols in Phimai during the experiment were also strongly influenced by industrial and vehicular emissions from the Bangkok metropolitan region and long-range transport from southern China. High humidity played an important role in determining the aerosol composition and properties in the region. Sulfate was primarily formed via aqueous phase reactions, and hygroscopic growth could enhance the aerosol light scattering by up to 60%, at the typical morning RH level of 85%. The aerosol single scattering albedo demonstrated distinct diurnal variation, ranging from 0.86 +/- 0.04 in the evening to 0.92 +/- 0.02 in the morning. This experiment marks the first time such comprehensive characterization of aerosols was made for rural central Thailand. Our results indicate that aerosol pollution has developed into a regional problem for northern Indochina, and may become more severe as the region's population and economy continue to grow.

Li, Can↗

Canopy reflectance modeling in a tropical wooded grassland

Geometric/optical canopy reflectance modeling and spatial/spectral pattern recognition is used to study the form and structure of savanna in West Africa. An invertible plant canopy reflectance model is tested for its ability to estimate the amount of woody vegetation from remotely sensed data in areas of sparsely wooded grassland. Dry woodlands and wooded grasslands, commonly referred to as savannas, are important ecologically and economically in Africa, and cover approximately forty percent of the continent by some estimates. The Sahel and Sudan savannas make up the important and sensitive transition zone between the tropical forests and the arid Sahara region. The depletion of woody cover, used for fodder and fuel in these regions, has become a very severe problem for the people living there. LANDSAT Thematic Mapper (TM) data is used to stratify woodland and wooded grassland into areas of relatively homogeneous canopy cover, and then an invertible forest canopy reflectance model is applied to estimate directly the height and spacing of the trees in the stands. Because height and spacing are proportional to biomass in some cases, a successful application of the segmentation/modeling techniques will allow direct estimation of tree biomass, as well as cover density, over significant areas of these valuable and sensitive ecosystems. The model being tested in sites in two different bioclimatic zones in Mali, West Africa, will be used for testing the canopy model. Sudanian zone crop/woodland test sites were located in the Region of Segou, Mali.

Simonett, David↗

Relationship of multispectral satellite data to land surface evaporation from the Australian continent

Based on NOAA-9 AVHRR and Nimbus-7 SMMR satellite data, satellite indices of vegetation from the Australian continent are calculated for the period of May 1986 to April 1987. Visible (VIS) and near infrared (NIR) reflectances and the normalized difference (ND) vegetation index are calculated from the AVHRR sensor. The microwave polarization difference (PD) is also calculated as the difference between the vertically and horizontally polarized brightness temperatures at 37 GHz. ND, PD, VIS, and NIR indices were plotted against rainfall and water balance estimates of evaporation. It is concluded that direct satellite monitoring of annual evaporation across the Australian continent using PD or VIS satellite indices of vegetation biomass appears possible for areas with evaporation less than 600 mm/y and that use of the ND relationship at continental scale may underpredict monthly evaporation of forests relative to agriculture.

Smith, R. C. G.↗

Ammonia and nitric acid emissions from wetlands and boreal forest fires

Tests conducted during three (one boreal and two wetland) ecosystem fires have established the NH3- and HNO3-determination effectiveness of the 'tungsten oxide denuder' technique, using a low-flying helicopter to fly through biomass-burn smoke plumes. Both species were found to be present in the smoke plumes at levels much higher than background. Despite the differences between boreal and wetland ecosystems, HNO3 emissions were comparable; NH3 emissions, by contrast, were 5-8 times greater in the boreal fire than in the wetland fires. Biomass burning is found to make a significant role in the tropospheric ammonia budget.

Lebel, Peter J.↗

Mapping Land Cover Types in Amazon Basin Using 1km JERS-1 Mosaic

In this paper, the 100 meter JERS-1 Amazon mosaic image was used in a new classifier to generate a I km resolution land cover map. The inputs to the classifier were 1 km resolution mean backscatter and seven first order texture measures derived from the 100 m data by using a 10 x 10 independent sampling window. The classification approach included two interdependent stages: 1) a supervised maximum a posteriori Bayesian approach to classify the mean backscatter image into 5 general land cover categories of forest, savannah, inundated, white sand, and anthropogenic vegetation classes, and 2) a texture measure decision rule approach to further discriminate subcategory classes based on taxonomic information and biomass levels. Fourteen classes were successfully separated at 1 km scale. The results were verified by examining the accuracy of the approach by comparison with the IBGE and the AVHRR 1 km resolution land cover maps.

Saatchi, Sassan S.↗

Global geochemical problems

Application of remote sensing techniques to the solution of geochemical problems is considered with emphasis on the 'carbon-cycle'. The problem of carbon dioxide sinks and the areal extent of coral reefs are treated. In order to assess the problems cited it is suggested that remote sensing techniques be utilized to: (1)monitor globally the carbonate and bicarbonate concentrations in surface waters of the world ocean; (2)monitor the freshwater and oceanic biomass and associated dissolved organic carbon; (3) inventory the coral reef areas and types and the associated oceanographic climatic conditions; and (4)measure the heavy metal fluxes from forested and vegetated areas, from volcanos, from different types of crustal rocks, from soils, and from sea surfaces.

Harriss, R. C.↗

Preliminary analysis of ERS-1 SAR for forest ecosystem studies

An image obtained by the C-band VV-polarized ERS-1 SAR is examined with respect to potential land applications. A scene obtained near noon on August 15, 1991, along the U.S.-Canadian border near Sault Ste. Marie is calibrated relative to an array of trihedral corner reflectors and active radar calibrators distributed across the swath. Extensive contemporaneous ground observations of forest stands are used to predict the radar backscattering coefficient sigma at the time of the SAR overpass using a first-order vector radiative transfer model. These predictions generally agree with the calibrated ERS-1 data to within 1 dB. It is demonstrated that the dynamic range of sigma is sufficient to perform limited discrimination of various forest and grassland communities even for a single-date observation. Furthermore, retrieval of near-surface soil moisture is feasible for grass-covered soils when plant biomass is less than 1 tonne/ha.

Dobson, M. G.↗